CN108977002A - A kind of environmentally protective floor paint and its production method - Google Patents
A kind of environmentally protective floor paint and its production method Download PDFInfo
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- CN108977002A CN108977002A CN201811017770.1A CN201811017770A CN108977002A CN 108977002 A CN108977002 A CN 108977002A CN 201811017770 A CN201811017770 A CN 201811017770A CN 108977002 A CN108977002 A CN 108977002A
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- protective floor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The present invention relates to a kind of floor paints, and in particular to a kind of environmentally protective floor paint and its production method, the raw material including following parts by weight: 50~80 parts of epoxy resin；10~15 parts of pigment；15~20 parts of pittosporum tobira；5~10 parts of graphene；5~10 parts of tung oil；5~8 parts of aggregate；3~5 parts of Glycerin；1~3 part of thickener；2~3 parts of defoaming agent；1~3 part of levelling agent, environmentally protective floor paint obtained have it is nontoxic, it is environmentally protective, application property is good, storage and transportation and using it is safety and low cost the features such as.Rate of drying is fast, promotes hardness of paint film, has preferable bearing capacity and wearability.
Description
Technical field
The present invention relates to a kind of floor paints, and in particular to a kind of environmentally protective floor paint and its production method.
Background technique
Terrace is the part that bottom room is in contact with soil layer, it bears the load in bottom room, and floor paint is generally used for
Factory floor, field of aerospace, medicine and food manufacturing, hospital, airport, school, sports buildings, are write auto manufacturing
The ground construction of word building, Venue, underground parking or garage, freight yard, freight house, oil depot etc. environment, it is desirable that have one
Fixed strength and stiffness have many advantages, such as beautiful, wear-resisting, waterproof, anti-corrosion.
Chinese patent: a kind of crystallite epoxy flooring coating and preparation method thereof, application number 201510979107.X, abstract:
The present invention relates to chemical coating technical field more particularly to a kind of crystallite epoxy flooring coatings, including following mass percent
Raw material: epoxy resin 40~60%, diluent 5~10%, silicon powder 10~20%, reflective powder 15~30%, auxiliary agent 3
~12%；For the floor paint without containing harmful components such as formaldehyde, ether, the feature of environmental protection is good, will not be right in production or work progress
Human body damages, and will not cause seriously to pollute to environment.In addition, the hardness of paint film is high, wear-resisting after the floor paint drying and forming-film
Property it is good, be not easy to be spent and ruptured by tongue, surface color and polish is distinct, and brightness is high, improve the class of product, product it is good in economic efficiency.
Chinese patent: a kind of quick-drying type environmental protection water epoxy floor paint and preparation method thereof, the invention discloses one for abstract
Kind quick-drying type environmental protection water epoxy floor paint and preparation method thereof, the floor paint is composed of the following components by weight percentage: A
Component: ternary aqueous amine epoxy curing agent 34-36%, wetting agent 0.1-0.3%, titanium dioxide 8-12%, fumed silica 0.8-
The mesh of 1.2%, attapulgite 0.2-0.6%, 800 silica flour 14-16%, mineral oil antifoam agent 0.13-0.17%, organic silicon defoamer
0.13-0.17%, water 37-39%, wherein the sum of weight percent of A component is absolutely；B component: epoxy resin 89.5-
90.5%, epoxy active diluent 9.5-10.5%, wherein the sum of weight percent of B component is absolutely；A component and B
Component is uniformly mixed according to the weight proportion of 4:1.Preparation method includes preparation A component, prepares B component and prepares epoxy
Three steps of floor paint.Present invention obtains splendid coating performance, surface drying does solid work the time and has obtained shortening by a relatively large margin,
Coating mixing property is preferable, environmental protection, with aqueous color paste good compatibility.
Floor paint product currently on the market contains a large amount of benzene,toluene,xylene, free TDI, again based on oiliness
Metal etc. to human body and the harmful substance of environment, open by the raising with living standards of the people and the more concern to environmental issue
The environmentally friendly floor paint for sending out novel becomes a kind of trend.The present invention will study a kind of environmentally protective floor paint, nontoxic,
Environmentally protective, application property is good.
Summary of the invention
The purpose of the present invention is overcome the deficiencies of the prior art and provide a kind of environmentally protective floor paint and production method, solution
Determined larger to the pollution of environment at present, intolerant to sunlight, service life is limited, is easy the problems such as peeling, have it is nontoxic, it is green
The features such as colour circle is protected, and application property is good, storage and transportation and use are safety and low cost.
