CN109096717A - A kind of Antielectrostatic glass fiber reinforced plastic composite material - Google Patents
A kind of Antielectrostatic glass fiber reinforced plastic composite material Download PDFInfo
- Publication number
- CN109096717A CN109096717A CN201810566761.1A CN201810566761A CN109096717A CN 109096717 A CN109096717 A CN 109096717A CN 201810566761 A CN201810566761 A CN 201810566761A CN 109096717 A CN109096717 A CN 109096717A
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- Prior art keywords
- antielectrostatic
- composite material
- fiber reinforced
- reinforced plastic
- glass fiber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of Antielectrostatic glass fiber reinforced plastic composite material, raw material includes: 50-60 parts of unsaturated polyester resin, 70-80 parts of glass fibre according to parts by weight, 60-90 parts of aluminium powder, 3.5 parts of conductive black, 1-2 parts of lubricant, 3-4 parts of wetting dispersing agent, 0.5-1 parts of catalyst.Unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.The present invention provides the present invention and provides a kind of Antielectrostatic glass fiber reinforced plastic composite material, while meeting antistatic and fire-retardant demand, and resistivity is between 106Ω~108Ω, flame retardant property meet ASTM E84Class A class requirement.
Description
Technical field
The invention belongs to glass fiber reinforced plastics composite material technical fields, and in particular to a kind of Antielectrostatic glass fiber reinforced plastic composite material, especially
It is a kind of anti-electrostatic flame-retarded glass fibre reinforced plastics composite material.
Background technique
Present country's glass fiber reinforced plastics composite material reaches its maturity with transmission of electricity industry and rail traffic high speed development, cable bridge
Demand have stimulated the development of Lightweight high-strength composite material, the present universal insulating materials of cable bridge product significantly, the present invention mentions
For a kind of anti-electrostatic flame-retarded glass fibre reinforced plastics composite material.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, it is compound that the present invention provides a kind of Antielectrostatic glass fiber reinforced plastic
Material, while meeting antistatic and fire-retardant demand, resistivity is between 106Ω~108Ω, flame retardant property meet ASTM E84Class
A class requirement.
Technical solution: to achieve the above object, the present invention adopts the following technical scheme:
A kind of Antielectrostatic glass fiber reinforced plastic composite material, raw material include: according to parts by weight
Further, the unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.
Further, the oil factor of the conductive black is 300-350cc/100g.
Further, the glass fibre is specially ECR glass fibre；The tensile strength 2300- of impregnated glass fibre
2700Mpa and extension at break are stretch modulus 40-45Gpa.
Further, the lubricant is microcrystalline wax, butyl stearate and polyethylene wax according to weight ratio 3:(3-5):
The mixture of (1-3) composition.
Further, the wetting dispersing agent is lipophilicity.
Further, the catalyst is methyl isobutyl ketone peroxide and the ethylhexanoate tert-butyl ester according to weight
Than the mixture of 1:1 composition.
Unsaturated polyester resin is most common one kind in thermosetting resin, it is by monounsaturated dicarboxylic acid, unsaturated binary
Line polymer made of acid and dihydric alcohol polycondensation, diluted by cross-linking monomer or active solvent to be formed with certain viscosity
Resin solution, abbreviation UPR.The relative density of unsaturated polyester resin at 1.11~1.20 or so, solidification cubical contraction compared with
Greatly, some physical properties of solidified resin are as follows: heat resistance, mechanical property be strong, chemical corrosion resistance and dielectric properties are good.
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, and advantage is that good insulating, heat resistance are strong, anticorrosive
The good, high mechanical strength of property, glass fibre are typically used as the reinforcing material in composite material, electrically insulating material and adiabatic heat-insulation material
Material, the national economy every field such as circuit substrate.Glass fibre as reinforced plastics supporting material in application, maximum feature
It is that tensile strength is big.Tensile strength is 6.3~6.9g/d, 5.4~5.8g/d of moisture state in normal conditions.Density 2.54g/
cm3.It is heat-resist, intensity is not influenced when temperature is up to 300 DEG C, has excellent electrical insulating property, is advanced electrically insulating material,
For heat-insulating material and fire-proof shield material.
Aluminium powder is light, and floating force is high, and strong covering power is good to the reflecting properties of light and heat.It is dispersed in and carries intracorporal aluminium powder
Float occurs, the result of movement always makes itself parallel with by the ground of carrier coating, forms continuous aluminium powder layer, and
And this aluminium powder layer multilayer parallel in carrier film arranges.Hole between each layer aluminium powder is mutually staggered, and has cut off carrier film
Capillary micropore, extraneous moisture, gas can not reach ground through pore, and this feature is exactly the good physical shielding of aluminium powder
Property.
