A kind of high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet and its manufacture craft
Technical field
The invention belongs to rubber product technology fields, specifically, being related to a kind of high-strength high-elasticity dual density mould
Interior foamed rubber-plastic pallet and its manufacture craft.
Background technique
Chinese national standard " logistics terms " is to the definition of pallet (pallet): being used for packaging, stacking, carrying and transport
Place as the cargo of unit load and the levelling bench arrangement of product.As a kind of unit load devices similar with container,
Pallet has been widely used in the fields such as production, transport, storage and circulation.
Pallet generally has a foot or beam below upper flat plate and upper flat plate, some pallets there are also lower plate be connected to foot or
The lower section of person's beam.According to the shape of pallet, plane and grid type can be divided into according to the shape of plate;According to the number of plate
It is divided into single deck pallet and double-deck pallet;It is divided into nine footrest disks, river word pallet and field word pallet according to using foot or beam.Institute
Pallet pattern abundant, such as nine foot single deck pallet of network, nine foot single side of plane are formed after permutation and combination with above-mentioned pattern
Pallet, grid river word single deck pallet ... etc., have different moulder moistures in different occasions.
The plastics system or rubbery system of the existing general identical material of style type pallet, although two kinds of systems are all answered extensively
With, but all have the shortcomings that corresponding:
The plastic material price of the first system is high, and chance high temperature easily softens and wearability is poor;The molding side of plastic pallet
Formula mainly has injection molding method, extrusion-hollow blow molding method, vacuum suction moulding method.These modes are by pallet integration
Molding, processing cost are relatively high.Therefore occur built-up pallet in recent years, plate and foot or beam are processed respectively, then
It is assembled.Whether this mode significantly reduces cost, but assemble secured, and the convenience of assembling, is to need to examine
The problem of worry.
In second of system, the molding and vulcanization of rubber and plastic pallet, which will separate, to be carried out, although material cost is relatively low, work
Skill higher cost, moreover, if there is hole in inside, sulfidation is difficult to ensure entire semi-finished product vulcanization uniformly in sulfidation,
Finished product dynamic balancing effect is poor, and after vulcanization, intrapore high pressure gas is also easy to rapid expanding in die sinking and explodes, and causes hole
Gap thin-walled ruptures and becomes waste product, and in technical process, rejection rate is higher;It should also be noted that, vulcanization is in dedicated vulcanization machine
It carries out, need to pressurize again, heat to rubber product, consume energy, is time-consuming, at high cost, being a big disadvantage of rubber product technique.
Moreover, all there is damping effect difference in two kinds of systems, and for being easy during out of stock or rotation cargo, mistake
Hard contact is easy to produce causes cargo to damage because of damping effect difference.
Solving problem above can be considered dual density system, because of the size of rubber density itself, with it containing gas bubble (hair
Bubble) it is related, by gas foaming, the rubber material of different densities is obtained, it is general to use two sets to reach dual-density rubber product
Injection mechanism not only increases equipment cost, but also increases occupation area of equipment.
Through retrieving, Chinese patent publication No. CN 102952317 B, publication date 2018.04.06, denomination of invention: Yi Zhongmu
Composite pallet is moulded, is made from the following raw materials in parts by weight: high density polyethylene (HDPE) 50-60, copolymerized type propene polymer 20-30, modification
Wood powder 30-40, recycled plastics polymers 40-50, calcium activated 20-30, zinc stearate 1-2, calcium stearate 1-2, the positive fourth of methacrylic acid
Ester 2-3, polyethylene wax 0.3-0.5, vinyltriethoxysilane 0.4-0.6, antioxidant 1010 0.3-0.4, anti-aging agent
MB0.4-0.6, foaming control agent 8-10, ACM4-8, MBS4-8, oxidized polyethylene wax 25-30, foaming agent 0.2-0.3, TPE4-
8, chliorinated polyvinyl chloride 8-12, glass fibre 5-8, semi-reinforcing hydrocarbon black 3-4.The invention limits technique from formula and process conditions
Process, using traditional process equipment, production Plastic-wooden composite tray, injection and vulcanization are separately carried out, and consume energy, is time-consuming, at high cost.
Summary of the invention
1. technical problems to be solved by the inivention
Poor rubber and plastic pallet damping effect, the injection of dual density pallet and vulcanization separately progress exists in the prior art to overcome,
Energy consumption, time-consuming, problem at high cost, the present invention provide a kind of high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet and its system
Make technique.Dual-density rubber tray design of the invention density layer structure in pairs;During it makes, by double-density injection molding, hair
Bubble and vulcanization plant are integrated, reduce cost, the molding time of pallet product, and reduce energy consumption, moreover it is possible to disappear
Except shipping expense between pallet article process.
2. technical solution
To solve the above problems, the present invention adopts the following technical scheme:
A kind of high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet, including high density outer layer and low-density internal layer are
With the integral structure of mold depanning;The material of the high density outer layer and low-density internal layer is respectively high density sizing material and low close
Sizing material is spent, also uniformly buries in the low-density internal layer and to be covered with being longitudinally and/or laterally distributed perpendicular to tray body horizontal plane
Spring supporting;And it is completed in a mold using foaming-vulcanization trays production system in the two-way injection mold of dual density double
The two-way injection of density sizing material, foaming and sulfuration process are made, and can effectively avoid pallet product in the circulation of each process, to reduce
Production cost.
Further embodiment, spring-supported both ends are fixed with connecting plate, facilitate spring supporting synchronous in mold
It is preset and fixed, preset spring supporting is carried out before the vulcanization of rubber, connecting plate can effectively improve spring branch tight against high density outer layer
The bond strength of support and rubber, in the embeddable spring gap of rubber, spring may be selected it is consistent with low-density rubber layer elasticity,
To reinforce the support strength of low-density internal layer, it synchronous with spring can restore, play the role of skeletal support;Same mold is raw
It produces, the bond strength of spring and rubber is big, and composite effect is good, slows down elastic extenuation caused by low-density internal layer frequent deformation.
