CN109137514B - 一种免烫全棉面料及其制备方法 - Google Patents
一种免烫全棉面料及其制备方法 Download PDFInfo
- Publication number
- CN109137514B CN109137514B CN201810862816.3A CN201810862816A CN109137514B CN 109137514 B CN109137514 B CN 109137514B CN 201810862816 A CN201810862816 A CN 201810862816A CN 109137514 B CN109137514 B CN 109137514B
- Authority
- CN
- China
- Prior art keywords
- fabric
- parts
- solution
- drying
- ironing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 93
- 238000010409 ironing Methods 0.000 title claims abstract description 19
- 229920000742 Cotton Polymers 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000243 solution Substances 0.000 claims abstract description 46
- 238000001035 drying Methods 0.000 claims abstract description 26
- -1 polysiloxane Polymers 0.000 claims abstract description 25
- 238000003756 stirring Methods 0.000 claims abstract description 25
- 108010022355 Fibroins Proteins 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims abstract description 17
- 239000011259 mixed solution Substances 0.000 claims abstract description 15
- 108010009736 Protein Hydrolysates Proteins 0.000 claims abstract description 13
- NVKJOXRVEKMMHS-UHFFFAOYSA-N 5-nitro-1,2,4-triazol-3-one Chemical compound [O-][N+](=O)C1=NC(=O)N=N1 NVKJOXRVEKMMHS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- 108090000145 Bacillolysin Proteins 0.000 claims abstract description 9
- 241000193830 Bacillus <bacterium> Species 0.000 claims abstract description 9
- 102000035092 Neutral proteases Human genes 0.000 claims abstract description 9
- 108091005507 Neutral proteases Proteins 0.000 claims abstract description 9
- 108091005804 Peptidases Proteins 0.000 claims abstract description 9
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims abstract description 9
- 239000004365 Protease Substances 0.000 claims abstract description 9
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 9
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 9
- 235000019698 starch Nutrition 0.000 claims abstract description 9
- 239000008107 starch Substances 0.000 claims abstract description 9
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 8
- 229920002545 silicone oil Polymers 0.000 claims abstract description 8
- 239000000600 sorbitol Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 239000000047 product Substances 0.000 claims abstract description 7
- 239000002699 waste material Substances 0.000 claims abstract description 7
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 22
- 230000000694 effects Effects 0.000 claims description 15
- 229910021589 Copper(I) bromide Inorganic materials 0.000 claims description 14
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- 239000007983 Tris buffer Substances 0.000 claims description 14
- 150000001412 amines Chemical class 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 11
- 239000003531 protein hydrolysate Substances 0.000 claims description 11
- 238000000502 dialysis Methods 0.000 claims description 7
