CN109072680A - Deformable well flowering structure and formation comprising carbon nano-tube material and the method using this class formation - Google Patents

Deformable well flowering structure and formation comprising carbon nano-tube material and the method using this class formation Download PDF

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Publication number
CN109072680A
CN109072680A CN201780024797.0A CN201780024797A CN109072680A CN 109072680 A CN109072680 A CN 109072680A CN 201780024797 A CN201780024797 A CN 201780024797A CN 109072680 A CN109072680 A CN 109072680A
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CN
China
Prior art keywords
deformable
conducting element
cnt
deformable material
well
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CN201780024797.0A
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Chinese (zh)
Inventor
O·A·马兹亚
S·穆尔萨杰
V·N·哈巴斯赫斯库
D·N·文特罗
R·多洛哥
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Ge (ge) Beck Hughes Ltd
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Ge (ge) Beck Hughes Ltd
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Publication of CN109072680A publication Critical patent/CN109072680A/en
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/12Packers; Plugs
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/12Packers; Plugs
    • E21B33/1208Packers; Plugs characterised by the construction of the sealing or packing means

Abstract

Article includes: tubular part under a kind of deformable well for using in the wellbore, and the tubular part is configured to be placed in pit shaft;Deformable material, the deformable material are arranged around the outer surface of the tubular part;And conducting element, the conducting element include carbon nanotube (CNT) material for being bonded to the deformable material.In order to form article under such deformable well, deformable material is set around the outer surface of tubular part, and the conducting element comprising carbon nanotube (CNT) material is bonded to the deformable material.When in use, article under the deformable well can be located in pit shaft, and the deformable material may be expanded to swelling state.The expansion of the deformable material may make the carbon nanotube (CNT) material of the conducting element through strained, and can measure the electrical properties of the conducting element to be inferred to the information of the state about the deformable material.

Description

Deformable well flowering structure and formation comprising carbon nano-tube material and the such knot of use The method of structure
Prioity claim
15/063,034 " the DEFORMABLE of U.S. Patent Application Serial submitted this application claims on March 7th, 2016 DOWNHOLE STRUCTURES INCLUDING CARBON NANOTUBE MATERIALS, AND METHODS OF The equity of the date of application of FORMING AND USING SUCH STRUCTURES ".
Technical field
In various embodiments, the disclosure relates generally to for monitoring the deformable well flowering structure of setting in the wellbore Expansion material.More particularly, the embodiment of the disclosure is related to the carbon nanotube comprising being merged into deformable material The underground structure of material and formation and the method for using carbon nano-tube material and deformable material.
Background technique
Drilling well for oil and natural gas exploitation conventionally uses the section longitudinally extended of drilling rod or so-called " tubing string ", Larger-diameter drill bit is fixed on one end of the drilling rod.In the selected part for having drilled out pit shaft and reaming in some cases After the diameter big to the diameter than initially being drilled out with drill bit (here it is " neck eye " drill bit is referred to as), it will usually give well Cylinder is lined with or is cased with the tubing string or section of casing or bushing.Such casing or bushing show bigger than the drilling rod for drilling out pit shaft Diameter and the diameter smaller than the diameter of drill bit or the reamer for cutting-down.Conventionally, by casing or bushing tubing string After being put into pit shaft, casing or bushing tubing string be bonded in appropriate location with cement to be sealed in the outer of casing or bushing tubing string Between portion and well bore wall.
Tubulose tubing string (such as drilling rod, casing or bushing) can be (for example) by the inner wall or pit shaft of the outer wall of pipe and casing Annular space between wall is surround.Generally it is desirable that this ring-like space between the upper part and low portion of sealing well depth. The annular space can be sealed or filled with underground article (such as conformal device).Conformal device include packer, bridge plug, Sand control screen and sealant.The packer and bridge plug that can be expanded be particularly useful for seal annular space because the packer and Bridge plug can expand (for example, expansion) when being exposed to wellbore fluids, temperature in wellbore etc. and fill the cross section of annular space.
Summary of the invention
In some embodiments of the present disclosure, article includes: pipe under a kind of deformable well for using in the wellbore Shape component, the tubular part are configured to be placed in pit shaft;Deformable material, the deformable material is around the tubulose The outer surface of component is arranged;And conducting element, the conducting element include the carbon nanotube for being bonded to the deformable material (CNT) material.
The Additional embodiments of the disclosure include the method to form article under such deformable well.It for example, can be with ring Deformable material is set around the outer surface of tubular part, and can will include the conducting element key of carbon nanotube (CNT) material It is bonded to the deformable material.
The other embodiments of the disclosure include in the wellbore using the method for article under such deformable well.It can incite somebody to action Article is located in pit shaft under deformable well.Article may include tubular part, around the tubular portion under the deformable well The deformable material that the outer surface of part is arranged and the conducting element comprising carbon nanotube (CNT) material, the carbon nanotube material Material is bonded to the deformable material.The deformable material can be expanded into swelling state in the wellbore.The deformable material The expansion of material may make the carbon nanotube (CNT) material of the conducting element through strained, and can measure described The electrical properties of conducting element.The measurement result of the electrical properties can be used to be inferred to about the deformable material The information of state.