Further embodiment, low-density gum base ingredients are to add foaming agent in high density gum base ingredients.
Further embodiment, foaming-vulcanization trays production system includes pressing mold vulcanization in the two-way injection mold of dual density
The symmetrically arranged two injections machine base of platform and its left and right sides further includes the die venting of side before or after pressing mold vulcanizes platform
And inflation mechanism;Pressing mold molding and foaming vulcanization plant are fixed on the pressing mold vulcanization platform;Divide on 2 injections machine base
It is not fixed with sizing material injection device, 2 sizing material injection devices are oppositely arranged, respectively high density sizing material injection device and low-density
Sizing material injection device;The pressing mold molding and foaming vulcanization plant include two mold cores that shape is identical, specification is different, institute
It is respectively that two kinds of different plasticized rubber material of density are corresponding not to state high density sizing material injection device and low-density sizing material injection device
Same mold core is successively injected into the mold of pressing mold molding and foaming vulcanization plant, and the die venting and inflation mechanism exist
The air in the mold of pressing mold molding and the vulcanization plant that foams is emptied before injection device injection, is passed through high pressure gas after injection
In the mold of pressing mold molding and foaming vulcanization plant, the pressing mold molding and foaming vulcanization plant are to the plasticized rubber material in mold
Pressing mold foaming and vulcanization are carried out, foaming-vulcanization trays production system can be by injection moulding, row in the two-way injection mold of dual density
Inflation and foaming, vulcanization plant it is integrated, avoid in the prior art each process circulation caused by heat losses and process stream
Change into this, multiple pressurization, heating and the secondary glue for solving traditional rubber pallet production technology are pasted, energy consumption, time-consuming, at
This high big disadvantage.
Further embodiment, 2 sizing material injection devices include loading hopper, injection cylinder, barrel is injected in plasticizing, plasticizing adds
Hot device, injection nozzle control oil cylinder, injection head and injection seat Shift cylinder;The beginning phase of the loading hopper and plasticizing injection barrel
It is logical, in the cylinder barrel of the beginning insertion injection cylinder of plasticizing injection barrel, and tight against the injection ram in injection cylinder;The plasticizing
The built-in plasticizing injection screw of barrel is injected, the end point of injection screw is plasticized, prestores plasticizing material chamber;It is described to prestore plasticizing material
Chamber is connected to by feed pipe with the material chamber that the injection nozzle of plasticizing injection barrel bottom controls oil cylinder front end, the charging of the injection head
End is connected to chamber is expected, dispensing end form and foam with the pressing mold mold of vulcanization plant communicates;The injection nozzle controls oil cylinder
Cylinder barrel is fixedly connected with the cylinder barrel of injection seat Shift cylinder, and for the piston rod of the two backwards to being arranged, the injection seat Shift cylinder is living
Stopper rod and the injection cylinder are both secured on injection machine base, and the plasticizing heater circulating type is fixed on plasticizing injection barrel
Outer wall, for being plasticized sizing material.
Further embodiment, pressing mold molding and foaming vulcanization plant include die cylinder, upper mold half, lower mold half, mould
Have inner core one, mold core two and mold core rotational fuel tank;The lower mold half is fixed on pressing mold vulcanization platform, and lower mold half is just
Top is equipped with upper mold half, and the upper mold half is detachably connected with die cylinder;The die cylinder passes through fixation
Frame is fixed;The mold core one is identical with two shape of mold core, specification is different, and the two tail end is opposite, converts with mold core
Bracket is detachably fixed, and the mold core conversion support is T-shaped, after mold core rotational fuel tank is inserted into bottom end, with mold core rotational fuel tank
Shaft is fixedly connected;The mold core rotational fuel tank driven mold inner core one, mold core two upper mold half and lower mold half it
Between convert;Upper mold half, lower mold half, mold core one and mold core two are equipped with according to the shape of tray body;Institute
Mold core rotational fuel tank is stated to be fixed on pressing mold vulcanization platform;The pressing mold molding and foaming vulcanization plant further include molding crossbeam, institute
The hydraulic stem for stating die cylinder is fixedly connected with upper mold half again after the pilot hole of molding crossbeam;The molding crossbeam is fixed
In on the fixed frame that pressing mold formed and foamed vulcanization plant;The pressing mold molding and foaming vulcanization plant further include mold heating
Device;The die heater is set to the top of upper mold half and/or the lower part of lower mold half.
Further scheme, the high density sizing material injection device and low-density sizing material injection device respectively include highly dense
Degree sizing material injection head and low-density sizing material injection head, the high density sizing material injection head and low-density sizing material injection head are arranged on pressure
The mold two sides of mold forming and the vulcanization plant that foams, when injection, and the mould cavity for the vulcanization plant that forms and foam with pressing mold
It communicates.
Further scheme, the mold row in the two-way injection mold of dual density in foaming-vulcanization trays production system
Gas and inflation mechanism include bracket, cylinder, cylinder block and hydraulic station;The bracket is the annular gantry that there is through-hole in centre, institute
It states cylinder to be fixed on the circular table of bracket, the cylinder block is fixed on the bottom of the circular table of bracket, the cylinder
The built-in cylinder piston and oil cylinder piston for connecting same piston rod, the cylinder head pass through tracheae and pressure respectively with cylinder block
The mold inner-cavity of mold forming and the vulcanization plant that foams communicates;The cylinder block is divided into upper cavity and lower chamber by oil cylinder piston,
Two cavitys pass through an oil pipe respectively and communicate with hydraulic station.
Further scheme, mold core conversion support is lift, when sizing material is injected, in driven mold inner core one and mold
Core two moves down;The outer arm circulating type of the cylinder is fixed with block heater, and the bottom side of cylinder is provided with cylinder and unloads stomata;It is described
The diameter of cylinder is greater than cylinder block.
