Leather substance, artificial grain layer and the processing method formed based on artificial grain layer
Technical field
The leather material of surface layer production is granulated the present invention relates to the artificial grain layer processed by very thin collagenous fiber bundle, by the people
Material.
Background technique
Leather is common product in people's daily life, currently, leather mainly includes leather and simulated leather." corium
Leather " refers to the product made of animal dermis, with the development of industry, it has been developed that the simulated leather of many forms, simulated leather
It usually uses cloth made of chemical fibre as substrate, then is covered with paint, lacquer, colour wash, etc. with PU, PVC or other resinous materials in the one side of the above substrate
Or the method for paste layer, a kind of product in appearance like leather is made, this kind of product is also referred to as: artificial leather, synthetic leather etc..
" leather " is to form tool after a series of physics and chemical process processing with the skin stripped down with animal
There is certain acidproof, alkaline-resisting, wet-hot aging performance leather.It eliminates almost all of non-fibrous material, maintains collagenous fiber bundle
Original woven condition and structure.
Say that leather is divided into two layers from level: grain layer and lamina reticularis, the collagenous fibres in grain layer and lamina reticularis
Beam either fineness degree, compactness extent and type of weave is different, and the collagenous fiber bundle of grain layer is thin, and grain layer is by subreticulate
Laminated collagenous fibres beam diameter is generally at ten microns hereinafter, grain layer is got over closer to the laminated collagenous fiber bundle of epidermis
Carefully, it knits that angle is smaller closer to the collagenous fiber bundle of epidermis in grain layer, and is gradually parallel to the surface of epidermis, fiber
It weaves also even closer.
During processing leather, after epidermis and hair removing, grain layer surface shows roughness, likeness in form cream
Head, so grain layer is also referred to as papillaris pars, therefore, the rough shape of leather is also formed the day of leather finished product
This feature of right decorative pattern;The lamina reticularis collagenous fibres beam ratio grain layer of leather is coarse, the diameter of the collagenous fiber bundle of lamina reticularis
At 20-150 microns and braiding is close, and type of weave is generally divided into three classes: diamond weave, Curved braiding, waveform braiding, because
This lamina reticularis is to constitute and play major part and effect of the leather with mechanics strengths such as tear-proof.Grain layer and lamina reticularis
Between linked together by the collagenous fiber bundle for weaving loosely, also someone is referred to as transition zone.
The component of leather is mainly collagenous fiber bundle, also containing a small amount of other elastomers, reticular fibre, sweat
Gland, blood vessel etc., therefore, the various performances of leather each depend on the grain layer in collagenous fiber bundle, especially leather to people
The compatibility of body, comfort, from extremely fine and smooth collagenous fiber bundle.The process that collagenous fiber bundle is formed is as follows: procollagen
Molecule → protofibril (diameter 1.2-1.7nm) → subfibril (diameter 3-5nm) → fibrinogen (the general 20nm of diameter) → thin
Fiber (2-5 μm of diameter) → collagenous fiber bundle (20-150 μm of diameter).
In to rawhide treatment process, due to being processed the limitation of technique, the grain layer of the leather of meeting after treatment
In there are still elastomer, reticular fibre, sweat gland, blood vessel etc..And Animal Skin all more or less have disability, while
It saves and will also result in certain defect in process, such as stab, asperities, drawn grain, loose side, dyeing defect, therefore, in order to use
Needs, most of leather needs eliminate above-mentioned defect by having a shave, make leather flatness high, smooth, easypro
It fits.
In order to preferably utilize the collagenous fiber bundle in leather, present someone discongests leather leftover pieces etc.,
It is recycled after combing.Collagenous fiber bundle has the characteristics that the more to comb the more thin shorter, and the thinner collagenous fiber bundle the shorter, and branch also gets over
It is more, and merely stated that in the documents such as existing textbook, patent document, paper collagenous fiber bundle combing is imitative to that can make
The state of leather substrate, and always nobody thought or accomplished repeatedly to comb collagenous fiber bundle or by existing slurrying
The fineness that technique makes collagenous fiber bundle reach or approach leather grain layer collagenous fiber bundle carrys out making artificial grain layer, allows artificial
Grain layer and the structure of grain layer in leather and performance are extremely approximate.