A kind of environmentally protective floor paint, the raw material including following parts by weight:
50~80 parts of epoxy resin；
10~15 parts of pigment；
15~20 parts of pittosporum tobira；
5~10 parts of graphene；
5~10 parts of tung oil；
5~8 parts of aggregate；
3~5 parts of Glycerin；
1~3 part of thickener；
2~3 parts of defoaming agent；
1~3 part of levelling agent；
Water surplus.
The epoxy resin selects bisphenol F epoxy resin, hydrogenated bisphenol A epoxy resin, methylol bisphenol A-type, weight ratio
Example is 1:3:1；
The pigment is titanium dioxide or phthalocyanine green；
The pittosporum tobira selects the extracting solution of oriental variegated coralbean leaf；
The graphene, the piece diameter of graphene are 5~30um, and thickness is less than 10 layers, specific surface area 30 less than 20 nanometers, the number of plies
~200m2/g；
The tung oil is dried tung oil using microwave, and by moisture evaporating completely, moisture content is 1%~3%；
The aggregate is by natural gravel, bark, clinker, rice husk, old wheel rouge, concrete regenerating fragment, waste plastics or cullet
In any 3 kinds of composition described above；
The thickener is 3551 thickener of DSX；
The defoaming agent is polypropylene glycol or polyacrylic acid；
The levelling agent is levelling agent BYK-320, levelling agent BYK-354 and levelling agent EFKA 3772 according to weight ratio 3:1:2
Mixing.
A kind of production method of environmentally protective floor paint, steps are as follows:
1, early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.4~2.8, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 35~40h, filtering, squeezing filter residue is squeezed
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution by liquid, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:
2~1:5；
(3) paulownia seed to be dried, moisture content is 1%~4%, and shelling purification, being crushed to granularity is 35~45 mesh, it puts into extraction kettle,
It is 40~60 DEG C that temperature, which is arranged, and pressure is 25~35MPa, is extracted, is extracted into 35~45min, temperature is then adjusted to 25
~35 DEG C, pressure is 10~15MPa, extracts tung oil, spare；
2, preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, it is super in 36~38kHz
Sound 35~40 minutes, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 36~38kHz
Ultrasound 35~40 minutes, obtains mixture B；
(3) tung oil is uniformly mixed with pigment, in 36~38kHz ultrasound 35~40 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 60~65 DEG C of rotary evaporation in vacuo to water content be 9~10%, floor paint；
(5) spray bottle is packed, and obtains finished product.
Each raw material plays the role of in coating of the invention:
1, epoxy resin is the organic compound referred in molecule containing two or more epoxy groups, point of epoxy resin
Minor structure be in strand contain active epoxy group be its feature, epoxy group can be located at strand end, in
Between or circlewise structure.It due to containing active epoxy group in molecular structure, send out them can with a plurality of types of curing agent
It gives birth to cross-linking reaction and forms the insoluble high polymer with three-dimensional reticular structure.As the major ingredient in coating of the present invention, have excellent
Good water resistance, corrosion resistance, chemical resistance.
2, the aggregate that the present invention is added is natural gravel, bark, clinker, rice husk, old wheel rouge, concrete regenerating fragment, gives up
Plastics or cullet, performance are better than traditional earth material, have good water penetration, gas permeability, weatherability and extremely strong bonding
Power, short construction period are easy to operate.
3, trihydroxy methyl propane is a trihydroxylic alcohol, and there are three primary hydroxyl, an alkyl branch, the present invention is added into
In floor paint, the solubility of epoxy resin is increased.Due to its special hydrocarbon branched structure, when being applied in this coating, compared with
The polyalcohols such as glycerol, pentaerythrite show better transparency, gloss, dissolubility.Trihydroxy methyl propane is added, can make to set
The performance of rouge is more balanced, and the form of expression is being obviously improved for film clarity.
4, graphene (Graphene) be it is a kind of by carbon atom with sp2 hybridized orbit form hexangle type be in honeycomb lattice two
Tie up carbon nanomaterial.Graphene is the two-dimensional material of a carbon atom thickness, has special honeycomb lattice structure form, it is
The highest substance of mechanical strength known to the mankind, it is also harder than diamond, taller upper 100 times of the intensity steel more best than the world.It
It is the most conductive material in the world, electronics has reached the 1/300 of the light velocity in movement velocity wherein, considerably beyond electronics
Movement velocity in general conductor.It also has good flexibility, high thermal conductivity, the property such as chemical stabilization and physical shielding
Energy.Graphene microchip and other high molecular materials are compound, the mechanical property and shielding of improvement high molecular material that can be splendid
Energy.Graphene is applied in this coating, the lamellar structure of graphene can improve corrosion-inhibiting coating, play the work of shielding barrier
With.