A kind of production technology of high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet, step are as follows:
Step 1: high density stock rubber is plasticized: high density sizing material injection nozzle controls oil cylinder first by high density sizing material feeding
Pipe and the closing of high density sizing material injection head, increase density stock rubber pellet by high density sizing material loading hopper and enter high density glue
Material plasticizing injection barrel, high density sizing material is plasticized injection screw rotation, and while rotation, high density sizing material plasticizing injection screw is supported
Tight high density sizing material injection ram persistently moves back, and the sizing material after plasticizing is intracavitary temporary in high density sizing material plasticizing material;
Step 2: molding: mold core rotational fuel tank rotates mold core conversion support, and mold core one is inserted into upper mold half under
At center between half mold, starting die cylinder is moved down, and upper mold half is closed up with lower mold half;
Step 3: vacuumizing: starting hydraulic station, high pressure oil enter cylinder block epicoele by high-pressure oil pipe, push oil cylinder
Piston moves down, and oil cylinder piston drives cylinder piston to move together, and upper chamber of air cylinder forms vacuum, and the inner chamber gas of molding is drained;
Step 4: injection: starting high density sizing material injection seat Shift cylinder, after the insertion molding of high density sizing material injection head
Upper mold half and lower mold half in, start high density sizing material injection cylinder, high density sizing material injection ram Forward, by high density
In high density stock rubber injection mold in sizing material pre-firing material-holding chamber;High density sizing material injection head is closed;Start high density glue
Expect injection seat Shift cylinder, high density sizing material injection head is exited into mold, molding is stood after injection;
Step 5: low-density stock rubber is plasticized: low-density sizing material injection nozzle controls oil cylinder first by low-density sizing material feeding
Pipe and the closing of low-density sizing material injection head, add low-density stock rubber pellet to enter low-density glue by low-density sizing material loading hopper
Material plasticizing injection barrel, low-density sizing material is plasticized injection screw rotation, and while rotation, low-density sizing material plasticizing injection screw is supported
Tight low-density sizing material injection ram persistently moves back, and the sizing material after plasticizing is intracavitary temporary in low-density sizing material plasticizing material;
Step 6: die sinking: starting die cylinder moves up, and opens the upper of the tray body for including half of high density outer layer respectively
Half mold and lower mold half start mold core rotational fuel tank, and mold core conversion support extracts mold core one out, and by mold core two
It is inserted at the center between upper mold half and lower mold half;
Step 7: pre-buried spring: spring being embedded in the tray body of half of high density outer layer of lower mold half, is vulcanized
, can be very easily pre-buried by spring in preceding tray body, connecting plate can be disposably pre-buried by spring as a whole, easy to operate;
Step 8: molding: starting die cylinder moves down, and upper mold half is closed up with lower mold half, by two indwelling of mold core;
Step 9: injection: the decline of mold core conversion support reserves the injection position of low-density sizing material injection head;Start low-density
Sizing material injection seat Shift cylinder starts in the upper mold half and lower mold half after the insertion molding of low-density sizing material injection head low
Density sizing material injection cylinder, low-density sizing material injection ram Forward, by the low-density sizing material in low-density sizing material pre-firing material-holding chamber
Rubber injects in mold;Low-density sizing material injection head is closed;Start low-density sizing material injection seat Shift cylinder, by low-density sizing material
Injection head exits mold;
Step 10: mold core conversion support rises to original position, start mold core rotational fuel tank, mold core conversion support is by mold core
Two extractions;
Step 11: molding again: starting die cylinder moves down, will include respectively the upper mold half of half of tray body with
Lower mold half is closed up again, the hollow form after removing inside tray body in mold core two;
Step 12: high-pressure aerated: starting hydraulic station, high pressure oil enter cylinder block cavity of resorption by high-pressure oil pipe, push
Oil cylinder piston moves up, and oil cylinder piston drives cylinder piston to move up together, and cylinder piston leads to the pressure high temperature hot gas of upper chamber of air cylinder
It crosses air tube and squeezes into upper mold half and lower mold half inner cavity;
Step 13: foaming and vulcanization: heating up to the tray body of upper mold half and lower mold half inner cavity and pressurization, adjusts
Die cylinder back pressure makes die cylinder switch to floating position, and foaming agent reduces foaming, and rubber swelling is made to form spongy state,
Pressure maintaining is carried out again, heat preservation, protects the time, reaches cures requirements;
Step 14: pressure release: by internal high temperature and high pressure gas pressure release;
Step 15: die sinking: starting die cylinder moves up, and opens upper mold half and lower mold half, takes out tray body.
