CN109053174A - 一种雪花白砂瓷砖及其制备方法 - Google Patents

一种雪花白砂瓷砖及其制备方法 Download PDF

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CN109053174A
CN109053174A CN201811243269.7A CN201811243269A CN109053174A CN 109053174 A CN109053174 A CN 109053174A CN 201811243269 A CN201811243269 A CN 201811243269A CN 109053174 A CN109053174 A CN 109053174A
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Abstract

本发明公开了一种雪花白砂瓷砖及其制备方法,属于瓷砖材料领域。所述雪花白砂瓷砖包括以下重量份的原料:雪花白砂80‑110份、硅藻土25‑33份、石英粉18‑22份、钾长石48‑56份、轻质碳酸钙7‑9份、白泥12‑16份、叶腊石15‑19份、纳米二氧化钛5‑9份、空心玻璃微珠13‑15份、助悬剂2‑4份、粘接剂3‑5份。本发明所述雪花白砂瓷砖及其制备方法增加了耐磨性能,提高了抗龟裂能力,降低产品的破损率,提高了材料整体性能且使用度更广。

Description

一种雪花白砂瓷砖及其制备方法
技术领域
本发明瓷砖材料领域,具体涉及一种雪花白砂瓷砖及其制备方法。
背景技术
瓷砖,是以耐火的金属氧化物及半金属氧化物,经由研磨、混合、压制、施釉、烧结而制成的过程,形成的一种耐酸碱的瓷质或石质等,广泛应用于建筑或装饰材料,称之为瓷砖。其原材料多由粘土、石英石等等混合而成。随着我国建筑瓷砖行业的飞速发展,使得人们对瓷砖的性能要求也越来越高。目前市场上的瓷砖存在着耐磨性差的缺点,使用过程肿容易摩擦损耗非常严重,极大地缩短了其使用寿命,无法满足市场需求。
雪花白砂具有优异的性能,它是由纯净石英块经先进的超细研磨工艺加工而成,而且是用途极为广泛的无机非金属材料。雪花白砂具有介电性能优异、热膨胀系数低、导热系数高、悬浮性能好等优点。其中,雪花白砂的二氧化硅含量为99.3%,硬度莫氏7级,白度大于91,粒度分布比较理想。雪花白砂的质感也非常的纯净细腻,光泽度高,经常被用于建筑装修、水磨石骨料、真石漆、彩砂涂料等。目前市场上还没有以雪花白砂作为原料的瓷砖。
发明内容
本发明的目的在于提供一种雪花白砂瓷砖及其制备方法,其增加了耐磨性能,提高了抗龟裂能力,降低产品的破损率,提高了材料整体性能且使用度更广。
为实现上述目的,本发明提供如下技术方案:
一种雪花白砂瓷砖,包括以下重量份的原料:雪花白砂80-110份、硅藻土25-33份、石英粉18-22份、钾长石48-56份、轻质碳酸钙7-9份、白泥12-16份、叶腊石15-19份、纳米二氧化钛5-9份、空心玻璃微珠13-15份、助悬剂2-4份、粘接剂3-5份。
优选地,所述雪花白砂瓷砖,包括以下重量份的原料:雪花白砂95份、硅藻土29份、石英粉20份、钾长石52份、轻质碳酸钙8份、白泥14份、叶腊石17份、纳米二氧化钛7份、空心玻璃微珠14份、助悬剂3份、粘接剂4份。
优选地,所述一种雪花白砂瓷砖的制备方法,包括以下步骤:
(1)将雪花白砂、硅藻土、石英粉、钾长石、轻质碳酸钙、叶腊石、纳米二氧化钛投入至球磨机进行研磨,得到粉料;
(2)将白泥、助悬剂、粘接剂、空心玻璃微珠在10-13℃水浴下混合搅拌均匀,搅拌时间为10-20min后,将温度逐渐降低到0℃,继续搅拌25-30min,然后放入裂解斧中反应20-30min,即得辅料;
(3)将粉料和辅料加水混合均匀,辅以微波照射,然后投入研磨机中进行研磨,得到浆料;
(4)采用喷雾塔浆料进行雾化,干燥制粒,然后静置陈腐24-28h后进行制坯、施釉、烧制、磨边,即得所述雪花白砂瓷砖。
优选地,所述步骤(1)中,粉料的粒径500-600目。
优选地,所述步骤(1)中,球磨机的转速为165-185r/min,研磨时间为1-1.5h。
