CN109157973A - A kind of absorption tower slurries PH auto-adjustment control method - Google Patents

A kind of absorption tower slurries PH auto-adjustment control method Download PDF

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Publication number
CN109157973A
CN109157973A CN201811048503.0A CN201811048503A CN109157973A CN 109157973 A CN109157973 A CN 109157973A CN 201811048503 A CN201811048503 A CN 201811048503A CN 109157973 A CN109157973 A CN 109157973A
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CN
China
Prior art keywords
value
absorption tower
slurry
control method
slurries
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811048503.0A
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Chinese (zh)
Inventor
王军锋
张安祥
樊建平
齐少林
王崇博
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WEIHE THERMAL POWER PLANT DATANG SHAANXI POWER GENERATION Co Ltd
Datang Shaanxi Power Generation Co Ltd
Original Assignee
WEIHE THERMAL POWER PLANT DATANG SHAANXI POWER GENERATION Co Ltd
Datang Shaanxi Power Generation Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by WEIHE THERMAL POWER PLANT DATANG SHAANXI POWER GENERATION Co Ltd, Datang Shaanxi Power Generation Co Ltd filed Critical WEIHE THERMAL POWER PLANT DATANG SHAANXI POWER GENERATION Co Ltd
Priority to CN201811048503.0A priority Critical patent/CN109157973A/en
Publication of CN109157973A publication Critical patent/CN109157973A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80Semi-solid phase processes, i.e. by using slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/346Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D21/00Control of chemical or physico-chemical variables, e.g. pH value
    • G05D21/02Control of chemical or physico-chemical variables, e.g. pH value characterised by the use of electric means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Automation & Control Theory (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention provides a kind of absorption tower slurries PH auto-adjustment control method, this method comprises: setting pH value target value;Detect the pH value of absorption tower exit slurries;According to the interlocking of the pH target value deviation of the pH value and setting detected for starching switch on/off electric valve events, to controlling the pH value in the pH target value.The present invention carries out automatically controlling absorption tower plasm PH value in the way of using closed loop intermittent controlled for slurry switch on/off electric valve, within the set range by pH value control, improves absorption tower desulfuration efficiency, and be rinsed automatically to slurry pipeline, prevents slurry pipeline from blocking.

