CN109207125A - A kind of preparation method of the pectase liquid applied to snow melt liquid - Google Patents
A kind of preparation method of the pectase liquid applied to snow melt liquid Download PDFInfo
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- CN109207125A CN109207125A CN201810919004.8A CN201810919004A CN109207125A CN 109207125 A CN109207125 A CN 109207125A CN 201810919004 A CN201810919004 A CN 201810919004A CN 109207125 A CN109207125 A CN 109207125A
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- liquid
- vegetables
- rim charge
- fruits
- pectase
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The present invention relates to environmental improvement, in particular to a kind of preparation methods of the pectase liquid applied to snow melt liquid, including five pretreatment of raw material, mashing, enzymatic hydrolysis, fermentation, secondary fermentation steps.The present invention uses fruits and vegetables rim charge to produce for raw material, not only reduces cost, and the process for eliminating processing rim charge, beneficial to environmental protection;The auxiliary material safety and environmental protection used, it is conventional to forbid or control chemicals;Production method is simple, it is easy to accomplish automation control;Performance stabilization, good fluidity are easy to save and transport.The present invention is used among snow melt liquid, to metal material such as reinforcing bar non-corroding, to cement without destroy, it is pollution-free to soil and water body, do not damage road, bridge facility and concrete component, do not destroy vegetation, not polluted source, it is harmless.
Description
Technical field
The present invention relates to environmental improvement, in particular to the preparation method of a kind of pectase liquid applied to snow melt liquid.
Background technique
Deicing salt also known as changes cryosel, road antifreezing agent, is mainly used for winter airport, expressway, square, parking railway, city
Snow removing and antifreeze effect are played in city street etc..The deicing salt ingredient of present large-scale use is with sodium chloride, calcium chloride, magnesium chloride
Based on equal inorganic salts.Since deicing salt has many advantages, such as easy to use, moderate, use scope is also more and more extensive.But
It is that the inorganic salts deicing salt largely used does not only result in afforestation vegetation mortality, highway, bridge concrete road surface are by serious rotten
After erosion destroys, and the snow for being doped into deicing salt melts infiltration earth's surface, rivers, underground water can be also polluted, destroy ecological environment.
The pectase liquid of Industrial routes production and other material liquids are cooperated into the snow melt liquid produced, can effectively be changed
Many drawbacks such as longer the time required to being apt to big waste when existing solid-state deicing salt uses, low efficiency, melting ice and snow.Current fruits and vegetables
Enzyme liquid is mostly retrofit product, is mainly used in food, among cosmetic industry, and manufacture craft is cumbersome and raw material is high
It is expensive, it is not suitable among the snow melt liquid produced and used on a large scale.
Summary of the invention
For above-mentioned deficiency in the prior art, the present invention provides a kind of environment-friendly type pectase snow melt liquid, environmentally friendly,
Stablize.
In order to achieve the above object of the invention, the technical solution adopted by the present invention are as follows:
A kind of preparation method of the pectase liquid applied to snow melt liquid, includes the following steps:
(1) it pretreatment of raw material: is drained after taking a certain amount of fruits and vegetables rim charge, processing clean;
(2) it is beaten: fruits and vegetables rim charge is beaten, the water for accounting for fruits and vegetables rim charge weight 20~40% is added, fermentor is then added
In;
(3) it digests: calcium acetate, pectase and cellulase being added in the fermenter, after digesting 15-20h, be warming up to 80
DEG C, 20min is kept the temperature, then be cooled to 36-38 DEG C;
(4) it ferments: saccharomyces cerevisiae being added in the fermenter and stirs evenly, continuing fermentation, is measured by sampling since the 6th day
The alcoholic strength of fermentation liquid, continuous 2 days alcoholic strengths are constant, stop fermenting, and filtering obtains one time fermentation liquid;
(5) secondary fermentation: being added triethanolamine and acetic acid bacteria in one time fermentation liquid, and sufficiently logical oxygen after 40-45 days, obtains
Pectase liquid.
Preferably, the vegetables rim charge that the preferred tartaric acid content of the fruits and vegetables rim charge is high, sugariness is high, content of cellulose is high
With fruit rim charge.
Preferably, the optimum weight of water used is the fruits and vegetables rim charge weight during (2) are beaten
30%.
