CN109181382A - A kind of formula of anticorrosion type zinc rich primer - Google Patents
A kind of formula of anticorrosion type zinc rich primer Download PDFInfo
- Publication number
- CN109181382A CN109181382A CN201811017682.1A CN201811017682A CN109181382A CN 109181382 A CN109181382 A CN 109181382A CN 201811017682 A CN201811017682 A CN 201811017682A CN 109181382 A CN109181382 A CN 109181382A
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- China
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- parts
- agent
- type zinc
- rich primer
- zinc rich
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
Abstract
The invention discloses a kind of formulas of anticorrosion type zinc rich primer, the priming paint includes the composition of following parts by weight: component A: 60~80 parts of acrylate, 5~15 parts of water-compatible amino resin, 2~6 parts of silicone coupling agents, 20~30 parts of ethylene glycol, 0.5~1 part of levelling agent, 0.3~0.8 part of defoaming agent, 0.5~1.5 part of dispersing agent, 2~6 parts of coalescing agent, 1~3 part of inorganic antiseptic；B component: 20~30 parts of nano zine oxide, 3~8 parts of ferrophosphorus powder, 1~3 part of anti-settling agent, 8~12 parts of rust resisting pigment；Wherein, the anti-settling agent is the organobentonite of 1~2:1 of weight ratio and the mixture of silica solution.Anticorrosion type zinc rich primer in the present invention not only has good adhesive force, but also has the advantages that corrosion resistant, suitable industrialization.
Description
Technical field
The present invention relates to paint technology fields, more particularly to a kind of formula of anticorrosion type zinc rich primer.
Background technique
Metal erosion refers to the phenomenon that metal is destroyed by chemistry or the electrochemical action of surrounding medium.Corrosion causes huge
Huge economic loss, according to incompletely statistics, the 1/3 of the every annual steel yield in the whole world are lost because of corrosion；China it is annual because
Direct economic loss caused by metal erosion accounts for about the 4% of gross national product, it can be seen that, the protection of corrosion is particularly significant.
It was verified that using coating to metal carry out anti-corrosion be it is most effective, most economical, using most common method.Coating
To the obstacle that diffuses to form of corrosive medium, the adhesion strength of the matrixes such as coating and steel and to the barrier property of medium to the service life of coating
It plays a crucial role.The corrosion rate of coating depends on: water seeped coating and in coating/substrate interface product by spreading
Poly- and medium ionic seeps overprotection layer by diffusion and conduction and corrosion reaction finally occurs.Coating mainly passes through barrier
It shields with chemical mechanism to substrate.
For this reason, it is necessary to be able to solve existing in view of the above-mentioned problems, propose a kind of formula of anticorrosion type zinc rich primer
The problem of technology.
Summary of the invention
The purpose of the present invention is to provide a kind of formula of anticorrosion type zinc rich primer, with overcome it is in the prior art not
Foot.
To achieve the above object, the invention provides the following technical scheme:
A kind of formula of anticorrosion type zinc rich primer, the priming paint include the composition of following parts by weight: component A: acrylic acid
60~80 parts of ester, 5~15 parts of water-compatible amino resin, 2~6 parts of silicone coupling agents, 20~30 parts of ethylene glycol, levelling agent 0.5~1
Part, 0.3~0.8 part of defoaming agent, 0.5~1.5 part of dispersing agent, 2~6 parts of coalescing agent, 1~3 part of inorganic antiseptic；B component: it receives
20~30 parts of zinc oxide, 3~8 parts of ferrophosphorus powder, 1~3 part of anti-settling agent, 8~12 parts of rust resisting pigment of rice；Wherein, the anti-settling agent is
The organobentonite of 1~2:1 of weight ratio and the mixture of silica solution.
Preferably, the priming paint includes the composition of following parts by weight: component A: 65~75 parts of acrylate, aqueous amino tree
7.5~12.5 parts of rouge, 3~5 parts of silicone coupling agents, 23~28 parts of ethylene glycol, 0.6~0.8 part of levelling agent, defoaming agent 0.4~
0.65 part, 0.75~1.25 part of dispersing agent, 3~5 parts of coalescing agent, 1.5~2.5 parts of inorganic antiseptic；B component: nano oxidized
22.5~27.5 parts of zinc, 4.5~6 parts of ferrophosphorus powder, 1.5~2.5 parts of anti-settling agent, 9~11 parts of rust resisting pigment.
