CN109137593A - A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized - Google Patents

A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized Download PDF

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Publication number
CN109137593A
CN109137593A CN201811056084.5A CN201811056084A CN109137593A CN 109137593 A CN109137593 A CN 109137593A CN 201811056084 A CN201811056084 A CN 201811056084A CN 109137593 A CN109137593 A CN 109137593A
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China
Prior art keywords
coating
paper
electrolytic capacitor
pulp
carbonized
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Pending
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CN201811056084.5A
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Chinese (zh)
Inventor
华鸣
华一鸣
左磊刚
李南华
邵卫勇
占浩
何江
颜鲁鸣
其他发明人请求不公开姓名
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Zhejiang Kaine Special Paper Co Ltd
KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
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Zhejiang Kaine Special Paper Co Ltd
KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
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Application filed by Zhejiang Kaine Special Paper Co Ltd, KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG filed Critical Zhejiang Kaine Special Paper Co Ltd
Priority to CN201811056084.5A priority Critical patent/CN109137593A/en
Publication of CN109137593A publication Critical patent/CN109137593A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21DTREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
    • D21D1/00Methods of beating or refining; Beaters of the Hollander type
    • D21D1/02Methods of beating; Beaters of the Hollander type

Abstract

The invention belongs to electrolytic capacitor paper fields, and in particular to a kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized.A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper that is carbonized, and the raw material of the electrolytic capacitor paper is made of jute pulp and chemical fibre;The beating degree of jute pulp is 10 ~ 30 ° of SR, and weight in wet base is 10 ~ 40g;The length of chemical fibre is 1.5 ~ 15mm, and fiber number is 0.1 ~ 3dtex;By dry weight percentages, jute pulp is 10 ~ 80%, and chemical fibre is 20 ~ 90%, and the surface spray spraying of the electrolytic capacitor paper or dip coated have enhancement layer, and coating weight accounts for the 1 ~ 10% of paper absolute dry mass after coating.Paper is coated, the intensity of paper can be further enhanced, is more conducive to ensureing the smooth production of capacitor.