优选地,所述步骤(2)中,裂解斧的温度为400-450℃。
优选地,所述步骤(3)中,研磨机的转速为150-200r/min,研磨时间为30-45min。
与现有技术相比,本发明的有益效果是:
(1)以雪花白砂为主要原料,通过添加硅藻土、石英粉、叶腊石、轻质碳酸钙,增强了瓷砖的耐磨性能,通过添加钾长石、纳米二氧化钛,提高了瓷砖的整体性能。
(2)白泥、助悬剂、粘接剂、空心玻璃微珠制成辅料,提高了粉料的粘接效果,同时,提高了瓷砖的抗龟裂能力,其次,改善了瓷砖的吸音效果。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例1
本实施例中所述的一种雪花白砂瓷砖,包括以下重量份的原料:雪花白砂80份、硅藻土25份、石英粉18份、钾长石48份、轻质碳酸钙7份、白泥12份、叶腊石15份、纳米二氧化钛5份、空心玻璃微珠13份、助悬剂2份、粘接剂3份。
所述一种雪花白砂瓷砖的制备方法,包括以下步骤:
(1)将雪花白砂、硅藻土、石英粉、钾长石、轻质碳酸钙、叶腊石、纳米二氧化钛投入至球磨机进行研磨,球磨机的转速为165r/min,研磨时间为1h,得到粉料,粉料的粒径500目;
(2)将白泥、助悬剂、粘接剂、空心玻璃微珠在10℃水浴下混合搅拌均匀,搅拌时间为10min后,将温度逐渐降低到0℃,继续搅拌25min,然后放入裂解斧中反应20min,裂解斧的温度为400℃,即得辅料;
(3)将粉料和辅料加水混合均匀,辅以微波照射,然后投入研磨机中进行研磨,研磨机的转速为150r/min,研磨时间为30min,得到浆料;
(4)采用喷雾塔浆料进行雾化,干燥制粒,然后静置陈腐24h后进行制坯、施釉、烧制、磨边,即得所述雪花白砂瓷砖。
实施例2
本实施例中所述的一种雪花白砂瓷砖,包括以下重量份的原料:雪花白砂95份、硅藻土29份、石英粉20份、钾长石52份、轻质碳酸钙8份、白泥14份、叶腊石17份、纳米二氧化钛7份、空心玻璃微珠14份、助悬剂3份、粘接剂4份。
所述一种雪花白砂瓷砖的制备方法,包括以下步骤:
(1)将雪花白砂、硅藻土、石英粉、钾长石、轻质碳酸钙、叶腊石、纳米二氧化钛投入至球磨机进行研磨,球磨机的转速为175r/min,研磨时间为1.2h,得到粉料,粉料的粒径550目;
(2)将白泥、助悬剂、粘接剂、空心玻璃微珠在12℃水浴下混合搅拌均匀,搅拌时间为15min后,将温度逐渐降低到0℃,继续搅拌27min,然后放入裂解斧中反应25min,裂解斧的温度为425℃,即得辅料;
(3)将粉料和辅料加水混合均匀,辅以微波照射,然后投入研磨机中进行研磨,研磨机的转速为175r/min,研磨时间为38min,得到浆料;
(4)采用喷雾塔浆料进行雾化,干燥制粒,然后静置陈腐26h后进行制坯、施釉、烧制、磨边,即得所述雪花白砂瓷砖。
实施例3
本实施例中所述的一种雪花白砂瓷砖,包括以下重量份的原料:雪花白砂110份、硅藻土33份、石英粉22份、钾长石56份、轻质碳酸钙9份、白泥16份、叶腊石19份、纳米二氧化钛9份、空心玻璃微珠15份、助悬剂4份、粘接剂5份。
所述一种雪花白砂瓷砖的制备方法,包括以下步骤:
(1)将雪花白砂、硅藻土、石英粉、钾长石、轻质碳酸钙、叶腊石、纳米二氧化钛投入至球磨机进行研磨,球磨机的转速为185r/min,研磨时间为1.5h,得到粉料,粉料的粒径600目;
(2)将白泥、助悬剂、粘接剂、空心玻璃微珠在13℃水浴下混合搅拌均匀,搅拌时间为20min后,将温度逐渐降低到0℃,继续搅拌30min,然后放入裂解斧中反应30min,,裂解斧的温度为450℃,即得辅料;
(3)将粉料和辅料加水混合均匀,辅以微波照射,然后投入研磨机中进行研磨,研磨机的转速为200r/min,研磨时间为45min,得到浆料;
(4)采用喷雾塔浆料进行雾化,干燥制粒,然后静置陈腐28h后进行制坯、施釉、烧制、磨边,即得所述雪花白砂瓷砖。
以上内容仅仅是对本发明结构所作的举例和说明,所属本技术领域的技术人员对所描述的具体实施例做各种各样的修改或补充或采用类似的方式替代,只要不偏离本发明的结构或者超越本权利要求书所定义的范围,均应属于本发明的保护范围。