Preferably, the priming paint includes the composition of following parts by weight: component A: 70 parts of acrylate, water-compatible amino resin 10
Part, 4 parts of silicone coupling agents, 25 parts of ethylene glycol, 0.7 part of levelling agent, 0.5 part of defoaming agent, 1 part of dispersing agent, 4 parts of coalescing agent,
2 parts of inorganic antiseptic；B component: 25 parts of nano zine oxide, 5.2 parts of ferrophosphorus powder, 2 parts of anti-settling agent, 10 parts of rust resisting pigment.
Preferably, it is different pungent to be selected from ethyl acrylate, butyl acrylate, n-octyl, acrylic acid for the acrylate
One of ester is a variety of.
Preferably, the acrylate is selected from ethyl acrylate.
Preferably, the partial size of the nano zine oxide is 100~200nm.
Preferably, the inorganic antiseptic is the mixture of magnesium phosphate and silver orthophosphate.
Preferably, the defoaming agent is organic silicon defoaming agent.
Compared with the prior art, the advantages of the present invention are as follows: the anticorrosion type zinc rich primer in the present invention not only has good
Good adhesive force, but also have the advantages that corrosion resistant, suitable industrialization.
Specific embodiment
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood.
However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used
In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of formula of anticorrosion type zinc rich primer, and the priming paint includes the composition of following parts by weight: A group
Point: 60~80 parts of acrylate, 5~15 parts of water-compatible amino resin, 2~6 parts of silicone coupling agents, 20~30 parts of ethylene glycol, stream
0.5~1 part of flat agent, 0.3~0.8 part of defoaming agent, 0.5~1.5 part of dispersing agent, 2~6 parts of coalescing agent, inorganic antiseptic 1~3
Part；B component: 20~30 parts of nano zine oxide, 3~8 parts of ferrophosphorus powder, 1~3 part of anti-settling agent, 8~12 parts of rust resisting pigment；Wherein, institute
State the mixture of organobentonite and silica solution that anti-settling agent is 1~2:1 of weight ratio.
Wherein, the acrylate is selected from ethyl acrylate, butyl acrylate, n-octyl, Isooctyl acrylate monomer
One of or it is a variety of, it is preferred that the acrylate be selected from ethyl acrylate；The partial size of the nano zine oxide be 100~
200nm, it is preferred that the partial size of the nano zine oxide is 150nm；The inorganic antiseptic is the mixing of magnesium phosphate and silver orthophosphate
The weight ratio of object, the magnesium phosphate and the silver orthophosphate is 2:1；The defoaming agent is organic silicon defoaming agent.
Following formulas that the anticorrosion type zinc rich primer in the present invention is illustrated with specifically embodiment.
Embodiment 1
The priming paint includes the composition of following parts by weight: component A: 60 parts of acrylate, 5 parts of water-compatible amino resin, and silicon oxygen
It is 2 parts of alkane coupling agent, 20 parts of ethylene glycol, 0.5 part of levelling agent, 0.3 part of defoaming agent, 0.5 part of dispersing agent, 2 parts of coalescing agent, inorganic anti-
1 part of microbial inoculum；B component: 20 parts of nano zine oxide, 3 parts of ferrophosphorus powder, 1 part of anti-settling agent, 8 parts of rust resisting pigment.
Embodiment 2
The priming paint includes the composition of following parts by weight: component A: 65 parts of acrylate, 7.5 parts of water-compatible amino resin, and silicon
3 parts of oxygen alkane coupling agent, 23 parts of ethylene glycol, 0.6 part of levelling agent, 0.4 part of defoaming agent, 0.75 part of dispersing agent, 3 parts of coalescing agent, nothing
1.5 parts of machine antibacterial agent；B component: 22.5 parts of nano zine oxide, 4.5 parts of ferrophosphorus powder, 1.5 parts of anti-settling agent, 9 parts of rust resisting pigment.
