CN109294108A - 一种新型人造革 - Google Patents

一种新型人造革 Download PDF

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Publication number
CN109294108A
CN109294108A CN201811011332.4A CN201811011332A CN109294108A CN 109294108 A CN109294108 A CN 109294108A CN 201811011332 A CN201811011332 A CN 201811011332A CN 109294108 A CN109294108 A CN 109294108A
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parts
artificial leather
pvc
agent
plasticizer
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方忠华
曹忠德
姜志军
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ZHEJIANG HUAXIANG LEATHER Co Ltd
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ZHEJIANG HUAXIANG LEATHER Co Ltd
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    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09J127/04—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
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Abstract

本发明提供一种新型人造革，包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：PVC、耐磨剂、抗菌剂、AC发泡剂、增塑剂、热稳定剂，所述的粘合层包括如下质量分数的组分：PVC、增塑剂、热稳定剂、阻燃剂、氯化石蜡、填充剂。本发明的有益效果是通过在PVC面层加入耐磨剂和抗菌剂，提高人造革的抗菌性能和耐磨性能，便于使用者的使用。

Description

一种新型人造革
技术领域
本发明属于生产人造革技术领域，尤其是涉及一种新型人造革及其生产工艺。
背景技术
随着工业技术的发展，人造皮革的制作技术亦日益进步，其可搭配不同的基材，以及运用不同的加工方式，制作出不同特性以及表面花纹的人造皮革，因此，与天然皮革相比，人造皮革具有多功能及多样化的优点。
现有的人造革抗菌性能差，尤其是在服装上，给使用者带来不便；市场上的人造革耐磨性虽然满足要求，但是随着使用时间的推移，其耐磨性逐渐下降，导致使用寿命不长。
发明内容
本发明的目的是提供一种结构简单、提高耐磨性、提高抗菌性能的新型人造革，尤其适合用于生产人造革中。
本发明的技术方案是：
一种新型人造革，包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：
PVC 100份
耐磨剂 3-5份
抗菌剂 8-10份
AC发泡剂 3-10份
增塑剂 60-120份
热稳定剂 0.1-10份，
所述的粘合层包括如下质量分数的组分：
PVC 100份
增塑剂 50-60份
热稳定剂 2-3份
阻燃剂 4-6份
氯化石蜡 5份
填充剂 15-20份，
所述的阻燃剂由三氧化二锑、DOP按照质量比为3:1混合后制得。
所述的填充剂为碳酸钙、硅灰石、滑石粉、陶土等。
进一步的，所述增塑剂采用 DOP、DINP和DOA中的一种或几种混合物。
进一步的，所述热稳定剂采用硬脂酸钡、硬脂酸镉、硬脂酸 锌和硬脂酸铅中的一种或几种混合物。
进一步的，所述的抗菌剂为银离子抗菌剂。
进一步的，所述的耐磨剂由以下重量百分比的物质组成：1H,1H,2H,2H- 全氟辛基甲基二甲氧基硅烷20 ～ 30％、纳米级碳化硅10 ～ 20％、聚四氟乙烯微粉5 ～ 10％，余量为苯胺甲基甲基二甲氧基硅烷。
所述的PVC面层的各种原料最优质量分数的组分为：
PVC 100份
耐磨剂 4份
抗菌剂 9份
AC发泡剂 7份
增塑剂 90份
热稳定剂 5份，
所述的粘合层的各种原料最优质量分数的组分：
PVC 100份
增塑剂 55份
热稳定剂 2.5份
阻燃剂 5份
氯化石蜡 5份
填充剂 17份。
本发明具有的优点和积极效果是：由于采用上述技术方案，通过在PVC面层加入耐磨剂和抗菌剂，提高人造革的抗菌性能和耐磨性能，便于使用者的使用。
具体实施方式
实施例1
本发明的技术方案为一种新型人造革，包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：
PVC 100份
耐磨剂 4份
抗菌剂 9份
AC发泡剂 7份
增塑剂 90份
热稳定剂 5份，
所述的粘合层包括如下质量分数的组分：
PVC 100份
增塑剂 55份
热稳定剂 2.5份
阻燃剂 5份
氯化石蜡 5份
填充剂 17份，
所述的阻燃剂由三氧化二锑、DOP按照质量比为3:1混合后制得。
所述的填充剂为碳酸钙、硅灰石、滑石粉、陶土等。
本实施例中，所述增塑剂采用 DOP、DINP和DOA中的一种或几种混合物。
本实施例中，所述热稳定剂采用硬脂酸钡、硬脂酸镉、硬脂酸 锌和硬脂酸铅中的一种或几种混合物。
本实施例中，所述的抗菌剂为银离子抗菌剂。
本实施例中，所述的耐磨剂由以下重量百分比的物质组成：1H,1H,2H,2H- 全氟辛基甲基二甲氧基硅烷25％、纳米级碳化硅15％、聚四氟乙烯微粉7％，余量为苯胺甲基甲基二甲氧基硅烷。
实施例2
一种新型人造革，包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：
PVC 100份
耐磨剂 5份
抗菌剂 10份
AC发泡剂 10份
增塑剂 60份
热稳定剂 10份，
所述的粘合层包括如下质量分数的组分：
PVC 100份
增塑剂 60份
热稳定剂 2份
阻燃剂 4份
氯化石蜡 5份
填充剂 20份，
所述的阻燃剂由三氧化二锑、DOP按照质量比为3:1混合后制得。
所述的填充剂为碳酸钙、硅灰石、滑石粉、陶土等。
本实施例中，所述增塑剂采用 DOP、DINP和DOA中的一种或几种混合物。
本实施例中，所述热稳定剂采用硬脂酸钡、硬脂酸镉、硬脂酸 锌和硬脂酸铅中的一种或几种混合物。
本实施例中，所述的抗菌剂为银离子抗菌剂。
本实施例中，所述的耐磨剂由以下重量百分比的物质组成：1H,1H,2H,2H- 全氟辛基甲基二甲氧基硅烷30％、纳米级碳化硅20％、聚四氟乙烯微粉5％，余量为苯胺甲基甲基二甲氧基硅烷。
实施例3
一种新型人造革，包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：
PVC 100份
耐磨剂 3份
抗菌剂 8份
AC发泡剂 3份
增塑剂 120份
热稳定剂 0.1份，
所述的粘合层包括如下质量分数的组分：
PVC 100份
增塑剂 50份
热稳定剂 3份
阻燃剂 4份
氯化石蜡 5份
填充剂 15份，
所述的阻燃剂由三氧化二锑、DOP按照质量比为3:1混合后制得。
所述的填充剂为碳酸钙、硅灰石、滑石粉、陶土等。
本实施例中，所述增塑剂采用 DOP、DINP和DOA中的一种或几种混合物。
本实施例中，所述热稳定剂采用硬脂酸钡、硬脂酸镉、硬脂酸 锌和硬脂酸铅中的一种或几种混合物。
本实施例中，所述的抗菌剂为银离子抗菌剂。
本实施例中，所述的耐磨剂由以下重量百分比的物质组成：1H,1H,2H,2H- 全氟辛基甲基二甲氧基硅烷20％、纳米级碳化硅10％、聚四氟乙烯微粉5 ％，余量为苯胺甲基甲基二甲氧基硅烷。
通过对实施例1-3的人造革进行抗菌和耐磨测试，对比普通的人造革，本发明的人造革抗菌性能和耐磨性明显高于普通的人造革。
以上对本发明的一个实施例进行了详细说明，但所述内容仅为本发明的较佳实施例，不能被认为用于限定本发明的实施范围。凡依本发明申请范围所作的均等变化与改进等，均应仍归属于本发明的专利涵盖范围之内。