Detailed description of the invention
Although specification ends up, cum rights claim is considered as this public affairs to particularly point out and be distinctly claimed The things for the embodiment opened, but when reading in conjunction with the drawings from being described below of the exemplary implementation scheme to the disclosure The various feature and advantage of the embodiment of the disclosure can more easily be understood, in which:
The example that Fig. 1 shows pit shaft, the pit shaft include article under at least one deformable well being disposed therein;
Fig. 2A be under the deformable well similar with article under the deformable well in Fig. 1 the simplification of article and schematically The side cross-sectional view shown, article includes that the deformable material in compressive state and having is set under the deformable well The winding fiber of the CNT material therein for being in the first strain regime;
Fig. 2 B be under the deformable well in Fig. 2A the simplification of article and the side cross-sectional view that schematically shows, show The winding fiber for being in the deformable material of swelling state in pit shaft, and being provided in CNT material therein be in The second different strain regime of first strain regime;
Fig. 2 C be under the deformable well in Fig. 2 B the simplification of article and the expanded view that schematically shows;
Fig. 3 A to Fig. 3 C be include winding fiber in Fig. 2A to Fig. 2 C circuit simplification and schematically show Circuit diagram;
Fig. 4 A be under deformable well the simplification of another embodiment of article and the sectional side that schematically shows View, under the deformable well article include the deformable material in compressive state and having be disposed therein in the The winding fiber of the CNT material of one strain regime;
Fig. 4 B be under the deformable well in Fig. 3 A the simplification of article and the side cross-sectional view that schematically shows, show The winding fiber for being in the deformable material of swelling state in pit shaft, and being provided in CNT material therein be in The second different strain regime of first strain regime;
Fig. 4 C be under the deformable well in Fig. 4 B the simplification of article and the expanded view that schematically shows;
Fig. 5 A to Fig. 5 C be include winding fiber in Fig. 4 A to Fig. 4 C circuit simplification and schematically show Circuit diagram;
Fig. 6 is according to the simplification of the CNT material of another embodiment being set in deformable material and illustrates The expanded view shown to property;
Fig. 7 A to Fig. 7 C is to show to form article under deformable well as described in this article using reaction and injection molding process Simplification side cross-sectional view;
Fig. 8 A is article under the deformable well similar with article under the deformable well in Fig. 1 according to another embodiment Perspective view;
Fig. 8 B be under the deformable well in Fig. 8 A the simplification of article and the view that schematically shows;
Fig. 8 C shows the operation under the deformable well that deformable material is arranged in Fig. 8 A on the tubular part of article;
Fig. 9 A is article under the deformable well similar with article under the deformable well in Fig. 1 according to another embodiment Simplification and the view that schematically shows;
Fig. 9 B be under the deformable well in Fig. 9 A the simplification of article and the sectional view that schematically shows;And
Fig. 9 C shows the operation under the deformable well that deformable material is arranged in Fig. 9 A on the tubular part of article.
Specific embodiment
Diagram presented herein is not intended to any particular elements, the actual view of device or system, and is only for The idealization for describing implementation of the disclosure scheme indicates.Common element can keep identical numerical value between all figures.
Article under deformable well (such as inflatable (for example, conformal) packer, bridge plug and sand control screen) may include can Deformable material, the deformable material are being exposed to wellbore fluids, temperature in wellbore, the activation stream provided from the surface of subsurface formations It can expand after body etc. and the outer surface of tubular element and inner wall (the exposure table on stratum in such as pit shaft of pit shaft can be filled Face) between annular space cross section.In some cases, it may be desirable to verify the expansion of deformable material to ensure The normal function of article under deformable well.The embodiment of the disclosure can enable the user of article under deformable well true Approve that the deformable material of deformation underground article has expanded (that is, expansion) to ensure that article will be it is anticipated that rise under deformable well Effect.
Carbon nanotube (CNT) can show high conductivity.It include carbon nanotube according to the embodiment of the disclosure (CNT) conducting element of material can be bonded to the deformable material of article under deformable well, and in use, deformable material The expansion of material may make carbon nanotube (CNT) material of conducting element through strained.CNT material may result in through strained The variation of at least one electrical properties of CNT material.For example, CNT may be shown when through strained conductivity and Measurable variation of resistivity.The electrical properties of conducting element can be measured, and the survey of the electrical properties can be used Result is measured to be inferred to the information of the state about deformable material.
Fig. 1 shows the non-limiting example of wellbore system 100, and the wellbore system includes pit shaft 110, and the pit shaft passes through Subsurface formations 112 drill out and enter in a pair of of producing formation or reservoir 114,116, it is desirable to open from this producing formation or reservoir It produces hydrocarbon or extracts mineral, oil and natural gas etc. in other ways.In some embodiments, pit shaft 110 can be lined with gold Belong to casing.Many perforation 118 can be penetrated and be extended in stratum 114,116, allow Produced Liquid 121 from stratum 114, 116 flow into pit shaft 110.Pit shaft 110 can have substantially vertical supporting leg 117 and deflection or substantially horizontal supporting leg 119.Pit shaft 110 may include that the flow string being disposed therein by tubular part 122 or component (generally refer at 120 Show), the tubular part extends downwardly at ground 126 from drilling machine 124.It produces component 120 and limits inner shaft along its length To flow orifice 128.Annular space 130 can be limited between production component 120 and wellbore casing (if present) or well bore wall 132.It is raw Producing region 134 is positioned at selected location along production component 120 as shown.A pair of of packer dress can be passed through in pit shaft 110 It sets 136 each production district 134 is isolated.Although only showing three production districts 134 in Fig. 1, there may be along vertical Supporting leg 117 and horizontal support legs 119 press a large amount of such area of continuation mode arrangement.
Each production district 134 may include flow control or production volume control device 138, enter production component with control The one or more aspects of the stream of one or more fluids in 120.As used herein, term " a kind of fluid " or " a variety of streams Body " includes that liquid, gas, hydrocarbon, heterogeneous fluid, the mixture of two or more fluids, water, salt water, engineering fluid (such as bore Well mud), from ground inject fluid (such as water) and naturally occurring fluid (such as oil and natural gas).
Fig. 2A shows the packer device 136 of wellbore system 100 shown in Fig. 1.Packer device 136 is deformable well Lower article, it includes the deformable materials 150 being arranged around the outer surface of tubular part 122.Fig. 2A, which is shown, to be in initially not Expand or the deformable material 150 of compressive state, it is described do not expand or compressive state under, deformable material 150 has than well The small diameter of the diameter of the wall 132 of cylinder 110.Deformable material 150 can surround one section of the tubular part 122 in pit shaft 110. Tubular part 122 can be other tubular parts in down-hole casing or bushing tubing string, production pipeline or pipe or pit shaft 110 A part.Tubular part 122 may include multiple holes 123, and the hole is configured to make Produced Liquid 121 from stratum 114,116 Flow through production component 120.After the selected location that tubular part 122 is located in pit shaft 110, deformable material may be made Material 150 expands (for example, expansion).When not expanding state, packer device 136 is determined in initial in deformable material 150 Position in pit shaft 110, it is described do not expand state under, deformable material 150 have than pit shaft 110 wall 132 (Fig. 1) diameter Small diameter.
As shown in Figure 2 B, after the selected location that packer device 136 is located in pit shaft 110, deformable material Material expands (for example, expansion) in radial directions.In some embodiments, deformable material can be made by being exposed to wellbore fluids 150 expand and contact the wall 132 of pit shaft 110 between tubular part 122 and wall 132 formed compression, it is fluid-tight close Envelope.Therefore, the outer diameter of deformable material 150 can increase, until the wall 132 that it contacts the pit shaft 110 in subsurface formations 112 is Only.In other embodiments, pipe, casing, the inner wall of bushing or other surfaces can be around packer devices 136 circumferentially Setting, and deformable material 150 can tubular part 122 and pipe, casing, bushing inner wall or other surfaces between shape At compression, fluid-tight sealing.Therefore, once deformable material 150 expand, just substantially prevent fluid (for example, from Stratum 114,116) by annular space 130 by longitudinal stream of the outside of packer device 136 (in terms of the visual angle of Fig. 2 B, vertical On direction).