Description

A kind of enhanced low tightness of coating exempts from be carbonized solid electrolytic capacitor paper and its preparation Method
Technical field
The invention belongs to electrolytic capacitor paper fields, and in particular to a kind of enhanced low tightness of coating exempts from the solid state electrolysis that is carbonized Kraft capacitor paper and preparation method thereof.
Background technique
Electrolyte in solid electrolytic capacitor is solid-state conductive high molecular material, the structure packet of solid electrolytic capacitor Include anode, cathode, electrolytic paper and solid-state conductive high molecular material.Electrolytic capacitor paper be prepare electrolytic capacitor can not or One of scarce raw material is mainly used for adsorbing monomer and oxidant in the capacitor, forms polymer, while playing isolation pole plate Effect, prevents anode and cathode from directly contacting and short-circuit.
Traditional electrolytic capacitor paper is holocellulos material, weaker to the adsorption capacity of monomer, while being contained in cellulose There is a large amount of hydroxyl, side reaction can be generated in conductive high polymer monomer polymerization, influence the performance of capacitor;In addition, general electricity Fiber combination is more close in solution paper, and conductive high polymer monomer is difficult to be adsorbed in electrolytic paper completely, leads to conducting polymer list It is unevenly distributed in electrolytic paper after body polymerization, influences capacitor performance.Currently, the solid electrolytic capacitor produced in the market, It needs to carry out carbonization treatment to electrolytic paper at 250 ~ 270 DEG C in production process, to improve the sponginess of electrolytic paper and to monomer Adsorptivity.It under this technique, needs for entire capacitor to be heated under higher temperature, production technology is complicated, and high temperature cabonization Process will cause destruction to the structure of cathode and anode foil, cause properties of product unstable, leakage current is easy exceeded;Further, since plus Hot temperature is high, needs to consume a large amount of energy, adds somewhat to the production cost of enterprise.
Therefore, in order to simplify the production technology of solid electrolytic capacitor, production energy consumption is reduced, a kind of low tightness is developed and exempts from Carbonization solid electrolytic capacitor paper (number of patent application: 2018091011182, the applying date: on September 10th, 2018), this capacitor Device paper has preferable adsorptivity to conductive high polymer monomer, and can reduce side reaction when conductive high polymer monomer polymerization, It is not necessarily to carry out kraft capacitor paper carbonization treatment in capacitor production process simultaneously, but the intensity of the solid electrolytic capacitor paper Not enough.
Summary of the invention
In order to solve the above technical problems, it is an object of the present invention to provide a kind of pair of monomers to have preferably absorption Property, side reaction is less, the electrolytic capacitor paper of carbonization treatment is not necessarily in capacitor production process, and have good intensity. Another object of the present invention is to provide the preparation method of above-mentioned electrolytic capacitor paper.
In order to realize above-mentioned first purpose, the invention adopts the following technical scheme:
A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper that is carbonized, and the raw material of the electrolytic capacitor paper is by jute pulp and change Learn fiber composition;Jute pulp includes sisal hemp pulp, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose latex, pineapple leaves slurry and wingceltis One or more of latex, the beating degree of jute pulp are 10 ~ 30 ° of SR, and weight in wet base is 10 ~ 40g;The chemical fibre includes polyester One or more of fiber, Fypro, polyolefine fiber, vinylon fibre and polyacrylonitrile fibre, the length of chemical fibre Degree is 1.5 ~ 15mm, and fiber number is 0.1 ~ 3dtex;By dry weight percentages, jute pulp is 10 ~ 80%, chemical fibre is 20 ~ 90%;The surface spray of the electrolytic capacitor paper sprays or dip coated has enhancement layer, and coating weight accounts for paper over dry after coating The 1 ~ 10% of quality.
Preferably, pressing dry weight percentages, jute pulp is 40 ~ 60%, and chemical fibre is 40 ~ 60%.
Preferably, the beating degree of jute pulp is 10 ~ 20 ° of SR, weight in wet base is 10 ~ 35g.
Preferably, the length of chemical fibre is 2 ~ 10mm, fiber number is 0.2 ~ 2dtex.
Preferably, the ingredient of spraying coating liquid or dip coated liquid is polyvinyl alcohol and its derivative, polyacrylamide One or more of with starch.
In order to realize above-mentioned second purpose, the invention adopts the following technical scheme:
A method of it preparing the enhanced low tightness of coating and exempts from the solid electrolytic capacitor paper that is carbonized, this method includes following The step of:
1) dispersion is discongested after jute pulp being added water, obtains slurry A;
2) chemical fibre is uniformly dispersed, obtains slurry B;
3) slurry A and slurry B is sufficiently mixed, and obtains mixed slurry;
4) mixed slurry is subjected to online drainage and formation, using squeezing, drying, spraying coating or dip coated, drying, batched And cutting, it obtains the enhanced low tightness of coating and exempts from the solid electrolytic capacitor paper that is carbonized.
Further, forming is manufactured paper with pulp using cylinder in step 4), and Top wire former concentration is 0.01 ~ 0.5%.
Further, the coating fluid mass concentration of spraying coating and dip coated is 0.1 ~ 10%.