Embodiment 3
The priming paint includes the composition of following parts by weight: component A: 70 parts of acrylate, 10 parts of water-compatible amino resin, and silicon oxygen
4 parts of alkane coupling agent, 25 parts of ethylene glycol, 0.7 part of levelling agent, 0.5 part of defoaming agent, 1 part of dispersing agent, 4 parts of coalescing agent, inorganic antibacterial
2 parts of agent；B component: 25 parts of nano zine oxide, 5.2 parts of ferrophosphorus powder, 2 parts of anti-settling agent, 10 parts of rust resisting pigment.
Embodiment 4
The priming paint includes the composition of following parts by weight: component A: 75 parts of acrylate, 12.5 parts of water-compatible amino resin, and silicon
5 parts of oxygen alkane coupling agent, 28 parts of ethylene glycol, 0.8 part of levelling agent, 0.65 part of defoaming agent, 1.25 parts of dispersing agent, 5 parts of coalescing agent, nothing
2.5 parts of machine antibacterial agent；B component: 27.5 parts of nano zine oxide, 6 parts of ferrophosphorus powder, 2.5 parts of anti-settling agent, 11 parts of rust resisting pigment.
Embodiment 5
The priming paint includes the composition of following parts by weight: component A: 80 parts of acrylate, 15 parts of water-compatible amino resin, and silicon oxygen
6 parts of alkane coupling agent, 30 parts of ethylene glycol, 1 part of levelling agent, 0.8 part of defoaming agent, 1.5 parts of dispersing agent, 6 parts of coalescing agent, inorganic antibacterial
3 parts of agent；B component: 30 parts of nano zine oxide, 8 parts of ferrophosphorus powder, 3 parts of anti-settling agent, 12 parts of rust resisting pigment.
Anticorrosion type zinc rich primer in above-described embodiment 1~5 not only has good adhesive force, but also has corrosion resistant
The advantages of erosion.By the zinc rich primer in above-described embodiment 1~5 is placed in 25 DEG C, to carry out salt fog resistance in 5% sodium chloride solution real
It tests, the results showed that, which has preferable salt fog resistance.In addition, making the zinc rich primer by addition inorganic antiseptic
With preferable anti-microbial property.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive
Property include so that include a series of elements process, method, article or equipment not only include those elements, but also
Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic
Element.
Claims (8)
1. a kind of formula of anticorrosion type zinc rich primer, which is characterized in that the priming paint includes the composition of following parts by weight: A group
Point: 60~80 parts of acrylate, 5~15 parts of water-compatible amino resin, 2~6 parts of silicone coupling agents, 20~30 parts of ethylene glycol, stream
0.5~1 part of flat agent, 0.3~0.8 part of defoaming agent, 0.5~1.5 part of dispersing agent, 2~6 parts of coalescing agent, inorganic antiseptic 1~3
Part；B component: 20~30 parts of nano zine oxide, 3~8 parts of ferrophosphorus powder, 1~3 part of anti-settling agent, 8~12 parts of rust resisting pigment；Wherein, institute
State the mixture of organobentonite and silica solution that anti-settling agent is 1~2:1 of weight ratio.
2. the formula of anticorrosion type zinc rich primer according to claim 1, which is characterized in that the priming paint includes following weight
The composition of amount part: component A: 65~75 parts of acrylate, 7.5~12.5 parts of water-compatible amino resin, 3~5 parts of silicone coupling agents,
23~28 parts of ethylene glycol, 0.6~0.8 part of levelling agent, 0.4~0.65 part of defoaming agent, 0.75~1.25 part of dispersing agent, coalescing agent
3~5 parts, 1.5~2.5 parts of inorganic antiseptic；B component: 22.5~27.5 parts of nano zine oxide, 4.5~6 parts of ferrophosphorus powder, anti-settling
1.5~2.5 parts of agent, 9~11 parts of rust resisting pigment.
