CN109021882A - A kind of house leakage-repairing glue - Google Patents
A kind of house leakage-repairing glue Download PDFInfo
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- CN109021882A CN109021882A CN201810692839.4A CN201810692839A CN109021882A CN 109021882 A CN109021882 A CN 109021882A CN 201810692839 A CN201810692839 A CN 201810692839A CN 109021882 A CN109021882 A CN 109021882A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of house leakage-repairing glues, belong to technical field of polymer materials.According to parts by weight, it successively weighs: 50~60 parts of acrylic acid ester emulsions, 10~15 parts of epoxy resin, 2~3 parts of pigments and fillers, 5~6 parts of dispersing agents, 4~6 parts of surfactants, 2~3 parts of acidification carbon fibers, 8~12 parts of modified graphenes, 8~10 parts of sustained release agents and 10~15 parts of water；Acrylic acid ester emulsion and epoxy resin are mixed in blender, and surfactant is added into blender, carbon fiber, modified graphene, sustained release agent, dispersing agent, pigments and fillers and water is acidified, after being stirred, obtains house leakage-repairing glue.The house leakage-repairing glue of technical solution of the present invention preparation has the characteristics that excellent mechanical property and anti-permeability performance, has broad prospects in the development of high molecular material industry.
Description
Technical field
The invention discloses a kind of house leakage-repairing glues, belong to technical field of polymer materials.
Background technique
Building leakage problem is that very distinct issues, building leakage directly influence the use function in house in Cheng Jianshe
Energy, user security and service life, also cause huge economic losses to enterprise.In building leakage governance process, leakage is generated
It is not a simple process, made of this thing gradually accumulates.It needs to carry out the supervision and management of construction, and needs to building
The place that leakage is likely to occur in building carries out special processing, and carries out comprehensive
Waterproof work.Building leakage-repairing glue has had certain basic condition, and multifunctional house plugging material is in recent years
Come a kind of new material developed, the problem of it can solve wall and leakage of underground engineering water, have moisture-proof, impervious, leak stopping,
The characteristics of bonding.
With emerging in multitude for all kinds of building constructions, building roof, roof tank, floor and waterpipe jointing and municipal administration are net
It is more and more to build to water factory the gap for being possible to occur.It is expected that there are an all kinds of building amounts of thousands of seats in every city every year, and this
The expansion joint waterproof measure on the roof, clear water reserviors, treatment tank of engineerings is produced because of reasons such as construction, quality, material agings a bit
After life phenomena such as rupture etc. and breakage, directly affect using quality, rent situations such as leak is without sealing often occurs, gives
Engineering use and management causes damages, increase trouble.For this purpose, industry develops a kind of leakage-repairing glue, it is coated on gap
Plugging watertight is completed using the characteristic of leakage-repairing glue in place.Existing leakage-repairing glue is mainly the solid paste or artificialization of stationery class
Work high molecular material, leak repairing effect persistence is unsatisfactory, and preparation method is more complex.
And traditional house leakage-repairing glue the problem of can not being further increased there is also mechanical property and leak resistance, therefore,
How to improve conventional house leakage-repairing glue mechanical property and the shortcomings that can not further increasing of leak resistance, is developed in the hope of exploring
House leakage-repairing glue with good comprehensive performance is problem to be solved.
Summary of the invention
The present invention solves the technical problem of: it can not be into for conventional house leakage-repairing glue mechanical property and leak resistance
The shortcomings that one step improves, provides a kind of house leakage-repairing glue.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of house leakage-repairing glue, is made of the raw material of following parts by weight: 50~60 parts of acrylic acid ester emulsions, 10~15 parts of rings
Oxygen resin, 2~3 parts of pigments and fillers, 5~6 parts of dispersing agents, 4~6 parts of surfactants, 2~3 parts of acidification carbon fibers, 8~12 parts change
Property graphene, 8~10 parts of sustained release agents and 10~15 parts of water；It is characterized by:
The modified graphene the preparation method comprises the following steps:
Graphene oxide solution is mixed with ethanol amine 10:1~10:2 in mass ratio, and graphene oxide solution quality is added
0.01~0.08 times of ethylenediamine after being stirred, must pre-process graphene oxide mixture, and pretreatment graphene oxide is mixed
It closes object to mix with hydrazine hydrate 8:1~10:1 in mass ratio, after being stirred, concentrated by rotary evaporation is dry, obtains modified graphene；
The sustained release agent the preparation method comprises the following steps:
Polylactic acid is mixed with methylene chloride 1:10~3:10 in mass ratio, and the tea for being added 0.5~0.8 times of polylactic acid quality is more
Phenol after ultrasonic disperse, obtains interior phase mixture, interior phase mixture is mixed with gelatin solution 2:5~3:5 in mass ratio, and stirring is anti-
Ying Hou is filtered, and is washed, dry, obtains sustained release agent.