The present invention is by adopting the above-described technical solution, the enhanced low tightness of coating of the invention exempts from the solid state electrolysis electricity that is carbonized Container paper has good adsorptivity to monomer, and can be reduced the generation of side reaction during monomer polymerization, while paper has There is lower tightness, monomer is uniformly distributed in paper.Therefore, without to capacitor in the production process of capacitor Device paper carries out carbonization treatment.In above-mentioned component chemical fibre to conductive high polymer monomer have preferable adsorptivity, therefore Chemical fibre is added in paper can improve paper to the adsorptivity of conductive high polymer monomer, be distributed monomer in paper It is even;And since binding force is weaker between pure chemistry fiber, it is difficult to be manufactured paper with pulp by wet-formed, it is therefore desirable to a certain amount of plant Fibres assign the paper certain intensity, can smoothly manufacture paper with pulp.In addition, being coated to paper, can further enhance The intensity of paper is more conducive to ensureing the smooth production of capacitor.
Specific embodiment
Reference example 1
Manila pulp discongest after beating degree and weight in wet base be respectively 17 ° of SR, 27.5g, discongest rear pulp density 2%;PET polyester After fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, horse after mixing Buddhist nun draws jute pulp and PET polyester fiber to account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fibers After mixing, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, batch and obtained after cutting Finished product.
Reference example 2
Sisal hemp pulp discongest after beating degree and weight in wet base be respectively 15 ° of SR, 15.3g, discongest rear pulp density 2%;PET polyester fiber After being dispersed, starching dense is 2%, fibre length 5mm, fiber number 1.5dtex.Two kinds of fibers are mixed, Manila after mixing Jute pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fiber mixing After uniformly, by cylinder forming, Top wire former concentration is 0.1%, then through squeezing, drying, batch and obtain finished product after cutting.
Embodiment 1
Manila pulp discongest after beating degree and weight in wet base be respectively 17 ° of SR, 27.5g, discongest rear pulp density 2%;PET polyester After fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, horse after mixing Buddhist nun draws jute pulp and PET polyester fiber to account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fibers After mixing, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, volume Finished product is taken and obtains after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 1.5%, coating weight is that paper is exhausted after being coated with The 2% of dry mass.
Embodiment 2
Manila pulp discongest after beating degree and weight in wet base be respectively 17 ° of SR, 27.5g, discongest rear pulp density 2%;PET polyester After fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 1.5dtex.Two kinds of fibers are mixed, horse after mixing Buddhist nun draws jute pulp and PET polyester fiber to account for 45%, the 55% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fibers After mixing, by cylinder forming, Top wire former concentration is 0.1%, then through squeezing, drying, spraying coating, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2%, coating weight is paper over dry matter after coating The 2% of amount.
Embodiment 3
Manila pulp discongest after beating degree and weight in wet base be respectively 17 ° of SR, 27.5g, discongest rear pulp density 2%;PET polyester After fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, horse after mixing Buddhist nun draws jute pulp and PET polyester fiber to account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fibers After mixing, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, volume Finished product is taken and obtains after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2.5%, coating weight is that paper is exhausted after being coated with The 4% of dry mass.
Embodiment 4
Manila pulp discongest after beating degree and weight in wet base be respectively 17 ° of SR, 27.5g, discongest rear pulp density 2%;PET polyester After fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 1.5dtex.Two kinds of fibers are mixed, horse after mixing Buddhist nun draws jute pulp and PET polyester fiber to account for 55%, the 45% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fibers After mixing, by cylinder forming, Top wire former concentration is 0.1%, then through squeezing, drying, dip coated, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2%, coating weight is paper over dry matter after coating The 4.5% of amount.
Embodiment 5
Sisal hemp pulp discongest after beating degree and weight in wet base be respectively 15 ° of SR, 15.3g, discongest rear pulp density 2%;PET polyester fiber After being dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, Manila after mixing Jute pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fiber mixing After uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2%, coating weight is paper absolute dry mass after coating 1.8%.
Embodiment 6
Sisal hemp pulp discongest after beating degree and weight in wet base be respectively 15 ° of SR, 15.3g, discongest rear pulp density 2%;PET polyester fiber After being dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, Manila after mixing Jute pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fiber mixing After uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2%, coating weight is paper absolute dry mass after coating 2.5%.
Embodiment 7
Sisal hemp pulp discongest after beating degree and weight in wet base be respectively 15 ° of SR, 15.3g, discongest rear pulp density 2%;PET polyester fiber After being dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, Manila after mixing Jute pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fiber mixing After uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2%, coating weight is paper absolute dry mass after coating 4%.
Embodiment 8
Sisal hemp pulp discongest after beating degree and weight in wet base be respectively 15 ° of SR, 15.3g, discongest rear pulp density 2%;PET polyester fiber After being dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, Manila after mixing Jute pulp and PET polyester fiber account for 60%, the 40% of fiber over dry total amount respectively, and slurry concentration is 1% after mixing, two kinds of fiber mixing After uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 3%, coating weight is paper absolute dry mass after coating 5%.