Claims (5)

1.一种新型人造革，其特征在于：包括依次通过粘合层相连的基底层、PVC面层和表面修饰层，所述的基底层以针织布为基底材料组成，所述的PVC面层包括如下质量分数的组分：
PVC 100份
耐磨剂 3-5份
抗菌剂 8-10份
AC发泡剂 3-10份
增塑剂 60-120份
热稳定剂 0.1-10份，
所述的粘合层包括如下质量分数的组分：
PVC 100份
增塑剂 50-60份
热稳定剂 2-3份
阻燃剂 4-6份
氯化石蜡 5份
填充剂 15-20份，
所述的阻燃剂由三氧化二锑、DOP按照质量比为3:1混合后制得。
2.根据权利要求1所述的一种新型人造革，其特征在于：所述增塑剂采用 DOP、DINP和DOA中的一种或几种混合物。
3.根据权利要求1所述的一种新型人造革，其特征在于：所述热稳定剂采用硬脂酸钡、硬脂酸镉、硬脂酸 锌和硬脂酸铅中的一种或几种混合物。
4.根据权利要求1所述的一种新型人造革，其特征在于：所述的抗菌剂为银离子抗菌剂。
5.根据权利要求1所述的一种新型人造革，其特征在于：所述的耐磨剂由以下重量百分比的物质组成：1H,1H,2H,2H- 全氟辛基甲基二甲氧基硅烷20 ～ 30％、纳米级碳化硅10～ 20％、聚四氟乙烯微粉5 ～ 10％，余量为苯胺甲基甲基二甲氧基硅烷。
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