CN109052958A - Dry granular, dry granular glaze and dry granular glazed tile - Google Patents
Dry granular, dry granular glaze and dry granular glazed tile Download PDFInfo
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- CN109052958A CN109052958A CN201810980018.0A CN201810980018A CN109052958A CN 109052958 A CN109052958 A CN 109052958A CN 201810980018 A CN201810980018 A CN 201810980018A CN 109052958 A CN109052958 A CN 109052958A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The application provides a kind of dry granular, dry granular glaze and dry granular glazed tile.A kind of dry granular, by percentage to the quality, comprising: Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%, MgO5-12%, BaO4-10%, ZnO2-5%, RuO20.1-0.5%.A kind of dry granular glaze, 40-50 parts of the dry granular, further includes: glaze 10-20 parts of protection, 1-3 parts of kaolinite soil paste, 0.5-1.5 parts of burning talcum slurry, 90-110 parts of suspending agent and 0.05-0.1 parts of venting agent.A kind of dry granular glazed tile, including adobe, ground coat enamel and the dry granular glaze.Dry granular, dry granular glaze and dry granular glazed tile provided by the present application, inherit the superpower hardness of the unique Cultural Elements of Antique Imitation Tiles itself and polished bricks, and impart the texture of its more lifelike stone, while sense of touch is gentle as beautiful, without the ice-cold feeling of stone material.
Description
Technical field
The present invention relates to ceramic fields, in particular to a kind of dry granular, dry granular glaze and dry granular glazed tile.
Background technique
Modern imitations brick occupation rate of market was higher and higher in recent years, betray come sense of history, sense of nostalgia, natural sense,
Return sense, the Cultural Elements such as personalization and both with fashion landscape gradually obtain more and more concerns and approval.
The soft and moist dry granular glazed tile of dumb light belongs to a kind of upgrading products of modern imitations brick, it not only inherits the unique text of Antique Imitation Tiles itself
Change the superpower hardness of element and polished bricks, and impart the texture of its more lifelike stone, while sense of touch is gentle as beautiful, without
The ice-cold feeling of stone material.The soft and moist dry granular glazed tile of dumb light is that a kind of texture is stronger, sense of touch is more soft and moist, hardness is stronger and antifouling anti-
The sliding better floor tile of effect.Such floor tile is different from the feeling that other floor tiles step on ice-cold to people, stiff, glutinous foot, and dumb light is soft
Profit dry granular glazed tile can allow people feel as snug as a bug in a rug, step on feeling that is steady and sure, warm, loosening, be well suited for advocating recurrence
Natural crowd.
The prior art has the disadvantage in that product surface has card dirt and soil pick-up.There are many such currently on the market
Product after being only simply mixed in a certain ratio with dry granular and suspending agent, is uniformly sprayed on product surface with glaze spraying cabinet.It should
Technique is mostly used on brick product modelled after an antique, plays the role of decorative product surface tactile sensation, but since product surface is uneven, dry granular it
Between gap it is either large or small, in product after paving, surface is easy that card is dirty and soil pick-up.
In view of this, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is a kind of dry granular glaze that a kind of dry granular provided, second are designed to provide, and uses
Dry granular glaze is made in the dry granular, can obtain the dry granular glazed tile that surface depolluting properties are good, ornamental performance modelled after an antique is good.
The third object of the present invention is to provide above-mentioned dry granular glazed tile.
In order to realize above-mentioned purpose of the invention, the following technical scheme is adopted:
A kind of dry granular, by percentage to the quality, comprising:
Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%, MgO5-12%, BaO4-10%, ZnO2-
5%, RuO20.1-0.5%.
RuO2Highly stable when firing, 1400 DEG C or more can just decompose.At 1170-1185 DEG C, on the surface of brick
Stable distritation center is formed, other compositions are in melting or semi-molten state, and then are formed together the relatively uniform hemisphere of size
Shape particle is covered on product surface, plays the role of preventing card dirty and soil pick-up, while keeping glaze paint sense of touch gentle comfortable.