Deformable material 150, which can be formulated into before filling up annular space 130, to be expanded always.In some embodiment party In case, the diameter of pit shaft 110 may be insufficient to allow for deformable material 150 to completely return to swelling state.In addition, deformable material 150 may not equably expand (for example, expansion), because the diameter of pit shaft 110 may not be uniform.Expanding may lead The radius (measuring from tubular part 122 to the outer surface of deformable material 150) of deformable material 150 is caused to increase deformable About the 20% to about 300% of the initial radium of material 150.In some embodiments, the initial radium of deformable material 150 can It is about 1 inch and more particularly to be in about 0.5 inch (1.27cm) to about 2 inches (5.08cm) of range (2.54cm)。
Deformable material 150 may include the deformable material of any suitable type.As used herein, term is " variable Shape material " indicates and including that can expand, expand or with other at least one dimension after being exposed to subsurface environment Mode increases any material of size.Non-limiting example is enumerated, deformable material 150 may include as in following any case Described adaptive material: entitled " the Process for the Preparation of that on July 28th, 2015 promulgates (hereinafter referred to as ' 012 specially for the United States Patent (USP) 9,090,012 of Conformable Materials for Downhole Screens " Benefit);Entitled " Sand Screen, the Expandable Screen and Method of that on April 1st, 2014 promulgates The United States Patent (USP) 8,684,075 of Making ";Entitled " the Conformable Materials that on January 5th, 2016 promulgates The United States Patent (USP) of Containing Heat Transfer Nanoparticles and Devices Made Using Same " 9,228,420;And entitled " the Swellable Downhole Structures that on December 24th, 2013 submits Including Carbon Nitride Materials, and Methods of Forming and Using Such The U.S. Patent Publication No.2015/0176363 of Structures ", the complete disclosure of above each case is hereby by reference It is incorporated herein.Such adaptive material can be used in conformal sand control screen, such as be purchased from Houston on the market, TX's Baker Hughes Inc.'sConformal sand control management system.Non-limiting example, deformable material are enumerated again Material 150 may include that material is expanded as described in following any case: promulgate on 2 21st, 2012 entitled The United States Patent (USP) 8,118,092 of " Swelling Delay Cover for a Packer ";The hair that on July 24th, 2012 promulgates The United States Patent (USP) of bright entitled " Sealing Feed Through Lines for Downhole Swelling Packers " 8,225,861;Entitled " the Water Swelling Rubber Compound for submitted on September 30th, 2008 The U.S. Patent Publication No.2009/ of Use in Reactive Packers and Other Downhole Tools " 0084550;Entitled " the Enhanced Water Swellable Compositions " submitted on March 13rd, 2014 U.S. Patent Publication No.2015/0210825;Entitled " the Wrap-On Reactive that on June 6th, 2008 submits The U.S. Patent Publication No.2009/ of Element Barrier Packer and Method of Creating Same " 0139708;And entitled " the Water Swelling Rubber Compound for that on May 22nd, 2012 promulgates The United States Patent (USP) 8,181,708 of Use in Reactive Packers and Other Downhole Tools " is (hereinafter referred to as " ' 708 patent "), the complete disclosure of above each case is hereby incorporated herein by reference.
As non-limiting examples, deformable material 150 can be open-cell foam materials.The open-cell foam materials can be with Including viscoplasticity shape memory polymeric material.Such viscoplasticity shape memory polymer material can show one-way shape memory Effect.In other words, viscoplasticity shape-memory material by (for example) change material temperature, so that material is exposed to pit shaft stream Body allows material to be restored to original shape and/or big when being exposed to electro photoluminescence, chemical stimulation or another stimulation triggering It is small.
The open-cell foam materials that (for example, showing shape memory effect) can be expanded include various polymer. This quasi polymer may include polyurethane, polyamide, polyureas, polyvinyl alcohol, polyvinyl alcohol-co-vinyl base ester copolymer, phenolic aldehyde polymerization Object, polybenzimidazoles, the copolymer comprising polyoxyethylene units with and combinations thereof.It for example, include polyethylene glycol oxide list Polyethylene glycol oxide/acrylic acid/methacrylic acid copolymer that the copolymer of member includes and N, N '-methylene-bis-acrylamide are crosslinked Object, polyethylene glycol oxide/methacrylic acid/n-vinyl-2-pyrrolidone copolymerization with ethylene glycol dimethacrylate crosslinking Object and the polyethylene glycol oxide/polymethyl methacrylate/N- vinyl -2- pyrroles being crosslinked with ethylene glycol dimethacrylate Alkanone copolymer.In some embodiments, foam adaptive material may include by making polycarbonate polyol and poly- isocyanide Acid esters reacts polyurethane obtained.This quasi polymer chemically or at least can physically be crosslinked to show shape Shape remembers property.
According to the embodiment of the disclosure, tubular part 122 can be formed by high-strength material.In some embodiments In, tubular part 122 includes metal.A part of tubular part 122 may include dielectric substance.For example, shape above It may include dielectric substance at the part for the tubular part 122 for having deformable material 150.
According to the embodiment of the disclosure, packer device 136 further includes at least one conducting element 152, it is described at least One conducting element includes carbon nanotube (CNT) material for being bonded to deformable material 150.As discussed in more detail below, it leads Electric device 152, which is positioned and is configured so that, applies stress for conductive member 152 after deformable material 150 expands, Conducting element 152 is in response to the stress and through strained.
In the embodiment shown in Fig. 2A and Fig. 2 B, conducting element 152 includes the plurality of fibers for being arranged to coil.Institute State the carbon nanotube that fiber includes crosslinking.Fig. 2A and Fig. 2 B is intercepted in the plane parallel with the longitudinal axis of tubular part 122 The side cross-sectional view of packer device 136.As in figs. 2 a and 2b, coil can be orientated in deformable material 150, be made The axis 154 for obtaining coil extends and in deformable material 150 perpendicular to the longitudinal axis of tubular part 122 from tubular part 122 Extend radially outwardly.In other words, coil can be orientated in deformable material 150, so that the axis 154 of coil is along can The radius of deformable material 150 extends.Although two winding fibers are illustrated only in Fig. 2A and Fig. 2 B, in the reality of the disclosure Apply any number of winding fiber that CNT material can be used in scheme.In the embodiment of the plurality of fibers using CNT material In, winding fiber concentrically and along the length of tubular part 122 can be dispersed in deformable material around tubular part 122 In 150.