In existing technology, " the similar grain layer " seen in simulated leather is made by plastic raw materials such as PU, PVC
It forms, such as discloses a kind of non-woven base of collagenous fibres in the patent document that Chinese Patent Application No. is 201210072419.9
Material surface treatment method, it is first that collagenous fibres nonwoven substrates surface fiber in homogeneous thickness processing is flat thin, reproduce one layer of class
Then grain layer successively carries out water spray light on class grain layer, makes leather lines, processing pliability and flatness, finally uses
Common process does surface color processing to class grain layer and surface is emphasized to handle.The present invention has the advantages that this method avoids often
Rule make face in substrate surface using release paper delivery medium, this product close to corium head layer effect, show leather appearance and
Character, simple process and low cost, product obtained no matter substrate or used in any material reach outlet and it is interior
The environmental requirement for selling market reaches resistance to dry, wet-milling and wipes, and the leathers physical index such as tortuous, cold-resistant complications of resistance to room temperature reaches detection
Wet friction standard 200 times, 4-5 grades of Bearable dry and wet wipe.It also discloses the class grain layer simultaneously to manufacture in accordance with the following methods: by class
Grain layer raw material is equably smoothed out with roll coater in substrate surface, mends roller roller coating 2-5g/sf with scraping for the first time, roller coating the again after doing
It is secondary, with No. 17 roller roller coating 10-20g/sf, it is obvious that the grain layer for making non-leather at present is made of chemical raw material
It forms, using this grain layer, although can copy the grain layer in leather in appearance, its comfort, environment-friendly type etc. cannot
Reach the requirement of grain layer in leather.Moreover, the collagen after never utilization on the books is discongested, combed in the prior art is fine
Dimension beam forms the collagenous fiber bundle close to leather grain layer fineness to make and the extremely approximate people of leather grain layer performance
It is granulated surface layer and its leather substance.
Summary of the invention
The first object of the present invention, which is to provide, a kind of to be formed based on the artificial grain layer processed by very thin collagenous fiber bundle
Leather substance, the structure remake artificial grain layer using the collagenous fiber bundle in leather and then form leather with bottom
Material makes performance, structure, appearance and the grain layer of leather of artificial grain layer in leather substance extremely approximate, to improve
The comfort of leather substance, compatibility are made of chemical material " grain layers " and right to solve alternative leather various at present
The defects of comfort property of human body is poor, compatibility is poor.
The second object of the present invention, which is to provide, a kind of to be formed based on the artificial grain layer processed by very thin collagenous fiber bundle
The processing method of leather substance, using the processing method, simple process and low cost, and can allow production artificial grain layer property
Energy, structure, appearance and the grain layer of leather are extremely approximate, to improve comfort, the compatibility of leather substance.It is current to solve
It is various it is alternative leather be made of chemical material " grain layer " and it is poor, compatibility is poor to the comfort property of human body the defects of.
The third object of the present invention is to provide a kind of using based on the artificial grain layer shape processed by very thin collagenous fiber bundle
At leather substance processing method made from leather substance, utilize the processing method processing the leather with artificial grain layer
The performance of artificial grain layer in material, structure, appearance and the grain layer of leather are extremely approximate, to improve relaxing for leather substance
Adaptive, compatibility.With solve alternative leather various at present be made of chemical material " grain layer " and to the comfort of human body
Can be poor, compatibility is poor the defects of.
The fourth object of the present invention be to provide it is a kind of based on processed by very thin collagenous fiber bundle artificial the inside layer,
To reach above-mentioned first purpose, the leather material that is formed based on the artificial grain layer processed by very thin collagenous fiber bundle
Material, including artificial grain layer and bottom, artificial grain layer include very thin collagenous fiber bundle, the very thin collagen in artificial grain layer is fine
Dimension beam and its branch intertwine with each other, and the fineness of the very thin collagenous fiber bundle main body in artificial grain layer is less than the master of fiber in bottom
Body.
The leather substance of above structure is logical using the collagenous fiber bundle extracted from leather or leather leftover pieces
It crosses combing and forms very thin collagenous fiber bundle, the fineness of the very thin collagenous fiber bundle is less than the collagenous fiber bundle of production lamina reticularis at present
Fineness, by repeatedly comb and/or existing pulping process make collagenous fiber bundle reach or approach the fineness of leather grain layer come
Making artificial grain layer, the very thin collagenous fiber bundle and its branch allowed in artificial grain layer are intertwine with each other, and allow artificial grain layer
Leather substance is formed in conjunction with bottom, the people is granulated collagenous fiber bundle of the raw material sources of surface layer in leather, and non-existing
The plastic chemistries raw material such as PU, PVC in technology, therefore, artificial grain layer in leather substance such as comfort, compatibility, thoroughly
The performances such as gas, hygroscopicity, structure, appearance and the grain layer in leather are extremely approximate, and it is equal to solve alternative leather various at present
It is made of chemical material " grain layer " and causes that comfort property is poor, compatibility is poor, permeability is poor, moisture pick-up properties difference etc. lacks
It falls into.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
Further, artificial grain layer and bottom are compounded to form by gluing.The simple process, and its performance and leather
It is extremely approximate.
Further, entanglement someone is granulated very thin collagenous fiber bundle and its branch in surface layer on bottom.Due to the bottom of at
Tangling in layer has very thin collagenous fiber bundle and its branch, therefore, makes the bond strength of bottom and artificial grain layer higher, so that skin
The mechanical property for removing from office material is good.
Further, bottom is woven fabric, knitted fabric or non-woven cloth.
Further, enhancement layer is equipped between artificial grain layer and bottom.Since artificial grain layer is with very thin collagen
Fibre bundle is formed and intertwineing with each other, if tension is not achieved in bottom when the performances such as splitting, it is whole to improve to need to increase enhancement layer
The tension of a leather substance such as splits at the performances.
Further, the enhancement layer is woven fabric, knitted fabric or non-woven cloth.