Preferably, the dry granular is by percentage to the quality, further includes: V2O50.1-0.5% and Bi2O30.1-0.5%.
Vanadic anhydride can be decomposed into oxygen and vanadium tetraoxide at 700-1125 DEG C or so, and this variation meeting is so that firing
In the process, the microstructure for improving glaze paint, effectively improves anti-pollution.Just there are three types of different crystal forms for bismuth oxide, this
The cooperation of different crystal forms can change the composition of dry granular after being added to it among dry granular, make to obtain in preparation process optimal
Molten condition, and then better surface texture is obtained, obtain outstanding anti-pollution.
It is further preferred that the granularity of the dry granular is 120-200 mesh.
The control of granularity can make configuration of surface more optimize, and anti-pollution is more preferable.
The application also provides a kind of dry granular glaze, based on parts by weight, including described 40-50 parts of dry granular, further includes:
Glaze 10-20 parts of protection, 1-3 parts of kaolinite soil paste burn 0.5-1.5 parts of talcum slurry, 90-110 parts of suspending agent and venting agent
0.05-0.1 parts.
The effect for protecting glaze is that effective filing effect is formed between dry granular, so that glaze paint obtains the semicircle of appropriate size
Shape protrusion, improves surface texture, improves anti-fouling effect；Kaolinite soil paste is kaolin and water, can be with while playing peptizaiton
Improve the firing temperature of dry granular glaze；Talcum slurry is burnt to burn talcum and water, primarily serves the effect for reducing the firing temperature of dry granular glaze,
It cooperates with kaolinite soil paste, obtains suitable firing temperature, is conducive to control dry granular and protects shape of the ingredient of glaze when firing
State obtains preferably melting or semi-molten form, so that it is guaranteed that glaze paint microstructure, guarantees anti-pollution.The use of suspending agent
It is in order to guarantee that each component can be preferably dispersed in system to prevent from that part unevenly bring matter occurs in sintering procedure
Measure flaw；The use of venting agent is in order to avoid following situations: causing ink-jet printed position and water since grease cannot be simultaneous molten
Property glaze junction generate water-oil separating, in turn result in ceramic tile firing rear surface and generate contracting glaze, pit and the defects of bubble, seriously
Influence product quality.Venting agent can also greatly improve glaze slip levelling and caking property in addition to it can overcome disadvantages described above, and then improve glaze
Face is smooth and caking ability.
Preferably, the dry granular glaze specific gravity is 1.23-1.27g/ml, and fineness is the siccative weight percent after 200 meshes
For 0.4%-0.6%.
Controlling specific gravity and tailing over is to obtain better properties of product.
It is further preferred that the protection glaze includes transparent powdered frit 55-65%, carboxymethyl cellulose by mass percentage
Sodium 0.2-0.5%, sodium tripolyphosphate 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-2%, 12 hydrazine aluminum sulfate potassium 1-
2%, water 30-36% and print cream 1-5%.
The preferred of glaze is protected, can preferably be cooperated with dry granular, optimal surface microstructure is obtained, and then is obtained best
Anti-pollution.
It is further preferred that the suspending agent is sodium carboxymethylcellulose, the venting agent is polyacrylamide, polypropylene
One of acid, polyvinylpyrrolidone, polyvinyl alcohol, polymaleic anhydride, poly-quaternary ammonium salt and polyethylene glycol.
Suspending agent and venting agent it is optional there are many kinds of, above-mentioned preferred result can make overall performance reach best.
The application also provides a kind of dry granular glazed tile, including adobe, ground coat enamel and the dry granular glaze.
Preferably, the ground coat enamel includes SiO by mass percentage240-55%, Al2O310-15%, CaO8-10%,
MgO5-8%, ZnO10-15%, K2O4-6%, Na2O1-3%, BaO1-3%.
The selection of ground coat enamel, can to cooperate between adobe, ground coat enamel and dry granular glaze more preferable, and intensity and performance modelled after an antique are more
It is good.