The invention has the benefit that fruits and vegetables rim charge is used to be produced for raw material, cost is not only reduced, and save
The process of processing rim charge, beneficial to environmental protection;The auxiliary material safety and environmental protection used, it is conventional to forbid or control chemicals;Producer
Method is simple, it is easy to accomplish automation control;Performance stabilization, good fluidity are easy to save and transport.The present invention is used for snow melt liquid
Among, to metal material such as reinforcing bar non-corroding, to cement without destroy, it is pollution-free to soil and water body, do not damage road, bridge is set
It applies and concrete component, does not destroy vegetation, not polluted source, it is harmless.
Specific embodiment
In order that the present invention can be more clearly and readily understood, below by technical solution in the embodiment of the present invention
It is clearly and completely described.
A kind of preparation method of the pectase liquid applied to snow melt liquid, includes the following steps:
(1) it pretreatment of raw material: is drained after taking a certain amount of fruits and vegetables rim charge, processing clean;
(2) it is beaten: fruits and vegetables rim charge is beaten, the water for accounting for fruits and vegetables rim charge weight 20~40% is added, fermentor is then added
In;
(3) it digests: calcium acetate, pectase and cellulase being added in the fermenter, after digesting 15-20h, be warming up to 80
DEG C, 20min is kept the temperature, then be cooled to 36-38 DEG C;
(4) it ferments: saccharomyces cerevisiae being added in the fermenter and stirs evenly, continuing fermentation, is measured by sampling since the 6th day
The alcoholic strength of fermentation liquid, continuous 2 days alcoholic strengths are constant, stop fermenting, and filtering obtains one time fermentation liquid;
(5) secondary fermentation: being added triethanolamine and acetic acid bacteria in one time fermentation liquid, and sufficiently logical oxygen after 40-45 days, obtains
Pectase liquid.
Preferably, the vegetables rim charge that the preferred tartaric acid content of the fruits and vegetables rim charge is high, sugariness is high, content of cellulose is high
With fruit rim charge.
Preferably, the optimum weight of water used is the 30% of the fruits and vegetables rim charge weight during (2).
The invention has the benefit that fruits and vegetables rim charge is used to be produced for raw material, cost is not only reduced, and save
The process of processing rim charge, beneficial to environmental protection;The auxiliary material safety and environmental protection used, it is conventional to forbid or control chemicals;Producer
Method is simple, it is easy to accomplish automation control;Performance stabilization, good fluidity are easy to save and transport.The present invention is used for snow melt liquid
Among, to metal material such as reinforcing bar non-corroding, to cement without destroy, it is pollution-free to soil and water body, do not damage road, bridge is set
It applies and concrete component, does not destroy vegetation, not polluted source, it is harmless, it is green environment-friendlysnow-melting snow-melting liquid.
A kind of embodiment of the invention is to be added in snow melt liquid, a kind of environment-friendly type pectase snow melt liquid, by following substance
Composition: 40~60 parts of acetate, 10~20 parts of formates, 2~5 parts of carbonate, 1~5 part of polyalcohol, viscosity-controlling agent 1~5
Part, 30~40 parts of starch saturated solution, 20~40 parts of pectase liquid.
Wherein, the acetate is fruit vinegar, sodium acetate, potassium acetate, calcium acetate, one or more kinds of in calcium magnesium acetate
Any combination;
The formates is sodium formate, potassium formate, any combination one or more kinds of in calcium formate;
The carbonate is sodium carbonate, any combination one or two kinds of in potassium carbonate.
The polyalcohol is ethylene glycol, propylene glycol, any combination one or more kinds of in glycerol, preferably the third two
Alcohol.
The viscosity-controlling agent is cane molasses, beet molasses, wheat molasses, range of number-average molecular weight are 100,000~bis-
100000 and ion degree be the cationic-type polyacrylamide of range 15~30%, range of number-average molecular weight 80,000~160,000 it is poly-
Vinyl alcohol, range of number-average molecular weight 100,000~150,000 sodium cellulose glycolate in one or more kinds of any combination,
It is preferred that cane molasses.
