CN109161354A - 一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备方法 - Google Patents

一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备方法 Download PDF

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CN109161354A
CN109161354A CN201810944120.5A CN201810944120A CN109161354A CN 109161354 A CN109161354 A CN 109161354A CN 201810944120 A CN201810944120 A CN 201810944120A CN 109161354 A CN109161354 A CN 109161354A
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王振庆
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Shandong Jinding Waterproof Technology Ltd By Share Ltd
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Abstract

本发明提供一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备方法，包括抗老化层、AL反光层、保温隔音层、防水粘结层和隔离层。所述的抗老化层，原料由PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合制备而成。本发明防水卷材具有良好的保温隔热隔音抗紫外线效果。

Description

一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备 方法
技术领域
本发明涉及防水卷材，具体涉及一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备方法，属于自粘防水卷材领域。
背景技术
自粘防水卷材是一种以SBS等合成橡胶、增粘剂及优质道路石油沥青等配制成的自粘橡胶沥青为基料，强韧的高密度聚乙烯膜或铝箔作为上表面材料，可剥离的涂硅隔离膜或涂硅隔离纸为下表面防粘隔离材料制成的防水材料。它是一点，可常温施工、施工速度快、符合环保要求。
CN201510927431.7 种植屋面用自粘防水卷材及其制备方法 ，公开了一种种植屋面用自粘防水卷材，包括胎基、浸涂在胎基上的涂盖层，所述涂盖层由以下重量份数的组分组成：90#沥青1500~3000份，橡胶粉500~800份，芳烃油200~500份，SBS200~400份，C5石油树脂50~250份，方解石粉500~2000份，化学阻根剂20~60份和抗老化剂2~20份。本发明的优点是：能很好地保证建筑物的防水要求，避免对屋顶产生破坏。
CN201610011564.4 一种高粘结性自粘防水卷材 ，公开了一种高粘结性自粘防水卷材，由下列成份制备而成：沥青，环烷油，SBS，聚异丁烯与聚异戊二烯的混合物，松香树脂，APAO，普通胶粉和碳酸钙；其中所述聚异丁烯的分子量小于50000，所述聚异戊二烯小于100000；所述SBS为苯乙烯-丁二烯共聚物，所述APAO为聚丙烯。本发明的高粘性自粘防水卷材通过加入液体聚异丁烯和聚异戊二烯的混合物，使得卷材不仅适用于一般温度的环境，特别提高了卷材在低温例如我国北方地区、特别是温度变化频繁时的粘性。
CN201510740061.6 一种高初粘性自粘防水卷材及其制备方法 ，公开了一种高初粘性自粘防水卷材，包含以下成分，以质量百分比计：石油沥青35%~55%，软化剂5%~25%，改性剂5%~25%，增粘剂2%~8%，界面剂0.1%~2%，防老剂0.1%~3%，填充剂5%~20%；其中，软化剂为环烷油与芳烃类助溶剂的混合物；改性剂为苯乙烯-异戊二烯-苯乙烯嵌段共聚物、热塑性弹性体POE、丁苯橡胶以及丁腈再生胶的混合物；增粘剂为C5石油树脂与液态松香树脂的混合物。本发明的自粘防水卷材具有很好的初粘性，即使在基层表面有少许灰尘，潮湿基层及温度较低的情况下与基层也能够进行良好的粘接，且粘接后不易剥离，能够保证在剥离后在基层上留下完整的改性沥青料，确保较高的防水性能。
现有技术的自粘防水卷材往往在粘结性能、低温柔性、自愈性等方面进行深入的研究和开发，但市面上鲜有保温隔热隔音抗紫外线效果好的自粘防水卷材。
因此，发明人团队经历多年研究开发了一种保温隔热隔音抗紫外线效果好的自粘防水卷材，解决现有技术存在的保温、隔热、隔音、抗紫外线等效果差的问题。
发明内容
本发明提供了一种保温隔热隔音抗紫外线高分子自粘防水卷材及其制备方法。该方法制备的防水卷材能够在保证防水性能和自粘性能的基础上，实现优异的保温、隔热、隔音、抗紫外线的效果；特别适用于钢结构屋面。
为达到该目的，本发明的技术方案是：
一种保温隔热隔音抗紫外线高分子自粘防水卷材，包括抗老化层、AL反光层、保温隔音层、防水粘结层和隔离层。