It is further preferred that firing temperature is 1170-1185 DEG C.
The control of firing temperature be in order to control each ingredient in dry granular glaze fire when obtain optimal micromorphology,
Reach optimal and work in coordination and coat form, to obtain optimal anti-pollution.
Compared with prior art, the invention has the benefit that
1. especially adding ruthenic oxide by the ingredient of selection dry granular, making it after high temperature firing, forms size and compare
Uniform hemi-spherical granule is covered on product surface, keeps glaze paint sense of touch gentle comfortable；
2. protection glaze is added in dry granular glaze, plays and can solve the work that the gap between particle and particle does not block dirt and soil pick-up
With；
3. preferred ingredient and firing temperature, the molten condition formed in sintering process obtain optimal surface after cooling
Microstructure improves anti-pollution.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
Embodiment 1
Dry granular glazed tile is prepared as steps described below:
1, the adobe that press is accomplished fluently makes the moisture of adobe less than 0.5% by the Free water inside drying and removing；Adobe goes out
It sprays water after dry kiln on its surface, is formed on its surface water membrane；
2, ground coat enamel then is drenched to billet surface, glaze amount is 87g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO240%, Al2O315%, CaO10%, MgO8%, ZnO15%, K2O6%, Na2O3%, BaO3%；
3, ink jet printer printing pattern, it is dry through second of dry kiln, shorten the drying time of ink；
4, spray drying grain glaze；Dry granular glaze flow velocity is 26s, and specific gravity 1.27g/ml, glaze amount is 67g (pallet of 340*670), carefully
Degree is that siccative weight percent is 0.4% after 200 meshes；Dry granular glaze based on parts by weight, including 40 parts of dry granular, protection glaze 20
Part, 1 part of kaolinite soil paste, 1.5 parts of burning talcum slurry, 90 parts of suspending agent and 0.1 part of venting agent；
Dry granular includes Al by mass percentage2O35%, SiO255%, CaO10%, K2O10%, MgO5%,
BaO10%, ZnO4.5%, RuO20.5%；The granularity of dry granular is 120 mesh；
Protect glaze includes transparent powdered frit 60%, sodium carboxymethylcellulose 0.3%, sodium tripolyphosphate by mass percentage
0.2%, aluminium chloride 1%, aluminum sulfate 1.5%, 12 hydrazine aluminum sulfate potassium 2%, water 30% and print cream 5%；Transparent powdered frit is with matter
Measuring percentages includes Al2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4.5%, ZnO5%,
Lu2O30.5%；
Suspending agent is sodium carboxymethylcellulose, and the venting agent is polyacrylamide；
5, the adobe for being jetted through dry granular glaze enters burning kiln after dry kiln third time is dried, by 1170 DEG C (with firing ring
Subject to the temperature measured), high temperature fires 70min and obtains semi-finished product；
6, semi-finished product are packaged after the soft throwing inspection matter of the fiber polishing block combiner of edging and 800 mesh numbers and are used as finished product.
