CN109351703A - A kind of waste metal cleaning method - Google Patents

A kind of waste metal cleaning method Download PDF

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Publication number
CN109351703A
CN109351703A CN201811246299.3A CN201811246299A CN109351703A CN 109351703 A CN109351703 A CN 109351703A CN 201811246299 A CN201811246299 A CN 201811246299A CN 109351703 A CN109351703 A CN 109351703A
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CN
China
Prior art keywords
metalwork
cleaning
service sink
waste metal
cleaning method
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811246299.3A
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Chinese (zh)
Inventor
苏木阳
黄亮
马靓
陈精智
龙在华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Jinyang Resources Co Ltd
Original Assignee
Hubei Jinyang Resources Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Jinyang Resources Co Ltd filed Critical Hubei Jinyang Resources Co Ltd
Priority to CN201811246299.3A priority Critical patent/CN109351703A/en
Publication of CN109351703A publication Critical patent/CN109351703A/en
Withdrawn legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/08Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B1/00Cleaning by methods involving the use of tools
    • B08B1/10Cleaning by methods involving the use of tools characterised by the type of cleaning tool
    • B08B1/12Brushes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • B08B3/14Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to metal smelt technical field, in particular to a kind of waste metal cleaning method has preferable cleaning ability to the sump oil on metalwork surface, meanwhile, it is capable to handle the waste water after cleaning, reduces wastewater discharge, reduce environmental pollution.Main technological steps include: S1: being cleared up first the solid sundries on metalwork surface;S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, cleaning agent is added into service sink;S3: 2- acrylamido-methyl propane sulfonic acid is added into service sink;S4: heating liquid in service sink, meanwhile, metalwork surface is cleared up using the cleaning brush in service sink;S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain;S6: the colloidal solid sundries that removal metalwork surface is adhered;S7: the metalwork after S6 step process is cleaned using clear water, the metalwork cleaned up can be obtained.