所述的抗老化层，原料由PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合制备而成；
所述的AL反光层，为铝箔层；厚度为0.015-0.017mm，不透明度为65%；
所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂50-60份、交联剂8.5-8.8份、发泡剂6-7份、EPE 25-29份、十二烷基硫酸钠19-21份、纳米硅酸铝粉4-5份、石蜡油7-9份、硬脂酸钙3-4份、石墨烯2-3份、远红外陶瓷粉8.4-8.9份、聚苯乙烯4-5份、膨胀珍珠岩7-8份。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅；
所述的防水粘结层：以重量份计，包括以下原料组分：SBS橡胶40-45份、SIS橡胶20-25份 、丁腈橡胶18-20份、伊利石粉6-9份、高岭土4-7份、顺式-1，4-聚丁二烯橡胶9-13份、环氧亚麻子油6-10份、丙烯酸酯10-15份、炭黑6-10份。
所述隔离层为硅油纸。
所述防水卷材的制备方法：
步骤1、按配方比例称取各原料组分。
步骤2、制备防水粘结层
（1） 加入橡胶
向反应釜中加入SBS橡胶、SIS橡胶，加热至140℃，加入丁腈橡胶、顺式-1，4-聚丁二烯橡胶，开启搅拌，转速保持在250r/min，搅拌10min；
（2）加入填料
在120℃下，加入伊利石粉、炭黑，搅拌20min，转速保持在160r/min ；加入高岭土，之后缓慢升温至220℃；
（3）加入余料
在200℃下，分3次加入环氧亚麻子油；在160℃下，加入丙烯酸酯，计时搅拌1.5小时，转速保持在250r/min；
（4）研磨
开启胶体磨，研磨，循环研磨3次，研磨时间为1h/次；
（5）制得防水粘结层胶料
将研磨后的物料由冷却***降温到100℃；得到防水粘结层胶料。
步骤3、制备保温隔音层
（1）加入树脂
将低密度聚乙烯树脂、EPE混合，加入反应釜中，开启搅拌，1500rpm搅拌30min。
（2）加入助剂
将十二烷基硫酸钠、纳米硅酸铝粉、石蜡油依次加入反应釜中，升温至80-85℃，1000rpm搅拌45min。
（3）加入填料
将硬脂酸钙、远红外陶瓷粉、膨胀珍珠岩依次加入反应釜中，升温至110-115℃，1000rpm搅拌30min。
（4）加入余料并反应
将石墨烯、聚苯乙烯依次加入反应釜中，升温至250-280℃，加入交联剂、发泡剂，在600rpm搅拌速率下，反应1.5h；反应后，导入成型机，成型并冷却，制得厚度为1-1.2mm的保温隔音层。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅。
步骤4、制备抗老化层
将PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合，并在480-520℃条件下，搅拌反应2.5h；反应完成后，采用吹膜机制成厚度为0.2-0.3mm的抗老化层。
步骤5、制得成品
将步骤2制备的防水粘结层胶料涂覆在保温隔音层的上下两侧，厚度分别为1.5mm；涂覆后，在上侧防水粘结层复合AL反光层；AL反光层上侧复合抗老化层；抗老化层厚度为0.2-0.3mm。在下侧防水粘结层复合隔离层。压覆定型后，得到成品防水卷材。
与现有技术相比，本发明技术方案具有以下有益效果：
（1）本发明防水卷材用于钢结构屋面的户外防水，粘结效果好，防水性能高；粘结时间为4-5.5 s，剥离强度为2.5-3.8 N/mm；0.6Mpa 4-5h不透水。
（2）本发明防水卷材用于钢结构屋面的户外防水，防紫外线效果显著，125 nm紫外线直射220小时后，拉力保持率99.2-99.6%，延伸率保持率99.1-99.4%，0.3MPa 4h不透水。
（3）本发明防水卷材耐高温100℃，耐低温-40℃。
（4）本发明防水卷材用于钢结构屋面的户外防水，隔音、保温效果显著；若不使用本发明卷材，钢结构屋内温度与室外温度相差在1-2℃，使用本发明卷材后，钢结构屋内外温度差达6-8℃；并且，本发明隔音效果明显，与未使用本发明卷材相比，室外检测声音降低10分贝以上。
具体实施方式
实施例1
一种保温隔热隔音抗紫外线高分子自粘防水卷材，包括抗老化层、AL反光层、保温隔音层、防水粘结层和隔离层。
所述的抗老化层，原料由PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合制备而成；
所述的AL反光层，为铝箔层；厚度为0.015-0.017mm，不透明度为65%；
所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂50份、交联剂8.5份、发泡剂6.5份、EPE 27份、十二烷基硫酸钠19份、纳米硅酸铝粉4份、石蜡油8份、硬脂酸钙3.6份、石墨烯3份、远红外陶瓷粉8.9份、聚苯乙烯4份、膨胀珍珠岩7份。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅；