A kind of preparation method of environment-friendly type pectase snow melt liquid, includes the following steps:
(1) it pretreatment of raw material: is drained after taking a certain amount of fruits and vegetables rim charge, processing clean;
(2) it is beaten: fruits and vegetables rim charge is beaten, the water for accounting for fruits and vegetables rim charge weight 20~40% is added, fermentor is then added
In;
(3) it digests: calcium acetate, pectase and cellulase being added in the fermenter, after digesting 15-20h, be warming up to 80
DEG C, 20min is kept the temperature, then be cooled to 36-38 DEG C;
(4) it ferments: saccharomyces cerevisiae being added in the fermenter and stirs evenly, continuing fermentation, is measured by sampling since the 6th day
The alcoholic strength of fermentation liquid, continuous 2 days alcoholic strengths are constant, stop fermenting, and filtering obtains one time fermentation liquid;
(5) secondary fermentation: being added triethanolamine and acetic acid bacteria in one time fermentation liquid, and sufficiently logical oxygen after 40-45 days, obtains
Pectase liquid.
(6) snow melt liquid configures: acetate, formates, carbonate, polyalcohol, viscosity-controlling agent, starch saturated solution are carried out
Proportion mixing, then plus water enters pectase liquid and stirs to dissolve, and is uniformly mixed to get environment-friendly type pectase snow melt liquid.
Wherein, the vegetables rim charge and fruit that the preferred tartaric acid content of the fruits and vegetables rim charge is high, sugariness is high, content of cellulose is high
Rim charge.
Preferably, the optimum weight of water used is the fruits and vegetables rim charge weight during (2) are beaten
30%;During the configuration of (6) snow melt liquid, temperature when stirring is 60~80 DEG C.
Preferably, the dynamic viscosity of the environment-friendly type pectase snow melt liquid finished product is 600~900mPa.s (0
℃)。
The present embodiment, which adheres to, " to be prevented and treated rubbish with rubbish, is solved with garbage disposal rubbish with rubbish with waste control rubbish
The environmental protection concept of rubbish " is started with from fruits and vegetables waste resource, develops a kind of environment-friendly type pectase snow melt formula of liquid and its preparation side
Method avoids the defect of inorganic salts solid deicing salt, realizes fruits and vegetables waste resource cycling and reutilization, thoroughly solves rubbish from source
Pollution.
Environment-friendly type pectase snow melt liquid provided in this embodiment is that natural biologic material is as main component, environment is friendly
Good type ice-melt snow removing liquid, reaches the advanced level of domestic and international similar research.Without chlorine etc. to plant, soil in the product of the present embodiment
Earth and the poisonous and hazardous substance of environment avoid long-time service inorganic salts deicing salt and cause the potential danger such as soil hardening, salinization of soil
Evil, while using the fertility that can increase soil after this product, supplemented with microelement beneficial to biological growth in soil, snow melt
Remaining ingredient can promote plant production, realizes secondary use, it is two-in-one to realize " snow melt fertilising ".
For the product of the present embodiment compared with sodium chloride deicing salt, freezing point is lower;With sodium chloride and potassium acetate class snow melt
Agent is compared, and appropriate working temperature is low;Compared with the common solid fraction deicing salt such as existing sodium chloride, calcium acetate magnesium salt, potassium acetate, continue
The snow melt time is long;Compared with existing common solid fraction deicing salt, good fluidity is easy to spray construction, has spreading mode entirely mechanical
Change, dispense the characteristics of uniform, spreading number is reduced.
Not only Snow-melting speed is fast for the product of the present embodiment, adds that dosage is small, also has certain stable soil, control dust
Effect.In addition, being specifically added the ingredients such as special-purpose protecting agent in this product, solves traditional product to road and bridge reinforcing bar
Etching problem reduces influence and destruction of the deicing salt to road and environment, road pavement and communal facility fanout free region to greatest extent.
It convenient for storage transport, is widely used, adapts to wide, the particular locations place such as urban road, highway, airport, military key area
It can be used.Moreover, the shortcomings that being effectively utilized fruits and vegetables waste resource, overcoming organic deicing salt selling at exorbitant prices, for from source
Head thoroughly solves refuse pollution, is of great significance.
The above description is only a preferred embodiment of the patent of the present invention, is not intended to limit the invention patent, all at this
Made any modifications, equivalent replacements, and improvements etc., should be included in the invention patent within the spirit and principle of patent of invention
Protection scope within.