3. beneficial effect
Compared with prior art, the present invention has the following obvious advantages:
(1) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, the carcass setting of double-layer structure, can increase
Add elastic effect, without additional inflation, low-density internal layer is buried when being covered with spring supporting, plays the role of skeletal support, same mold
The bond strength of production, spring and rubber is big, and composite effect is good, and spring is optional consistent with low-density caoutchouc elasticity, with
The support strength for reinforcing low-density internal layer slows down the decaying of elastic fatigue caused by low-density internal layer frequent deformation;
(2) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, spring-supported end is fixed with company
Fishplate bar facilitates spring supporting synchronous preset and fixed in mold, preset spring supporting is carried out before the vulcanization of rubber, can be effective
The bond strength for improving spring supporting and rubber, in the embeddable spring gap of rubber, can recovery synchronous with spring, play increasing
The supporting role of strong skeleton;
(3) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, high density sizing material injection device can be infused
Penetrate high density sizing material rubber material (such as density=1), low-density sizing material injection device injectable low-density sizing material (such as density=0.5),
High density sizing material mold core (by exchanging oil cylinder control for) is set in advance in die cavity, after the completion of injection, opens mold, exchanges high density glue for
Mold core is expected to low-density sizing material mold core, and Guan Bi mould carries out the injection of low-density sizing material and (mixes in advance according to the technological requirements in sizing material
Have foaming agent), temperature-pressure is molded, the decomposition of its foaming agent is made to release gas, adjusts (the die cylinder switching of die cylinder back pressure
To floating position), foaming agent decomposes the inflation for releasing gas associating die venting and inflation mechanism, it is sufficient to overcome by rubber bag
It encloses to form cell pressure, rubber swelling is made to form spongy state, then carry out pressure maintaining, heat preservation, protect the time, reach cures requirements, open
Mould takes out product, converts without process, easy to operate, high production efficiency;
(4) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, high density sizing material and low-density glue
Expect component formula, the high density outer layer and low-density internal layer of generation comply fully with the comparison requirement of dual-layer density, pallet obtained
Elasticity and wearability are high, and resistance to tearing is strong, can act synergistically with spring supporting, further increase pallet elasticity and wearability;
(5) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, can complete in a system mold
Injection, foaming, vulcanization manufacturing process can effectively solve secondary pressurization again in rubber pallet production process, heats, causes to consume
Energy, time-consuming, problem at high cost to reduce the cost of rubber product, molding time, reduce energy consumption, and can eliminate rubber system
Shipping expense between product process;It furthermore reduces reheating bring noxious gas emission, reduces reheating and brings
Rubber pallet rejection rate, reduce reheating pressurization bring energy consumption, achieved the effect that environmental protection and energy saving;Mold
Exhaust and hollow inflatable mechanism are integrated by inflatable and exhaust device by same piston rod, reciprocal by hydraulic station driving piston rod
Mobile, piston moves back pumping, and piston Forward is inflated, and cylinder piston and oil cylinder piston area ratio are the ratio of oil pressure and air pressure
Value adjusts hydraulic station pressure, it is ensured that the blowing pressure, the speed of piston traveling speed is related with flow of aerating air in mold, adjusts
High pressure oil flow, i.e., the controllable piston speed of service, can meet flow of aerating air, and then reach the blowing pressure and purging vacuum degree
Requirement;
(6) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, to guarantee its flexibility, dual density is double
Into injection mold, foaming-vulcanization trays production system makes full use of the axial force in plasticizing injection screw rotary course backward
Effect is not necessarily to apply extra power to plasticizing injection screw, and plasticizing material chamber can be realized and be gradually increased and reach what sizing material was kept in
Purpose;Die heater makes sizing material keep stable soft state in sulfidation, moreover, stomata is automatic after sizing material foaming
Sealing is not necessarily to secondary seal, in turn ensures vulcanization effect;
(7) high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the invention, the two-way injection foam-in-mould of dual density
The molding of the entire mold of molding-vulcanization trays production system (including upper mold half, lower mold half and mold core one, two)
It accomplishs without any letup with seal operation, it is simple, convenient quick;
(8) production technology of the invention can continue production free of discontinuities, production efficiency and high degree of automation.
Detailed description of the invention
Fig. 1 is top view after middle-high density outer layer of the present invention removal;
Fig. 2 is longitudinal sectional view of the invention;
Fig. 3 is the operation system structure schematic diagram in the present invention;
Fig. 4 is schematic diagram after the mould part amplification in the present invention;
Fig. 5 is that rear side viewing schematic diagram is amplified in the pressing mold molding and foaming vulcanization plant part in the present invention;
Fig. 6 is schematic diagram after die venting and the amplification of inflation mechanism part in the present invention.
In figure: 1, injecting machine base;2, high density sizing material injection device;3, pressing mold molding and foaming vulcanization plant;4, low
Density sizing material injection device;5, pressing mold vulcanizes platform;6, tray body;7, tracheae;8, die venting and inflation mechanism;21, highly dense
Spend sizing material loading hopper;22, high density sizing material injection cylinder;23, high density sizing material plasticizing injection barrel;24, high density sizing material is moulded
Change heater;25, high density sizing material prestores plasticizing material chamber;26, high density sizing material feed pipe;27, high density sizing material injection nozzle control
Liquefaction cylinder;28, high density sizing material injection head;29, high density sizing material injection seat Shift cylinder;31, die cylinder;32, molding is horizontal
Beam;33, upper mold half;34, lower mold half;35, mold core one;36, mold core two;37, mold core conversion support;38, mould
Has heater;39, mold core rotational fuel tank;41, low-density sizing material loading hopper;42, low-density sizing material injection cylinder;43, low-density
Sizing material plasticizing injection barrel;44, low-density sizing material is plasticized heater;45, low-density sizing material prestores plasticizing material chamber;46, low-density
Sizing material feed pipe;47, low-density sizing material injection nozzle controls oil cylinder;48, low-density sizing material injection head;49, low-density sizing material is injected
Seat Shift cylinder;61, high density outer layer;62, low-density internal layer;63, spring supporting;64, connecting plate;80, cylinder connecting tube connects
Head;81, cylinder;82, block heater;83, cylinder unloads stomata;84, cylinder block;85, oil pipe;86, hydraulic station;88, piston
Bar;89, bracket;221, high density sizing material injection ram;231, high density sizing material is plasticized injection screw;421, high density sizing material is infused
Penetrate piston;431, high density sizing material is plasticized injection screw;811, cylinder piston;812, support limit block;813, refractory seals
Circle;841, oil cylinder piston.
Specific embodiment
To further appreciate that the contents of the present invention, this present invention is described in detail in conjunction with attached drawing.
Embodiment 1
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, as shown in Figure 1, 2, including outside high density
Layer 61 and low-density internal layer 62, for the integral structure with mold depanning;The high density outer layer 61 and low-density internal layer 62
Material is respectively high density sizing material and low-density sizing material, also uniformly buries and is covered with perpendicular to tray body in the low-density internal layer 62
The equally distributed spring supporting 63 in the longitudinal direction of 6 horizontal planes, plays the role of skeletal support by settable 3 to 6, is similar to concrete
In reinforcing bar, spring may be selected it is consistent with low-density caoutchouc elasticity, to reinforce the support strength of low-density internal layer, slow down low
The decaying of elastic fatigue caused by density inner layer frequent deformation.