Further, artificial grain layer distinguishes networking overlapping by the very thin collagenous fiber bundle of two layers or more of different fineness
Very thin collagenous fiber bundle and its branch is set to intertwine with each other to be formed together, artificial grain layer is from bottom to the one side far from bottom
The fineness of very thin collagenous fiber bundle is gradually reduced.Using this structure, grain in the structure and leather of artificial grain layer is allowed
The structure of layer is extremely approximate, simultaneously as the thickness of very thin collagenous fiber bundle successively changes, on the one hand improves artificial grain layer
Intensity, on the other hand allow artificial grain layer surface more fine and smooth, comfortable.
To reach above-mentioned second purpose, a kind of leather formed based on the artificial grain layer processed by very thin collagenous fiber bundle
The processing method of material, includes the following steps:
(1) very thin collagenous fiber bundle is made;
(2) the very thin collagenous fiber bundle networking of production is utilized;
(3) leather substance including artificial grain layer and bottom is processed by water jet process, artificial grain layer includes fibre
Thin collagenous fiber bundle, very thin collagenous fiber bundle and its branch in artificial grain layer are intertwine with each other, very thin in artificial grain layer
The fineness of collagenous fiber bundle main body is less than the main body of fiber in bottom.
Above-mentioned processing method, by by animal dermis leather or animal dermis remove from office leftover pieces by discongest, repeatedly combing and/or
The step of the step of the step of existing pulping process forms very thin collagenous fiber bundle, networking and spun lacing, forms leather material of the invention
Material, therefore, simple process and low cost.
The leather substance formed by above-mentioned processing method is passed through using the collagenous fiber bundle extracted from leather
Combing forms very thin collagenous fiber bundle and is fabricated to artificial grain layer, allows very thin collagenous fiber bundle and its branch in artificial grain layer
It intertwine with each other, and artificial grain layer is allowed to form leather substance in conjunction with bottom, the people is granulated the raw material sources and leather of surface layer
In collagenous fiber bundle, rather than the plastic chemistries raw material such as PU, PVC in the prior art, therefore, the artificial grain in leather substance
Such as comfort of layer, compatibility, gas permeability, hygroscopicity performance, structure, appearance and the grain layer in leather are extremely approximate,
Moreover, the artificial grain layer of the structure is compared with existing emulation grain layer, since very thin collagenous fiber bundle and its branch mutually twine
Knot, therefore the people is granulated surface layer and splits in tension, is higher than existing emulation grain layer in the performances such as intensity, solves current various generations
It is made of chemical material " grain layer " with leather and causes that comfort property is poor, compatibility is poor, permeability is poor, moisture pick-up properties
The defects of poor.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
Further, the step of making very thin collagenous fiber bundle are as follows:
A. raw material screening: various animal dermis is selected to remove from office or animal dermis leather leftover pieces;
B. liquid defibering: collagenous fiber bundle point is carried out by be put into the fiber uncoiling machine for fill liquid by the raw material for the processing that eases back
Solution is extracted;
C. it drains shredding: water extrusion is made into collagenous fiber bundle by drying press by the collagenous fiber bundle decomposited in b step
In moisture content between 35%-40%, pre- shredding is carried out to collagenous fiber bundle by the opener of weaving;
D. it dries: natural drying, vacuum drying or heated-air drying will be passed through by the collagenous fiber bundle of pre- shredding in step c
The method collagenous fiber bundle good to the above shredding be dried.
E. it combs: above together combing and/or existing slurrying is carried out to the collagenous fiber bundle in Step d by carding machine
Technique makes the continuous longitudinal splitting of collagenous fiber bundle obtain very thin collagenous fiber bundle.
Pre- shredding is carried out to collagenous fiber bundle, can allow collagenous fiber bundle is more thorough to become very thin collagenous fiber bundle.
Further, networking is carried out to very thin collagenous fiber bundle using wet-laying or dry laying processes.
Further, the manufacturing process of step (3) are as follows: very thin glue is allowed by water jet process after very thin collagenous fiber bundle networking
Fibrinogen beam and its branch intertwine with each other to form artificial grain layer, then the side that the bottom made is compound by gluing
Formula forms leather substance in conjunction with artificial grain layer.
Further, the manufacturing process of step (3) are as follows: the bottom made is provided, very thin collagenous fiber bundle is spread
Be located on bottom or be laid with very thin collagenous fiber bundle then be laid with bottom, then by water jet process allow very thin collagenous fiber bundle and
Its branch intertwine with each other in artificial grain layer itself, meanwhile, the very thin collagenous fiber bundle in part and its branch are entangled on bottom.
In this way, very thin collagenous fiber bundle and its branch can be entangled on bottom, the intensity of the leather substance is allowed to be improved.
Further, the manufacturing process of step (3) are as follows: by the textile fabric place Min layers of very thin collagenous fiber bundle and bottom
If then allow very thin collagenous fiber bundle and its branch to intertwine with each other in artificial grain layer itself by water jet process, meanwhile, portion
Very thin collagenous fiber bundle and its branch is divided to be entangled on bottom.In this way, allowing very thin collagenous fiber bundle and its branch that can be entangled to bottom
On layer, the intensity of the leather substance is allowed to be improved.