Description

A kind of waste metal cleaning method
Technical field
The invention belongs to metal smelt technical field, in particular to a kind of waste metal cleaning method.
Background technique
Instantly alloy production enterprise is when producing different types of alloy, it will usually select the waste metal part such as oil of recycling Cylinder etc. is produced as raw material.But the metalwork generally recycled due to itself use environment or abandon when by Other impurity pollutions cause its surface contaminants more, and especially greasy dirt is more.
The metalwork of recycling when in use first cleans in metallurgical production enterprise, usually the cleaning of multipass water and cleaning Agent cleaning, still, this cleaning way and existing cleaning agent are difficult more thoroughly to clean up metalwork, to make gold Belong to part surface and still remain a large amount of oils hydrocarbons, during subsequent smelting, oily substance carbonization is penetrated into production In alloy, product quality is influenced;Meanwhile a large amount of waste water are generated during cleaning, environmental pollution is more serious.
Summary of the invention
The object of the present invention is to provide a kind of waste metal cleaning methods, have to the sump oil on metalwork surface preferable Cleaning ability reduces wastewater discharge meanwhile, it is capable to handle the waste water after cleaning, reduces environmental pollution.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of waste metal cleaning method, comprising the following steps:
S1: the solid sundries on metalwork surface are cleared up first;
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, cleaning agent is added into service sink;
S3: 2- acrylamido-methyl propane sulfonic acid is added into service sink;
S4: heating liquid in service sink, meanwhile, metalwork surface is carried out using the cleaning brush in service sink clear Reason;
S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain;
S6: the colloidal solid sundries that removal metalwork surface is adhered;
S7: the metalwork after S6 step process is cleaned using clear water, the metalwork cleaned up can be obtained.
Further, heating temperature is 90-150 DEG C in step S4.
Further, in step S5, room temperature control is drained at 5-20 DEG C.
Further, in step s 5, after metalwork being taken out out of service sink, thickener is added into service sink, stirs After mixing uniformly, stand.
Further, after standing, there is lamination in the liquid in service sink, and upper layer sump oil layer is removed, lower layer's mixing It is re-used for cleaning after liquid layer recycling.
Further, the thickener is polyacrylamide.
Further, the time of repose is 1-2h.
The beneficial effects of the present invention are:
1. the present invention is modified cleaning agent by the way that 2- acrylamido-methyl propane sulfonic acid is added into service sink, make The cleaning effect of metalwork surface and oil contaminant is preferable.Reason is: the greasy dirt on metalwork surface is mostly lubricating oil, and main component is more For mineral base oil, chemical composition is generally alkane (straight chain, branch, highly branched chain), cycloalkane (monocycle, bicyclic, polycyclic), virtue The hydrocarbon compounds such as hydrocarbon (mononuclear aromatics, polycyclic aromatic hydrocarbon), 2- acrylamido-methyl propane sulfonic acid can be to the poles of hydrocarbon compound Property group interfered, reduce hydrocarbon compound in the adhesive force on metalwork surface, make sump oil easily from metalwork sur-face peeling.
2. on the other hand, containing highly polar groups such as acyl group, sulfonic groups in 2- acrylamido-methyl propane sulfonic acid, in dirt After oil is detached from from metalwork surface, 2- acrylamido-methyl propane sulfonic acid replaces sump oil to be attached to metalwork surface, avoids sump oil Symbol is glued again on metalwork surface.Again due to the hydrophobic performance of acyl group, class thixotropy is made it have, in the environment of low temperature drying (be such as placed on low temperature drains interior), the 2- acrylamido-methyl propane sulfonic acid for being attached to metalwork surface are gradually done Dry solidification, process of the process similar to ink setting;After the drying, the solid sundries on metalwork surface are removed by external force, Cleaner metalwork can be obtained.Compared with the other application documents applied on the same day, present embodiments condition Under cleaning effect it is more preferable on the whole, consider that reason may is that the change of 2- acrylamido-methyl propane sulfonic acid, 2- acryloyl Amido-methyl propane sulfonic acid is in acidity, and general cleaning agent is alkalinity, this also overcomes tradition and passes through alkalinity cleaning to sump oil Technology prejudice.
3. sump oil is swum in the cleaning solution containing 2- acrylamido-methyl propane sulfonic acid, Xiang Qi after metalwork cleaning Middle addition thickener polyacrylamide, due to polyacrylamide and 2- acrylamido-methyl propane sulfonic acid similar compatibility, with alkane Hydrocarbon, cycloalkane sump oil are immiscible, thus, the cleaning solution containing 2- acrylamido-methyl propane sulfonic acid gradually thickens, final clear There is lamination in liquid in wash pool, also due to the class thixotropy of 2- acrylamido-methyl propane sulfonic acid itself, after making thickening Layered effect becomes apparent from.After the removal of sump oil layer, layer of cleaning solution can be continued to use.Although due to thickener etc., cleaning Effect is substantially reduced, but can be still recycled 2-3 times under heating conditions.
Specific embodiment
Below in conjunction with specific embodiment, technical solution of the present invention is clearly and completely described.Obviously, it is retouched The embodiment stated is only a part of the embodiments of the present invention, instead of all the embodiments.Based on the embodiment of the present invention, originally Field those of ordinary skill every other embodiment obtained without creative efforts, belongs to the present invention The range of protection.
Embodiment 1
A kind of waste metal cleaning method, specific step is as follows.
S1: clear up first the solid sundries on metalwork surface: the sundries for the bulk that metalwork surface is adhered is broken Bits are cleaned out, and the greasy dirt that can not be removed only is retained.
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, commercially available cleaning is added into service sink Agent (the present embodiment is used to sell stainless steel detergent for Europe MOOTAA brand), the volume ratio of the detergent and cleaning pool inner water For 1:80.
S3: 2- acrylamido-methyl propane sulfonic acid powder being added into service sink, and the weight ratio with cleaning pool inner water is 1:150 is uniformly mixed.
S4: heating liquid in service sink, temperature at 120 DEG C or so, meanwhile, utilize the cleaning brush pair in service sink Metalwork surface is cleared up, and comes into full contact with cleaning agent with metalwork surface.