The solid content of the acrylic acid ester emulsion is 55~60%.
The epoxy resin is any one in epoxy resin E-51 or epoxy resin E-44.
The pigments and fillers are titanium dioxide, any one in chrome yellow or iron oxide red.
The dispersing agent is dispersing agent NNO, any one in Dispersant MF or dispersing agent 5040.
The surfactant is neopelex, lauryl sodium sulfate, Arlacel-80 or emulsifier op-10
In any one.
The graphene oxide solution is to mix graphene oxide with water 1:100~1:300 in mass ratio, ultrasound point
It dissipates, obtains graphene oxide solution.
The acidification carbon fiber is that 1:3 is mixed by volume with sulfuric acid by nitric acid, mix acid liquor is obtained, by carbon fiber and acetone
The mixing of 1:20~1:30 in mass ratio, filtering obtain pretreatment carbon fiber, will pre-process carbon fiber and mix acid liquor in mass ratio 1:
10~1:15 mixing, impregnates, and filtering, washing to cleaning solution is neutrality, obtains acidification carbon fiber.
The beneficial effects of the present invention are:
(1) modified graphene is added when preparing house leakage-repairing glue in the present invention, firstly, graphene oxide is after modification, second
Amido and graphene surface in hydramine generate interaction force, prevent graphene oxide from reuniting in reduction process same
When so that graphene can be dispersed in water, secondly, modified graphene be added can in product use process with addition
It is acidified carbon fiber to combine, so that the bond strength inside system be made to improve, and then improves the tensile strength of product；
(2) sustained release agent is added when preparing house leakage-repairing glue in the present invention, on the one hand, joined tea polyphenols in sustained release agent, can produce
Slow release in product use process protonates the amido of modified graphene surface grafting, in turn so that the pH of system be made to reduce
Ethanol amine is set to fall off, graphene starts to reunite in the product, forms hydrophobic layer in interiors of products, proposes the leak preventing effect of product
Height, on the other hand, since amido falls off because of protonation, part ethylenediamine can be contacted with the epoxy resin being added in product, from
And make epoxy resin cure, and then further increase the tensile strength of product and leak preventing effect.
Specific embodiment
1:3 is mixed the sulfuric acid for being 70~80% by nitric acid and mass fraction that mass fraction is 60~70% by volume, is obtained
Mix acid liquor mixes carbon fiber with acetone 1:20~1:30 in mass ratio, in temperature be 80~85 DEG C, revolving speed be 200~
After being stirred 40~50h under conditions of 300r/min, filtering obtains pretreatment carbon fiber, by pretreatment carbon fiber and mixed acid
Liquid 1:10~1:15 in mass ratio mixing, after impregnating 5~6h under conditions of being 60 DEG C in temperature, filtering obtains filter cake, filter cake is used
Water washing to cleaning solution is neutrality, obtains acidification carbon fiber；Graphene oxide is mixed with water 1:100~1:300 in mass ratio, in
Under conditions of frequency is 45~55kHz after 30~40min of ultrasonic disperse, graphene oxide solution is obtained；By graphene oxide solution
Be mixed in beaker with ethanol amine 10:1~10:2 in mass ratio, and into beaker be added graphene oxide solution quality 0.01~
0.08 times of ethylenediamine is 45~65 DEG C in temperature, and revolving speed is stirred 60~90min under conditions of being 300~500r/min
Afterwards, graphene oxide mixture must be pre-processed, by pretreatment graphene oxide mixture and hydrazine hydrate 8:1~10:1 in mass ratio
Mixing is 95~98 DEG C in temperature, after revolving speed is stirred 6~7h under conditions of being 300~500r/min, obtains modified graphene
Mixture, by modified graphene mixture in temperature be 60~80 DEG C, revolving speed be 120~150r/min, pressure be 500~