- 238000002791 soaking Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical class [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000000643 oven drying Methods 0.000 claims description 6
- 239000000376 reactant Substances 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 239000012265 solid product Substances 0.000 claims description 6
- 238000000108 ultra-filtration Methods 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000000413 hydrolysate Substances 0.000 claims description 4
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 claims description 2
- 229940083037 simethicone Drugs 0.000 claims description 2
- 230000003670 easy-to-clean Effects 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 230000037303 wrinkles Effects 0.000 abstract description 3
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003999 initiator Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical group NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical group [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/392—Nitroso compounds; Nitro compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提供了一种免烫全棉面料的制备方法，首选在面料表面接枝大分子聚合物，将其浸入含PEG‑400和十二烷基苯磺酸钠的山梨醇溶液中处理30‑50min，将废蚕丝完全溶解后用淀粉液化芽孢杆菌蛋白酶和中性蛋白酶进行水解，制得丝素蛋白水解液，将丝素蛋白水解液15‑30份、氨基改性聚硅氧烷8‑16份、5‑硝基‑1,2,3‑苯三酸6‑12份、二甲基硅油5‑10份进行混合得到混合液，将处理后的面料浸入混合液中，搅拌1‑3h后甩干水分，将面料进行烘干制得产品。本发明制得的面料缩水率低，水洗后稳定性良好，同时面料具有良好的恢复性和平整度，不易折皱，该面料易于打理、穿着舒适，因此作为一种免烫面料具有广泛的前景。
Description
技术领域
本发明属于纺织技术领域，具体涉及一种免烫全棉面料及其制备方法。
背景技术
棉纤维织物性能优良，如吸湿性好、透气性好和手感好等，但弹性和回复性差，洗涤后不易打理，在纺织印染或服用过程中易产生剧烈的收缩，不能保持平整的外观，因此，对棉织物进行抗皱整理，改善其弹性，提高其干、湿态抗皱性能，已成为亟需解决的问题。传统防皱整理剂（N-羟甲基酰胺类化合物）整理的织物在存放或穿着过程中会分解或释放出甲醛，影响人身健康。随着绿色环保意识的日益增强，开发天然免烫面料是必然的发展趋势，具有重要的意义。
发明内容
本发明所要解决的技术问题：针对全棉面料力学性能差，在机械作用力或者高温条件下面料易发生褶皱变形，导致面料不得不进行频繁熨烫，从而影响面料质量和使用寿命，本发明提供了一种免烫全棉面料的制备方法，首先在全棉面料表面接枝大分子提高面料的力学性能和机械强度，然后将大分子接枝的面料用含PEG-400和十二烷基苯磺酸钠的山梨醇溶液进行渗透处理，提高对后续溶剂的吸收性，然后再用丝素蛋白水解液、氨基改性聚硅氧烷、5-硝基-1,2,3-苯三酸、二甲基硅油进行柔软抗皱处理，制得免烫全棉面料。
本发明的技术方案如下：
一种免烫全棉面料的制备方法，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在100-200r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌10-20min后，加入三（二甲胺基丙基）胺和引发剂，然后将温度升高至50-70℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应2-4h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为（8-15）:（3-5）:（2-6）:（1-5）:（1-3）；
（2）将废蚕丝浸于1-2%的碳酸氢钠溶液中于100℃的煮沸溶液中处理20-30min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；干燥后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析4-6次，将透析后的溶液以3000-5000r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为50-100U/mL淀粉液化芽孢杆菌蛋白酶和30-50U/mL的中性蛋白酶，在室温下搅拌处理1-2h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含30-60% PEG-400和20-50%十二烷基苯磺酸钠的山梨醇溶液中30-50min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液15-30份、氨基改性聚硅氧烷8-16份、5-硝基-1,2,3-苯三酸6-12份、二甲基硅油5-10份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌1-3h后甩干水分，将面料进行烘干制得产品。
进一步的，所述引发剂为过硫酸盐。
优选的，所述聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三（二甲胺基丙基）胺和过硫酸铵的摩尔比为12:4:4:3:2。
优选的，所述淀粉液化芽孢杆菌蛋白酶和中性蛋白酶的最终活力分别为75U/mL和40U/mL。