The coil for the crosslinking carbon nanotube that can be used in the embodiment of the disclosure can be by by carbon nanotube mats In pad roll and formed, be such as purchased from Tucson, those of MER Corporation of Arizona carbon nanometer in the market Pipe pad.
In some embodiments, CNT can winding fiber at least one direction each other in general alignment with.? In some embodiments, CNT can be along the length of the winding fiber of CNT material each other in general alignment with and/or deformable Material 150 expand after on the direction of the estimated strain of conducting element 172 each other in general alignment with.In other embodiments In, CNT can be randomly oriented and be dispersed in the winding fiber of CNT material.In addition, in the CNT material of conducting element 152 CNT may include single wall CNT, double-walled CNT and multi wall CNT.
In some embodiments, conducting element 152 can be set in deformable material 150.In such embodiment In, conducting element 152 can be by deformable material 150 at least substantially around (for example, entirely around).
Conducting element 152 can be covalently bonded to deformable material 150.In other words, can conducting element 152 with can Covalent atomic bond is directly provided between deformable material 150.In such configuration, in deformable material 150 from the state in Fig. 2A When the state being expanded into Fig. 2 B, the expansion of deformable material 150 may apply stress, and conducting element 152 is in response to described Stress and be subjected to stress, and conducting element 152 does not have relative to adjacent deformable material 150 along interface therebetween Very big relative displacement.In some embodiments, the CNT of the CNT material of conducting element 152 can be covalently bonded to deformable Material 150.
Packer device 136 can also include at least one electronic component 155.Fig. 2 C is summarized in fig. 2b including electricity The enlarged drawing of a part of the packer device 136 of subassembly 155.In some embodiments, at least one electronic component 155 It can be coupled to the capacitor C of conducting element 152, the conducting element may be used as inductor L, to be formed shown in Fig. 3 A LC (for example, resonance) circuit.In other embodiments, electronic device 156 may include the electricity for being coupled to conducting element 152 Device R is hindered, the conducting element may be used as inductor L, to form RL shown in Fig. 3 B (for example, resistor-inductor) electricity Road.In a further embodiment, as shown in FIG. 3 C, conducting element 152 can be coupled to capacitor C and resistor R with shape At rlc circuit.In additional embodiment, conducting element 152 can in parallel or be coupled in series to resistor and capacitor Any combination of device.Electric conductor (for example, electric wire) can be operatively coupled to conducting element 152 and electronic component 155 (for example, Capacitor or resistor).
With continued reference to Fig. 2A to Fig. 2 C, packer device 136 can also include inductive logging tool 140.Induction logging work Tool 140 can be provided in deformable material 150 and be separated by tubular part 122 with deformable material 150.Induction logging Tool 140 may include the cable 141 that ground 126 is extended to from inductive logging tool 140.Ground installation 142 (Fig. 1) can wrap It includes and is mentioned for one or more emitter coils 143 into inductive logging tool 140 with one or more receiver coils 144 For the power supply unit of electric power.In other embodiments, at power supply unit and/or launcher signal driver and receiver Managing device can be located in inductive logging tool 140.Inductive logging tool 140 may be configured to measurement conducting element 152 extremely A kind of few electrical properties (for example, conductivity, resistivity, inductance etc.).For example, inductive logging tool 140 can be in conduction Element through it is strained when measurement conducting element 152 inductance variation.
Referring to Fig. 2 C, in some embodiments, the axis 145 of emitter coil 143 and the axis of conducting element 142 154 can be it is coaxial.Emitter coil 143 and conducting element 142 can be further aligned with the hole 123 of tubular part 122. In other embodiments, emitter coil 143 and conducting element 142 can not be coaxial and/or can not be right with hole 123 It is quasi-.The diameter of conducting element 142 and/or emitter coil 143 can be less than the diameter in hole 123.For example, hole 123 is straight Diameter can be in about 0.5 inch (1.27cm) to about 2 inches (5.08cm) of range, and more particularly, be about 1 inch (2.54cm).In other embodiments, the diameter of conducting element 142 and/or emitter coil 143 can be greater than hole 123 Diameter.
The physical principle of inductive logging tool 140 is described in (for example) Doll, Introduction to Induction Logging and Application to Logging of Wells Drilled with Oil Based Mud, volume 1, 6th phase (in June, 1949), in page 148 to page 162, the disclosure of the article is integrally incorporated herein by reference In.Enumerate non-limiting example, inductive logging tool 140 can be the inductive logging tool as described in following case: 2007 Entitled " the Method and Apparatus for Internal Calibration in that on March 13, in promulgates The United States Patent (USP) 7,190,169 of Induction Logging Instruments ";The denomination of invention that on July 16th, 2013 promulgates For " Performing Downhole Measurement Using Tuned Transmitters and Untuned The United States Patent (USP) 8,487,625 of Receivers ";And entitled " the Apparatus that on December 29th, 2015 promulgates and Method for Capacitive Measuring of Sensor Standoff in Boreholes Filled The United States Patent (USP) 9 of with Oil Based Drilling Fluid ", 223,046, the complete disclosure of above each case is to draw It is incorporated herein with mode.Strain suffered by conducting element 152 may result in the induction emitted around conducting element 152 or electricity Measurable variation in magnetic field can be surveyed according to the power loss or resonance frequency measured in inductive logging tool 140 Measure the variation.
Fig. 4 A to Fig. 4 C is similar with Fig. 2A to Fig. 2 C and show can be in wellbore system (all wellbore systems as shown in figure 1 100) another embodiment of the packer device 170 used in.Packer device 170 is article under deformable well, with envelope Similar every device device 136, herein with reference to described by Fig. 2A to Fig. 2 C as before, article includes tubulose under the deformable well Component 122 and the deformable material 150 being arranged around tubular part 122.Packer device 170 further includes conducting element 152, institute State conducting element include be bonded to carbon nanotube (CNT) material of deformable material 150, and conducting element 152 by positioning and It is configured so that after deformable material 150 expands to apply conductive member 152 and strain.