Description

A kind of absorption tower slurries PH auto-adjustment control method
Technical field
The invention belongs to thermal power plant absorption tower slurries regulation technology fields, and in particular to a kind of absorption tower slurries PH is adjusted automatically Save control method.
Background technique
Absorption tower plasm PH value is the important operating parameter of limestone-gypsum wet desulfuration system, and pH value reflects absorption tower CaCO in slurries3, CaSO3.1/2H2O, CaSO4. 2H2O content and solubility influence desulfuration efficiency very big.PH value is general Control range is 4.6-5.8, and absorption tower pH value control system is mainly the stream for passing through and adjusting and flowing into lime stone slurry in absorption tower For amount to guarantee plasm PH value, controlling and flowing into the limestone slurry flow quantity on absorption tower is generally to pass through absorption tower plasm PH value and setting Value be compared after through single loop or cascade loop control lime stone for starching the aperture of pitch.Due to the original of process system itself Cause, this control mode there are biggish deferred, and due to pitch control so that when big when for slurry flow it is small, be easy blocking and supply Starch pipeline.
Summary of the invention
The present invention provides a kind of absorption tower slurries PH auto-adjustment control method, controls plasm PH value, prevents slurry pipeline Blocking.
The technical scheme is that a kind of absorption tower slurries PH auto-adjustment control method, this method comprises: setting PH It is worth target value;Detect the pH value of absorption tower exit slurries;It is interlocked according to the pH target value deviation of the pH value and setting detected For starching switch on/off electric valve events, to controlling the pH value in the pH target value.
Scheme further, it is described for slurry switch on/off electric valve using closed loop intermittent controlled mode to absorption tower plasm PH value into Row automatically controls.
Further, described for slurry switch on/off electric valve control method be that pH value is less than setting value 0.02 in the absorption tower to scheme When, it automatically opens and absorption tower, when pH value is greater than the set value 0.01 in absorption tower, be automatically closed for slurry for slurry motor-driven valve Stop for slurry motor-driven valve for slurry.
Scheme further includes that slurry pipeline rinses, after carrying out pH value adjustment, flushing valve is automatically opened to for slurry further Pipeline is rinsed, and flushing valve is automatically closed after rinsing 60 seconds.
Further, the pH value target value is 5.0-5.8 to scheme.
The invention has the advantages that the present invention starches absorption tower in the way of using closed loop intermittent controlled for slurry switch on/off electric valve Liquid pH value carries out automatically controlling, and within the set range by pH value control, improves absorption tower desulfuration efficiency, and automatically to slurry pipeline It is rinsed, prevents slurry pipeline from blocking.
Detailed description of the invention
Fig. 1 is the present invention for starching motor-driven valve control principle drawing;
Fig. 2 is that the present invention rinses motor-driven valve control principle drawing.
Specific embodiment
Clear and complete description is done to the present invention with reference to the accompanying drawing, so that those skilled in the art is not needing to make Under conditions of creative work, it can sufficiently implement the present invention.
A specific embodiment of the invention is: being the present invention for slurry motor-driven valve control principle drawing and flushing as shown in Figs. 1-2 Motor-driven valve control principle drawing, a kind of absorption tower slurries PH auto-adjustment control method, this method comprises: setting pH value target value; Detect the pH value of absorption tower exit slurries;According to the interlocking of the pH target value deviation of the pH value and setting detected for slurry switch electricity Dynamic valve events, to controlling the pH value in the pH target value.
Further, described that absorption tower plasm PH value is carried out certainly using closed loop intermittent controlled mode for slurry switch on/off electric valve Dynamic control.
Further, it is described for slurry switch on/off electric valve control method be when in absorption tower pH value be less than setting value 0.02 when, It automatically opens and absorption tower is carried out for slurry motor-driven valve, when pH value is greater than the set value 0.01 in absorption tower, confession to be automatically closed for slurry Motor-driven valve is starched to stop for slurry.
It further, further include that slurry pipeline rinses, after carrying out pH value adjustment, flushing valve is automatically opened to slurry pipeline It is rinsed, flushing valve is automatically closed after rinsing 60 seconds.
Further, the pH value target value, can random groups load, desulphurization system inlet flue gas SO between 5.0-5.82 Concentration, exhaust gas volumn etc. artificially change setting value.
Presently preferred embodiments of the present invention is described above, it should be pointed out that the invention is not limited to above-mentioned Particular implementation, devices and structures not described in detail herein should be understood as gives reality with the common mode in this field It applies;Anyone skilled in the art, without departing from the scope of the technical proposal of the invention, technology according to the present invention Essence any simple modifications, equivalents, and modifications made to the above embodiment still fall within technical solution of the present invention protection In the range of.

Claims (5)

1. a kind of absorption tower slurries PH auto-adjustment control method, which is characterized in that this method comprises: setting pH value target value; Detect the pH value of absorption tower exit slurries;According to the interlocking of the pH target value deviation of the pH value and setting detected for slurry switch electricity Dynamic valve events, to controlling the pH value in the pH target value.
2. a kind of absorption tower slurries PH auto-adjustment control method according to claim 1, which is characterized in that described for slurry Switch on/off electric valve carries out automatically controlling absorption tower plasm PH value using closed loop intermittent controlled mode.
3. a kind of absorption tower slurries PH auto-adjustment control method according to claim 2, which is characterized in that described for slurry Switch on/off electric valve control method is to automatically open for slurry motor-driven valve when pH value is less than setting value 0.02 in absorption tower to absorption tower It carries out for slurry, when pH value is greater than the set value 0.01 in absorption tower, is automatically closed and stops for slurry motor-driven valve for slurry.
4. a kind of absorption tower slurries PH auto-adjustment control method according to claim 1, which is characterized in that further include supplying Pipe flushing is starched, after carrying out pH value adjustment, flushing valve, which automatically opens, is rinsed slurry pipeline, closes automatically after rinsing 60 seconds Close flushing valve.
5. a kind of absorption tower slurries PH auto-adjustment control method according to claim 1, which is characterized in that the pH value Target value is 5.0-5.8.
CN201811048503.0A 2018-09-10 2018-09-10 A kind of absorption tower slurries PH auto-adjustment control method Pending CN109157973A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811048503.0A CN109157973A (en) 2018-09-10 2018-09-10 A kind of absorption tower slurries PH auto-adjustment control method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811048503.0A CN109157973A (en) 2018-09-10 2018-09-10 A kind of absorption tower slurries PH auto-adjustment control method

Publications (1)

Publication Number Publication Date
CN109157973A true CN109157973A (en) 2019-01-08