Under conditions of 600kPa after 1~2h of concentrated by rotary evaporation, concentrate is obtained, dry 30 under conditions of being 70~80 DEG C in temperature by concentrate
After~60min, modified graphene is obtained；Polylactic acid and methylene chloride 1:10~3:10 in mass ratio are mixed in flask, and to
0.5~0.8 times of polylactic acid quality of tea polyphenols are added in flask, in 20~40min of ultrasonic disperse that frequency is 45~55kHz
Afterwards, interior phase mixture is obtained, interior phase mixture is mixed with gelatin solution 2:5~3:5 in mass ratio that mass fraction is 2~5%,
It is 45~55 DEG C in temperature, after revolving speed is stirred to react 6~10h under conditions of being 300~400r/min, filtering obtains sustained release agent base
Material, after being water washing 5~6 times of 0~3 DEG C by sustained release agent blank temperature, dry 6 under conditions of being 30~40 DEG C in temperature~
After 8h, sustained release agent is obtained；According to parts by weight, it successively weighs: 50~60 parts of acrylic acid ester emulsions, 10~15 parts of epoxy resin, 2~
3 parts of pigments and fillers, 5~6 parts of dispersing agents, 4~6 parts of surfactants, 2~3 parts of acidification carbon fibers, 8~12 parts of modified graphenes, 8
~10 parts of sustained release agents and 10~15 parts of water；Acrylic acid ester emulsion and epoxy resin are mixed in blender, and into blender
Surfactant is added, is acidified carbon fiber, modified graphene, sustained release agent, dispersing agent, pigments and fillers and water, in temperature be 45~55
DEG C, under conditions of revolving speed is 300~500r/min, after being stirred 30~40min, obtain house leakage-repairing glue.The acrylate
The solid content of lotion is 55~60%.The epoxy resin is any one in epoxy resin E-51 or epoxy resin E-44.It is described
Pigments and fillers are titanium dioxide, any one in chrome yellow or iron oxide red.The dispersing agent is dispersing agent NNO, Dispersant MF or dispersing agent
Any one in 5040.The surfactant is neopelex, lauryl sodium sulfate, Arlacel-80 or emulsification
Any one in agent OP-10.
Example 1
1:3 is mixed the sulfuric acid for being 80% by nitric acid and mass fraction that mass fraction is 70% by volume, mix acid liquor is obtained, by carbon
Fiber is mixed with acetone 1:30 in mass ratio, in temperature be 85 DEG C, revolving speed be 300r/min under conditions of be stirred 50h after,
Filtering, obtains pretreatment carbon fiber, pretreatment carbon fiber is mixed with mix acid liquor 1:15 in mass ratio, the item for being 60 DEG C in temperature
After impregnating 6h under part, filtering obtains filter cake, and filter cake is washed with water to cleaning solution as neutrality, obtains acidification carbon fiber；By graphite oxide
Alkene is mixed with water 1:1:300 in mass ratio, and under conditions of frequency is 55kHz after ultrasonic disperse 40min, it is molten to obtain graphene oxide
Liquid；Graphene oxide solution and ethanol amine 10:2 in mass ratio are mixed in beaker, and graphene oxide is added into beaker
The ethylenediamine that 0.08 times of solution quality is 65 DEG C in temperature, after revolving speed is stirred 90min under conditions of being 500r/min, obtains
Graphene oxide mixture is pre-processed, pretreatment graphene oxide mixture is mixed with hydrazine hydrate 10:1 in mass ratio, Yu Wen
Degree is 98 DEG C, after revolving speed is stirred 7h under conditions of being 500r/min, obtains modified graphene mixture, modified graphene is mixed
It is 80 DEG C, revolving speed 150r/min that object, which is closed, in temperature, under conditions of pressure is 600kPa after concentrated by rotary evaporation 2h, obtains concentrate, will
Under conditions of concentrate is 80 DEG C in temperature after dry 60min, modified graphene is obtained；In mass ratio by polylactic acid and methylene chloride