High density gum base ingredients formula and its respective parts by weight include: 35~55 parts of compounded rubber, reclaimed rubber 40~60
Part, 3~5 parts of carbon black, 4~8 parts of butadiene rubber, 0.2~0.5 part of polyethylene glycol, 0.8~1.8 part of compound accelerant, stearic acid
0.4~0.7 part, 2~5 parts of zinc oxide, 1.5~3.8 parts of composite vulcanizing agent;Sole elasticity and wearability obtained are strong, in hardness
Property.Compounded rubber is naphthenic oil, butyl rubber, butadiene rubber, natural rubber, white carbon black, the black N330 of black wood charcoal, stearic acid, zinc oxide
With the composition of secondary K glue plastics;The carbon black is carbon black N330;The polyethylene glycol is PEG-4000;The compound promotion
The composition that agent is 0.3~0.8 part and 0.5~1 part of CZ promotor of parts by weight DM-80 promotor;The composite vulcanizing agent is attached most importance to
Measure 1~3 part and 0.5~0.8 part of DTDM vulcanizing agent of part S-80 vulcanizing agent of composition.Secondary K glue plastics, i.e. K glue regenerated plastics,
K glue, that is, butadiene-styrene polymer, selects in the present embodiment clear, colorless, garden spherical or the K glue of ellipse garden shape particle is regenerating
Plastics, dosage are 10% or so of compounded rubber gross weight, and the size of particle should be 2~5mm in any direction, be not contain more than
The metal impurities of 0.3um mechanical admixture visible with other.Its apparent density is about 1.01g/cm3, bulk density is about 0.62g/
cm3, bending strength >=34Mps, thermal deformation >=70 DEG C, elongation at break >=160%, hardness >=71Shore D, gamma transition temperature
Spend 115 DEG C of -70 ∽, impact strength >=27J/m.Low-density gum base ingredients are to add foaming agent in high density gum base ingredients, are foamed
Agent is that chemical foaming agent can be H series, AC series etc.;Can also use swelling agent, for physical blowing agent can be expandable microspheres,
Supercritical CO2Deng;Additive amount is the 1.0~5.0% of gross weight, and tire flexibility made from the component and wearability are high, tear-resistant
Property is strong.
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, using being sent out in the two-way injection mold of dual density
Soak that type-vulcanization trays production system completes the two-way injection of dual-density rubber material in a mold, foaming and sulfuration process are made,
It can effectively avoid pallet product in the circulation of each process, reduce production cost.As shown in Fig. 3,4,5,6, the two-way injection of dual density
Foam-in-mould molding-vulcanization trays production system includes pressing mold vulcanization platform 5 and its symmetrically arranged two injectors in the left and right sides
Pedestal 1 further includes the die venting and inflation mechanism 8 of side before or after pressing mold vulcanizes platform 5;It is solid on the pressing mold vulcanization platform 5
Surely there are pressing mold molding and foaming vulcanization plant 3;Sizing material injection device, 2 glue are respectively fixed on 2 injections machine base 1
Material injection device is oppositely arranged, respectively high density sizing material injection device 2 and low-density sizing material injection device 4;It is described to be compression molded into
Type and foaming vulcanization plant 3 include two mold cores that shape is identical, specification is different, the high density sizing material injection device 2
Two kinds of different plasticized rubber material of density different mold cores is corresponded to respectively with low-density sizing material injection device 4 successively to inject
In the mold for entering pressing mold molding and foaming vulcanization plant 3, the die venting and inflation mechanism 8 injection device 2 inject it is preceding will
Air emptying in the mold of pressing mold molding and foaming vulcanization plant 3, is passed through pressing mold molding and foaming for high pressure gas after injection
In the mold of vulcanization plant 3, the pressing mold molding and foaming vulcanization plant 3 carry out pressing mold foaming to the plasticized rubber material in mold
And vulcanization, foaming-vulcanization trays production system can be by injection moulding, inflatable and exhaust and hair in the two-way injection mold of dual density
Bubble, vulcanization plant are integrated, avoid heat losses caused by each process circulation in the prior art and process circulation cost, solve
Multiple pressurization, heating and the secondary glue of traditional rubber pallet production technology are pasted, energy consumption, time-consuming, at high cost one big
Disadvantage.
High density sizing material injection device 2 includes high density sizing material loading hopper 21, high density sizing material injection cylinder 22, high density
Sizing material plasticizing injection barrel 23, high density sizing material plasticizing heater 24, high density sizing material injection nozzle control oil cylinder 27, high density glue
Expect injection head 28 and high density sizing material injection seat Shift cylinder 29;The high density sizing material loading hopper 21 is plasticized with high density sizing material
The beginning of injection barrel 23 communicates, the beginning insertion high density sizing material injection cylinder 22 of high density sizing material plasticizing injection barrel 23
In cylinder barrel, and tight against the injection ram in high density sizing material injection cylinder 22;It is high built in high density sizing material plasticizing injection barrel 23
Density sizing material is plasticized injection screw, and high density sizing material is plasticized the end point of injection screw, and reserved high density sizing material prestores plasticizing material
Chamber 25;The high density sizing material prestores plasticizing material chamber 25 and passes through high density sizing material feed pipe 26 and high density sizing material plasticizing injection spiral shell
Cylinder 23 bottoms high density sizing material injection nozzle control 27 front end of oil cylinder material chamber connection, the high density sizing material injection head 28 into
Material end is connected to material chamber, and dispensing end is communicated with the mold of pressing mold vulcanization plant 3;High density sizing material injection nozzle controls 27 cylinder barrel of oil cylinder
It is fixedly connected with the cylinder barrel of high density sizing material injection seat Shift cylinder 29, the piston rod of the two backwards to being arranged, infuse by high density sizing material
It penetrates 29 piston rod of a Shift cylinder and the injection cylinder is both secured on injection machine base 1, high density sizing material is plasticized heater
24 circulating types are fixed on the outer wall of high density sizing material plasticizing injection barrel 23, the plasticizing of sizing material and are temporarily stored in same height before injection