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111729481A (en) * 2020-06-05 2020-10-02 浙江浩普智能科技有限公司 Pulse control method and system for limestone slurry in wet desulphurization of coal-fired power plant
CN111888904A (en) * 2020-06-16 2020-11-06 华电电力科学研究院有限公司 Slurry density and pH control method for preventing scaling of desulfurization secondary absorption tower
CN111905536A (en) * 2020-06-17 2020-11-10 天津国电津能滨海热电有限公司 Automatic control system for pH value of slurry passing through desulfurization absorption tower
CN112107977A (en) * 2020-09-29 2020-12-22 聂鹏飞 Automatic pH value adjusting method, system and device based on desulfurization system

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2159507A (en) * 1984-04-19 1985-12-04 Mitsubishi Heavy Ind Ltd Method for regulating concentration of carbonate
CN104020795A (en) * 2014-05-26 2014-09-03 国家电网公司 Method for preventing pH value sudden change in desulfurization system of thermal power plant
CN204778995U (en) * 2015-07-03 2015-11-18 西安西热水务环保有限公司 White lime is thrown with system among water processing system
CN105263604A (en) * 2013-06-10 2016-01-20 株式会社Ihi Device for removing impurities from water-containing gas and impurities removal system
CN205760591U (en) * 2016-06-15 2016-12-07 中国大唐集团科学技术研究院有限公司 A kind of efficient desulfurizing tower with giant
CN206138982U (en) * 2016-11-07 2017-05-03 大连科林能源工程技术开发有限公司 Contain washing of multistage fluidization of sulphur waste gas, ultralow pollutant discharge system of utilization
CN107511056A (en) * 2017-09-08 2017-12-26 华北电力大学(保定) Limestone-gypsum wet desulfuration system regulating and controlling water quality method and regulation device
CN206996249U (en) * 2017-07-07 2018-02-13 金川集团股份有限公司 A kind of accurate adder-subtractor of flue gas acid preparing tail gas absorption

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Publication number Priority date Publication date Assignee Title
GB2159507A (en) * 1984-04-19 1985-12-04 Mitsubishi Heavy Ind Ltd Method for regulating concentration of carbonate
CN105263604A (en) * 2013-06-10 2016-01-20 株式会社Ihi Device for removing impurities from water-containing gas and impurities removal system
CN104020795A (en) * 2014-05-26 2014-09-03 国家电网公司 Method for preventing pH value sudden change in desulfurization system of thermal power plant
CN204778995U (en) * 2015-07-03 2015-11-18 西安西热水务环保有限公司 White lime is thrown with system among water processing system
CN205760591U (en) * 2016-06-15 2016-12-07 中国大唐集团科学技术研究院有限公司 A kind of efficient desulfurizing tower with giant
CN206138982U (en) * 2016-11-07 2017-05-03 大连科林能源工程技术开发有限公司 Contain washing of multistage fluidization of sulphur waste gas, ultralow pollutant discharge system of utilization
CN206996249U (en) * 2017-07-07 2018-02-13 金川集团股份有限公司 A kind of accurate adder-subtractor of flue gas acid preparing tail gas absorption
CN107511056A (en) * 2017-09-08 2017-12-26 华北电力大学(保定) Limestone-gypsum wet desulfuration system regulating and controlling water quality method and regulation device

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阎维平等: "《电站燃煤锅炉石灰石湿法烟气脱硫装置运行与控制》", 31 August 2005, 中国电力出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111729481A (en) * 2020-06-05 2020-10-02 浙江浩普智能科技有限公司 Pulse control method and system for limestone slurry in wet desulphurization of coal-fired power plant
CN111888904A (en) * 2020-06-16 2020-11-06 华电电力科学研究院有限公司 Slurry density and pH control method for preventing scaling of desulfurization secondary absorption tower
CN111905536A (en) * 2020-06-17 2020-11-10 天津国电津能滨海热电有限公司 Automatic control system for pH value of slurry passing through desulfurization absorption tower
CN112107977A (en) * 2020-09-29 2020-12-22 聂鹏飞 Automatic pH value adjusting method, system and device based on desulfurization system

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Inventor after: Wang Junfeng

Inventor after: Qi Shaolin

Inventor after: Fan Jianping

Inventor after: Zhang Anxiang

Inventor after: Wang Chongbo

Inventor before: Wang Junfeng

Inventor before: Zhang Anxiang

Inventor before: Fan Jianping

Inventor before: Qi Shaolin

Inventor before: Wang Chongbo

RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190108