5, volatile component in oriental variegated coralbean leaf, respectively hendecane (undecane, 31.1%), 4- methyl-1,3- pentadiene
(4-methyl-1,3-pentadiene, 11.3%), 1,3- dimethyl -2- cyclobutenyl benzene [(1,3-dimethyl-2-
Butenyl) benzene, 5.45%], limonene (L-limonene, 14.1%) etc.；Pittosporum tobira shell and seed contain more oil
Rouge, main component are as follows: palmitinic acid (palmitic acid) and oleic acid (oleic acid).
Hendecane (chemical formula: C11H24, formula weight 156.31) colourless liquid.- 26 DEG C of fusing point, 196 DEG C of boiling point, density
0.74g/mL, 60 DEG C of flash-point.It is not soluble in water, it is miscible in alcohol, ether.Stablize under normal temperature and pressure, oxide interface is avoided to be present in
In cured tobacco leaf, flue gas.For manufacturing refrigerant, insecticide, lubricant, paint etc..
By pittosporum tobira be applied to terrace paint coating of the invention in, environmental protection, can also anticorrosion, the performances such as antirust.
6, tung oil is a kind of excellent band dry vegetable oil, it is the primary raw material of manufacture paint, ink, the present invention by its
For in floor paint, having the characteristics that chemical resistance, anti-corrosion, antirust.
Compared with prior art, present invention substantive distinguishing features outstanding and significant progress are:
1, epoxy resin has excellent water resistance, corrosion resistance, chemical resistance as the major ingredient in coating of the present invention；
The aggregate that the present invention is added has good water penetration, gas permeability, weatherability and extremely strong cohesive force；Trihydroxy methyl propane makes
Obtain being obviously improved for film clarity；Graphene plays the role of shielding barrier to improve corrosion-inhibiting coating；Pittosporum tobira makes with tung oil
This coating has the characteristics that chemical resistance, anti-corrosion, antirust.
2, solve larger to the pollution of environment at present, intolerant to sunlight, service life is limited, is easy the problems such as peeling, tool
Have it is nontoxic, it is environmentally protective, application property is good, storage and transportation and using it is safety and low cost the features such as.Rate of drying is fast, promotes paint
Film hardness has preferable bearing capacity and wearability.
Specific embodiment
Embodiment 1
A kind of environmentally protective floor paint, the raw material including following parts by weight: 50 parts of epoxy resin；10 parts of pigment；15 parts of pittosporum tobira；
5 parts of graphene；5 parts of tung oil；5 parts of aggregate；3 parts of Glycerin；1 part of thickener；2 parts of defoaming agent；1 part of levelling agent；Water surplus.
The pigment is titanium dioxide；The pittosporum tobira selects the extracting solution of oriental variegated coralbean leaf；The graphene, the piece diameter of graphene
For 15um, thickness is less than 10 layers, specific surface area 30m less than 20 nanometers, the number of plies2/g；The tung oil, using microwave to tung oil into
Row drying, by moisture evaporating completely, moisture content 3%；The aggregate is made of natural gravel, bark, clinker；The defoaming
Agent is polypropylene glycol.
A kind of production method of environmentally protective floor paint, steps are as follows:
1, early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.4, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 35h, filtering, squeezing filter residue obtains pressed liquor, will
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:2；
(3) paulownia seed is dried, moisture content 3%, shelling purification, being crushed to granularity is 35 mesh, is put into extraction kettle, and temperature is arranged
It is 40 DEG C, pressure 25MPa is extracted, and 35min is extracted into, and temperature is then adjusted to 25 DEG C, pressure 10MPa, extracts paulownia
Oil, it is spare；
2, preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, in 36kHz ultrasound 35
Minute, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 36kHz ultrasound
35 minutes, obtain mixture B；
(3) tung oil is uniformly mixed with pigment, in 36kHz ultrasound 35 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 60 DEG C of rotary evaporation in vacuo to water content be 9%, floor paint；
(5) spray bottle is packed, and obtains finished product.
Embodiment 2
A kind of environmentally protective floor paint, the raw material including following parts by weight: 60 parts of epoxy resin；12 parts of pigment；17 parts of pittosporum tobira；
7 parts of graphene；7 parts of tung oil；6 parts of aggregate；4 parts of Glycerin；2 parts of thickener；3 parts of defoaming agent；2 parts of levelling agent；Water surplus.