Further, the very thin collagenous fiber bundle for being overlapped laying different thicknesses up and down by more than two lappers is formed
Two layers or more of very thin collagenous fiber bundle layer, then forms artificial grain net by water jet process, makes one to be granulated surface layer from bottom
Fineness to the very thin collagenous fiber bundle of the one side far from bottom is gradually reduced.The artificial grain layer formed by the technique, allows
The thickness of very thin collagenous fiber bundle of the one side of artificial grain layer to another side is tapered, and allows the structure of artificial grain layer and true
The structure of grain layer in leather is extremely approximate, simultaneously as the thickness of very thin collagenous fiber bundle successively changes, on the one hand improves
On the other hand the intensity of artificial grain layer allows artificial grain layer surface more fine and smooth, comfortable.
To reach above-mentioned third purpose, a kind of leather formed based on the artificial grain layer processed by very thin collagenous fiber bundle
Material is made using the processing method of the above-mentioned leather substance formed based on the artificial grain layer processed by very thin collagenous fiber bundle
The leather substance that the artificial grain layer formed and bottom are collectively formed is intertwine with each other by very thin collagenous fiber bundle and its branch, it is artificial
The fineness of very thin collagenous fiber bundle main body in grain layer is less than the main body of fiber in bottom.
The leather substance formed by above-mentioned processing method is passed through using the collagenous fiber bundle extracted from leather
Combing forms very thin collagenous fiber bundle and is fabricated to artificial grain layer, allows very thin collagenous fiber bundle and its branch in artificial grain layer
It intertwine with each other, and artificial grain layer is allowed to form leather substance in conjunction with bottom, the people is granulated the raw material sources of surface layer in leather
In collagenous fiber bundle, rather than the plastic chemistries raw material such as PU, PVC in the prior art, therefore, the artificial grain in leather substance
Such as comfort of layer, compatibility, gas permeability, hygroscopicity performance, structure, appearance and the grain layer in leather are extremely approximate,
Moreover, the artificial grain layer of the structure is compared with existing emulation grain layer, since very thin collagenous fiber bundle and its branch mutually twine
Knot, therefore the people is granulated surface layer and splits in tension, is higher than existing emulation grain layer in the performances such as intensity, solves current various generations
It is made of chemical material " grain layer " with leather and causes that comfort property is poor, compatibility is poor, permeability is poor, moisture pick-up properties
The defects of poor.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
It is further, a kind of based on the artificial grain layer processed by very thin collagenous fiber bundle, including very thin collagenous fiber bundle,
Very thin collagenous fiber bundle and its branch intertwine with each other, and the main fineness of very thin collagenous fiber bundle is less than 15 μm.
The artificial grain layer of above structure utilizes the collagenous fiber bundle extracted from leather or leather leftover pieces
Very thin collagenous fiber bundle is formed by combing, which makes glue by repeatedly combing and/or existing pulping process
The fineness that fibrinogen beam reaches or approaches leather grain layer carrys out making artificial grain layer, allows very thin collagen in artificial grain layer
Fibre bundle and its branch intertwine with each other, and the people is granulated collagenous fiber bundle of the raw material sources of surface layer in leather, and non-existing
The plastic chemistries raw material such as PU, PVC in technology, therefore, in artificial grain layer such as comfort, compatibility, gas permeability, hygroscopicity
Etc. performances, structure, appearance and the grain layer in leather are extremely approximate, solve at present it is various it is alternative leather be by chemical material
Manufactured " grain layer " and cause the defects of comfort property is poor, compatibility is poor, permeability is poor, moisture pick-up properties is poor.
Detailed description of the invention
Fig. 1 is the schematic diagram that the present inventor is granulated surface layer.
Fig. 2 is the side schematic view that the present inventor is granulated surface layer.
Fig. 3 is the schematic diagram of very thin collagenous fiber bundle.
Fig. 4 is the schematic diagram of the first structure of leather substance.
Fig. 5 is the schematic diagram of second of structure of leather substance.
Fig. 6 is the schematic diagram of the third structure of leather substance.
Specific embodiment
The present invention will be described in further detail with reference to the accompanying drawings and detailed description.
Embodiment 1.
As shown in Figures 1 to 4, the leather substance formed based on the artificial grain layer processed by very thin collagenous fiber bundle includes
Artificial grain layer 100 and the bottom 2 combined with artificial grain layer 100, artificial grain layer 100 include very thin collagenous fiber bundle 200,
Very thin collagenous fiber bundle 200 and its branch 201 in artificial grain layer 100 are intertwine with each other, the very thin glue in artificial grain layer 100
The fineness of fibrinogen beam main body is less than the main body of fiber in bottom, and the fineness of very thin collagenous fiber bundle main body is less than 15um.
It can be also possible to have weight percent in artificial grain layer in artificial grain layer with all very thin collagenous fiber bundles
For 50% or more very thin collagenous fiber bundle, others are other fibers in addition to very thin collagenous fiber bundle.