S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain, drains room temperature on 5 DEG C of left sides It is right.As metalwork temperature gradually decreases, there is colloidal solid sundries in metalwork surface.
S6: it is removed by the colloidal solid sundries that metalwork surface is adhered by sharp weapon or other tools.
S7: the metalwork after S6 step process being cleaned using clear water, natural air drying later, be can be obtained and is cleaned up Metalwork.
Embodiment 2
A kind of waste metal cleaning method, specific step is as follows.
S1: clear up first the solid sundries on metalwork surface: the sundries for the bulk that metalwork surface is adhered is broken Bits are cleaned out, and the greasy dirt that can not be removed only is retained.
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, commercially available cleaning is added into service sink Agent (the present embodiment is used to sell stainless steel detergent for Europe MOOTAA brand), the volume ratio of the detergent and cleaning pool inner water For 1:90.
S3: 2- acrylamido-methyl propane sulfonic acid powder being added into service sink, and the weight ratio with cleaning pool inner water is 1:130 is uniformly mixed.
S4: heating liquid in service sink, temperature at 90 DEG C or so, meanwhile, utilize the cleaning brush pair in service sink Metalwork surface is cleared up, and comes into full contact with cleaning agent with metalwork surface.
S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain, drains room temperature on 10 DEG C of left sides It is right.As metalwork temperature gradually decreases, there is colloidal solid sundries in metalwork surface.After metalwork taking-up, to service sink Interior addition thickener polyacrylamide, stirs evenly, and stands 1.5 hours.Lamination gradually occurs for the liquid in service sink, Sump oil swims in upper layer, and lower layer is mixing liquid layer;Upper layer sump oil layer is removed, lower layer, which stays in service sink, continues cleaning use, That is recycling and reusing.Experiment discovery, mixing liquid layer cleaning effect after the recovery are decreased obviously, and after being recycled 2-3 times, are needed The cleaning solution renewed.
S6: it is removed by the colloidal solid sundries that metalwork surface is adhered by sharp weapon or other tools.
S7: the metalwork after S6 step process being cleaned using clear water, natural air drying later, be can be obtained and is cleaned up Metalwork.
Embodiment 3
A kind of waste metal cleaning method, specific step is as follows.
S1: clear up first the solid sundries on metalwork surface: the sundries for the bulk that metalwork surface is adhered is broken Bits are cleaned out, and the greasy dirt that can not be removed only is retained.
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, commercially available cleaning is added into service sink Agent (the present embodiment is used to sell stainless steel detergent for Europe MOOTAA brand), the volume ratio of the detergent and cleaning pool inner water For 1:90.
S3: 2- acrylamido-methyl propane sulfonic acid powder being added into service sink, and the weight ratio with cleaning pool inner water is 1:100 is uniformly mixed.
S4: heating liquid in service sink, temperature at 150 DEG C or so, meanwhile, utilize the cleaning brush pair in service sink Metalwork surface is cleared up, and comes into full contact with cleaning agent with metalwork surface.
S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain, drains room temperature on 20 DEG C of left sides It is right.As metalwork temperature gradually decreases, there is colloidal solid sundries in metalwork surface.After metalwork taking-up, to service sink Interior addition thickener polyacrylamide, stirs evenly, and stands 2 hours.Lamination gradually occurs for the liquid in service sink, dirty For oil float on upper layer, lower layer is mixing liquid layer;Upper layer sump oil layer is removed, lower layer, which stays in service sink, continues cleaning use, i.e., Recycling and reusing.Experiment discovery, mixing liquid layer cleaning effect after the recovery are decreased obviously, and after being recycled 2-3 times, need to change New cleaning solution.
S6: it is removed by the colloidal solid sundries that metalwork surface is adhered by sharp weapon or other tools.
S7: the metalwork after S6 step process being cleaned using clear water, natural air drying later, be can be obtained and is cleaned up Metalwork.
Comparative example
A kind of waste metal cleaning method, specific step is as follows.
S1: clear up first the solid sundries on metalwork surface: the sundries for the bulk that metalwork surface is adhered is broken Bits are cleaned out, and the greasy dirt that can not be removed only is retained.
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, commercially available cleaning is added into service sink Agent (the present embodiment is used to sell stainless steel detergent for Europe MOOTAA brand), the volume ratio of the detergent and cleaning pool inner water For 1:80.
S3: heating liquid in service sink, temperature at 120 DEG C or so, meanwhile, utilize the cleaning brush pair in service sink Metalwork surface is cleared up, and comes into full contact with cleaning agent with metalwork surface.
S4: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain, drains room temperature on 5 DEG C of left sides It is right.The metalwork cleaned up can be obtained.
Cleaning ability detects (gravimetric method)
It is hard that LY 12 (BCZ) is prepared according to professional standard JB/T 4323.1-1999 " water base metal cleaning agent test method " N46HL hydraulic oil is soaked in aluminum metal test piece.When pendulum is washed, by metal testing plate as above-described embodiment 1-3 and the service sink of comparative example It is interior according to the pendulum mode of washing carry out pendulum wash, for the test piece tested according to the experiment condition of embodiment 1-3, wash end in pendulum Afterwards, surface glue solids is removed by external force, and again after cleaning, drying, using this weight as whole weight.Calculate cleaning energy Power h, h=(P2-P3)/(P2-P1) * 100%;Wherein P1 is the net weight of test piece;P2 be by oil immersion it is wet after, test piece and oil gross weight Amount;P3 is the total weight of test piece and oil residues after the completion of processing.
Number P1/g P2/g P3/g h
Embodiment 1 2.9 4.3 2.93 97.9%
Embodiment 2 3.1 4.2 3.12 98.2%
Embodiment 3 3.0 4.3 3.05 96.2%
Comparative example 3.0 4.3 3.35 73.1%
By above-mentioned experimental result it is found that compared with comparative example, each experiment condition of the embodiment of the present application 1 into embodiment 3 Lower cleaning agent is preferable to sump oil cleaning ability, and cleaning rate is up to 98.2%.Reason may is that in the application to be added in cleaning solution Enter 2- acrylamido-methyl propane sulfonic acid to be handled, so that more thoroughly to sump oil cleaning.