优选的，所述步骤（4）中丝素蛋白水解液22份、氨基改性聚硅氧烷12份、5-硝基-1,2,3-苯三酸9份、二甲基硅油8份。
有益效果：本发明提供了一种免烫全棉面料的制备方法，首先通过在面料表面接枝生物大分子，提高面料表面的交联密度，改善收缩性能，然后将其置入含PEG-400和十二烷基苯磺酸钠的山梨醇中，在提高面料渗透性的同时增加PEG-400和十二烷基苯磺酸钠对面料的作用，降低面料表面张力，再将其浸入丝素蛋白水解液、氨基改性聚硅氧烷、5-硝基-1,2,3-苯三酸、二甲基硅油混合液中，提高面料的柔软度和回弹性。通过从测试结果得出，本发明制得的面料缩水率低，水洗后稳定性良好，同时面料具有良好的回复性和平整度，不易折皱，该面料易于打理、穿着舒适，因此作为一种免烫面料具有广泛的前景。
具体实施方式
下面结合具体实施例来进一步描述本发明，但实施例仅是范例性的，并不对本发明的范围构成任何限制。本领域技术人员应该理解的是，在不偏离本发明的精神和范围下可以对本发明技术方案的细节和形式进行修改或替换，但这些修改和替换均落入本发明的保护范围内。
实施例1
一种免烫全棉面料的制备方法，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在150r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌15min后，加入三（二甲胺基丙基）胺和引发剂，然后将温度升高至60℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应3h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为12:4:4:3:2；
（2）将废蚕丝浸于1.5%的碳酸氢钠溶液中于100℃的煮沸溶液中处理25min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；干燥后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析5次，将透析后的溶液以4000r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为75U/mL淀粉液化芽孢杆菌蛋白酶和40U/mL的中性蛋白酶，在室温下搅拌处理1.5h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含45% PEG-400和35%十二烷基苯磺酸钠的山梨醇溶液中40min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液22份、氨基改性聚硅氧烷12份、5-硝基-1,2,3-苯三酸9份、二甲基硅油8份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌2h后甩干水分，将面料进行烘干制得产品。
所述引发剂为过硫酸钠。
实施例2
一种免烫全棉面料的制备方法，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在100r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌10min后，加入三（二甲胺基丙基）胺和引发剂，然后将温度升高至50℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应2h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为8:3:2:1:1；
（2）将废蚕丝浸于1%的碳酸氢钠溶液中于100℃的煮沸溶液中处理20min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；干燥后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析4次，将透析后的溶液以3000r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为50U/mL淀粉液化芽孢杆菌蛋白酶和30U/mL的中性蛋白酶，在室温下搅拌处理1h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含30% PEG-400和20%十二烷基苯磺酸钠的山梨醇溶液中30min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液15份、氨基改性聚硅氧烷8份、5-硝基-1,2,3-苯三酸6份、二甲基硅油5份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌1-3h后甩干水分，将面料进行烘干制得产品。
所述引发剂为过硫酸铵。
实施例3
一种免烫全棉面料的制备方法，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在120r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌12min后，加入三（二甲胺基丙基）胺和引发剂，然后将温度升高至55℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应2.5h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为10:3.5:3:2:1.5；
（2）将废蚕丝浸于1.2%的碳酸氢钠溶液中于100℃的煮沸溶液中处理22min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；干燥后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析5次，将透析后的溶液以3500r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为60U/mL淀粉液化芽孢杆菌蛋白酶和35U/mL的中性蛋白酶，在室温下搅拌处理1.2h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含40% PEG-400和30%十二烷基苯磺酸钠的山梨醇溶液中35min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液20份、氨基改性聚硅氧烷10份、5-硝基-1,2,3-苯三酸8份、二甲基硅油6份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌1.2h后甩干水分，将面料进行烘干制得产品。
所述引发剂为过硫酸钾。
实施例4