In the present embodiment, artificial grain layer 100 is compounded to form with bottom 2 by gluing.Bottom 2 is woven fabric, knitting
Object or non-woven cloth.
Processing method based on the leather substance that the artificial grain layer processed by very thin collagenous fiber bundle is formed are as follows:
(1) very thin collagenous fiber bundle 200 is made.Specific step:
A. raw material screening: various animal dermis is selected to remove from office or leather leftover pieces.
B. the processing that eases back is carried out to the raw material of screening: rotary drum will be put into after the raw material shearing in step a, then according to raw material
Water is added in humidity, so that the water content of raw material is reached 65%-75%, can be added in a little leather industries in the water of addition and commonly return
Emulsifier used in humectant, softening treasured and leather industry.
C. liquid defibering: collagenous fiber bundle point is carried out by be put into the fiber uncoiling machine for fill liquid by the raw material for the processing that eases back
Solution is extracted;The fiber uncoiling machine is existing equipment, be may also be referred to as liquid opening machine, then this is repeated no more.
D. it drains shredding: water extrusion is made into collagenous fiber bundle by drying press by the collagenous fiber bundle decomposited in step c
In moisture content between 35%-40%, pre- three to five road of shredding is carried out to collagenous fiber bundle by the opener of weaving.?
In the present invention, drying press is existing equipment.
E. it dries: natural drying, vacuum drying or heated-air drying will be passed through by the collagenous fiber bundle of pre- shredding in Step d
The method collagenous fiber bundle good to the above shredding be dried.
F. it combs: the combing above together is carried out to the collagenous fiber bundle in step e by the roller and clearer card of wool spinning
And/or existing pulping process, so that the continuous longitudinal splitting of collagenous fiber bundle is obtained very thin collagenous fiber bundle, in carding process to the greatest extent
Amount reduces the transverse breakage of collagenous fiber bundle, is maximally maintained the length of collagenous fiber bundle, to reach this requirement, per pass
The needle cloth of machine, cylinder, working roll used in combing will gradually become smaller from width.
(2) the very thin collagenous fiber bundle networking of production is utilized;In utilizing very thin collagenous fiber bundle net process, due to fibre
Thin collagenous fiber bundle is thin and short, is difficult to realize with dry-lay techniques, it is therefore preferable that wet-laying, is also not exclusively by certainly
Dry-laying.
(3) after very thin collagenous fiber bundle networking, very thin collagenous fiber bundle and its branch are intertwine with each other by water jet process
Form artificial grain layer.In this step, 2 to 5 road spun lacings are generally carried out, spun lacing pressure cannot be too high, and per pass spun lacing pressure is answered
10 between 60bar.
Then artificial grain layer obtained is compounded to form leather substance by gluing with the bottom made.
Above-mentioned processing method, by by animal dermis leather or leather leftover pieces by discongest, repeatedly combing and/or it is existing
Pulping process forms the step of the step of the step of very thin collagenous fiber bundle, networking and spun lacing and forms leather substance of the invention,
Therefore, simple process and low cost.It is that collagenous fiber bundle is allowed to be more easier to be discongested out to the raw material processing that ease back, to glue
The pre- shredding of fibrinogen Shu Jinhang can allow collagenous fiber bundle is more thorough to become very thin collagenous fiber bundle.
The leather substance formed by above-mentioned processing method is passed through using the collagenous fiber bundle extracted from leather
Repeatedly combing or/and pulping process form very thin collagenous fiber bundle and are fabricated to artificial grain layer, allow very thin in artificial grain layer
Collagenous fiber bundle and its branch intertwine with each other, and artificial grain layer is allowed to form leather substance in conjunction with bottom, and the people is granulated surface layer
Collagenous fiber bundle of the raw material sources in leather, rather than the plastic chemistries raw material such as PU, PVC in the prior art, therefore, skin
Remove from office such as comfort of artificial grain layer in material, compatibility, gas permeability, hygroscopicity performance, structure, in appearance and leather
Grain layer it is extremely approximate, moreover, the artificial grain layer of the structure is compared with existing emulation grain layer, due to very thin collagenous fibres
Beam and its branch intertwine with each other, therefore the people is granulated surface layer and splits in tension, is higher than existing emulation grain layer in the performances such as intensity,
Solving alternative leather various at present is made of chemical material " grain layer " and causes that comfort property is poor, compatibility is poor, saturating
The defects of gas performance is poor, moisture pick-up properties is poor.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
Alternatively embodiment can also be mixed into artificial grain layer on a small quantity except other of very thin collagenous fiber bundle are fine
Dimension and non-fibrous material, non-fibrous material can be the change for passing through the existing leather industries such as impregnation acrylic acid, amino resins class
Work material.
Certainly, as shown in figure 5, the mechanical properties such as splitting to improve the tension of leather substance, can artificial grain layer 100 with
Compound one layer of enhancement layer 3 is bonded between bottom 2.The enhancement layer is woven fabric, knitted fabric or non-woven cloth.