所述的防水粘结层：以重量份计，包括以下原料组分：SBS橡胶40份、SIS橡胶22份 、丁腈橡胶20份、伊利石粉6份、高岭土4份、顺式-1，4-聚丁二烯橡胶10份、环氧亚麻子油6份、丙烯酸酯15份、炭黑6份。
所述隔离层为硅油纸。
实施例2
与实施例1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材配方相同，只改变以下：
所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂56份、交联剂8.7份、发泡剂6份、EPE 29份、十二烷基硫酸钠20份、纳米硅酸铝粉4.5份、石蜡油7份、硬脂酸钙4份、石墨烯2份、远红外陶瓷粉8.6份、聚苯乙烯5份、膨胀珍珠岩7.6份。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅；
所述的防水粘结层：以重量份计，包括以下原料组分：SBS橡胶43份、SIS橡胶20份 、丁腈橡胶18份、伊利石粉8份、高岭土6份、顺式-1，4-聚丁二烯橡胶9份、环氧亚麻子油10份、丙烯酸酯14份、炭黑8份。
实施例3
与实施例1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材配方相同，只改变以下：
所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂60份、交联剂8.8份、发泡剂7份、EPE 29份、十二烷基硫酸钠21份、纳米硅酸铝粉5份、石蜡油7份、硬脂酸钙3份、石墨烯2.5份、远红外陶瓷粉8.4份、聚苯乙烯5份、膨胀珍珠岩8份。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅；
所述的防水粘结层：以重量份计，包括以下原料组分：SBS橡胶44份、SIS橡胶25份 、丁腈橡胶20份、伊利石粉8份、高岭土7份、顺式-1，4-聚丁二烯橡胶13份、环氧亚麻子油10份、丙烯酸酯13份、炭黑10份。
实施例4
一种保温隔热隔音抗紫外线高分子自粘防水卷材，所述防水卷材的制备方法：
步骤1、按配方比例称取各原料组分。
步骤2、制备防水粘结层
（2） 加入橡胶
向反应釜中加入SBS橡胶、SIS橡胶，加热至140℃，加入丁腈橡胶、顺式-1，4-聚丁二烯橡胶，开启搅拌，转速保持在250r/min，搅拌10min；
（2）加入填料
在120℃下，加入伊利石粉、炭黑，搅拌20min，转速保持在160r/min ；加入高岭土，之后缓慢升温至220℃；
（3）加入余料
在200℃下，分3次加入环氧亚麻子油；在160℃下，加入丙烯酸酯，计时搅拌1.5小时，转速保持在250r/min；
（4）研磨
开启胶体磨，研磨，循环研磨3次，研磨时间为1h/次；
（5）制得防水粘结层胶料
将研磨后的物料由冷却***降温到100℃；得到防水粘结层胶料。
步骤3、制备保温隔音层
（1）加入树脂
将低密度聚乙烯树脂、EPE混合，加入反应釜中，开启搅拌，1500rpm搅拌30min。
（2）加入助剂
将十二烷基硫酸钠、纳米硅酸铝粉、石蜡油依次加入反应釜中，升温至80-85℃，1000rpm搅拌45min。
（3）加入填料
将硬脂酸钙、远红外陶瓷粉、膨胀珍珠岩依次加入反应釜中，升温至112-114℃，1000rpm搅拌30min。
（4）加入余料并反应
将石墨烯、聚苯乙烯依次加入反应釜中，升温至260-270℃，加入交联剂、发泡剂，在600rpm搅拌速率下，反应1.5h；反应后，导入成型机，成型并冷却，制得厚度为1-1.2mm的保温隔音层。
所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅。
步骤4、制备抗老化层
将PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合，并在490-500℃条件下，搅拌反应2.5h；反应完成后，采用吹膜机制成厚度为0.25mm的抗老化层。
步骤5、制得成品
将步骤2制备的防水粘结层胶料涂覆在保温隔音层的上下两侧，厚度分别为1.5mm；涂覆后，在上侧防水粘结层复合AL反光层；AL反光层上侧复合抗老化层；抗老化层厚度为0.25mm。在下侧防水粘结层复合隔离层。压覆定型后，得到成品防水卷材。
实施例1-4中所述的原料组分：
所述保温隔音层中，所述的低密度聚乙烯树脂：粒径为1.4-1.5mm；所述的纳米硅酸铝粉：PH值范围为9.7-10.8，细度为1250目；所述的硬脂酸钙：孔径0.075mm筛通过率99.5%，游离酸含量（以硬脂酸计）≤0.5%，钙含量6.5±0.6%；所述的远红外陶瓷粉：细度为800目。
所述的防水粘结层中，所述的伊利石粉：细度为1000目，含K2O 7%-8%，含Na2O 1%-1.5%；所述的炭黑：为日本三菱碳黑，型号为MA11。
实验检测：
实施例1-3的防水卷材采用实施例4的方法制备完成，得到的卷材实验检测，达到的指标如表1所示：
表1
所述粘结时间、剥离强度是用于钢结构屋面的的粘结时间和剥离强度。
除特殊说明的外，本发明所述的百分数均为质量百分数，所述的比值均为质量比。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (10)