Fig. 4 C is the enlarged drawing of a part for the packer device 170 summarized in Fig. 4 B.With continued reference to Fig. 4 A to Fig. 4 C, envelope Every the electronic device 156 that device device 170 can also include instead of inductive logging tool 140.Electronic device 156 can be operationally It is coupled to conducting element 152 and is configured to measure at least one electrical properties of conducting element 152 (for example, conductivity, electricity Resistance rate, inductance etc.).In some embodiments, electronic device 156 can be located in packer device 170, such as positioned at tubulose In recess or other containers in component 122.In other embodiments, electronic device 156 can be located at production component 120 In another component, such as in another connector in production component 120.In a further embodiment, electronic device 156 can be located at ground.
Electronic device 156 may include E-signal processor 158, memory device 160 and communication device 162.Packing Device device 170 can also include battery or other power supply units 164.Power supply unit 164 can be located in electronic device 156 Or it is located in deformable material 150.Packer device 170 may include being coupled to conducting element 152 and power supply unit 164 At least one electric component 174.In some embodiments, at least one electronic component 174 includes being coupled to conducting element 152 Capacitor C, the conducting element may be used as inductor L, to form LC as shown in Figure 5 A (for example, resonance) circuit. In other embodiments, electronic component 174 may include the resistor R for being coupled to conducting element 152, and the conducting element can For use as inductor L, to form RL as shown in Figure 5 B (for example, resistor-inductor) circuit.In other embodiments In, conducting element 152 can be coupled to capacitor C and resistor R to form rlc circuit as shown in Figure 5 C.Electric conductor (example Such as, electric wire) electronic component 174, conducting element 152 and power supply unit 164 can be operatively coupled to.Electric wire can be at two Or more conducting element 152 is contacted at position, allow power supply unit 164 to flow a current through conducting element via electric wire 152.Electronic component 174 and/or conducting element 152 further can be coupled to electronic device 156 by electric conductor.
Electronic device 156 may include multimeter or voltmeter, and the multimeter or voltmeter allow electronic device 156 to exist The electrical properties of conducting element 152 is measured during the use of packer device 136 and the expansion of deformable material 150.Citing comes It says, electronic device 156 can measure conductive element by the variation of the resonance frequency of measurement lc circuit, RL circuit or rlc circuit The inductance of part 152 or the variation of resistivity.Communication device 162 may include transmitter and/or receiver, the transmitter and/ Or receiver is used to the related information of measured electrical properties with conducting element 152 being transferred to ground 126 to be divided Analysis, and/or for receiving information, such as operational order from ground 126.Communication device 162 may include (for example) mud-pulse Telemetry system.
Fig. 6 shows another configuration for the conducting element 172 being arranged in deformable material 150.Conducting element 172 can be with Zigzag fashion with the oscillation of axis 176 around conducting element 172.Conducting element 172 can take in deformable material 150 To so that the axis 176 of zigzag fashion extends and in deformable material 150 perpendicular to the longitudinal axis of tubular part 122 from pipe Shape component 122 extends radially outwardly.In other words, conducting element 172 can be orientated in deformable material 150, so that line The axis 154 of circle extends along the radius of deformable material 150.Conducting element 172 is positioned and is configured in deformable material Material 150, which applies conductive member 172 after expanding, to be strained.Strain suffered by conducting element 172 may result in around conduction Measurable variation of induction or electromagnetic field that element 172 emits can such as before herein with reference to described by Fig. 2A to Fig. 2 C To measure the variation according to the power loss or resonance frequency measured in inductive logging tool 140.At this as before It, can also be by the way that conducting element 172 be coupled to electric component 174, power supply unit referring to described by Fig. 4 A to Fig. 4 C in text 164 and electronic device 156 measure strain suffered by conducting element 172.In other embodiments, it is set to deformable material Conducting element in 150 can have any other shape, and the shape, which is configured so that, expands it in deformable material 150 Conductive member 172 is applied afterwards and is strained.
As mentioned before, the CNT in the CNT material of conducting element 152,172 can be crosslinking, so that directly covalently Adjacent CNT is directly bound up by atom key in conducting element 152,172.In the CNT material of conducting element 152,172 Such crosslinking of CNT that the CNT material may be made to show compared with the CNT material with uncrosslinked CNT is increased Mechanical strength (for example, higher tensile strength or yield strength).Method for being crosslinked CNT is well known in the art And in the A Flexible Cross-Linked Multi-Walled Carbon of (for example) D.N.Ventura et al. Nanotube Paper for Sensing Hydrogen, Carbon 50 (2012) are disclosed in page 2672 to page 2674, The content of the article is integrally incorporated herein by reference.It for example, as disclosed therein, can be with amido to CNT It is functionalized to form amination CNT, and amination CNT can be crosslinked with benzoquinones.
In addition, the CNT in the CNT material of conducting element 152,172 can be impregnated with metal nanoparticle.In other words It says, metal nanoparticle can be attached to the outer wall of CNT.In some embodiments, CNT can with platinum, copper, silver, gold, ruthenium, Rhodium, tin or palladium nano-particles with and combinations thereof at least one of impregnated.Metal nanoparticle, which is attached to CNT, to be increased The conductivity of CNT.
The embodiment of the disclosure further includes forming article (such as packer device under deformable well as described in this article 136,170) method.For example, according to such method, deformable material can be set around the outer surface of tubular part 122 Material 150, the tubular part is configured to be placed in pit shaft, and can will include the conduction of carbon nanotube (CNT) material Element 152,172 is bonded to deformable material 150.
It in some embodiments, As shown in Fig. 7 A to Fig. 7 C, can be by using moulding process (such as reaction injection Moulding process) come surround tubular part 122 to deformable material 150 form surround tubular part 122 outer surface setting can Deformable material 150.
As shown in Figure 7A, tubular part 122 can be located at least partially within mold 180 wherein with type chamber 182 It is interior.The size and shape of type chamber 182 can correspond to will be in the deformable material 150 wherein formed around tubular part 122.? In some embodiments, the size and shape of type chamber 182 can correspond to be in swelling state shown in Fig. 2 B and Fig. 3 B The size and shape of deformable material 150.It, can be by (or the conducting element in Fig. 4 A to Fig. 4 C of conducting element 152 referring to Fig. 7 B 172) selected location being located in type chamber 182.Tubular part 122 can be positioned at least partially in mold 180 it It is preceding or conducting element 152 is located in type chamber 182 later.It can will be conductive under the swelling state shown in Fig. 2 B and Fig. 4 B Element 152 is arranged in type chamber 182.It as shown in fig. 7c, can be variable to provide around tubular part 122 in type chamber 182 Shape material 150.