It is carried out in density sizing material plasticizing injection barrel 23, while plasticizing, is prestored in plasticizing material chamber 25 in high density sizing material and complete injection
Preceding is temporary, avoids the transhipment of sizing material.Likewise, low-density sizing material injection device 4 includes low-density sizing material loading hopper 41, low
Density sizing material injection cylinder 42, low-density sizing material plasticizing injection barrel 43, low-density sizing material are plasticized heater 44, low-density sizing material
Injection nozzle controls oil cylinder 47, low-density sizing material injection head 48 and low-density sizing material injection seat Shift cylinder 49;The low-density glue
Material loading hopper 41 is communicated with the beginning that low-density sizing material is plasticized injection barrel 43, the beginning of low-density sizing material plasticizing injection barrel 43
It is inserted into the cylinder barrel of low-density sizing material injection cylinder 42, and tight against the injection ram in low-density sizing material injection cylinder 42;It is low close
Low-density sizing material built in spending sizing material plasticizing injection barrel 43 is plasticized injection screw, and low-density sizing material is plasticized the end of injection screw
Place, reserved low-density sizing material prestore plasticizing material chamber 45;The low-density sizing material prestores plasticizing material chamber 45 and is sent by low-density sizing material
The material chamber of low-density sizing material injection nozzle control 47 front end of oil cylinder of expects pipe 46 and low-density sizing material plasticizing injection 43 bottom of barrel connects
Logical, the feed end of the low-density sizing material injection head 48 is connected to material chamber, and dispensing end is communicated with the mold of pressing mold vulcanization plant 3;
Low-density sizing material injection nozzle control 47 cylinder barrel of oil cylinder is fixedly connected with the cylinder barrel of low-density sizing material injection seat Shift cylinder 49, the two
Piston rod backwards to being arranged, 49 piston rod of low-density sizing material injection seat Shift cylinder and the injection cylinder are both secured to injector
On pedestal 1, low-density sizing material plasticizing 44 circulating type of heater is fixed on the outer wall of low-density sizing material plasticizing injection barrel 43, sizing material
Plasticizing and injection before be temporarily stored in same low-density sizing material plasticizing injection barrel 43 and carry out, while plasticizing, in low-density
Sizing material, which prestores, is plasticized keeping in front of completing injection in material chamber 45, avoids the transhipment of sizing material.
Embodiment 2
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, basic structure improve it with embodiment 1
Be in: the both ends of spring supporting 63 are fixed with connecting plate 64, after connecting plate 64 links together spring supporting 63, in length and breadth
It is interspersed, facilitates spring supporting synchronous preset and fixed in mold, preset spring supporting can be carried out before the vulcanization of rubber
63, connecting plate 64 can effectively improve the bond strength of spring supporting and rubber, the embeddable spring of rubber tight against high density outer layer 61
In gap, synchronous with spring it can restore;As shown in Figure 4,5, pressing mold molding and foaming vulcanization plant 3 include die cylinder
31, upper mold half 33, lower mold half 34, mold core 1, mold core 2 36 and mold core rotational fuel tank 39;The female die
Tool 34 is fixed on pressing mold vulcanization platform 5, and the surface of lower mold half 34 is equipped with upper mold half 33, the upper mold half 33
It is detachably connected with die cylinder 31;The die cylinder 31 is fixed by fixed frame;In the mold core 1 and mold
2 36 shape of core is identical, specification is different, and the two tail end is opposite, is detachably fixed with mold core conversion support 37, and the mold core turns
It is T-shaped to change bracket 37, after mold core rotational fuel tank 39 is inserted into bottom end, is fixedly connected with the shaft of mold core rotational fuel tank 39;The mould
39 driven mold inner core 1 of core rotational fuel tank, mold core 2 36 are converted between upper mold half 33 and lower mold half 34;On
Half mold 33, lower mold half 34, mold core 1 and mold core 2 36 are equipped with according to the shape of tray body 6;Institute
Mold core rotational fuel tank 39 is stated to be fixed on pressing mold vulcanization platform 5;The pressing mold molding and foaming vulcanization plant 3 further include molding crossbeam
32, the hydraulic stem of the die cylinder 31 is fixedly connected with upper mold half 33 again after passing through the pilot hole for molding crossbeam 32;It is described
Molding crossbeam 32 is fixed on the fixed frame of pressing mold molding and foaming vulcanization plant 3;The pressing mold molding and foaming vulcanization plant 3
It further include die heater 38;The die heater 38 is set under top and/or the lower mold half 34 of upper mold half 33
Portion.High density sizing material injection device 2 and low-density sizing material injection device 4 respectively include high density sizing material injection head 28 and low-density
Sizing material injection head 48, the high density sizing material injection head 28 and low-density sizing material injection head 48 are arranged on pressing mold molding and foaming sulphur
3 mold two sides are set in makeup, and when injection, and the mould cavity for the vulcanization plant 3 that forms and foam with pressing mold communicates.Such as Fig. 6 institute
Show, the die venting and inflation mechanism 8 in the two-way injection mold of dual density in foaming-vulcanization trays production system include bracket
89, cylinder 81, cylinder block 84 and hydraulic station 86;The bracket 89 is the annular gantry that there is through-hole in centre, and the cylinder 81 is solid
Due on the circular table of bracket 89, the cylinder block 84 is fixed on the bottom of the circular table of bracket 89, the cylinder 81
With the cylinder piston 811 and oil cylinder piston 841 of the built-in same piston rod 88 of connection of the difference of cylinder block 84,81 top of cylinder
It is formed by tracheae 7 with pressing mold and the mold inner-cavity of foaming vulcanization plant 3 communicates;The cylinder block 84 is by oil cylinder piston 841
It is divided into upper cavity and lower chamber, two cavitys pass through an oil pipe 85 respectively and communicate with hydraulic station 86.Mold core conversion support 37 is lifting
Formula, when sizing material is injected, driven mold inner core 1 and mold core 2 36 are moved down, and can be the reserved injection position of injection.The cylinder
81 outer arm circulating type is fixed with block heater 82, and the bottom side of cylinder 81 is provided with cylinder and unloads stomata 83;The cylinder 81
Diameter is greater than cylinder block 84.