Artificial grain layer, which can also be, distinguishes networking overlapping by the very thin collagenous fiber bundle of two layers or more of different fineness
It intertwine with each other very thin collagenous fiber bundle and its branch to be formed through water jet process together, artificial grain layer is from bottom to the bottom of far from
The fineness of the very thin collagenous fiber bundle of the one side of layer is gradually reduced.
Embodiment 2.
As shown in Fig. 1 to 3 and Fig. 6, the leather substance that is formed based on the artificial grain layer processed by very thin collagenous fiber bundle
Including artificial grain layer 100 and the bottom 2 combined with artificial grain layer 100, artificial grain layer 100 includes very thin collagenous fiber bundle
200, very thin collagenous fiber bundle 200 and its branch 201 in artificial grain layer 100 are intertwine with each other, the fibre in artificial grain layer 100
The fineness of thin collagenous fiber bundle main body is less than the main body of fiber in bottom, and the fineness of very thin collagenous fiber bundle main body is less than 15um.
It can be also possible to have weight percent in artificial grain layer in artificial grain layer with all very thin collagenous fiber bundles
For 50% or more very thin collagenous fiber bundle, others are other fibers in addition to very thin collagenous fiber bundle.
In the present embodiment, entanglement someone is granulated very thin collagenous fiber bundle 200 and its branch in surface layer on bottom 2
201.Bottom 2 is woven fabric, knitted fabric or non-woven cloth.
The processing method of leather substance based on the artificial grain layer processed by very thin collagenous fiber bundle are as follows:
(1) very thin collagenous fiber bundle 200 is made.Specific step:
A. raw material screening: various animal dermis is selected to remove from office or leather leftover pieces.
B. the processing that eases back is carried out to the raw material of screening: rotary drum will be put into after the raw material shearing in step a, then according to raw material
Water is added in humidity, so that the water content of raw material is reached 65%-75%, can be added in a little leather industries in the water of addition and commonly return
Emulsifier used in humectant, softening treasured and leather industry.
C. liquid defibering: collagenous fiber bundle point is carried out by be put into the fiber uncoiling machine for fill liquid by the raw material for the processing that eases back
Solution is extracted;The fiber uncoiling machine is existing equipment, be may also be referred to as liquid opening machine, then this is repeated no more.
D. it drains shredding: water extrusion is made into collagenous fiber bundle by drying press by the collagenous fiber bundle decomposited in step c
In moisture content between 35%-40%, pre- three to five road of shredding is carried out to collagenous fiber bundle by the opener of weaving.?
In the present invention, drying press is existing equipment.
E. it dries: natural drying, vacuum drying or heated-air drying will be passed through by the collagenous fiber bundle of pre- shredding in Step d
The method collagenous fiber bundle good to the above shredding be dried.
F. it combs: the combing above together is carried out to the collagenous fiber bundle in step e by the roller and clearer card of wool spinning
And/or existing pulping process, so that the continuous longitudinal splitting of collagenous fiber bundle is obtained very thin collagenous fiber bundle, in carding process to the greatest extent
Amount reduces the transverse breakage of collagenous fiber bundle, is maximally maintained the length of collagenous fiber bundle, to reach this requirement, per pass
The needle cloth of machine, cylinder, working roll used in combing will gradually become smaller from width.
(2) the very thin collagenous fiber bundle networking of production is utilized;First the bottom made is laid, it is then sharp on bottom
With the very thin collagenous fiber bundle networking of following methods, it is of course also possible to first with the very thin collagenous fiber bundle networking of following methods,
Then it is laid with the bottom made.
In utilizing very thin collagenous fiber bundle net process, since very thin collagenous fiber bundle is thin and short, with dry-laying skill
Art is difficult to realize, it is therefore preferable that wet-laying, is also not exclusively by dry-laying certainly.
(3) after very thin collagenous fiber bundle networking, very thin collagenous fiber bundle and its branch are intertwine with each other by water jet process
Artificial grain layer is formed, while under the action of spun lacing, very thin collagenous fiber bundle and its branch can also be entangled on bottom, be formed
Artificial grain layer and the entangled leather substance of bottom.In this way, the combination of bottom and artificial grain layer is more reliable, mention
The mechanical properties such as high intensity.In this step, 2 to 5 road spun lacings are generally carried out, spun lacing pressure cannot be too high, per pass spun lacing pressure
Power should be 10 between 60bar.
Above-mentioned processing method, by by animal dermis leather or leather leftover pieces by discongest, repeatedly combing and/or it is existing
Pulping process forms the step of the step of the step of very thin collagenous fiber bundle, networking and spun lacing and forms leather substance of the invention,
Therefore, simple process and low cost.It is that collagenous fiber bundle is allowed to be more easier to be discongested out to the raw material processing that ease back, to glue
The pre- shredding of fibrinogen Shu Jinhang can allow collagenous fiber bundle is more thorough to become very thin collagenous fiber bundle.