3:10 is mixed in flask, and 0.8 times of polylactic acid quality of tea polyphenols are added into flask, in the ultrasound point that frequency is 55kHz
After dissipating 40min, interior phase mixture is obtained, interior phase mixture is mixed with the gelatin solution 3:5 in mass ratio that mass fraction is 5%, in
Temperature is 55 DEG C, and after revolving speed is stirred to react 10h under conditions of being 400r/min, filtering obtains sustained release agent blank, by sustained release agent blank
After being water washing 6 times of 3 DEG C with temperature, under conditions of being 40 DEG C in temperature after dry 8h, sustained release agent is obtained；According to parts by weight,
Successively weigh: 60 parts of acrylic acid ester emulsions, 15 parts of epoxy resin, 3 parts of pigments and fillers, 6 parts of dispersing agents, 6 parts of surfactants, 3 parts
It is acidified carbon fiber, 12 parts of modified graphenes, 10 parts of sustained release agents and 15 parts of water；Acrylic acid ester emulsion is mixed in epoxy resin and is stirred
It mixes in machine, and surfactant is added into blender, be acidified carbon fiber, modified graphene, sustained release agent, dispersing agent, pigments and fillers
And water, it is 55 DEG C in temperature, under conditions of revolving speed is 500r/min, after being stirred 40min, obtains house leakage-repairing glue.Described third
The solid content of olefin(e) acid ester lotion is 60%.The epoxy resin is epoxy resin E-51.The pigments and fillers are titanium dioxide.Described point
Powder is dispersing agent NNO.The surfactant is neopelex.
Example 2
1:3 is mixed the sulfuric acid for being 80% by nitric acid and mass fraction that mass fraction is 70% by volume, mix acid liquor is obtained, by carbon
Fiber is mixed with acetone 1:30 in mass ratio, in temperature be 85 DEG C, revolving speed be 300r/min under conditions of be stirred 50h after,
Filtering, obtains pretreatment carbon fiber, pretreatment carbon fiber is mixed with mix acid liquor 1:15 in mass ratio, the item for being 60 DEG C in temperature
After impregnating 6h under part, filtering obtains filter cake, and filter cake is washed with water to cleaning solution as neutrality, obtains acidification carbon fiber；By polylactic acid with
Methylene chloride 3:10 in mass ratio is mixed in flask, and 0.8 times of polylactic acid quality of tea polyphenols are added into flask, in frequency
After the ultrasonic disperse 40min of 55kHz, interior phase mixture is obtained, the gelatin solution that interior phase mixture is 5% with mass fraction is pressed
Mass ratio 3:5 mixing is 55 DEG C in temperature, and after revolving speed is stirred to react 10h under conditions of being 400r/min, filtering obtains sustained release agent
Blank after being water washing 6 times of 3 DEG C by sustained release agent blank temperature, under conditions of being 40 DEG C in temperature after dry 8h, must be sustained
Agent；According to parts by weight, it successively weighs: 60 parts of acrylic acid ester emulsions, 15 parts of epoxy resin, 3 parts of pigments and fillers, 6 parts of dispersing agents, 6
Part surfactant, 3 parts of acidification carbon fibers, 12 parts of graphenes, 10 parts of sustained release agents and 15 parts of water；By acrylic acid ester emulsion and epoxy
Resin is mixed in blender, and surfactant is added into blender, is acidified carbon fiber, graphene, sustained release agent, dispersion
Agent, pigments and fillers and water are 55 DEG C in temperature, under conditions of revolving speed is 500r/min, after being stirred 40min, obtain house leak repairing
Glue.The solid content of the acrylic acid ester emulsion is 60%.The epoxy resin is epoxy resin E-51.The pigments and fillers are titanium white
Powder.The dispersing agent is dispersing agent NNO.The surfactant is neopelex.