Lubricant can also play melting promotor, prevent adhesion and antistatic agent, slipping agent etc. are made other than improving mobility
With.
The utility model has the advantages that a kind of Antielectrostatic glass fiber reinforced plastic composite material of the invention has following excellent compared with prior art
Gesture: the present invention provides a kind of Antielectrostatic glass fiber reinforced plastic composite material, while meeting antistatic and fire-retardant demand, and resistivity is between 106
Ω~108Ω, flame retardant property meet ASTM E84Class A class requirement.
Specific embodiment
Below with reference to embodiment, the present invention will be further explained.
Embodiment 1
Raw material includes: according to parts by weight
Wherein, unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.
Preferably, the oil factor of the conductive black is 300-350cc/100g.
Preferably, the glass fibre is specially ECR glass fibre；The tensile strength 2300- of impregnated glass fibre
2700Mpa and extension at break are stretch modulus 40-45Gpa
Preferably, the lubricant is what microcrystalline wax, butyl stearate and polyethylene wax were formed according to weight ratio 3:3:1
Mixture.
Preferably, the wetting dispersing agent is lipophilicity.
Preferably, catalyst is methyl isobutyl ketone peroxide and the ethylhexanoate tert-butyl ester according to weight ratio 1:1
The mixture of composition.
The resistivity for the anti-electrostatic flame-retarded glass fibre reinforced plastics composite material that the present embodiment is prepared is between 106Ω~108Ω, resistance
Combustion performance meets ASTM E84Class A class requirement.
Embodiment 2
Raw material includes: according to parts by weight
Wherein, unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.
Preferably, the oil factor of the conductive black is 300-350cc/100g.
Preferably, the glass fibre is specially ECR glass fibre；The tensile strength 2300- of impregnated glass fibre
2700Mpa and extension at break are stretch modulus 40-45Gpa
Preferably, the lubricant is what microcrystalline wax, butyl stearate and polyethylene wax were formed according to weight ratio 3:4:2
Mixture.
Preferably, the wetting dispersing agent is lipophilicity.
Preferably, catalyst is methyl isobutyl ketone peroxide and the ethylhexanoate tert-butyl ester according to weight ratio 1:1
The mixture of composition.
The resistivity for the anti-electrostatic flame-retarded glass fibre reinforced plastics composite material that the present embodiment is prepared is between 106Ω~108Ω, resistance
Combustion performance meets ASTM E84Class A class requirement.
Embodiment 3
Raw material includes: according to parts by weight
Wherein, unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.
Preferably, the oil factor of the conductive black is 300-350cc/100g.
Preferably, the glass fibre is specially ECR glass fibre；The tensile strength 2300- of impregnated glass fibre
2700Mpa and extension at break are stretch modulus 40-45Gpa
Preferably, the lubricant is what microcrystalline wax, butyl stearate and polyethylene wax were formed according to weight ratio 3:5:3
Mixture.
Preferably, the wetting dispersing agent is lipophilicity.
Preferably, catalyst is methyl isobutyl ketone peroxide and the ethylhexanoate tert-butyl ester according to weight ratio 1:1
The mixture of composition.
The resistivity for the anti-electrostatic flame-retarded glass fibre reinforced plastics composite material that the present embodiment is prepared is between 106Ω~108Ω, resistance
Combustion performance meets ASTM E84Class A class requirement.
Embodiment 4
Raw material includes: according to parts by weight
Wherein, unsaturated polyester resin is low viscosity resin, and the viscosity at 23 DEG C is 100~200mPa.s.
Preferably, the oil factor of the conductive black is 300-350cc/100g.
Preferably, the glass fibre is specially ECR glass fibre；The tensile strength 2300- of impregnated glass fibre
2700Mpa and extension at break are stretch modulus 40-45Gpa
Preferably, the lubricant is what microcrystalline wax, butyl stearate and polyethylene wax were formed according to weight ratio 3:3:2
Mixture.
Preferably, the wetting dispersing agent is lipophilic.
Preferably, catalyst is methyl isobutyl ketone peroxide and the ethylhexanoate tert-butyl ester according to weight ratio 1:1
The mixture of composition.