3. the formula of anticorrosion type zinc rich primer according to claim 2, which is characterized in that the priming paint includes following weight
It measures the composition of part: component A: 70 parts of acrylate, 10 parts of water-compatible amino resin, 4 parts of silicone coupling agents, 25 parts of ethylene glycol, flowing
0.7 part of flat agent, 0.5 part of defoaming agent, 1 part of dispersing agent, 4 parts of coalescing agent, 2 parts of inorganic antiseptic；B component: nano zine oxide 25
Part, 5.2 parts of ferrophosphorus powder, 2 parts of anti-settling agent, 10 parts of rust resisting pigment.
4. the formula of anticorrosion type zinc rich primer according to claim 1, which is characterized in that the acrylate is selected from third
One of olefin(e) acid ethyl ester, butyl acrylate, n-octyl, Isooctyl acrylate monomer are a variety of.
5. the formula of anticorrosion type zinc rich primer according to claim 4, which is characterized in that the acrylate is selected from third
Olefin(e) acid ethyl ester.
6. the formula of anticorrosion type zinc rich primer according to claim 1, which is characterized in that the grain of the nano zine oxide
Diameter is 100~200nm.
7. the formula of anticorrosion type zinc rich primer according to claim 1, which is characterized in that the inorganic antiseptic is phosphorus
The mixture of sour magnesium and silver orthophosphate.
8. the formula of anticorrosion type zinc rich primer according to claim 1, which is characterized in that the defoaming agent is organosilicon
Class defoaming agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017682.1A CN109181382A (en) | 2018-09-02 | 2018-09-02 | A kind of formula of anticorrosion type zinc rich primer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017682.1A CN109181382A (en) | 2018-09-02 | 2018-09-02 | A kind of formula of anticorrosion type zinc rich primer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109181382A true CN109181382A (en) | 2019-01-11 |
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ID=64917890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811017682.1A Withdrawn CN109181382A (en) | 2018-09-02 | 2018-09-02 | A kind of formula of anticorrosion type zinc rich primer |
Country Status (1)
| Country | Link |
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| CN (1) | CN109181382A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6468336B1 (en) * | 1999-05-26 | 2002-10-22 | J.C. Hempel's Skibsfarve-Fabrik A/S | Water-borne zinc silicate shop primers |
| JP2005179472A (en) * | 2003-12-18 | 2005-07-07 | Dainippon Toryo Co Ltd | Highly corrosionproof zinc powder-containing coating composition |
| CN102337048A (en) * | 2010-07-28 | 2012-02-01 | 中国科学院金属研究所 | Nano modified inorganic zinc-rich paint and preparation method thereof |
| CN106010120A (en) * | 2016-06-30 | 2016-10-12 | 太仓市金新涂料有限公司 | Environment-friendly corrosion resistant and high-temperature resistant epoxy zinc rich primer and preparation method thereof |
| CN107189618A (en) * | 2017-05-27 | 2017-09-22 | 太仓卡斯特姆新材料有限公司 | A kind of waterborne inorganic einc-rich primer and preparation method thereof |
-
2018
- 2018-09-02 CN CN201811017682.1A patent/CN109181382A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6468336B1 (en) * | 1999-05-26 | 2002-10-22 | J.C. Hempel's Skibsfarve-Fabrik A/S | Water-borne zinc silicate shop primers |
| JP2005179472A (en) * | 2003-12-18 | 2005-07-07 | Dainippon Toryo Co Ltd | Highly corrosionproof zinc powder-containing coating composition |
| CN102337048A (en) * | 2010-07-28 | 2012-02-01 | 中国科学院金属研究所 | Nano modified inorganic zinc-rich paint and preparation method thereof |
| CN106010120A (en) * | 2016-06-30 | 2016-10-12 | 太仓市金新涂料有限公司 | Environment-friendly corrosion resistant and high-temperature resistant epoxy zinc rich primer and preparation method thereof |
| CN107189618A (en) * | 2017-05-27 | 2017-09-22 | 太仓卡斯特姆新材料有限公司 | A kind of waterborne inorganic einc-rich primer and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190111 |
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| WW01 | Invention patent application withdrawn after publication |