一种免烫全棉面料的制备方法，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在200r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌20min后，加入三（二甲胺基丙基）胺和引发剂，然后将温度升高至50-70℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应4h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为15:5:6:5:3；
（2）将废蚕丝浸于2%的碳酸氢钠溶液中于100℃的煮沸溶液中处理30min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；干燥后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析6次，将透析后的溶液以5000r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为50-100U/mL淀粉液化芽孢杆菌蛋白酶和50U/mL的中性蛋白酶，在室温下搅拌处理2h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含60% PEG-400和50%十二烷基苯磺酸钠的山梨醇溶液中50min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液30份、氨基改性聚硅氧烷16份、5-硝基-1,2,3-苯三酸12份、二甲基硅油10份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌3h后甩干水分，将面料进行烘干制得产品。
所述引发剂为过硫酸铵。
将本发明制得的面料进行以下性能测试，
弹性指标：ASTM D 3107—2003《弹力纱制织物伸展性能的标准试验方法》；
断裂强力：ASTM D 5035- 2003《纺织织物断裂强力和伸长的标准试验方法(条样法)》；
缩水率：AATCC 135- 2004《织物经家庭洗涤后的尺寸变化》；
撕破强力：《冲击摆锤方法测定撕破强力(埃尔门多夫)》；
平整度：AATCC 124- 2006《重复家庭洗涤后织物的外观》。
测试结果如表1所示，从表1中得出，本发明制得的面料缩水率低，水洗后稳定性良好，同时面料具有良好的恢复性和平整度，不易折皱，该面料易于打理、穿着舒适，因此作为一种免烫面料具有广泛的前景。
表1
Claims (4)
1.一种免烫全棉面料的制备方法，其特征在于，包括以下步骤：
（1）在圆底烧瓶中加入体积比为1:1的乙醇/水溶液，将面料置于溶液中浸没到液面以下，在100-200r/min转速的搅拌状态下依次加入聚乙二醇甲基丙烯酸酯、三乙胺、CuBr，搅拌10-20min后，加入三（二甲胺基丙基）胺和过硫酸铵，然后将温度升高至50-70℃，向反应体系中充入氮气使得反应在无氧条件下进行，保持此温度反应2-4h，将反应温度自然降至室温，取出织物并对其进行水洗烘干，即得大分子接枝面料；其中聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三(二甲胺基丙基)胺和过硫酸铵的摩尔比为（8-15）:（3-5）:（2-6）:（1-5）:（1-3）；
（2）将废蚕丝浸于1-2%的碳酸氢钠溶液中于100℃的煮沸溶液中处理20-30min后，将反应物用水进行清洗得到固体产物，于60℃的烘箱中烘干；烘干后的固体物加入60-65℃的9.3M的饱和溴化锂溶液中进行溶解，然后将其装入透析袋中进行透析，每隔2-3h换一次水，共透析4-6次，将透析后的溶液以3000-5000r/min的离心转速进行离心，收集上清液；向上清液中加入最终活力浓度为50-100U/mL淀粉液化芽孢杆菌蛋白酶和30-50U/mL的中性蛋白酶，在室温下搅拌处理1-2h，然后将溶液用截留分子量为10K的超滤管进行离心，收集离心出的液体，即得丝素蛋白水解液；
（3）将步骤（1）制得的大分子接枝面料浸入含30-60% PEG-400和20-50%十二烷基苯磺酸钠的山梨醇溶液中30-50min，然后甩干面料表面的水分；
（4）将步骤（2）制得的丝素蛋白水解液15-30份、氨基改性聚硅氧烷8-16份、5-硝基-1,2,3-苯三酸6-12份、二甲基硅油5-10份进行混合得到混合液，将步骤（3）处理后的面料浸入混合液中，搅拌1-3h后甩干水分，将面料进行烘干制得产品。
2.根据权利要求1所述的一种免烫全棉面料的制备方法，其特征在于，所述聚乙二醇甲基丙烯酸酯、三乙胺、CuBr、三（二甲胺基丙基）胺和过硫酸铵的摩尔比为12:4:4:3:2。
3.根据权利要求1所述的一种免烫全棉面料的制备方法，其特征在于，所述淀粉液化芽孢杆菌蛋白酶和中性蛋白酶的最终活力分别为75U/mL和40U/mL。
4.根据权利要求1所述的一种免烫全棉面料的制备方法，其特征在于，所述步骤（4）中丝素蛋白水解液22份、氨基改性聚硅氧烷12份、5-硝基-1,2,3-苯三酸9份、二甲基硅油8份。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810862816.3A CN109137514B (zh) | 2018-08-01 | 2018-08-01 | 一种免烫全棉面料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810862816.3A CN109137514B (zh) | 2018-08-01 | 2018-08-01 | 一种免烫全棉面料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109137514A CN109137514A (zh) | 2019-01-04 |
| CN109137514B true CN109137514B (zh) | 2021-11-19 |
Family
ID=64798878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810862816.3A Expired - Fee Related CN109137514B (zh) | 2018-08-01 | 2018-08-01 | 一种免烫全棉面料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109137514B (zh) |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7922929B2 (en) * | 2007-01-22 | 2011-04-12 | The Hong Kong Polytechnic University | Cellulosic fabric with silk peptide/building block nanopolymer |