Claims (8)

1. a kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper that is carbonized, which is characterized in that the electrolytic capacitor paper Raw material is made of jute pulp and chemical fibre;Jute pulp includes sisal hemp pulp, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose skin One or more of slurry, pineapple leaves slurry and wingceltis latex, the beating degree of jute pulp are 10 ~ 30 ° of SR, and weight in wet base is 10 ~ 40g;Described Chemical fibre includes one of polyester fiber, Fypro, polyolefine fiber, vinylon fibre and polyacrylonitrile fibre or several Kind, the length of chemical fibre is 1.5 ~ 15mm, and fiber number is 0.1 ~ 3dtex;By dry weight percentages, jute pulp is 10 ~ 80%, Chemical fibre is 20 ~ 90%;The surface spray of the electrolytic capacitor paper sprays or dip coated has enhancement layer, applies after coating Cloth amount accounts for the 1 ~ 10% of paper absolute dry mass.
2. the enhanced low tightness of a kind of coating according to claim 1 exempts from the solid electrolytic capacitor paper that is carbonized, feature exists In by dry weight percentages, jute pulp is 40 ~ 60%, and chemical fibre is 40 ~ 60%.
3. the enhanced low tightness of a kind of coating according to claim 1 exempts from the solid electrolytic capacitor paper that is carbonized, feature exists In the beating degree of jute pulp is 10 ~ 20 ° of SR, and weight in wet base is 10 ~ 30g.
4. the enhanced low tightness of a kind of coating according to claim 1 exempts from the solid electrolytic capacitor paper that is carbonized, feature exists In the length of chemical fibre is 2 ~ 10mm, and fiber number is 0.2 ~ 2dtex.
5. the enhanced low tightness of a kind of coating according to claim 1 exempts from the solid electrolytic capacitor paper that is carbonized, feature exists In the ingredient of spraying coating liquid or dip coated liquid is one of polyvinyl alcohol and its derivative, polyacrylamide and starch Or it is several.
6. a kind of enhanced low tightness of coating described in claim 1 ~ 5 any one claim for preparing exempts from the solid state electrolysis that is carbonized The method of kraft capacitor paper, which is characterized in that this method includes the following steps:
1) dispersion is discongested after jute pulp being added water, obtains slurry A;
2) chemical fibre is uniformly dispersed, obtains slurry B;
3) slurry A and slurry B is sufficiently mixed, and obtains mixed slurry;
4) mixed slurry is subjected to online drainage and formation, using squeezing, drying, spraying coating or dip coated, drying, batched And cutting, it obtains the enhanced low tightness of coating and exempts from the solid electrolytic capacitor paper that is carbonized.
7. Top wire former is dense according to the method described in claim 6, manufacturing paper with pulp it is characterized in that, shaping in step 4) using cylinder Degree is 0.01 ~ 0.5%.
8. according to the method described in claim 6, it is characterized in that, the coating fluid mass concentration of spraying coating and dip coated is 0.1~10%。
CN201811056084.5A 2018-09-11 2018-09-11 A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized Pending CN109137593A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN110718395A (en) * 2019-10-18 2020-01-21 肇庆绿宝石电子科技股份有限公司 Long-life conductive polymer solid capacitor and manufacturing method thereof
CN111608002A (en) * 2020-04-17 2020-09-01 仙鹤股份有限公司 Preparation method of carbonization-free solid capacitor paper
CN112431059A (en) * 2020-10-29 2021-03-02 浙江鹏辰造纸研究所有限公司 Temperature-resistant mineral fiber paper heat-insulating material and preparation method thereof
CN114351499A (en) * 2021-12-31 2022-04-15 浙江凯恩新材料有限公司 Low-tightness carbonization-free solid electrolytic capacitor paper and preparation method and application thereof
CN114541176A (en) * 2022-01-19 2022-05-27 浙江凯恩新材料有限公司 High-tensile-strength low-tightness electrolytic capacitor paper and preparation method and application thereof
CN116103957A (en) * 2023-02-07 2023-05-12 株洲时代华先材料科技有限公司 Capacitor paper and preparation method thereof

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CN108166320A (en) * 2018-01-04 2018-06-15 浙江凯恩特种材料股份有限公司 A kind of method that on-line coater prepares low tightness high intensity electrolytic capacitor paper
CN108166321A (en) * 2018-01-04 2018-06-15 浙江凯恩特种纸业有限公司 A kind of method for preparing low tightness high intensity electrolytic capacitor paper of spraying
CN108179652A (en) * 2018-01-04 2018-06-19 浙江凯恩特种纸业有限公司 A kind of reinforced electric electrolytic capacitor paper and preparation method thereof
CN108203893A (en) * 2018-01-04 2018-06-26 浙江凯恩特种纸业有限公司 A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof
CN108221487A (en) * 2018-01-04 2018-06-29 浙江凯恩特种纸业有限公司 A kind of low internal resistance super electrolytic capacitor paper and preparation method thereof

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CN108149521A (en) * 2018-01-04 2018-06-12 浙江凯恩特种纸业有限公司 A kind of method that spraying prepares reinforced electric electrolytic capacitor paper
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CN110718395A (en) * 2019-10-18 2020-01-21 肇庆绿宝石电子科技股份有限公司 Long-life conductive polymer solid capacitor and manufacturing method thereof
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CN114351499A (en) * 2021-12-31 2022-04-15 浙江凯恩新材料有限公司 Low-tightness carbonization-free solid electrolytic capacitor paper and preparation method and application thereof
CN114541176A (en) * 2022-01-19 2022-05-27 浙江凯恩新材料有限公司 High-tensile-strength low-tightness electrolytic capacitor paper and preparation method and application thereof
CN116103957A (en) * 2023-02-07 2023-05-12 株洲时代华先材料科技有限公司 Capacitor paper and preparation method thereof

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Application publication date: 20190104