In some embodiments, the moulding process for being used to form deformable material 150 may include reaction injection molding Technique.In this type of process, it can be injected into liquid precursors as liquid or paste in the type chamber 182 of mold 180.Chemistry Reaction may result in the crosslinking between molecule (for example, polymer chain or monomeric unit) to lead to not flowable polymer The formation of material.The polymer material can be as before herein with reference to described by Fig. 2A to Fig. 2 C.It is mentioned as before And deformable material 150 may include shape memory polymeric material.In some embodiments, deformable material 150 can be as Formation, the patent are incorporated herein by reference before as described in aforementioned ' 012 patent.
During moulding process, conducting element 152 can be bonded to deformable material as described herein before 150.Specifically, when forming deformable material 150 around tubular part 122, the carbon nanotube (CNT) of conducting element 152 CNT in material can be covalently bonded to deformable material 150.
For example, in some embodiments, deformable material 150 may include polyurethane.In such embodiment In, it can be by (for example) making to have the alcohol (examples of two or more reaction hydroxyls of per molecule in the type chamber 182 of mold 180 Such as, polyalcohol) it is reacted with the isocyanates with more than one isocyanate reaction base of per molecule to form polyurethane.Some It, can be with amido to leading before surrounding or forming deformable material 150 adjacent to conducting element 152,172 in embodiment CNT in carbon nanotube (CNT) material of electric device 152,172 is functionalized.During the formation of deformable material 150, Amination carbon nanotube can be made to react during reaction and injection molding process with polyisocyanate, cause CNT in CNT material with Covalent bond is formed between the polyurethane of deformable material 150.
It can permit deformable material 150 to solidify in the type chamber 182 of mold 180.Due to deformable material 150 and conduction Element 152,172 may be to be formed in the expanded state, therefore press deformable material 150 and conducting element 152,172 Contracting.It, can be with variable compression shape material 150, until deformable material 150 herein with reference to described by Fig. 2A and Fig. 2 B as before Diameter have the diameter smaller than the diameter of the wall 132 (Fig. 1) of pit shaft 110 until.It is compressed to deformable material 150 When, conducting element 152,172 can also be compressed to compressive state, under the compressive state, as shown in Fig. 2A and Fig. 4 A, The length of conducting element 152,172 reduces.
Fig. 8 A to Fig. 8 C shows the packer dress that can be used in wellbore system (all wellbore systems 100 as shown in figure 1) Set 200 another embodiment.Packer device 200 is article under deformable well, similar with packer device 136, described Article includes tubular part 122 under deformable well.The deformable material 202 being arranged around tubular part 122 may include rubber Or elastomer.In some embodiments, the elastomer of deformable material 202 may include as before herein with reference to Fig. 2A The deformable material 150 described to Fig. 2 C.For example, deformable material 202 can be such as U.S. Patent Publication No.2009/ 0139708 is incorporated by reference before with rubber or elastomer described in ' 708 patents, each of described patent Herein.
Fig. 8 B shows the partial section view for being provided with the deformable material 202 of conducting element 152.Herein as before In referring to described by Fig. 2A to Fig. 2 C, conducting element 152 can be orientated in deformable material 202, so that the axis 154 of coil Extend perpendicular to the longitudinal axis of tubular part 122 and extends radially outwardly in deformable material 150 from tubular part 122. In other words, coil can be orientated in deformable material 202, so that the axis 154 of coil is along the half of deformable material 202 Diameter extends.
Conducting element 152 is positioned conductive member 152 and is configured so that after deformable material 202 expands Apply stress.Conducting element 152 may be in response to the stress that is applied and through strained, and conducting element 152 does not have phase Very big relative displacement is occurred along interface therebetween for adjacent deformable material 202.Strain suffered by conducting element 152 May result in around conducting element 152 emit induction or electromagnetic field measurable variation, such as before herein with reference to Described by Fig. 2A to Fig. 2 C, it can be measured according to the power loss or resonance frequency measured in inductive logging tool 140 The variation.It, can also be by the way that conducting element 152 be coupled to electrically herein with reference to described by Fig. 4 A to Fig. 4 C as before Component 174, power supply unit 164 and electronic device 156 measure strain suffered by conducting element 152.In other embodiments In, the conducting element being set in deformable material 202 can have any other shape, and the shape is configured so that Deformable material 202, which applies conductive member 152 after expanding, to be strained.
The embodiment of the disclosure further includes the method to form article under deformable well (such as packer device 200).It lifts It,, can be with such as before herein with reference to described by Fig. 2A to Fig. 2 C, Fig. 4 A to Fig. 4 C and Fig. 6 according to such method for example Around the outer surface of tubular part 122, deformable material 202 is set, the tubular part is configured to be placed in pit shaft, and And the conducting element 152 comprising carbon nanotube (CNT) material is bonded to deformable material 202.
In some embodiments, conducting element 152 can be arranged when deformable material 202 is in uncured state In deformable material 202 and it is bonded to the rubber or elastomer of deformable material 202.In some embodiments, Ke Yiyong Mode as known in the art solidifies deformable material 202 on solidification plug.It in other embodiments, can be in tubular portion Solidify deformable material 202 on part 122.It for example, can be by being described in such as U.S. Patent Publication No.2009/0139708 Method solidify deformable material 202, it is before the patent incorporated herein by reference.Can will in solidification or not The solid state and deformable material 202 for being provided with conducting element 152 is wound on tubular part 122, such as by scheming On direction depicted in arrow 206 shown in 8C.
Fig. 9 A to Fig. 9 C shows the packer dress that can be used in wellbore system (all wellbore systems 100 as shown in figure 1) Set 210 another embodiment.Packer device 210 is article under deformable well, similar with packer device 136, described Article includes tubular part 122 under deformable well.Packer device 210 further includes deformable material 212, with before herein It is similar referring to the deformable material 202 of Fig. 8 A to Fig. 8 C description.Conducting element 214 can be set in deformable material 212.Such as Before herein with reference to described by Fig. 8 A to Fig. 8 C, conducting element 214 be can be set in deformable in uncured state In material 212.