| CN101982601B (zh) * | 2010-10-18 | 2012-02-22 | 南通曙光染织有限公司 | 一种生态免烫全棉高档面料制备方法 |
| CN102964544B (zh) * | 2012-11-02 | 2014-11-05 | 中科院广州化学有限公司 | 水分散性可交联型含氟聚合物及在制备超双疏表面的应用 |
| CN103613652B (zh) * | 2013-11-15 | 2015-12-30 | 苏州大学 | 一种丝素蛋白的提纯方法 |
| CN103696255B (zh) * | 2013-12-11 | 2015-12-30 | 际华三五零九纺织有限公司 | 用电子束辐射快速固化交联剂实现纯棉织物免烫整理方法 |
| CN104047159B (zh) * | 2014-06-25 | 2016-02-17 | 江苏东源纺织科技实业有限公司 | 一种全棉针织面料的生产工艺 |
| CN104294594B (zh) * | 2014-09-19 | 2016-05-18 | 苏州大学 | 一种拒水拒油超疏织物表面的制备方法 |
| CN105544209B (zh) * | 2016-01-21 | 2018-02-09 | 徐岩军 | 一种以丝素蛋白为媒介的织物后整理工艺 |
| CN106223080A (zh) * | 2016-07-27 | 2016-12-14 | 刘慧宝 | 一种新型环保耐高温染色渗透剂 |
-
2018
- 2018-08-01 CN CN201810862816.3A patent/CN109137514B/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN109137514A (zh) | 2019-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102828393B (zh) | 纯棉或涤棉织物的免烫整理方法 | |
| CN112813708B (zh) | 一种纤维素纺织品活性染料无盐少水循环染色的方法 | |
| CN1963012A (zh) | 一种防皱整理保护剂及用其对织物进行防皱整理的方法 | |
| CN104562386B (zh) | 一种新型免烫纺织品及其制备方法 | |
| CN104762821A (zh) | 一种蚕丝织物的免烫整理方法 | |
| CN106592224A (zh) | 一种衬衫的耐磨型免烫整理液及其整理方法 | |
| CN110273302B (zh) | 一种多功能超细纤维合成革的制备方法 | |
| CN1189617C (zh) | 纯棉织物免烫整理方法 | |
| CN112281496A (zh) | 一种棉氨纶针织品凉爽仿丝面料的染整方法 | |
| CN112281522A (zh) | 一种机可洗羊绒衫的生产方法 | |
| CN112921653B (zh) | 一种纤维素纤维织物亲水高强力保留的抗皱整理方法 | |
| CN109137514B (zh) | 一种免烫全棉面料及其制备方法 | |
| CN108797113B (zh) | 一种羊毛织物的耐久褶裥生产工艺 | |
| Drake JR et al. | Imparting crease resistance and crease retention to cotton with APO | |
| CN113605114A (zh) | 一种丝巾及其加工工艺 | |
| CN113789650A (zh) | 一种基于接枝聚合的涤纶织物抗静电整理方法 | |
| CN110219172B (zh) | 一种高挂干外观免烫面料及其制备方法 | |
| CN105256587A (zh) | 一种新型无甲醛低损伤抗皱整理剂及其整理方法 | |
| US3542505A (en) | Treatment of textiles with aziridine-modified polyurethanes | |
| KR940011788B1 (ko) | 직물 처리 방법 | |
| US5135541A (en) | Flame retardant treatment of cellulose fabric with crease recovery: tetra-kis-hydroxy-methyl phosphonium and methylolamide | |
| CN113756092A (zh) | 一种耐水洗抗菌面料及其制备方法 | |
| CN111826958A (zh) | 提升树脂整理折皱回复角的整理方法 | |
| CN112647293A (zh) | 一种高效持久抗菌面料及其制备方法 | |
| US2904388A (en) | Composition and process for crease-and wrinkleproofing cellulosic textile material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20211022 Address after: 310051 floor 15, huannuo building, 1568 South Ring Road, Changhe street, Binjiang District, Hangzhou, Zhejiang Applicant after: Zhejiang xuanri Technology Co.,Ltd. Address before: 215011 No.153 Shuyuan Road, high tech Zone, Suzhou City, Jiangsu Province Applicant before: SUZHOU TIANAO SPECIAL EMBROIDERY Co.,Ltd. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: The invention relates to a non ironing cotton fabric and a preparation method thereof Effective date of registration: 20220506 Granted publication date: 20211119 Pledgee: Hangzhou United Rural Commercial Bank Limited by Share Ltd. Baoshan Branch Pledgor: Zhejiang xuanri Technology Co.,Ltd. Registration number: Y2022330000645 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20211119 |