High density gum base ingredients formula and its respective parts by weight include: 35 parts of compounded rubber, and 40 parts of reclaimed rubber, carbon black 3
Part, 4 parts of butadiene rubber, 0.2 part of polyethylene glycol, 0.8 part of compound accelerant, 0.4 part of stearic acid, 2 parts of zinc oxide, composite vulcanizing agent
1.5 part.Compounded rubber is naphthenic oil, butyl rubber, butadiene rubber, natural rubber, white carbon black, the black N330 of black wood charcoal, stearic acid, oxidation
The composition of zinc and secondary K glue plastics;The carbon black is carbon black N330;The polyethylene glycol is PEG-4000;The compound rush
The composition for being 0.3 part and 0.5 part of CZ promotor of parts by weight DM-80 promotor into agent;The composite vulcanizing agent is parts by weight S-
80 1 part of vulcanizing agents and 0.5 part of DTDM vulcanizing agent of composition.Select clear, colorless, garden spherical in secondary K glue plastics the present embodiment
The K glue of particle is 10% or so of compounded rubber gross weight in regenerated plastics, dosage, and the size of particle should be in any direction
2mm is not contain more than metal impurities mechanical admixture visible with other of 0.3um.Its apparent density is about 1.01g/cm3, accumulation
Density is about 0.62g/cm3, bending strength >=34Mps, thermal deformation >=70 DEG C, elongation at break >=160%, hardness >=
71Shore D, 115 DEG C of -70 ∽ of glass transition temperature, impact strength >=27J/m.Low-density gum base ingredients are high density sizing material group
H series foaming agent is added in point, dosage is the 2% of gross weight.
The production technology of the high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, step are as follows:
Step 1: high density stock rubber is plasticized: high density sizing material injection nozzle control oil cylinder 27 first send high density sizing material
Expects pipe 26 and high density sizing material injection head 28 are closed, and are increased density stock rubber pellet by high density sizing material loading hopper 21 and are entered
High density sizing material plasticizing injection barrel 23, high density sizing material is plasticized injection screw 231 and rotates, while rotation, high density sizing material
Plasticizing injection screw 231 pushes against high density sizing material injection ram 221 and persistently moves back, and the sizing material after plasticizing is plasticized in high density sizing material
Expect to keep in chamber 25;
Step 2: molding: mold core rotational fuel tank 39 rotates mold core conversion support 37, and mold core 1 is inserted into upper mold section
At center between tool 33 and lower mold half 34, starting die cylinder 31 is moved down, and upper mold half 33 is closed up with lower mold half;
Step 3: vacuumizing: starting hydraulic station 86, high pressure oil enter 84 epicoele of cylinder block by high-pressure oil pipe, push
Oil cylinder piston 841 moves down, and oil cylinder piston 841 drives cylinder piston 811 to move together, and 81 epicoele of cylinder forms vacuum, will mold
Inner chamber gas drain;
Step 4: injection: high density sizing material injection head 28 is inserted into and closes by starting high density sizing material injection seat Shift cylinder 29
In upper mold half 33 and lower mold half 34 after mould, start high density sizing material injection cylinder 22, high density sizing material injection ram 221
Forward, will be in the high density stock rubber injection mold in high density sizing material pre-firing material-holding chamber 25;High density sizing material injection head 28
It closes;Start high density sizing material injection seat Shift cylinder 29, high density sizing material injection head 28 is exited into mold, is settled into after injection
Type;
Step 5: low-density stock rubber is plasticized: low-density sizing material injection nozzle control oil cylinder 47 first send low-density sizing material
Expects pipe 46 and low-density sizing material injection head 48 are closed, and are entered by low-density sizing material loading hopper 41 plus low-density stock rubber pellet
Low-density sizing material plasticizing injection barrel 43, low-density sizing material is plasticized injection screw 431 and rotates, while rotation, low-density sizing material
Plasticizing injection screw 431 pushes against low-density sizing material injection ram 421 and persistently moves back, and the sizing material after plasticizing is plasticized in low-density sizing material
Expect to keep in chamber 45;
Step 6: die sinking: starting die cylinder 31 moves up, and opens the tray body for including half of high density outer layer 61 respectively
6 upper mold half 33 and lower mold half 34, starts mold core rotational fuel tank 39, and mold core conversion support 37 takes out mold core 1
Out, and by mold core 2 36 it is inserted at the center between upper mold half 33 and lower mold half 34;
Step 7: pre-buried spring: spring is embedded in the tray body 6 of half of high density outer layer 61 of lower mold half 34
It is interior;, can be very easily pre-buried by spring in tray body before vulcanization, outer ring connecting plate 64 and inner ring connecting plate 65 can be by bullets
Spring overall time is pre-buried, easy to operate;
Step 8: molding: starting die cylinder 31 moves down, and upper mold half 33 is closed up with lower mold half 34, by mold core
2 36 indwellings;
Step 9: injection: mold core conversion support 37 declines, and reserves the injection position of low-density sizing material injection head 48;Start low
Density sizing material injection seat Shift cylinder 49, by the upper mold half 43 and lower mold half after the insertion molding of low-density sizing material injection head 48
In 44, start low-density sizing material injection cylinder 42, low-density sizing material injection ram 421 moves forward, and low-density sizing material pre-firing is held and is expected
In low-density stock rubber injection mold in chamber 45;Low-density sizing material injection head 48 is closed;Start low-density sizing material injection seat
Low-density sizing material injection head 48 is exited mold by Shift cylinder 49;
Step 10: mold core conversion support 37 rises to original position, start mold core rotational fuel tank 39, mold core conversion support 37 is by mould
Have inner core 2 36 to extract out;
Step 11: molding again: starting die cylinder 31 moves down, and will include the upper mold section of half of tray body 6 respectively
Tool 33 closes up again with lower mold half 34, the hollow form after removing inside tray body 6 in mold core 2 36;
Step 12: high-pressure aerated: starting hydraulic station 86, high pressure oil enter 84 cavity of resorption of cylinder block by high-pressure oil pipe,
Oil cylinder piston 841 is pushed to move up, oil cylinder piston 841 drives cylinder piston 811 to move up together, and cylinder piston 811 will be on cylinder 81
The pressure high temperature hot gas of chamber squeezes into upper mold half 33 and 36 inner cavity of lower mold half by air tube;
Step 13: foaming and vulcanization: the tray body 6 of upper mold half 33 and 34 inner cavity of lower mold half is heated up and is added
Pressure adjusts 31 back pressure of die cylinder, so that die cylinder 31 is switched to floating position, foaming agent reduces foaming, and makes rubber swelling shape
It at spongy state, then carries out pressure maintaining, heat preservation, protect the time, reach cures requirements;
Step 14: pressure release: by internal high temperature and high pressure gas pressure release;
Step 15: die sinking: starting die cylinder 31 moves up, and opens upper mold half 33 and lower mold half 34, takes out pallet
Ontology 6.