Conducting element 214 includes the fiber for being arranged to coil, and the coil is in deformable material 212 around tubular part 122 extend concentrically about.In some embodiments, herein with reference to Fig. 2A to Fig. 2 C, Fig. 4 A to Fig. 4 C and Fig. 6 as before Described, conducting element 214 may include carbon nanotube (CNT) material for being bonded to deformable material 202.In other embodiment party In case, conducting element 214 may include carbon nanotube (CNT) line being set in deformable material 202.Fig. 9 B be transverse to The sectional view of the packer device 210 intercepted in the plane of the longitudinal axis of tubular part 122.As shown in fig. 9b, conducting element 214 It surround at least part of tubular part 122 circumferentially.Conducting element 214 can around tubular part 122 circumference with Round or spiral fashion completely extends one or many.Although only showing a conducting element 214 in Fig. 9 A to Fig. 9 C, But any number conducting element 214 can be used in the embodiment of the disclosure.Using multiple conducting elements 214 In embodiment, each conducting element 214 can completely extend one or many around the circumference of tubular part 122.
In some embodiments, the end of conducting element 214 can be directly or indirectly in electrical contact.For example, conductive The end of element 214 can connect in circuit.In other words, the end of conducting element 214 can connect to such as before at this Referring to electric component 155 described in Fig. 2A to Fig. 3 C in text, or herein with reference to described in Fig. 4 A to Fig. 5 C as before Electric component 174.In other embodiments, the end of conducting element 214 can be coupled directly to each other.
Herein with reference to described by Fig. 8 A to Fig. 8 C as before, it is provided with the deformable material of conducting element 214 212 can form around tubular part 122.For example, the deformable material of conducting element 214 will can be provided with 212 directions depicted in the arrow 216 as shown in Fig. 9 C are wound around tubular part 122.
Conducting element 214 is positioned conductive member 214 and is configured so that after deformable material 212 expands Apply stress.Conducting element 214 can be in response to the stress that is applied and through strained, and conducting element 152 is without opposite Very big relative displacement occurs along interface therebetween in adjacent deformable material 212.Strain suffered by conducting element 214 can Measurable variation that the induction or electromagnetic field that emit around conducting element 214 can be will lead to, such as before herein with reference to figure Described by 2A to Fig. 2 C and as shown in fig. 9b, can according to the power loss measured in inductive logging tool 140 or Resonance frequency measures the variation.It, can also be by by conductive element herein with reference to described by Fig. 4 A to Fig. 4 C as before Part 152 is coupled to electric component 174, power supply unit 164 and electronic device 156 to measure strain suffered by conducting element 214. In other embodiments, the conducting element being set in deformable material 212 can have any other shape, the shape It is configured so that after deformable material 212 expands to apply conductive member 214 and strain.
In Additional embodiments, the disclosure is included in pit shaft 110 using (such as packer dress of article under deformable well Set 136, packer device 170, packer device 200 or packer device 210) method.It for example, can be deformable Material 150,202,212, which is in, not to be expanded or when compressive state (for example, state shown in Fig. 2A and Fig. 4 A) fills packer It sets at the desired position that 136,170,200,210 are located in pit shaft 110.Then can make deformable material 150,202, 212 expand at the selected location in pit shaft 110 or are expanded into swelling state (for example, state shown in Fig. 2 B and Fig. 4 B). Deformable material 150,202,212 can be made to expand (for example, swollen by applying stimulation (for example, being exposed in 110 environment of pit shaft) It is swollen).The stimulation can be thermostimulation, chemical stimulation, electro photoluminescence etc..Deformable material 150,202,212 is expanded or is expanded The expansion of conducting element 152,172,214 can be further resulted in, because conducting element 152,172,214 is positioned and is configured It is strained to apply by 150,202,212 conductive member 152,172,214 of deformable material.
As mentioned before, the expansion of deformable material 150,202,212 may change conducting element 152,172,214 Carbon nanotube (CNT) material strain regime, the inductance of conducting element 152,172,214 and resistivity may so changed Become.As a result, can be used the electronic device 156 of packer device 136,170,200,210 or inductive logging tool 140 comes can It is either directly or indirectly surveyed as described herein before during and/or after the expansion of deformable material 150,202,212 Measure the inductance or resistivity of conducting element 152,172,214.As a result, the expansion of deformable material 150,202,212 can be determined Rate and/or degrees of expansion so as to ensure deformable material 150,202,212 it is anticipated that expansion, and packer device 136, It 170,200,210 will be it is anticipated that safely operating.
Although the disclosure have been described include the conducting element formed by carbon nanotube (CNT) material deformable well under object The embodiment of product, but the present invention is not so limited.For example, merge the conducting element under deformable well in article It may include any conductive material, including but not limited to conductive metal.According to any embodiment of the disclosure, such conductive gold Category can optionally be coated with dielectric substance and be embedded in deformable material.
The additional non-restrictive illustrative embodiment of the disclosure has been set out below.
Embodiment 1: article under a kind of deformable well for using in the wellbore, article packet under the deformable well Include: tubular part, the tubular part are configured to be placed in pit shaft;Deformable material, the deformable material is around institute State the outer surface setting of tubular part;And conducting element, the conducting element include the carbon for being bonded to the deformable material Nanotube (CNT) material.
Embodiment 2: article under the deformable well as described in embodiment 1, wherein the conducting element positioned and by Be arranged so that the deformable material expand it is rear to the conducting element apply stress, and the conducting element respond In the applied stress through strained.
Embodiment 3: article under the deformable well as described in embodiment 1 or embodiment 2, object under the deformable well Product further include electronic device, and the electronic device is operatively coupled to the conducting element and is configured to measure described lead At least one electrical properties of electric device.
Embodiment 4: article under the deformable well as described in any embodiment in embodiment 1 to 3, wherein described CNT material extends radially outwardly from least part of the tubular part.
Embodiment 5: article under the deformable well as described in any embodiment in embodiment 1 to 3, wherein described CNT material includes crosslinking carbon nanotube, and the CNT material extends
Embodiment 6: article under the deformable well as described in any embodiment in embodiment 1 to 5, wherein described lead Electric device is covalently bonded to the deformable material.
Embodiment 7: article under the deformable well as described in any embodiment in embodiment 1 to 6, wherein described CNT material include crosslinking carbon nanotube (CNT), and wherein the CNT in the CNT material covalently bonded to described deformable Material.
Embodiment 8: article under the deformable well as described in any embodiment in embodiment 1 to 7, wherein described lead Electric device is arranged in the deformable material.
Embodiment 9: article under the deformable well as described in any embodiment in embodiment 1 to 8, wherein described CNT in CNT material is impregnated with metal nanoparticle.
Embodiment 10: article under the deformable well as described in embodiment 9, wherein the metal nanoparticle includes palladium Nano particle.
