CN109275702A - Antistaling agent for aquatic product bio ice temperature - Google Patents

Antistaling agent for aquatic product bio ice temperature Download PDF

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Publication number
CN109275702A
CN109275702A CN201811151902.XA CN201811151902A CN109275702A CN 109275702 A CN109275702 A CN 109275702A CN 201811151902 A CN201811151902 A CN 201811151902A CN 109275702 A CN109275702 A CN 109275702A
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CN
China
Prior art keywords
ice
fish
temperature
storing
xanthan gum
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Pending
Application number
CN201811151902.XA
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Chinese (zh)
Inventor
苏来金
徐仰丽
叶剑
林胜利
李彦坡
吴士专
余海
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Wenzhou Polytechnic
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Wenzhou Polytechnic
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Priority to CN201811151902.XA priority Critical patent/CN109275702A/en
Publication of CN109275702A publication Critical patent/CN109275702A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/06Freezing; Subsequent thawing; Cooling
    • A23B4/08Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals before or during cooling, e.g. in the form of an ice coating or frozen block
    • A23B4/09Freezing; Subsequent thawing; Cooling with addition of chemicals or treatment with chemicals before or during cooling, e.g. in the form of an ice coating or frozen block with direct contact between the food and the chemical, e.g. liquid N2, at cryogenic temperature
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/14Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
    • A23B4/18Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
    • A23B4/20Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Microbiology (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

The invention discloses a kind of antistaling agent for aquatic product bio ice temperature, contain Xanthan Gum in ingredient.The invention also discloses a kind of specific antistaling agents, including following component: Xanthan Gum, guar gum, sodium alginate.The present invention also provides a kind of combination antistaling agents, the method for combining the aquatic products such as the fresh-keeping fish of biological ice temperature using fluidisation ice pre-cooling, it can be used for the long short distance transportational process of fish, the organoleptic quality of fish can preferably be kept, inhibit the raising of its K value, pH value and microbiological indicator, delay the oxidation rate of the flesh of fish, the variation of effective control centre's temperature within a certain period of time, delay fat oxidation, protein catabolic rate, preferably maintain musculature morphology, shelf life can reach 20d or more, be especially suitable for the long-distance transport of the fish of high economic value.Low in cost simultaneously, easy to operate, fluidisation ice will not melt in transit, substantially reduce workload, can be applicable on a large scale.