1.一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：包括抗老化层、AL反光层、保温隔音层、防水粘结层和隔离层。
2.根据权利要求1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述的抗老化层，原料由PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合制备而成。
3.根据权利要求1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂50-60份、交联剂8.5-8.8份、发泡剂6-7份、EPE 25-29份、十二烷基硫酸钠19-21份、纳米硅酸铝粉4-5份、石蜡油7-9份、硬脂酸钙3-4份、石墨烯2-3份、远红外陶瓷粉8.4-8.9份、聚苯乙烯4-5份、膨胀珍珠岩7-8份。
4.根据权利要求3所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述的保温隔音层：以重量份计，包括以下原料组分：低密度聚乙烯树脂56份、交联剂8.7份、发泡剂6份、EPE 29份、十二烷基硫酸钠20份、纳米硅酸铝粉4.5份、石蜡油7份、硬脂酸钙4份、石墨烯2份、远红外陶瓷粉8.6份、聚苯乙烯5份、膨胀珍珠岩7.6份。
5.根据权利要求1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述的AL反光层，为铝箔层；厚度为0.015-0.017mm，不透明度为65%。
6.根据权利要求3所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述交联剂为N,N-亚甲基双丙烯酰胺；
所述发泡剂为碳化硅。
7.根据权利要求1所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材，其特征在于：所述的防水粘结层：以重量份计，包括以下原料组分：SBS橡胶40-45份、SIS橡胶20-25份、丁腈橡胶18-20份、伊利石粉6-9份、高岭土4-7份、顺式-1，4-聚丁二烯橡胶9-13份、环氧亚麻子油6-10份、丙烯酸酯10-15份、炭黑6-10份。
8.一种保温隔热隔音抗紫外线高分子自粘防水卷材的制备方法，其特征在于：包括制备防水粘结层、制备保温隔音层、制备抗老化层以及制得成品；
所述制备保温隔音层：包括加入树脂、加入助剂、加入填料、加入余料并反应；所述的加入余料并反应：将石墨烯、聚苯乙烯依次加入反应釜中，升温至250-280℃，加入交联剂、发泡剂，在600 rpm搅拌速率下，反应1.5h；反应后，导入成型机，成型并冷却，制得厚度为1-1.2mm的保温隔音层。
9.根据权利要求8所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材的制备方法，其特征在于：所述交联剂为N,N-亚甲基双丙烯酰胺；所述发泡剂为碳化硅。
10.根据权利要求8所述的一种保温隔热隔音抗紫外线高分子自粘防水卷材的制备方法，其特征在于：
所述制备防水粘结层：包括加入橡胶、加入填料、加入余料、研磨以及制得防水粘结层胶料；
所述制备抗老化层：将PE、PET、聚硫橡胶、乙酰柠檬酸三乙酯、间苯二甲酸酯按照80：65：11：7：5的质量比混合，并在480-520℃条件下，搅拌反应2.5h；反应完成后，采用吹膜机制成厚度为0.2-0.3mm的抗老化层。
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109914714A (zh) * 2019-03-20 2019-06-21 左麦斯建筑科技(南京)有限公司 一种基于分子离散聚合的改性沥青自沾防水隔汽膜