The leather substance formed by above-mentioned processing method is passed through using the collagenous fiber bundle extracted from leather
Repeatedly combing or/and pulping process form very thin collagenous fiber bundle and are fabricated to artificial grain layer, allow very thin in artificial grain layer
Collagenous fiber bundle and its branch intertwine with each other, and artificial grain layer is allowed to form leather substance in conjunction with bottom, and the people is granulated surface layer
Collagenous fiber bundle of the raw material sources in leather, rather than the plastic chemistries raw material such as PU, PVC in the prior art, therefore, skin
Remove from office such as comfort of artificial grain layer in material, compatibility, gas permeability, hygroscopicity performance, structure, in appearance and leather
Grain layer it is extremely approximate, moreover, the artificial grain layer of the structure is compared with existing emulation grain layer, due to very thin collagenous fibres
Beam and its branch intertwine with each other, therefore the people is granulated surface layer and splits in tension, is higher than existing emulation grain layer in the performances such as intensity,
Solving alternative leather various at present is made of chemical material " grain layer " and causes that comfort property is poor, compatibility is poor, saturating
The defects of gas performance is poor, moisture pick-up properties is poor.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
Alternatively embodiment can also be mixed into artificial grain layer on a small quantity except other of very thin collagenous fiber bundle are fine
Dimension and non-fibrous material, non-fibrous material can be the change for passing through the existing leather industries such as impregnation acrylic acid, amino resins class
Work material.
Certainly, the mechanical properties such as split to improve the tension of leather substance, it can be between artificial grain layer 100 and bottom 2
It is bonded compound one layer of enhancement layer 3.The enhancement layer is woven fabric, knitted fabric or non-woven cloth.In process, above-mentioned
In step (2), the enhancement layer made is laid between bottom and the net as formed by very thin collagenous fiber bundle.
Artificial grain layer, which can also be, distinguishes networking overlapping by the very thin collagenous fiber bundle of two layers or more of different fineness
It intertwine with each other very thin collagenous fiber bundle and its branch to be formed through water jet process together, artificial grain layer is from bottom to the bottom of far from
The fineness of the very thin collagenous fiber bundle of the one side of layer is gradually reduced.
Embodiment 3.
It include artificial grain layer 100 based on the leather substance formed is processed by artificial grain layer as shown in Fig. 1 to 3 and Fig. 6
With the bottom 2 combined with artificial grain layer 100, artificial grain layer 100 includes very thin collagenous fiber bundle 200, artificial grain layer 100
In very thin collagenous fiber bundle 200 and its branch 201 intertwine with each other, the very thin collagenous fiber bundle main body in artificial grain layer 100
Fineness be less than the main body of fiber in bottom, the fineness of very thin collagenous fiber bundle main body is less than 15um.
It can be also possible to have weight percent in artificial grain layer in artificial grain layer with all very thin collagenous fiber bundles
For 50% or more very thin collagenous fiber bundle, others are other fibers in addition to very thin collagenous fiber bundle.
In the present embodiment, entanglement someone is granulated very thin collagenous fiber bundle 200 and its branch in surface layer on bottom 2
201.Bottom 2 is woven fabric, knitted fabric or non-woven cloth.
Processing method based on the leather substance processed by artificial grain layer are as follows:
(1) very thin collagenous fiber bundle 200 is made.Specific step:
A. raw material screening: various animal dermis is selected to remove from office or leather leftover pieces.
B. the processing that eases back is carried out to the raw material of screening: rotary drum will be put into after the raw material shearing in step a, then according to raw material
Water is added in humidity, so that the water content of raw material is reached 65%-75%, can be added in a little leather industries in the water of addition and commonly return
Emulsifier used in humectant, softening treasured and leather industry.
C. liquid defibering: collagenous fiber bundle point is carried out by be put into the fiber uncoiling machine for fill liquid by the raw material for the processing that eases back
Solution is extracted;The fiber uncoiling machine is existing equipment, be may also be referred to as liquid opening machine, then this is repeated no more.
D. it drains shredding: water extrusion is made into collagenous fiber bundle by drying press by the collagenous fiber bundle decomposited in step c
In moisture content between 35%-40%, pre- three to five road of shredding is carried out to collagenous fiber bundle by the opener of weaving.?
In the present invention, drying press is existing equipment.
E. it dries: natural drying, vacuum drying or heated-air drying will be passed through by the collagenous fiber bundle of pre- shredding in Step d
The method collagenous fiber bundle good to the above shredding be dried.
F. it combs: the combing above together is carried out to the collagenous fiber bundle in step e by the roller and clearer card of wool spinning
And/or existing pulping process, so that the continuous longitudinal splitting of collagenous fiber bundle is obtained very thin collagenous fiber bundle, in carding process to the greatest extent
Amount reduces the transverse breakage of collagenous fiber bundle, is maximally maintained the length of collagenous fiber bundle, to reach this requirement, per pass
The needle cloth of machine, cylinder, working roll used in combing will gradually become smaller from width.
(2) the very thin collagenous fiber bundle networking of production is utilized;First textile fabric used in bottom is laid, is then existed
The very thin collagenous fiber bundle networking of following methods is utilized on bottom, it is of course also possible to fine with very thin collagen first with following methods
Beam networking is tieed up, textile fabric used in bottom is then laid with.