Embodiment 2
Dry granular glazed tile is prepared as steps described below:
1, the adobe that press is accomplished fluently makes the moisture of adobe less than 0.5% by the Free water inside drying and removing；Adobe goes out
It sprays water after dry kiln on its surface, is formed on its surface water membrane；
2, ground coat enamel then is drenched to billet surface, glaze amount is 93g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO255%, Al2O313%, CaO8%, MgO5%, ZnO10%, K2O5%, Na2O2%, BaO2%；
3, ink jet printer printing pattern, it is dry through second of dry kiln, shorten the drying time of ink；
4, spray drying grain glaze；Dry granular glaze flow velocity is 31s, and specific gravity 1.23g/ml, glaze amount is 73g (pallet of 340*670), carefully
Degree is that siccative weight percent is 0.6% after 200 meshes；Dry granular glaze based on parts by weight, including 50 parts of dry granular, protection glaze 10
Part, 3 parts of kaolinite soil paste, 0.5 part of burning talcum slurry, 110 parts of suspending agent and 0.05 part of venting agent；
Dry granular includes Al by mass percentage2O315%, SiO240%, CaO18%, K2O5.3%, MgO12%,
BaO4%, ZnO5%, RuO20.1%, V2O50.5% and Bi2O30.1%；The granularity of dry granular is 200 mesh；
Protect glaze includes transparent powdered frit 63%, sodium carboxymethylcellulose 0.2%, sodium tripolyphosphate by mass percentage
0.3%, aluminium chloride 2%, aluminum sulfate 1%, 12 hydrazine aluminum sulfate potassium 1%, water 30.5% and print cream 2%；Transparent powdered frit is with matter
Measuring percentages includes Al2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4.5%, ZnO5%,
Lu2O30.5%；
Suspending agent is sodium carboxymethylcellulose, and venting agent is polyacrylic acid；
5, the adobe for being jetted through dry granular glaze enters burning kiln after dry kiln third time is dried, by 1185 DEG C (with firing ring
Subject to the temperature measured), high temperature fires 70min and obtains semi-finished product；
6, semi-finished product are packaged after the soft throwing inspection matter of the fiber polishing block combiner of edging and 800 mesh numbers and are used as finished product.
Embodiment 3
Dry granular glazed tile is prepared as steps described below:
1, the adobe that press is accomplished fluently makes the moisture of adobe less than 0.5% by the Free water inside drying and removing；Adobe goes out
It sprays water after dry kiln on its surface, is formed on its surface water membrane；
2, ground coat enamel then is drenched to billet surface, glaze amount is 90g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO254%, Al2O310%, CaO9%, MgO7%, ZnO14%, K2O4%, Na2O1%, BaO1%；
3, ink jet printer printing pattern, it is dry through second of dry kiln, shorten the drying time of ink；
4, spray drying grain glaze；Dry granular glaze flow velocity is 29s, and specific gravity 1.25g/ml, glaze amount is 70g (pallet of 340*670), carefully
Degree is that siccative weight percent is 0.5% after 200 meshes；Dry granular glaze based on parts by weight, including 48 parts of dry granular, protection glaze 15
Part, 2 parts of kaolinite soil paste, 1 part of burning talcum slurry, 100 parts of suspending agent and 0.08 part of venting agent；
Dry granular includes Al by mass percentage2O39%, SiO250%, CaO15%, K2O5%, MgO10%, BaO8%,
ZnO2%, RuO20.4%, V2O50.1% and Bi2O30.5%；The granularity of dry granular is 150 mesh；
Protect glaze includes transparent powdered frit 55%, sodium carboxymethylcellulose 0.5%, sodium tripolyphosphate by mass percentage
0.4%, aluminium chloride 1%, aluminum sulfate 2%, 12 hydrazine aluminum sulfate potassium 1.1%, water 36% and print cream 4%；
Suspending agent is sodium carboxymethylcellulose, and venting agent is polyvinylpyrrolidone；
5, the adobe for being jetted through dry granular glaze enters burning kiln after dry kiln third time is dried, by 1180 DEG C (with firing ring
Subject to the temperature measured), high temperature fires 65min and obtains semi-finished product；
6, semi-finished product are packaged after the soft throwing inspection matter of the fiber polishing block combiner of edging and 800 mesh numbers and are used as finished product.