Claims (3)
1. a kind of preparation method of the pectase liquid applied to snow melt liquid, which comprises the steps of:
(1) it pretreatment of raw material: is drained after taking a certain amount of fruits and vegetables rim charge, processing clean;
(2) it is beaten: fruits and vegetables rim charge is beaten, the water for accounting for fruits and vegetables rim charge weight 20~40% is added, be then added in fermentor;
(3) it digests: calcium acetate, pectase and cellulase being added in the fermenter, after digesting 15-20h, be warming up to 80 DEG C, protect
Warm 20min, then it is cooled to 36-38 DEG C;
(4) it ferments: saccharomyces cerevisiae being added in the fermenter and stirs evenly, continuing fermentation, fermentation is measured by sampling since the 6th day
The alcoholic strength of liquid, continuous 2 days alcoholic strengths are constant, stop fermenting, and filtering obtains one time fermentation liquid;
(5) secondary fermentation: being added triethanolamine and acetic acid bacteria in one time fermentation liquid, and sufficiently logical oxygen after 40-45 days, obtains fruits and vegetables
Enzyme liquid.
2. a kind of preparation method of pectase liquid applied to snow melt liquid according to claim 1, it is characterised in that: institute
The vegetables rim charge and fruit rim charge that the preferred tartaric acid content of the fruits and vegetables rim charge stated is high, sugariness is high, content of cellulose is high.
3. a kind of preparation method of pectase liquid applied to snow melt liquid according to claim 1, it is characterised in that:
(2) during being beaten, the optimum weight of water used is the 30% of the fruits and vegetables rim charge weight.
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CN201810919004.8A CN109207125A (en) | 2018-08-14 | 2018-08-14 | A kind of preparation method of the pectase liquid applied to snow melt liquid |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109868114A (en) * | 2019-03-11 | 2019-06-11 | 曹先成 | The production method of fully natural green plant complex-type multipurpose snow melt powder |
CN110845991A (en) * | 2019-12-02 | 2020-02-28 | 北京市首发天人生态景观有限公司 | Novel ecological environment-friendly snow-melting material, preparation method and prepared ecological environment-friendly snow-melting agent |
ES2919234A1 (en) * | 2021-01-21 | 2022-07-22 | Cosmetica Cosbar S L | Vegetable hydrolyzed for use in cosmetics (Machine-translation by Google Translate, not legally binding) |
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CN106343547A (en) * | 2016-08-22 | 2017-01-25 | 宁波希诺亚海洋生物科技有限公司 | Preparation method for plant/fruit/vegetable enzymes |
CN107619323A (en) * | 2017-10-27 | 2018-01-23 | 马龙龙腾科技开发有限公司 | A kind of method that organic fertilizer is produced using fruit/vegetable waste and breeding waste as raw material |
CN107828376A (en) * | 2017-11-21 | 2018-03-23 | 李义民 | Environment-friendly type ferment liquid Snow Agent and preparation method thereof |
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2018
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106343547A (en) * | 2016-08-22 | 2017-01-25 | 宁波希诺亚海洋生物科技有限公司 | Preparation method for plant/fruit/vegetable enzymes |
CN107619323A (en) * | 2017-10-27 | 2018-01-23 | 马龙龙腾科技开发有限公司 | A kind of method that organic fertilizer is produced using fruit/vegetable waste and breeding waste as raw material |
CN107828376A (en) * | 2017-11-21 | 2018-03-23 | 李义民 | Environment-friendly type ferment liquid Snow Agent and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109868114A (en) * | 2019-03-11 | 2019-06-11 | 曹先成 | The production method of fully natural green plant complex-type multipurpose snow melt powder |
CN110845991A (en) * | 2019-12-02 | 2020-02-28 | 北京市首发天人生态景观有限公司 | Novel ecological environment-friendly snow-melting material, preparation method and prepared ecological environment-friendly snow-melting agent |
CN110845991B (en) * | 2019-12-02 | 2020-09-25 | 北京市首发天人生态景观有限公司 | Ecological environment-friendly snow-melting material, preparation method and prepared ecological environment-friendly snow-melting agent |
ES2919234A1 (en) * | 2021-01-21 | 2022-07-22 | Cosmetica Cosbar S L | Vegetable hydrolyzed for use in cosmetics (Machine-translation by Google Translate, not legally binding) |
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Application publication date: 20190115 |