Example 3
1:3 is mixed the sulfuric acid for being 80% by nitric acid and mass fraction that mass fraction is 70% by volume, mix acid liquor is obtained, by carbon
Fiber is mixed with acetone 1:30 in mass ratio, in temperature be 85 DEG C, revolving speed be 300r/min under conditions of be stirred 50h after,
Filtering, obtains pretreatment carbon fiber, pretreatment carbon fiber is mixed with mix acid liquor 1:15 in mass ratio, the item for being 60 DEG C in temperature
After impregnating 6h under part, filtering obtains filter cake, and filter cake is washed with water to cleaning solution as neutrality, obtains acidification carbon fiber；By graphite oxide
Alkene is mixed with water 1:1:300 in mass ratio, and under conditions of frequency is 55kHz after ultrasonic disperse 40min, it is molten to obtain graphene oxide
Liquid；Graphene oxide solution and ethanol amine 10:2 in mass ratio are mixed in beaker, and graphene oxide is added into beaker
The ethylenediamine that 0.08 times of solution quality is 65 DEG C in temperature, after revolving speed is stirred 90min under conditions of being 500r/min, obtains
Graphene oxide mixture is pre-processed, pretreatment graphene oxide mixture is mixed with hydrazine hydrate 10:1 in mass ratio, Yu Wen
Degree is 98 DEG C, after revolving speed is stirred 7h under conditions of being 500r/min, obtains modified graphene mixture, modified graphene is mixed
It is 80 DEG C, revolving speed 150r/min that object, which is closed, in temperature, under conditions of pressure is 600kPa after concentrated by rotary evaporation 2h, obtains concentrate, will
Under conditions of concentrate is 80 DEG C in temperature after dry 60min, modified graphene is obtained；According to parts by weight, it successively weighs: 60 parts
Acrylic acid ester emulsion, 15 parts of epoxy resin, 3 parts of pigments and fillers, 6 parts of dispersing agents, 6 parts of surfactants, 3 parts of acidification carbon fibers, 12
Part modified graphene and 15 parts of water；Acrylic acid ester emulsion and epoxy resin are mixed in blender, and are added into blender
Surfactant, is acidified carbon fiber, modified graphene, dispersing agent, pigments and fillers and water, in temperature be 55 DEG C, revolving speed 500r/
Under conditions of min, after being stirred 40min, house leakage-repairing glue is obtained.The solid content of the acrylic acid ester emulsion is 60%.The ring
Oxygen resin is epoxy resin E-51.The pigments and fillers are titanium dioxide.The dispersing agent is dispersing agent NNO.The surfactant
For neopelex.
Comparative example: the house leakage-repairing glue of Jinhua construction material Co., Ltd production.
The resulting house leakage-repairing glue of 1 to 3 example of example and comparative example product are subjected to performance detection, specific detection method is such as
Under:
It is impervious: to be measured according to GB12952.
Test specimen is separately formed according to JC/T547, by test specimen standard test conditions (environment temperature (23 ± 2) DEG C, relatively
Humidity (50 ± 5) %, trial zone recycle wind speed and are less than 0.2m/s) conserve progress tensile bond strength detection after 28d.
Specific testing result is as shown in table 1:
1 house leakage-repairing glue performance test results of table
| Detection project | Example 1 | Example 2 | Example 3 | Comparative example |
| It is impervious | 500mm water column ne-leakage for 24 hours | 500mm water column ne-leakage for 24 hours | 500mm water column ne-leakage for 24 hours | 500mm water column has leakage for 24 hours |
| Tensile strength/MPa | 3.6 | 3.1 | 2.3 | 1.4 |
By 1 testing result of table it is found that the house leakage-repairing glue of technical solution of the present invention preparation has excellent mechanical property and impervious
The characteristics of performance, has broad prospects in the development of high molecular material industry.
Claims (8)
1. a kind of house leakage-repairing glue, is made of the raw material of following parts by weight: 50~60 parts of acrylic acid ester emulsions, 10~15 parts
Epoxy resin, 2~3 parts of pigments and fillers, 5~6 parts of dispersing agents, 4~6 parts of surfactants, 2~3 parts of acidification carbon fibers, 8~12 parts
Modified graphene, 8~10 parts of sustained release agents and 10~15 parts of water；It is characterized by:
The modified graphene the preparation method comprises the following steps:
Graphene oxide solution is mixed with ethanol amine 10:1~10:2 in mass ratio, and graphene oxide solution quality is added
0.01~0.08 times of ethylenediamine after being stirred, must pre-process graphene oxide mixture, and pretreatment graphene oxide is mixed
It closes object to mix with hydrazine hydrate 8:1~10:1 in mass ratio, after being stirred, concentrated by rotary evaporation is dry, obtains modified graphene；
The sustained release agent the preparation method comprises the following steps:
Polylactic acid is mixed with methylene chloride 1:10~3:10 in mass ratio, and the tea for being added 0.5~0.8 times of polylactic acid quality is more
Phenol after ultrasonic disperse, obtains interior phase mixture, interior phase mixture is mixed with gelatin solution 2:5~3:5 in mass ratio, and stirring is anti-
Ying Hou is filtered, and is washed, dry, obtains sustained release agent.
2. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the solid content of the acrylic acid ester emulsion is
55~60%.
3. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the epoxy resin is epoxy resin E-51
Or any one in epoxy resin E-44.
4. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the pigments and fillers be titanium dioxide, chrome yellow or
Any one in iron oxide red.
5. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the dispersing agent is dispersing agent NNO, dispersion
Any one in agent MF or dispersing agent 5040.
6. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the surfactant is detergent alkylate
Any one in sodium sulfonate, lauryl sodium sulfate, Arlacel-80 or emulsifier op-10.
7. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the graphene oxide solution is that will aoxidize
Graphene is mixed with water 1:100~1:300 in mass ratio, and ultrasonic disperse obtains graphene oxide solution.
8. a kind of house leakage-repairing glue according to claim 1, it is characterised in that: the acidification carbon fiber is by nitric acid and sulphur
1:3 is mixed acid by volume, obtains mix acid liquor, carbon fiber is mixed with acetone 1:20~1:30 in mass ratio, filter, obtain pre- place
Carbon fiber is managed, carbon fiber will be pre-processed and mixed with mix acid liquor 1:10~1:15 in mass ratio, impregnated, filtering, washing to washing
Liquid is neutrality, obtains acidification carbon fiber.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110373168A (en) * | 2019-06-21 | 2019-10-25 | 李勇 | A kind of drilling fluid sealing agent |
| CN111718677A (en) * | 2020-03-17 | 2020-09-29 | 东莞市大乘建筑工程技术有限公司 | Adhesive anchor type steel-clad reinforcing bonding material and reinforcing construction method |
| CN115466504A (en) * | 2022-09-22 | 2022-12-13 | 中国电建集团成都勘测设计研究院有限公司 | Polyurethane for filling concrete expansion joint of hydraulic structure and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1640977A (en) * | 2005-01-05 | 2005-07-20 | 长春理工大学 | Polymeric adhesive for exposed wall thermal-insulation |
| CN105384890A (en) * | 2015-12-16 | 2016-03-09 | 江南大学 | Preparation methods of functionalized graphene and functionalized graphene modified waterborne photo-curable polyurethane |
| CN106883793A (en) * | 2017-02-22 | 2017-06-23 | 常州都铂高分子有限公司 | A kind of high temperature resistant peelable type pressure sensitive adhesive and the adhesive tape containing the pressure sensitive adhesive |
| CN107254268A (en) * | 2017-06-17 | 2017-10-17 | 常州瑞坦商贸有限公司 | A kind of acrylate pressure-sensitive adhesive and preparation method thereof |
-
2018
- 2018-06-29 CN CN201810692839.4A patent/CN109021882A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1640977A (en) * | 2005-01-05 | 2005-07-20 | 长春理工大学 | Polymeric adhesive for exposed wall thermal-insulation |
| CN105384890A (en) * | 2015-12-16 | 2016-03-09 | 江南大学 | Preparation methods of functionalized graphene and functionalized graphene modified waterborne photo-curable polyurethane |
| CN106883793A (en) * | 2017-02-22 | 2017-06-23 | 常州都铂高分子有限公司 | A kind of high temperature resistant peelable type pressure sensitive adhesive and the adhesive tape containing the pressure sensitive adhesive |
| CN107254268A (en) * | 2017-06-17 | 2017-10-17 | 常州瑞坦商贸有限公司 | A kind of acrylate pressure-sensitive adhesive and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 尚炎锋等: "《高分子防水卷材胶粘剂》行业标准修订介绍", 《中国建筑防水》 * |
| 朱晓华等: "《聚氯乙烯(PVC)防水卷材》标准解读", 《中国建筑防水》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110373168A (en) * | 2019-06-21 | 2019-10-25 | 李勇 | A kind of drilling fluid sealing agent |
| CN111718677A (en) * | 2020-03-17 | 2020-09-29 | 东莞市大乘建筑工程技术有限公司 | Adhesive anchor type steel-clad reinforcing bonding material and reinforcing construction method |
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