Embodiment 3
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, basic structure is the same as embodiment 2;
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, low-density gum base ingredients formula and its each
It include: 55 parts of compounded rubber from parts by weight, it is 60 parts of reclaimed rubber, 5 parts of carbon black, 8 parts of butadiene rubber, 0.5 part of polyethylene glycol, compound
1.8 parts of promotor, 0.7 part of stearic acid, 5 parts of zinc oxide, 3.8 parts of composite vulcanizing agent.Compounded rubber is naphthenic oil, butyl rubber, suitable
The black N330 of buna, natural rubber, white carbon black, black wood charcoal, stearic acid, zinc oxide and secondary K glue plastics composition;The carbon black
For carbon black N330;The polyethylene glycol is PEG-4000;The compound accelerant is 0.8 part of parts by weight DM-80 promotor and CZ
The composition that 1 part of promotor;The combination that the composite vulcanizing agent is 1 part and 0.5 part of DTDM vulcanizing agent of parts by weight S-80 vulcanizing agent
Object.Select the K glue of clear, colorless, ellipse garden shape particle in regenerated plastics in secondary K glue plastics the present embodiment, dosage is compounded rubber
10% or so of gross weight, the size of particle should be 5mm in any direction, be not contain more than 0.3um metal impurities and other
It can be seen that mechanical admixture.Its apparent density is about 1.01g/cm3, bulk density is about 0.62g/cm3, bending strength >=34Mps, heat
>=70 DEG C of deformation, elongation at break >=160%, hardness >=71Shore D, 115 DEG C of -70 ∽ of glass transition temperature, impact strength
≥27J/m.Low-density gum base ingredients are that AC series foaming agent is added in high density gum base ingredients, and dosage is the 5% of gross weight.
Foaming-vulcanization in the two-way injection mold of dual density of the rubber pallet for producing dual density layer of the present embodiment
The basic structure of pallet production system is the same as embodiment 3.
The production technology of the high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, step is the same as embodiment 2.
Embodiment 4
The high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, basic structure improve it with embodiment 3
It is in foaming in the two-way injection mold of dual density of the rubber pallet for producing dual density layer-vulcanization trays production system
The basic structure of system is theed improvement is that with embodiment 3: the bottom of the cavity of resorption of cylinder 81 is fixed with support limit block 812, and is
The cylinder unloads stomata 83 and reserves airspace, plays cylinder piston and moves down position-limiting action.In the outer rim of cylinder piston 811, with
High-temperature resistant seal ring 813 is set between 81 inner wall of cylinder, improves the sealing effect of cylinder upper and lower cavity, and avoids gas in sulfidation
Body leakage.High-temperature resistant seal ring 813 is polytetrafluoroethylene (PTFE) or viton seal ring, and service life can be improved, prevent long-term work
Gas leakage under state, and ensure that stability when leakproofness and vulcanization in turn;The both ends of tracheae 7 are connected by mold respectively
Pipe fitting and cylinder connecting tube connector 80 are fixed in upper mold half 33 and cylinder 81, improve the stability and leakproofness of connection.
High density gum base ingredients formula and its respective parts by weight include: 45 parts of compounded rubber, and 50 parts of reclaimed rubber, carbon black 4
Part, 6 parts of butadiene rubber, 0.35 part of polyethylene glycol, 1.3 parts of compound accelerant, 0.5 part of stearic acid, 4 parts of zinc oxide, composite sulfuration
2.6 parts of agent.Compounded rubber is naphthenic oil, butyl rubber, butadiene rubber, natural rubber, white carbon black, the black N330 of black wood charcoal, stearic acid, oxygen
Change the composition of zinc and secondary K glue plastics;The carbon black is carbon black N330;The polyethylene glycol is PEG-4000;It is described compound
The composition that promotor is 0.6 part and 0.75 part of CZ promotor of parts by weight DM-80 promotor;The composite vulcanizing agent is parts by weight
The composition that 2 parts and 0.65 part of DTDM vulcanizing agent of S-80 vulcanizing agent.The dosage and characteristic of secondary K glue plastics are same in the present embodiment
Embodiment 3.Low-density gum base ingredients are to add swelling agent in high density gum base ingredients, and it is micro- to can be expansion for physical blowing agent
Ball, supercritical CO2Deng;Additive amount is the 5.0% of gross weight.
The production technology of the high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet of the present embodiment, step is the same as embodiment 2.
Through detecting, high-strength high-elasticity dual density foam-in-mould rubber and plastic pallet obtained is heat-resisting, wear-resisting, weather-proof, moreover, together
The production of one die cavity, quality are stablized, and dynamic balancing even results are good.
Schematically the present invention and embodiments thereof are described above, description is not limiting, institute in attached drawing
What is shown is also one of embodiments of the present invention, and actual structure is not limited to this.So if the common skill of this field
Art personnel are enlightened by it, without departing from the spirit of the invention, are not inventively designed and the technical solution
Similar frame mode and embodiment, are within the scope of protection of the invention.