Claims (7)

1. a kind of waste metal cleaning method, which comprises the following steps:
S1: the solid sundries on metalwork surface are cleared up first;
S2: the metalwork after preliminary cleaning is dipped in service sink, is flooded not, cleaning agent is added into service sink;
S3: 2- acrylamido-methyl propane sulfonic acid is added into service sink;
S4: heating liquid in service sink, meanwhile, metalwork surface is cleared up using the cleaning brush in service sink;
S5: the metalwork after cleaning is taken out, and being placed in the room of draining, to drain surface water stain;
S6: the colloidal solid sundries that removal metalwork surface is adhered;
S7: the metalwork after S6 step process is cleaned using clear water, the metalwork cleaned up can be obtained.
2. a kind of waste metal cleaning method according to claim 1, it is characterised in that: heating temperature is in step S4 90-150℃。
3. a kind of waste metal cleaning method according to claim 1, it is characterised in that: in step S5, drain Indoor Temperature Degree control is at 5-20 DEG C.
4. a kind of waste metal cleaning method according to claim 1, it is characterised in that: in step s 5, by metalwork After taking out out of service sink, thickener is added into service sink, after mixing evenly, stands.
5. a kind of waste metal cleaning method according to claim 4, it is characterised in that: the liquid after standing, in service sink There is lamination in body, and upper layer sump oil layer is removed, and is re-used for cleaning after lower layer's mixing liquid layer recycling.
6. a kind of waste metal cleaning method according to claim 4, it is characterised in that: the thickener is polyacrylamide Amine.
7. a kind of waste metal cleaning method according to claim 4, it is characterised in that: the time of repose is 1-2h.
CN201811246299.3A 2018-10-25 2018-10-25 A kind of waste metal cleaning method Withdrawn CN109351703A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811246299.3A CN109351703A (en) 2018-10-25 2018-10-25 A kind of waste metal cleaning method

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Application Number Priority Date Filing Date Title
CN201811246299.3A CN109351703A (en) 2018-10-25 2018-10-25 A kind of waste metal cleaning method

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CN109351703A true CN109351703A (en) 2019-02-19

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567015B1 (en) * 1992-04-20 1997-11-19 Mitsubishi Chemical Corporation Method of and apparatus for cleaning oil-deposited material
CN1417143A (en) * 2001-11-09 2003-05-14 中国石油天然气股份有限公司 ABS sewage treating method
CN1450201A (en) * 2002-04-08 2003-10-22 兰州华洋特殊垢清洗防腐工程研究所 Degreasing agent for cleaning stainless steel
CN102358870A (en) * 2011-09-23 2012-02-22 王晗 Novel cleaning agent
CN104233327A (en) * 2014-09-14 2014-12-24 昆山强清金属材料有限公司 Surface cleaning process for metal product
CN107829103A (en) * 2017-11-15 2018-03-23 苏州锐耐洁电子科技新材料有限公司 A kind of stainless steel welds spot cleaning agent
CN108580407A (en) * 2018-01-23 2018-09-28 滁州英诺信电器有限公司 Base material cleaning procedure before printing

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0567015B1 (en) * 1992-04-20 1997-11-19 Mitsubishi Chemical Corporation Method of and apparatus for cleaning oil-deposited material
CN1417143A (en) * 2001-11-09 2003-05-14 中国石油天然气股份有限公司 ABS sewage treating method
CN1450201A (en) * 2002-04-08 2003-10-22 兰州华洋特殊垢清洗防腐工程研究所 Degreasing agent for cleaning stainless steel
CN102358870A (en) * 2011-09-23 2012-02-22 王晗 Novel cleaning agent
CN104233327A (en) * 2014-09-14 2014-12-24 昆山强清金属材料有限公司 Surface cleaning process for metal product
CN107829103A (en) * 2017-11-15 2018-03-23 苏州锐耐洁电子科技新材料有限公司 A kind of stainless steel welds spot cleaning agent
CN108580407A (en) * 2018-01-23 2018-09-28 滁州英诺信电器有限公司 Base material cleaning procedure before printing

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Application publication date: 20190219