CN108203893A - A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof - Google Patents

A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof Download PDF

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Publication number
CN108203893A
CN108203893A CN201810006278.8A CN201810006278A CN108203893A CN 108203893 A CN108203893 A CN 108203893A CN 201810006278 A CN201810006278 A CN 201810006278A CN 108203893 A CN108203893 A CN 108203893A
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China
Prior art keywords
electrolytic capacitor
pulp
paper
coating
high intensity
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Pending
Application number
CN201810006278.8A
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Chinese (zh)
Inventor
陈万平
占浩
毛香琴
李南华
雷荣
左磊刚
张文超
钟祥
张胜
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KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
Zhejiang Kaine Special Paper Co Ltd
Original Assignee
KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
Zhejiang Kaine Special Paper Co Ltd
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Application filed by KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG, Zhejiang Kaine Special Paper Co Ltd filed Critical KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
Priority to CN201810006278.8A priority Critical patent/CN108203893A/en
Publication of CN108203893A publication Critical patent/CN108203893A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10Composite fibres
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/06Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type
    • D21F11/08Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type paper or board consisting of two or more layers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H11/00Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
    • D21H11/12Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01GCAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G11/00Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/52Separators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of electrolytic capacitor papers and preparation method thereof.A kind of low tightness high intensity electrolytic capacitor paper, the raw paper pulp of the electrolytic capacitor paper are made of jute pulp, the mass concentration 2 ~ 5% of jute pulp, beating degree 30 ~ 60 ° of SR, 2 ~ 16g of weight in wet base;Raw paper pulp by double cylinder formings and carry out it is compound, squeezing, it is dry after in page surface applied coating solution, coating weight is 0.1 ~ 1.0 g/m2, coating fluid is polycarboxylic acids and PVA, and the mass ratio of polycarboxylic acids and PVA are 1:1~1:5.Production and on-line coater of the present invention by body paper, the low tightness high intensity electrolytic capacitor paper of acquisition, and have preferable intensity, good water absorbing properties, good loss value, excellent proof voltage energy, tensile strength increases 0.4 more than kN/m.