Embodiment 4
Dry granular glazed tile is prepared as steps described below:
1, the adobe that press is accomplished fluently makes the moisture of adobe less than 0.5% by the Free water inside drying and removing；Adobe goes out
It sprays water after dry kiln on its surface, is formed on its surface water membrane；
2, ground coat enamel then is drenched to billet surface, glaze amount is 91g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO253%, Al2O311%, CaO8%, MgO8%, ZnO14%, K2O4%, Na2O1%, BaO1%；
3, ink jet printer printing pattern, it is dry through second of dry kiln, shorten the drying time of ink；
4, spray drying grain glaze；Dry granular glaze flow velocity is 30s, and specific gravity 1.26g/ml, glaze amount is 69g (pallet of 340*670), carefully
Degree is that siccative weight percent is 0.45% after 200 meshes；Dry granular glaze based on parts by weight, including 48 parts of dry granular, protection glaze
18 parts, 2 parts of kaolinite soil paste, 1 part of burning talcum slurry, 95 parts of suspending agent and 0.1 part of venting agent；
Dry granular includes Al by mass percentage2O310%, SiO245%, CaO17%, K2O8%, MgO8%, BaO7%,
ZnO4%, RuO20.2%, V2O50.4% and Bi2O30.4%；The granularity of dry granular is 180 mesh；
Protect glaze includes transparent powdered frit 65%, sodium carboxymethylcellulose 0.2%, sodium tripolyphosphate by mass percentage
0.2%, aluminium chloride 1.6%, aluminum sulfate 1%, 12 hydrazine aluminum sulfate potassium 1%, water 30% and print cream 1%；
Suspending agent is sodium carboxymethylcellulose, and venting agent is polyvinyl alcohol；In other preferred embodiments, venting
Agent is also an option that polymaleic anhydride, poly-quaternary ammonium salt or polyethylene glycol.
5, the adobe for being jetted through dry granular glaze enters burning kiln after dry kiln third time is dried, by 1175 DEG C (with firing ring
Subject to the temperature measured), high temperature fires 68min and obtains semi-finished product；
6, semi-finished product are packaged after the soft throwing inspection matter of the fiber polishing block combiner of edging and 800 mesh numbers and are used as finished product.
Comparative example 1
Compared with Example 1, the difference is that, RuO is not contained in dry granular2；
Comparative example 2
Compared with Example 2, the difference is that, protection glaze is not contained in dry granular glaze；
Comparative example 3
Compared with Example 3, the difference is that, suspending agent and venting agent are not contained；
Comparative example 4
Compared with Example 1, the difference is that, 1200 DEG C of firing temperature.
The parameter of testing example 1-4 and comparative example 1-4 resulting product, as a result as shown in table 1 below:
1 test result of table
By upper table 1 it is found that RuO2、V2O5And Bi2O3Addition, can effectively improve the glossiness of finished product, make its acquisition
Matte effect changes puzzlement of the strong light to user's bring sense of discomfort and light pollution of directly reflection generation, meanwhile, it is capable to have
Effect improves anti-pollution；The use for protecting glaze, suspending agent and venting agent is conducive to improve incrustation performance, improves product
Intensity；The control of firing temperature is conducive to optimizing surface structure, improves anti-pollution and antique effect.
Using dry granular provided by the present application and dry granular glaze, dry granular glazed tile obtained is the soft and moist dry granular glazed tile of dumb light, is removed
Except anti-pollution is good, decorative effect is good, resultant effect can also to people's one kind as snug as a bug in a rug, steady and sure, the warm, sense loosened
Feel.
For those skilled in the art, various changes and changes are possible in this application.It is all in spirit herein
Within principle, any modification, equivalent replacement, improvement and so on be should be included within the scope of protection of this application.Although
The present invention is illustrate and described with specific embodiment, however will be appreciated that without departing substantially from the spirit and scope of the present invention
In the case of can make many other change and modification.It is, therefore, intended that in the following claims including belonging to this hair
All such changes and modifications in bright range.
Claims (10)
1. a kind of dry granular, which is characterized in that by percentage to the quality, comprising:
Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%, MgO5-12%, BaO4-10%, ZnO2-5%,
RuO20.1-0.5%.
2. dry granular according to claim 1, which is characterized in that by percentage to the quality, further includes: V2O50.1-0.5% and
Bi2O30.1-0.5%.
3. dry granular according to claim 1 or 2, which is characterized in that the granularity of the dry granular is 120-200 mesh.