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090010907U (ko) * 2008-04-22 2009-10-27 김기철 자착식 단열방수시트 및 이를 이용한 방수방법
CN204820553U (zh) * 2015-07-29 2015-12-02 盘锦女娲防水材料有限公司 一种聚乙烯胎防水卷材
CN205386966U (zh) * 2015-12-31 2016-07-20 隋鹏飞 一种自粘砂面夹筋pvc防水卷材
CN205467667U (zh) * 2016-03-04 2016-08-17 广东天骄建材有限公司 一种金属铝箔防水卷材
CN206124372U (zh) * 2016-08-30 2017-04-26 常熟市三恒建材有限责任公司 反应***叉强力膜丁基橡胶自粘防水卷材

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20090010907U (ko) * 2008-04-22 2009-10-27 김기철 자착식 단열방수시트 및 이를 이용한 방수방법
CN204820553U (zh) * 2015-07-29 2015-12-02 盘锦女娲防水材料有限公司 一种聚乙烯胎防水卷材
CN205386966U (zh) * 2015-12-31 2016-07-20 隋鹏飞 一种自粘砂面夹筋pvc防水卷材
CN205467667U (zh) * 2016-03-04 2016-08-17 广东天骄建材有限公司 一种金属铝箔防水卷材
CN206124372U (zh) * 2016-08-30 2017-04-26 常熟市三恒建材有限责任公司 反应***叉强力膜丁基橡胶自粘防水卷材

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
中国腐蚀与防护学会《金属防腐蚀手册》编写组: "《金属防腐蚀手册》", 30 June 1989, 上海科学技术出版社 *
曲远方等: "《现代陶瓷材料及技术》", 31 May 2008, 华东理工大学出版社 *
李子东等: "《胶黏剂助剂》", 30 June 2009, 化学工业出版社 *
马世昌等: "《化学物质辞典》", 30 April 1999, 陕西科学技术出版社 *
魏文德等: "《有机化工原料大全下卷》", 31 August 1999, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109914714A (zh) * 2019-03-20 2019-06-21 左麦斯建筑科技(南京)有限公司 一种基于分子离散聚合的改性沥青自沾防水隔汽膜

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