Description

Antistaling agent for aquatic product bio ice temperature
Technical field
The present invention relates to a kind of antistaling agents for aquatic product bio ice temperature, belong to technical field of aquatic product preservation.
Background technique
Xanthan Gum is also known as yellow glue, xanthan gum, xanthan gum, and Xanthan Gum is that one kind is sent out by pseudo xanthomonas The monospore polysaccharides that ferment generates due to its macromolecular special construction and colloid property, and have multiple functions, can be used as emulsification Agent, stabilizer, gelling thickener, size, film forming agent etc., are widely used in all fields of national economy.
In field of food, xanthan gum is mainly used for thickener, in addition, in field of food preservation, the research of xanthan gum and It reports fewer.
Aquatic products such as fish, shrimp, crab etc. easily cause bacterial reproduction and putrid and deteriorated because it is rich in protein and moisture, such as Its Volatile Base Nitrogen is greater than 30mg/100g when by the 10th~13 day after fresh turbot deepfreeze.To prevent aquatic products Corruption, traditional method are to be freezed, and bacterium is made to be difficult to breed at low temperature, although avoiding corruption, the result of frost makes The aquatic products human body changes colour, meat dries out, harden or gruel, delicate flavour are had a greatly reduced quality.For this purpose, people are devoted to research water all the time The non-freezing process for antistaling method of product.Currently, mostly use antistaling agent immersion process greatly to preservation of fishery, and antistaling agent is substantially all It is the chemical substances such as composite phosphate, sulphite, chlorine dioxide or sodium acetate, it is difficult to guarantee food safety.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of new aquatic product fresh keeping agents and preservation method.
The present invention passes through the study found that Xanthan Gum (xanthan gum) can be applied on preservation of fishery.
Aquatic product fresh keeping agent provided by the invention, which is characterized in that contain Xanthan Gum in ingredient.Specifically, this Invention provides a kind of specific antistaling agent, including following component: Xanthan Gum, guar gum, sodium alginate.
Preferably, Xanthan Gum, guar gum, sodium alginate mass ratio be 1-10:1-3:1.
Further, in use, antistaling agent needs to configure solution use, divides in specific preparation proportion 100mL water Not Jia Ru 1-10g:1-3g:1g Xanthan Gum, guar gum, sodium alginate.
Using antistaling agent of the invention, the preservation method that a kind of fluidisation ice pre-cooling combines biological ice temperature is also provided, including under Column step:
(1) it by fresh aquatic products (fish) cleaned standby seam, is put into above-mentioned antistaling agent solution and impregnates 10-15min.
(2) after impregnating, aquatic products are put into storing at ice temperature in the equipment such as refrigerator or refrigerator-freezer, storing at ice temperature temperature is -2 ~-5 DEG C;Maintain 30-70min.
(3) compound concentration is the saline solution of 2.5-4.5%, and prepared salting liquid is produced fluidisation ice with fluidisation ice maker Slurry.
(4) the fluidisation ice slurry prepared is laid in bubble chamber bottom, the aquatic products that storing at ice temperature is finished are according to layer ice Layer fish is placed in ice slurry, and bubble chamber bottommost ice thickness 2-5cm covers every layer of ice 2-3cm on fish body surface, and ice fish volume ratio is 0.5-1:1, fluidisation ice will embed fish body, starvation completely;The bubble chamber storing at ice temperature that will be handled well, storing at ice temperature temperature It is -2~-5 DEG C.
Preferably, when step 3) compound concentration is the saline solution of 2.5-4.5%, antistaling agent provided by the invention is added. The mass fraction that antistaling agent is added is 0.5-5%.
The beneficial effects of the present invention are:
In periodical " application study progress of the bio-preservative in preservation of fishery " text, bio-preservative is described Present Research.Antistaling agent provided by the invention belongs to the scope of bio-preservative, it can reduce internal moisture volatilization, delay Fat oxidation extends the shelf life of fish body with suppressing growth of microorganism, and safety is non-hazardous to human body, and fresh-keeping effect is significant.
The present invention also provides a kind of combination antistaling agents, combine the water such as the fresh-keeping fish of biological ice temperature using fluidisation ice pre-cooling The method of product can be used for the long short distance transportational process of fish, can preferably keep the organoleptic quality of fish, inhibit its K value, The raising of pH value and microbiological indicator delays the oxidation rate of the flesh of fish, within a certain period of time the variation of effective control centre's temperature, Delay fat oxidation, protein catabolic rate, preferably maintenance musculature morphology, shelf life can reach 20d or more, especially suitable Close the long-distance transport of the fish of high economic value.Low in cost simultaneously, easy to operate, fluidisation ice will not melt in transit, Workload is substantially reduced, can be applicable on a large scale.
Specific embodiment
The fresh-keeping effect of 1 Xanthan Gum of embodiment is verified
The aquatic products that the present embodiment selects are Penaeus Vannmei, and fresh Penaeus Vannmei is cleaned up.
Antistaling agent is configured using two ways in experimental group:
Testing one group is the pure water solution for using Xanthan Gum, in the aqueous solution of Xanthan Gum in 100mL water It is separately added into the Xanthan Gum of 3g.
Testing two groups is to be separately added into Xanthan Gum, guar gum, sodium alginate in specific preparation proportion 100mL water, Ratio is 3g:1g:1g.
As the Penaeus Vannmei of control, aqueous solution is uniformly sprayed on to prawn surface.
Then it is packaged into bag, after being packaged into bag, vacuumized, inflated and hot-seal carries out controlled atmospheric packing with gas-control packing device. Product after being packaged into bag refrigerates under conditions of 4 DEG C ± 1 DEG C.
When saving the 10th day, the Penaeus Vannmei total plate count as control is 9.21 × 107CFU/g, volatility alkali Nitrogen (mg/100g) is 16.29, and the processed Penaeus Vannmei of antistaling agent, the total plate count of one group of experiment is 5.33 × 104CFU/g;Volatile Base Nitrogen (mg/100g) is 10.35;The total plate count for testing two groups is 7.28 × 103CFU/g;Volatilization Property alkali nitrogen (mg/100g) be 8.18.
Embodiment 2
Fluidisation ice pre-cooling provided in this embodiment combines the preservation method of biological ice temperature, including the following steps:
(1) it by fresh aquatic products (fish) cleaned standby seam, is put into antistaling agent solution and impregnates 10min.
(2) after impregnating, aquatic products are put into storing at ice temperature in the equipment such as refrigerator or refrigerator-freezer, storing at ice temperature temperature is -5 ℃;Maintain 60min.
(3) saline solution that mass concentration is 4.5% is prepared, prepared salting liquid is produced into fluidisation ice with fluidisation ice maker Slurry.
(4) the fluidisation ice slurry prepared is laid in bubble chamber bottom, the aquatic products that storing at ice temperature is finished are according to layer ice Layer fish is placed in ice slurry, bubble chamber bottommost ice thickness 3cm, covers every layer of ice 3cm on fish body surface, and ice fish volume ratio is 1:1, Fluidisation ice will embed fish body, starvation completely;The bubble chamber storing at ice temperature that will be handled well, storing at ice temperature temperature are -5 DEG C.
Antistaling agent provided in this embodiment is Xanthan Gum.
In step 1, by fresh aquatic products (fish) cleaned standby seam, it is put into antistaling agent solution and impregnates, antistaling agent solution Mass fraction be 1%.
Embodiment 3
Fluidisation ice pre-cooling provided in this embodiment combines the preservation method of biological ice temperature, including the following steps:
(1) it by fresh aquatic products (fish) cleaned standby seam, is put into antistaling agent solution and impregnates 15min.
(2) after impregnating, aquatic products are put into storing at ice temperature in the equipment such as refrigerator or refrigerator-freezer, storing at ice temperature temperature is -3 ℃;Maintain 40min.
(3) saline solution that mass concentration is 2.5% is prepared, prepared salting liquid is produced into fluidisation ice with fluidisation ice maker Slurry.
(4) the fluidisation ice slurry prepared is laid in bubble chamber bottom, the aquatic products that storing at ice temperature is finished are according to layer ice Layer fish is placed in ice slurry, bubble chamber bottommost ice thickness 5cm, covers every layer of ice 3cm on fish body surface, and ice fish volume ratio is 1:1, Fluidisation ice will embed fish body, starvation completely;The bubble chamber storing at ice temperature that will be handled well, storing at ice temperature temperature are -2 DEG C.
When step 3) prepares the saline solution that mass concentration is 2.5%, antistaling agent is added, the mass fraction of antistaling agent is added It is 3%.
In step 1, by fresh aquatic products (fish) cleaned standby seam, it is put into antistaling agent solution and impregnates, antistaling agent solution Mass fraction be 4%.
Antistaling agent provided in this embodiment is Xanthan Gum.
The fresh-keeping experiment contrast of 4 Larimichthys crocea of embodiment
1, Experimental fish: fresh and alive Larimichthys crocea be purchased from Wenzhou City seafood wholesale market, select posture uniformly, bright color, essence The full fresh and alive individual of mind.
2, experimental design: experiment is divided into 4 groups, and every group of fresh-keeping treating method is as follows:
First group: carrying out fresh-keeping storage according to the method that embodiment 2 provides.
Second group: carrying out fresh-keeping storage according to the method that embodiment 3 provides.
Third group: fresh-keeping storage is carried out according to the method that embodiment 2 provides, unlike first group, step 1) will be new Fresh aquatic products (fish) cleaned standby seam, is put into antistaling agent solution and impregnates 10min, remove antistaling agent, be directly placed into ice water 10min is impregnated, the purpose of this control group is to verify the fresh-keeping effect of antistaling agent provided by the invention.
4th group: be pre-chilled with trash ice, transport and storage processing.
3, Experimental Evaluation
Storage period carried out sense palace, hardness, total bacteria count, volatility alkali to chilled Larimichthys crocea every 5 days since the 5th day Total nitrogen (TVB-N), thiobarbituricacidα- (TBA) and total acidity detection.
3.1 subjective appreciation
The evaluation criteria that the present invention uses is as follows:
Score value Color Smell The elasticity of muscle
5 Normally, muscle cross-sectional is glossy It is intrinsic fragrance, pure and fresh Solid high resilience
4 Normally, muscle cross-sectional is glossy It is intrinsic fragrance, more pure and fresh It is solid flexible
3 Slightly dim, muscle cross-sectional is slightly glossy Intrinsic fragrance, light, slightly peculiar smell It is flexible
2 Dimer, muscle cross-sectional is matt No intrinsic fragrance has fishy smell It is slightly elastic
1 Dimness, not gloss There is strong fishy smell It is nonelastic
Sensory evaluation validity check: it was measured with the 20th day of storage, concrete outcome is as follows:
Project First group Second group Third group 4th group
Color 5 5 4 2
Smell 4 4 3 1
The elasticity of muscle 4 5 3 1
The measurement of 3.2 total plate counts
Measuring method is operated with reference to GB/T4789.2-2010, takes the 25g flesh of fish under aseptic condition, is put in 225ml containing bead Sterile saline in, mix well, the dilution of 1:10 be made, according to sample degree of spoilage, select appropriate dilution, often A dilution is done three times in parallel, measures total plate count using inverted plate method, the total plate count measurement result in 4 fresh-keeping group:
Project First group Second group Third group 4th group
It is measured in parallel 1 3.21×104CFU/g 5.11×103CFU/g 8.25×104CFU/g 2.91×105CFU/g
It is measured in parallel 2 4.91×104CFU/g 4.91×103CFU/g 6.97×104CFU/g 3.78×105CFU/g
It is measured in parallel 3 4.24×104CFU/g 5.37×103CFU/g 8.22×104CFU/g 2.84×105CFU/g
3.3 total volatile basic nitrogens (TVB-N) measurement
It is measured using Kang Wei ware method, weighs the 10g flesh of fish, rubbed and mix, be transferred in conical flask, 100ml distilled water is added, Shaking sufficiently, is filtered after 30min, takes 1ml filtrate to be added to diffusion boat mistress with micropipettor, 1ml saturated carbon is added in the other side Sour potassium solution, two liquid do not contact directly, will change by the uniform diffusion boat upper cover of water-soluble glue coating and screw.Diffusion boat is existed It in the direction of the clock and is rotated in an anti-clockwise direction respectively on desktop, is sufficiently mixed sample liquid with lye, is placed in 37 DEG C of insulating boxs 2h uncovers, and is titrated with normal hydrochloric acid liquid (0.01mol/L), and terminal is in bluish violet.
Present invention demonstrates that fluidisation ice pre-cooling combination with ice-temperature has played extraordinary preservation in fish transport, in short-term It is interior to can be effectively controlled fish body temperature change, seafood degree is maintained, operating method is simple and easy, increases aquatic products carrying capacity, saves Human and material resources have broad application prospects.