The resistivity for the anti-electrostatic flame-retarded glass fibre reinforced plastics composite material that the present embodiment is prepared is between 106Ω~108Ω, resistance
Combustion performance meets ASTM E84Class A class requirement.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (7)
1. a kind of Antielectrostatic glass fiber reinforced plastic composite material, it is characterised in that: raw material includes: according to parts by weight
2. Antielectrostatic glass fiber reinforced plastic composite material according to claim 1, it is characterised in that: the unsaturated polyester resin is
Low viscosity resin, the viscosity at 23 DEG C are 100~200mPa.s.
3. Antielectrostatic glass fiber reinforced plastic composite material according to claim 1, it is characterised in that: the oil factor of the conductive black
For 300-350cc/100g.
4. Antielectrostatic glass fiber reinforced plastic composite material according to claim 1, it is characterised in that: the glass fibre is specially
ECR glass fibre；The tensile strength 2300-2700Mpa and extension at break of impregnated glass fibre are stretch modulus 40-45Gpa.
5. Antielectrostatic glass fiber reinforced plastic composite material according to claim 1, it is characterised in that: the lubricant is microlite
Wax, butyl stearate and polyethylene wax are according to weight ratio 3:(3-5): the mixture of (1-3) composition.
6. Antielectrostatic glass fiber reinforced plastic composite material according to claim 1, it is characterised in that: the wetting dispersing agent is oleophylic
Property.
7. Antielectrostatic glass fiber reinforced plastic antenna house according to claim 1, it is characterised in that: the catalyst is methyl
The mixture that isobutyl ketone and the ethylhexanoate tert-butyl ester are formed according to weight ratio 1:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810566761.1A CN109096717A (en) | 2018-06-05 | 2018-06-05 | A kind of Antielectrostatic glass fiber reinforced plastic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810566761.1A CN109096717A (en) | 2018-06-05 | 2018-06-05 | A kind of Antielectrostatic glass fiber reinforced plastic composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109096717A true CN109096717A (en) | 2018-12-28 |
Family
ID=64796696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810566761.1A Withdrawn CN109096717A (en) | 2018-06-05 | 2018-06-05 | A kind of Antielectrostatic glass fiber reinforced plastic composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN109096717A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110054879A (en) * | 2019-04-02 | 2019-07-26 | 苏州海晨塑胶有限公司 | A kind of flame-retardant and anti-static polyester material and preparation method thereof |
| CN112778707A (en) * | 2021-02-04 | 2021-05-11 | 宜宾三江机械有限责任公司 | Dielectric isolation material with thermosetting resin as matrix and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977574A (en) * | 2012-12-04 | 2013-03-20 | 中铁八局集团电务工程有限公司 | Glass fiber reinforced plastic curing agent composition and glass fiber reinforced plastic composite material prepared by same as well as cable trough |
| CN103724926A (en) * | 2013-12-30 | 2014-04-16 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition for improving appearance and preparation method of aesthetic resin composition |
| CN108017891A (en) * | 2016-11-04 | 2018-05-11 | 无锡创达新材料股份有限公司 | A kind of anlistatig unsaturated polyester glass fibre enhancing tubular molding compound |
-
2018
- 2018-06-05 CN CN201810566761.1A patent/CN109096717A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977574A (en) * | 2012-12-04 | 2013-03-20 | 中铁八局集团电务工程有限公司 | Glass fiber reinforced plastic curing agent composition and glass fiber reinforced plastic composite material prepared by same as well as cable trough |
| CN103724926A (en) * | 2013-12-30 | 2014-04-16 | 上海锦湖日丽塑料有限公司 | Aesthetic resin composition for improving appearance and preparation method of aesthetic resin composition |
| CN108017891A (en) * | 2016-11-04 | 2018-05-11 | 无锡创达新材料股份有限公司 | A kind of anlistatig unsaturated polyester glass fibre enhancing tubular molding compound |
Non-Patent Citations (2)
| Title |
|---|
| 杨小利等: "导电复合材料的研究 ", 《玻璃钢/复合材料》 * |
| 汪水平等: "炭黑对不饱和聚酯/玻纤复合材料导电性能的影响 ", 《纤维复合材料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110054879A (en) * | 2019-04-02 | 2019-07-26 | 苏州海晨塑胶有限公司 | A kind of flame-retardant and anti-static polyester material and preparation method thereof |
| CN112778707A (en) * | 2021-02-04 | 2021-05-11 | 宜宾三江机械有限责任公司 | Dielectric isolation material with thermosetting resin as matrix and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181228 |
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| WW01 | Invention patent application withdrawn after publication |