Description

A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof
Technical field
The present invention relates to a kind of electrolytic capacitor papers and preparation method thereof.
Background technology
Electrolytic capacitor paper is to prepare one of indispensable raw material of electrolytic capacitor, between capacitor anode and cathode Play buffer action, prevent anode and cathode is in direct contact and it is short-circuit.
Electrolytic capacitor paper had both belonged to speciality paper scope, also belonged to electronic component, therefore, different from general paper, electricity Electrolytic capacitor paper has following requirement:(1)Purity is high, and the impurity for influencing electrolyte and electrode foil performance will be controlled strictly;(2) Papery is uniform, and thickness and tightness are uniform, and fiber alignment uniformly, while will be unable to the paper defects such as hole and fibre bundle;(3)Have Necessary electrical strength and mechanical strength;(4)There are good wellability and retentivity to electrolyte;(5)With electrolyte group During into complex, there is low resistance.
The tightness and thickness of electrolytic capacitor paper are higher, and the loss of the electrolytic capacitor of preparation can be bigger, and prepares low damage The electrolytic capacitor of consumption generally requires electrolytic capacitor paper to have relatively low a tightness and thickness, but the reduction of tightness and thickness, The intensity of electrolytic capacitor paper can be caused to decline, the resistance to burr property of electrolytic capacitor paper is reduced, also result in electrolytic capacitor Production efficiency reduce.At present, it for this problem, is difficult to solve using usual manner.
Invention content
In order to solve the above technical problems, there is opposite high intensity it is an object of the present invention to provide one kind and be lost opposite Relatively low electrolytic capacitor paper, another object of the present invention are to provide the preparation method of above-mentioned electrolytic capacitor paper.
To achieve these goals, the present invention uses following technical scheme:
A kind of low tightness high intensity electrolytic capacitor paper, the raw paper pulp of the electrolytic capacitor paper are made of jute pulp, the matter of jute pulp Measure concentration 2 ~ 5%, beating degree 30 ~ 60 ° of SR, 2 ~ 16g of weight in wet base;Raw paper pulp by double cylinder formings and carry out it is compound, it is squeezing, dry In page surface applied coating solution after dry, coating weight is 0.1 ~ 1.0 g/m2, coating fluid is polycarboxylic acids and PVA, polycarboxylic acids and PVA Mass ratio be 1:1~1:5.
Preferably, the jute pulp include sisal hemp pulp, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose latex, One or more of pineapple leaves slurry and wingceltis latex.
Preferably, the mass concentration 2 ~ 4% of the jute pulp, beating degree 40 ~ 50 ° of SR, 8 ~ 12g of weight in wet base.
Preferably, the coating solution amount is 0.2 ~ 0.6g/m2
Preferably, the polycarboxylic acids and the mass ratio of PVA are 1:2~1:3.
In order to realize above-mentioned second purpose, present invention employs following technical schemes:
A kind of preparation method for preparing the low tightness high intensity electrolytic capacitor paper, this method include the following steps:
1)2 ~ 5% mass concentration original slurry material will be made after jute pulp plus water;
2)Original slurry material is obtained into mass concentration 2 ~ 5%, 20 ~ 96 ° of SR of beating degree, 2 ~ 16g of weight in wet base by beater or fiberizer Slurry A;
3)Slurry A carried out through double cylinders it is compound, it is compound after by squeezing, being coated with, drying, press polish and batch to obtain body paper B, body paper B obtains electrolytic capacitor paper after cutting;Coating solution amount is 0.1 ~ 1.0 g/m2, coating fluid be polycarboxylic acids and PVA, poly- carboxylic The mass ratio of acid and PVA are 1:1~1:4.
Preferably, the mashing mode includes the mashing of hollanderbeater free type, single or double mill shiny beating In one kind.The coating method includes atomizing coating, impregnated coating, scraper type coating, metering rod coating, air-blade type One kind in coating.
The present invention is as a result of above-mentioned technical solution, production and on-line coater by body paper, the low tightness of acquisition High intensity electrolytic capacitor paper, and have preferable intensity, good water absorbing properties, good loss value, excellent proof voltage energy, Tensile strength increases 0.4 more than kN/m.
Specific embodiment
Reference example 1
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, after squeezing through drying, dryer temperature 145 DEG C, then through press polish, batch and obtain finished product, quantification of 15g/m after cutting2
Reference example 2
The beating degree and weight in wet base of sisal hemp pulp are respectively 50 ° of SR, 8.8g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, after squeezing through drying, dryer temperature 150 DEG C, then through press polish, batch and obtain finished product, quantification of 15g/m after cutting2
Embodiment 1
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight 0.1g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2
Embodiment 2
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight 0.1g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2
Embodiment 3
The beating degree and weight in wet base of sisal hemp pulp are respectively 50 ° of SR, 8.8g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight 0.1g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 145 DEG C, quantification of 15g/m2
Embodiment 4
The beating degree and weight in wet base of sisal hemp pulp are respectively 40 ° of SR, 10g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:2, coating fluid a concentration of 2%, coating weight 0.3g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2
Embodiment 5
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight 0.3g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2
Embodiment 6
The beating degree and weight in wet base of sisal hemp pulp are respectively 45 ° of SR, 9.4g, are beaten and carried out by free type using hollanderbeater, Beating consistency 2.5%.After the completion of mashing, by double cylinder formings and carry out it is compound, squeezing, it is dry after by spray pattern in paper The mass ratio of page frame table spraying polycarboxylic acids and PVA, polycarboxylic acids and PVA are 1:3, coating fluid a concentration of 2%, coating weight 0.5g/ m2.Then drying, press polish, batch and finished product obtained after cutting, dryer temperature be 150 DEG C, quantification of 15g/m2
The test data of above-mentioned each electrolytic capacitor paper is as follows:
Index name Tightness Thickness Breakdown voltage Machine direction tensile strength Suction head mm/10min D Rs
Unit g/cm3 μm V kN/m Longitudinal direction Laterally / Ω
Reference example 1 0.552 26.5 415 1.52 36 28 1.98 3.16
Reference example 2 0.501 29.8 431 1.66 32 24 2.01 3.18
Embodiment 1 0.551 26.1 449 2.09 42 31 2.11 3.22
Embodiment 2 0.505 29.4 461 2.08 37 28 2.16 3.55
Embodiment 3 0.558 25.8 451 2.11 36 26 2.29 3.48
Embodiment 4 0.508 29.6 465 2.19 40 27 2.14 3.22
Embodiment 5 0.552 26.4 454 2.24 37 26 2.08 3.12
Embodiment 6 0.502 30.1 468 2.36 36 25 2.26 3.45

Claims (8)