Claims (7)

1. application of the Xanthan Gum on preservation of fishery.
2. a kind of aquatic product fresh keeping agent, which is characterized in that contain Xanthan Gum in ingredient.
3. a kind of aquatic product fresh keeping agent, including following component: Xanthan Gum, guar gum, sodium alginate.
4. aquatic product fresh keeping agent according to claim 3, which is characterized in that Xanthan Gum, guar gum, sodium alginate Mass ratio be 1-10:1-3:1.
5. application of the aquatic product fresh keeping agent as claimed in claim 4 in biological storing at ice temperature.
6. the preservation method that a kind of fluidisation ice pre-cooling combines biological ice temperature, characterized in that it comprises the following steps:
(1) it by fresh aquatic products (fish) cleaned standby seam, is put into antistaling agent solution described in any of the above-described claim Impregnate 10-15min;
(2) after impregnating, aquatic products are put into storing at ice temperature in the equipment such as refrigerator or refrigerator-freezer, storing at ice temperature temperature is -2~-5 ℃;Maintain 30-70min;
(3) compound concentration is the saline solution of 2.5-4.5%, and prepared salting liquid is produced fluidisation ice slurry with fluidisation ice maker;
(4) the fluidisation ice slurry prepared is laid in bubble chamber bottom, the aquatic products that storing at ice temperature is finished are according to layer ice sheet fish It is placed in ice slurry, bubble chamber bottommost ice thickness 2-5cm, covers every layer of ice 2-3cm on fish body surface, ice fish volume ratio is 0.5- 1:1, fluidisation ice will embed fish body, starvation completely;The bubble chamber storing at ice temperature that will be handled well, storing at ice temperature temperature are -2 ~-5 DEG C.
7. preservation method according to claim 6, which is characterized in that step 3) compound concentration is that the salt of 2.5-4.5% is water-soluble When liquid, antistaling agent is added.
CN201811151902.XA 2018-09-29 2018-09-29 Antistaling agent for aquatic product bio ice temperature Pending CN109275702A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112400973A (en) * 2020-11-06 2021-02-26 温州大学 Aquatic product rapid freezing method based on electric field synergy

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585659A (en) * 1983-10-13 1986-04-29 Hussey Edwin S Process for preserving seafood
US5645880A (en) * 1993-07-08 1997-07-08 Mcardle; Blaise Protein-polysaccharide complex composition and method of use
CN106857790A (en) * 2017-04-18 2017-06-20 上海海洋大学 A kind of method of the fluidisation ice preservation butterfish of bamboo vinegar liquid antistaling agent
CN107361120A (en) * 2017-07-19 2017-11-21 海南职业技术学院 Marine product hypnosis preservation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4585659A (en) * 1983-10-13 1986-04-29 Hussey Edwin S Process for preserving seafood
US5645880A (en) * 1993-07-08 1997-07-08 Mcardle; Blaise Protein-polysaccharide complex composition and method of use
CN106857790A (en) * 2017-04-18 2017-06-20 上海海洋大学 A kind of method of the fluidisation ice preservation butterfish of bamboo vinegar liquid antistaling agent
CN107361120A (en) * 2017-07-19 2017-11-21 海南职业技术学院 Marine product hypnosis preservation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112400973A (en) * 2020-11-06 2021-02-26 温州大学 Aquatic product rapid freezing method based on electric field synergy
CN112400973B (en) * 2020-11-06 2023-06-27 温州大学 Aquatic product rapid freezing method based on electric field cooperation

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Application publication date: 20190129