Embodiment 11: article under the deformable well as described in embodiment 7, wherein CNT and benzene in the CNT material Quinone crosslinking.
Embodiment 12: article under the deformable well as described in any embodiment in embodiment 1 to 11, wherein described Deformable material includes shape-memory polymer.
Embodiment 13: article under the deformable well as described in embodiment 12, wherein the shape-memory polymer packet Include polyurethane.
Embodiment 14: a method of forming article under the deformable well for using in the wellbore, the method packet It includes: deformable material being set around the outer surface of tubular part, the tubular part is configured to be placed in pit shaft;And it will Conducting element comprising carbon nanotube (CNT) material is bonded to the deformable material.
Embodiment 15: the method as described in embodiment 14, wherein the outer surface around the tubular part is set Setting the deformable material includes forming around the tubular part to the deformable material.
Embodiment 16: the method as described in embodiment 15, wherein around the tubular part to the deformable material Material molding includes reaction and injection molding process.
Embodiment 17: the method as described in any embodiment in embodiment 14 to 16, wherein will include the carbon The conducting element of nanotube (CNT) material be bonded to the deformable material include by the conducting element covalently bonded to The deformable material.
Embodiment 18: a method of in the wellbore using article under deformable well, which comprises will be deformable Underground article positions in the wellbore, and article includes tubular part, the outer surface around the tubular part under the deformable well The deformable material of setting and conducting element comprising carbon nanotube (CNT) material, the carbon nano-tube material are bonded to institute State deformable material;The deformable material is set to be expanded to swelling state, the expansion of the deformable material in the pit shaft Make the carbon nanotube (CNT) material of the conducting element through strained;And the electrical properties of the measurement conducting element.
Embodiment 19: the method as described in embodiment 18, wherein measuring the electrical properties of the conducting element Resistivity or inductance including measuring the conducting element.
Embodiment 20: the method as described in embodiment 18 or embodiment 19, the method also includes passing through survey The measurement result measuring the electrical properties of the conducting element and obtaining is related to the degrees of expansion of the deformable material.
Embodiment 21: the method as described in any embodiment in embodiment 18 to 20, wherein the conducting element Covalently bonded to the deformable material.
Although having described the disclosure, the ordinary skill of this field relative to certain shown embodiments herein Personnel will recognize that and recognize that the disclosure is not so limited.But in the scope of the present disclosure (packet for not departing from statement as follows Include its legal equivalents) in the case where, many can be carried out to shown embodiment and increase, delete and modify.In addition, as invented Expect set by people, the feature from an embodiment can include in conjunction with the feature of another embodiment, while still Within the scope of this disclosure.

Claims (20)

1. article under a kind of deformable well for using in the wellbore, article includes: under the deformable well
Tubular part, the tubular part are configured to be placed in pit shaft;
Deformable material, the deformable material are arranged around the outer surface of the tubular part;And
Conducting element, the conducting element include carbon nanotube (CNT) material for being bonded to the deformable material.
2. article under deformable well as described in claim 1, wherein the conducting element is positioned and is configured so that The backward conducting element that the deformable material expands applies stress, and the conducting element is applied in response to described Stress and through strained.
3. article under deformable well as described in claim 1, article further includes electronic device under the deformable well, the electricity Sub-device is operatively coupled to the conducting element and is configured to measure at least one electrical resistance of the conducting element Matter.
4. article under deformable well as described in claim 1, wherein at least one from the tubular part of the CNT material Divide and extends radially outwardly.
5. article under deformable well as described in claim 1, wherein the CNT rings of material is around at least the one of the tubular part Part is circumferentially.
6. article under the deformable well as described in any one of claims 1 to 5, wherein the conducting element is covalently bonded to institute State deformable material.
7. article under the deformable well as described in any one of claims 1 to 5, wherein the CNT material includes the carbon of crosslinking Nanotube (CNT), and wherein the CNT in the CNT material covalently bonded to the deformable material.
8. article under the deformable well as described in any one of claims 1 to 5, wherein the CNT metal in the CNT material Nano particle is impregnated.
9. article under deformable well as claimed in claim 8, wherein the metal nanoparticle includes palladium nano-particles.
10. article under deformable well as claimed in claim 7, wherein the CNT and benzoquinones in the CNT material are crosslinked.
11. article under the deformable well as described in any one of claims 1 to 5, wherein the deformable material includes shape Memory polymer.
12. article under deformable well as claimed in claim 11, wherein the shape-memory polymer includes polyurethane.
13. a kind of method of article under deformable well formed for using in the wellbore, which comprises
Deformable material is set around the outer surface of tubular part, the tubular part is configured to be placed in pit shaft;And
Conducting element comprising carbon nanotube (CNT) material is bonded to the deformable material.
14. method as claimed in claim 13, wherein described deformable around the setting of the outer surface of the tubular part Material includes forming around the tubular part to the deformable material.
15. method as claimed in claim 14, wherein including anti-to deformable material molding around the tubular part Answer injection molding technique.
16. the method as described in any one of claim 13 to 15, wherein will include the institute of the carbon nanotube (CNT) material Stating conducting element and being bonded to the deformable material includes by the conducting element covalently bonded to the deformable material.
17. a kind of in the wellbore using the method for article under deformable well, which comprises
In the wellbore by article positioning under deformable well, article includes tubular part, around the tubulose under the deformable well The deformable material that the outer surface of component is arranged and the conducting element comprising carbon nanotube (CNT) material, the carbon nanotube Material binds are to the deformable material;
The deformable material is set to be expanded to swelling state in the pit shaft, the expansion of the deformable material makes the conduction The carbon nanotube (CNT) material of element is through strained;And
Measure the electrical properties of the conducting element.
18. method as claimed in claim 17, wherein the electrical properties for measuring the conducting element includes described in measurement The resistivity or inductance of conducting element.
19. method as claimed in claim 17, the method also includes will be by measuring the described electrical of the conducting element Property and the measurement result that obtains is related to the degrees of expansion of the deformable material.
20. the method as described in any one of claim 17 to 19, wherein the conducting element is covalently bonded to described variable Shape material.
CN201780024797.0A 2016-03-07 2017-03-06 Deformable well flowering structure and formation comprising carbon nano-tube material and the method using this class formation Pending CN109072680A (en)

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US20170254170A1 (en) 2017-09-07
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RU2018133552A3 (en) 2020-07-03
EP3426876A4 (en) 2019-10-16

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