In utilizing very thin collagenous fiber bundle net process, since very thin collagenous fiber bundle is thin and short, with dry-laying skill
Art is difficult to realize, it is therefore preferable that wet-laying, is also not exclusively by dry-laying certainly.
(3) entangled by bottom and artificial grain layer by water jet process after very thin collagenous fiber bundle networking, simultaneously
Under the action of spun lacing, very thin collagenous fiber bundle and its branch in artificial grain layer are intertwine with each other, very thin collagenous fiber bundle and
Its branch can also be entangled on bottom, form artificial grain layer and the entangled leather substance of bottom.In this way, bottom and people
The combination for being granulated surface layer is more reliable, improves the mechanical properties such as intensity.In this step, 2 to 5 road spun lacings are generally carried out.
Above-mentioned processing method, by by animal dermis leather or leather leftover pieces by discongest, repeatedly combing and/or it is existing
Pulping process forms the step of the step of the step of very thin collagenous fiber bundle, networking and spun lacing and forms leather substance of the invention,
Therefore, simple process and low cost.It is that collagenous fiber bundle is allowed to be more easier to be discongested out to the raw material processing that ease back, to glue
The pre- shredding of fibrinogen Shu Jinhang can allow collagenous fiber bundle is more thorough to become very thin collagenous fiber bundle.
The leather substance formed by above-mentioned processing method is passed through using the collagenous fiber bundle extracted from leather
Repeatedly combing or/and existing pulping process form very thin collagenous fiber bundle and are fabricated to artificial grain layer, allow in artificial grain layer
Very thin collagenous fiber bundle and its branch intertwine with each other, and artificial grain layer is allowed to form leather substance in conjunction with bottom, and the people is granulated
Collagenous fiber bundle of the raw material sources of surface layer in leather, rather than the plastic chemistries raw material such as PU, PVC in the prior art, because
This, such as comfort of the artificial grain layer in leather substance, compatibility, gas permeability, hygroscopicity performance, structure, appearance and true
Grain layer in leather is extremely approximate, moreover, the artificial grain layer of the structure is compared with existing emulation grain layer, due to very thin glue
Fibrinogen beam and its branch intertwine with each other, therefore the people is granulated surface layer and splits in tension, is higher than existing emulation in the performances such as intensity
Grain layer, solving alternative leather various at present is made of chemical material " grain layer " and causes comfort property poor, affine
The defects of property is poor, permeability is poor, moisture pick-up properties is poor.
In the prior art, collagenous fiber bundle is only fabricated to base fabric, forms alternative leather, need to lead in base fabric
The structure that the plastic materials such as PU, PVC form similar grain layer is crossed, and always nobody goes to consider by repeatedly combing and/or existing
The fineness for having pulping process that collagenous fiber bundle is made to reach or approach leather grain layer carrys out making artificial grain layer.
Alternatively embodiment can also be mixed into artificial grain layer on a small quantity except other of very thin collagenous fiber bundle are fine
Dimension and non-fibrous material, non-fibrous material can be the change for passing through the existing leather industries such as impregnation acrylic acid, amino resins class
Work material.
Certainly, the mechanical properties such as split to improve the tension of leather substance, it can be between artificial grain layer 100 and bottom 2
It is bonded compound one layer of enhancement layer 3.The enhancement layer is woven fabric, knitted fabric or non-woven cloth.In process, above-mentioned
In step (2), by the material-paving of enhancement layer between bottom and the net as formed by very thin collagenous fiber bundle.
Artificial grain layer, which can also be, distinguishes networking overlapping by the very thin collagenous fiber bundle of two layers or more of different fineness
It intertwine with each other very thin collagenous fiber bundle and its branch to be formed through water jet process together, artificial grain layer is from bottom to the bottom of far from
The fineness of the very thin collagenous fiber bundle of the one side of layer is gradually reduced.
Embodiment 4.
As depicted in figs. 1 and 2, a kind of based on the artificial grain layer processed by very thin collagenous fiber bundle, including very thin collagen
Fibre bundle 200, very thin collagenous fiber bundle 200 and its branch 201 intertwine with each other, and the main fineness of very thin collagenous fiber bundle is less than 15
μm。
The artificial grain layer of above structure utilizes the collagenous fiber bundle extracted from leather or leather leftover pieces
Very thin collagenous fiber bundle is formed by combing, which makes glue by repeatedly combing and/or existing pulping process
The fineness that fibrinogen beam reaches or approaches leather grain layer carrys out making artificial grain layer, allows very thin collagen in artificial grain layer
Fibre bundle and its branch intertwine with each other, and the people is granulated collagenous fiber bundle of the raw material sources of surface layer in leather, and non-existing
The plastic chemistries raw material such as PU, PVC in technology, therefore, in artificial grain layer such as comfort, compatibility, gas permeability, hygroscopicity
Etc. performances, structure, appearance and the grain layer in leather are extremely approximate, solve at present it is various it is alternative leather be by chemical material
Manufactured " grain layer " and cause the defects of comfort property is poor, compatibility is poor, permeability is poor, moisture pick-up properties is poor.