4. a kind of dry granular glaze, which is characterized in that based on parts by weight, including the described in any item dry granular 40-50 of claim 1-3
Part, further includes:
Glaze 10-20 parts of protection, 1-3 parts of kaolinite soil paste burn 0.5-1.5 parts of talcum slurry, 90-110 parts of suspending agent and venting agent 0.05-
0.1 part.
5. dry granular glaze according to claim 4, which is characterized in that the dry granular glaze specific gravity is 1.23-1.27g/ml, fineness
For after 200 meshes siccative weight percent be 0.4%-0.6%.
6. dry granular glaze according to claim 4, which is characterized in that the protection glaze includes clear frit by mass percentage
Powder 55-65%, sodium carboxymethylcellulose 0.2-0.5%, sodium tripolyphosphate 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-
2%, 12 hydrazine aluminum sulfate potassium 1-2%, water 30-36% and print cream 1-5%.
7. dry granular glaze according to claim 4, which is characterized in that the suspending agent is sodium carboxymethylcellulose, the row
Black agent is polyacrylamide, polyacrylic acid, polyvinylpyrrolidone, polyvinyl alcohol, polymaleic anhydride, poly-quaternary ammonium salt and poly- second two
One of alcohol.
8. a kind of dry granular glazed tile, which is characterized in that including adobe, ground coat enamel and the described in any item dry granular glaze of claim 4-7.
9. dry granular glazed tile according to claim 8, which is characterized in that the ground coat enamel includes by mass percentage
SiO240-55%, Al2O310-15%, CaO8-10%, MgO5-8%, ZnO10-15%, K2O4-6%, Na2O1-3%, BaO1-
3%.
10. dry granular glazed tile according to claim 8, which is characterized in that firing temperature is 1170-1185 DEG C.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810980018.0A CN109052958B (en) | 2018-08-27 | 2018-08-27 | Dry granules, dry granules glaze and dry granules glazed tile |
| PCT/CN2018/114130 WO2020042355A1 (en) | 2018-08-27 | 2018-11-06 | Dry granules, dry granular glaze, and dry granular glazed tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810980018.0A CN109052958B (en) | 2018-08-27 | 2018-08-27 | Dry granules, dry granules glaze and dry granules glazed tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109052958A true CN109052958A (en) | 2018-12-21 |
| CN109052958B CN109052958B (en) | 2020-11-03 |
Family
ID=64757074
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810980018.0A Active CN109052958B (en) | 2018-08-27 | 2018-08-27 | Dry granules, dry granules glaze and dry granules glazed tile |
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|---|---|
| CN (1) | CN109052958B (en) |
| WO (1) | WO2020042355A1 (en) |
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| CN110981197A (en) * | 2019-12-20 | 2020-04-10 | 佛山欧神诺陶瓷有限公司 | Preparation method of wet-process dry-grain polished crystal brick and polished crystal brick |
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| CN108911701B (en) * | 2018-08-27 | 2021-04-27 | 佛山石湾鹰牌陶瓷有限公司 | Matte dry particle glazed tile and preparation method thereof |
| CN109053226B (en) * | 2018-08-27 | 2021-03-12 | 河源市东源鹰牌陶瓷有限公司 | Method for preparing matte dry particle glazed tile |
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| CN106007377A (en) * | 2016-05-20 | 2016-10-12 | 河源市东源鹰牌陶瓷有限公司 | Super-flat glazed brick |
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| CN113443926A (en) * | 2021-07-19 | 2021-09-28 | 广东道氏技术股份有限公司 | Digital protective glaze ink with dry particle effect and application thereof |
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| CN115448598A (en) * | 2022-09-19 | 2022-12-09 | 江西新明珠建材有限公司 | Dry particle protective glaze, soft marble tile and preparation method thereof |
| CN115448598B (en) * | 2022-09-19 | 2023-09-01 | 江西新明珠建材有限公司 | Dry grain protective glaze, soft marble tile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109052958B (en) | 2020-11-03 |
| WO2020042355A1 (en) | 2020-03-05 |
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