1. a kind of low tightness high intensity electrolytic capacitor paper, which is characterized in that the raw paper pulp of the electrolytic capacitor paper is by jute pulp Composition, the mass concentration 2 ~ 5% of jute pulp, beating degree 30 ~ 60 ° of SR, 2 ~ 16g of weight in wet base;Raw paper pulp is gone forward side by side by double cylinder formings Row is compound, and in page surface applied coating solution after squeezing, drying, coating weight is 0.1 ~ 1.0 g/m2, coating fluid for polycarboxylic acids and The mass ratio of PVA, polycarboxylic acids and PVA are 1:1~1:5.
2. a kind of low tightness high intensity electrolytic capacitor paper according to claim 1, which is characterized in that jute pulp includes sisal hemp One or more of slurry, manila pulp, jute slurry, Chinese jute pulp, flax pulp, wild goose latex, pineapple leaves slurry and wingceltis latex.
3. a kind of low tightness high intensity electrolytic capacitor paper according to claim 1, which is characterized in that the quality of jute pulp is dense Degree 2 ~ 4%, beating degree 40 ~ 50 ° of SR, 8 ~ 12g of weight in wet base.
A kind of 4. low tightness high intensity electrolytic capacitor paper according to claim 1, which is characterized in that coating solution amount For 0.2 ~ 0.6g/m2
5. a kind of low tightness high intensity electrolytic capacitor paper according to claim 1, which is characterized in that polycarboxylic acids and PVA Mass ratio be 1:2~1:3.
6. a kind of preparation for preparing the low tightness high intensity electrolytic capacitor paper described in claim 1 ~ 4 any one claim Method, which is characterized in that this method includes the following steps:
1)2 ~ 5% mass concentration original slurry material will be made after jute pulp plus water;
2)Original slurry material is obtained into mass concentration 2 ~ 5%, 20 ~ 96 ° of SR of beating degree, 2 ~ 16g of weight in wet base by beater or fiberizer Slurry A;
3)Slurry A carried out through double cylinders it is compound, it is compound after by squeezing, being coated with, drying, press polish and batch to obtain body paper B, body paper B obtains electrolytic capacitor paper after cutting;Coating solution amount is 0.1 ~ 1.0 g/m2, coating fluid be polycarboxylic acids and PVA, poly- carboxylic The mass ratio of acid and PVA are 1:1~1:4.
7. preparation method according to claim 6, which is characterized in that the mashing mode is swum including hollanderbeater From one kind in formula mashing, single or double mill shiny beating.
8. preparation method according to claim 6, which is characterized in that the coating method includes atomizing coating, leaching One kind in the coating of stain formula, scraper type coating, metering rod coating, air-blade type coating.
CN201810006278.8A 2018-01-04 2018-01-04 A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof Pending CN108203893A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109056403A (en) * 2018-09-10 2018-12-21 浙江凯恩特种纸业有限公司 A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof
CN109137593A (en) * 2018-09-11 2019-01-04 浙江凯恩特种材料股份有限公司 A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN109208369A (en) * 2018-09-10 2019-01-15 浙江凯恩特种纸业有限公司 A kind of low-loss electrolytic capacitor paper and preparation method thereof
CN111809433A (en) * 2019-04-11 2020-10-23 中国制浆造纸研究院有限公司 Low-sodium ion content insulating paper for extra-high voltage transformer and manufacturing method thereof
CN113445350A (en) * 2020-03-24 2021-09-28 中国制浆造纸研究院有限公司 High-oil-medium breakdown strength insulating paper for extra-high voltage transformer and manufacturing method thereof
CN116103957A (en) * 2023-02-07 2023-05-12 株洲时代华先材料科技有限公司 Capacitor paper and preparation method thereof
CN117166282A (en) * 2023-09-06 2023-12-05 仙鹤股份有限公司 Preparation method of composite electrolytic capacitor paper

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1626731A (en) * 2003-12-09 2005-06-15 浙江凯恩特种材料股份有限公司 Paper of electrolytic capacitor and preparation method
CN103026530A (en) * 2010-08-11 2013-04-03 科德宝两合公司 Separator with increased puncture resistance
CN104988809A (en) * 2015-06-26 2015-10-21 浙江凯恩特种材料股份有限公司 High voltage resistant electrolytic capacitor paper and preparation method thereof
WO2017104336A1 (en) * 2015-12-14 2017-06-22 ニッポン高度紙工業株式会社 Separator for alkaline batteries, and alkaline battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1626731A (en) * 2003-12-09 2005-06-15 浙江凯恩特种材料股份有限公司 Paper of electrolytic capacitor and preparation method
CN103026530A (en) * 2010-08-11 2013-04-03 科德宝两合公司 Separator with increased puncture resistance
CN104988809A (en) * 2015-06-26 2015-10-21 浙江凯恩特种材料股份有限公司 High voltage resistant electrolytic capacitor paper and preparation method thereof
WO2017104336A1 (en) * 2015-12-14 2017-06-22 ニッポン高度紙工業株式会社 Separator for alkaline batteries, and alkaline battery

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109056403A (en) * 2018-09-10 2018-12-21 浙江凯恩特种纸业有限公司 A kind of high intensity super electrolytic capacitor diaphragm paper and preparation method thereof
CN109208369A (en) * 2018-09-10 2019-01-15 浙江凯恩特种纸业有限公司 A kind of low-loss electrolytic capacitor paper and preparation method thereof
CN109137593A (en) * 2018-09-11 2019-01-04 浙江凯恩特种材料股份有限公司 A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN111809433A (en) * 2019-04-11 2020-10-23 中国制浆造纸研究院有限公司 Low-sodium ion content insulating paper for extra-high voltage transformer and manufacturing method thereof
CN113445350A (en) * 2020-03-24 2021-09-28 中国制浆造纸研究院有限公司 High-oil-medium breakdown strength insulating paper for extra-high voltage transformer and manufacturing method thereof
CN116103957A (en) * 2023-02-07 2023-05-12 株洲时代华先材料科技有限公司 Capacitor paper and preparation method thereof
CN117166282A (en) * 2023-09-06 2023-12-05 仙鹤股份有限公司 Preparation method of composite electrolytic capacitor paper
CN117166282B (en) * 2023-09-06 2024-05-10 仙鹤股份有限公司 Preparation method of composite electrolytic capacitor paper

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Application publication date: 20180626