Claims (7)

1.一种雪花白砂瓷砖,其特征在于,包括以下重量份的原料:雪花白砂80-110份、硅藻土25-33份、石英粉18-22份、钾长石48-56份、轻质碳酸钙7-9份、白泥12-16份、叶腊石15-19份、纳米二氧化钛5-9份、空心玻璃微珠13-15份、助悬剂2-4份、粘接剂3-5份。
2.根据权利要求1所述的一种雪花白砂瓷砖,其特征在于,包括以下重量份的原料:雪花白砂95份、硅藻土29份、石英粉20份、钾长石52份、轻质碳酸钙8份、白泥14份、叶腊石17份、纳米二氧化钛7份、空心玻璃微珠14份、助悬剂3份、粘接剂4份。
3.根据权利要求1-2任一项所述的一种雪花白砂瓷砖的制备方法,其特征在于,包括以下步骤:
(1)将雪花白砂、硅藻土、石英粉、钾长石、轻质碳酸钙、叶腊石、纳米二氧化钛投入至球磨机进行研磨,得到粉料;
(2)将白泥、助悬剂、粘接剂、空心玻璃微珠在10-13℃水浴下混合搅拌均匀,搅拌时间为10-20min后,将温度逐渐降低到0℃,继续搅拌25-30min,然后放入裂解斧中反应20-30min,即得辅料;
(3)将粉料和辅料加水混合均匀,辅以微波照射,然后投入研磨机中进行研磨,得到浆料;
(4)采用喷雾塔浆料进行雾化,干燥制粒,然后静置陈腐24-28h后进行制坯、施釉、烧制、磨边,即得所述雪花白砂瓷砖。
4.根据权利要求3所述的一种雪花白砂瓷砖的制备方法,其特征在于:所述步骤(1)中,粉料的粒径500-600目。
5.根据权利要求3所述的一种雪花白砂瓷砖的制备方法,其特征在于:所述步骤(1)中,球磨机的转速为165-185r/min,研磨时间为1-1.5h。
6.根据权利要求3所述的一种雪花白砂瓷砖及其制备方法,其特征在于:所述步骤(2)中,裂解斧的温度为400-450℃。
7.根据权利要求3所述的一种雪花白砂瓷砖及其制备方法,其特征在于:所述步骤(3)中,研磨机的转速为150-200r/min,研磨时间为30-45min。
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