The epoxy resin selects bisphenol F epoxy resin, hydrogenated bisphenol A epoxy resin, methylol bisphenol A-type, weight ratio
Example is 1:3:1；The pigment is phthalocyanine green；The pittosporum tobira selects the extracting solution of oriental variegated coralbean leaf；The graphene, the piece of graphene
Diameter is 20um, and thickness is less than 10 layers, specific surface area 50m less than 20 nanometers, the number of plies2/g；The tung oil, using microwave to tung oil
It is dried, by moisture evaporating completely, moisture content 3%；The aggregate is made of natural gravel, rice husk and old wheel rouge；Institute
Defoaming agent is stated, is polyacrylic acid.
A kind of production method of environmentally protective floor paint, steps are as follows:
1, early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.5, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 38h, filtering, squeezing filter residue obtains pressed liquor, will
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:3；
(3) paulownia seed is dried, moisture content 3%, shelling purification, being crushed to granularity is 40 mesh, is put into extraction kettle, and temperature is arranged
It is 50 DEG C, pressure 30MPa is extracted, and 40min is extracted into, and temperature is then adjusted to 30 DEG C, pressure 12MPa, extracts paulownia
Oil, it is spare；
2, preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, in 37kHz ultrasound 40
Minute, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 37kHz ultrasound
40 minutes, obtain mixture B；
(3) tung oil is uniformly mixed with pigment, in 37kHz ultrasound 40 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 62 DEG C of rotary evaporation in vacuo to water content be 10%, floor paint；
(5) spray bottle is packed, and obtains finished product.
Embodiment 3
A kind of environmentally protective floor paint, the raw material including following parts by weight: 70 parts of epoxy resin；13 parts of pigment；18 parts of pittosporum tobira；
8 parts of graphene；8 parts of tung oil；7 parts of aggregate；5 parts of Glycerin；3 parts of thickener；3 parts of defoaming agent；3 parts of levelling agent；Water surplus.
The epoxy resin selects bisphenol F epoxy resin, hydrogenated bisphenol A epoxy resin, methylol bisphenol A-type, weight ratio
Example is 1:3:1；The pigment is titanium dioxide；The pittosporum tobira selects the extracting solution of oriental variegated coralbean leaf；The graphene, the piece of graphene
Diameter is 15um, and thickness is less than 10 layers, specific surface area 100m less than 20 nanometers, the number of plies2/g；The tung oil, using microwave to paulownia
Oil is dried, by moisture evaporating completely, moisture content 3%；The aggregate is by old wheel rouge, concrete regenerating fragment and useless modeling
Material composition；The defoaming agent is polypropylene glycol.
A kind of production method of environmentally protective floor paint, steps are as follows:
1, early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.6, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 38h, filtering, squeezing filter residue obtains pressed liquor, will
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:4；
(3) paulownia seed is dried, moisture content 4%, shelling purification, being crushed to granularity is 45 mesh, is put into extraction kettle, and temperature is arranged
It is 50 DEG C, pressure 35MPa is extracted, and 45min is extracted into, and temperature is then adjusted to 35 DEG C, pressure 15MPa, extracts paulownia
Oil, it is spare；
2, preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, in 38kHz ultrasound 35
Minute, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 38kHz ultrasound
35 minutes, obtain mixture B；
(3) tung oil is uniformly mixed with pigment, in 38kHz ultrasound 35 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 65 DEG C of rotary evaporation in vacuo to water content be 10%, floor paint；
(5) spray bottle is packed, and obtains finished product.
Embodiment 4
A kind of environmentally protective floor paint, the raw material including following parts by weight: 80 parts of epoxy resin；15 parts of pigment；20 parts of pittosporum tobira；
10 parts of graphene；10 parts of tung oil；8 parts of aggregate；5 parts of Glycerin；3 parts of thickener；3 parts of defoaming agent；3 parts of levelling agent；More than water
Amount.
The epoxy resin selects bisphenol F epoxy resin, hydrogenated bisphenol A epoxy resin, methylol bisphenol A-type, weight ratio
Example is 1:3:1；The pigment, phthalocyanine green；The pittosporum tobira selects the extracting solution of oriental variegated coralbean leaf；The graphene, the piece diameter of graphene
For 20um, thickness is less than 10 layers, specific surface area 150m less than 20 nanometers, the number of plies2/g；The tung oil, using microwave to tung oil
It is dried, by moisture evaporating completely, moisture content 3%；The aggregate is by natural gravel, concrete regenerating fragment and broken glass
Glass composition；The defoaming agent is polyacrylic acid.
A kind of production method of environmentally protective floor paint, steps are as follows:
1, early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.8, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 40h, filtering, squeezing filter residue obtains pressed liquor, will
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:5；
(3) paulownia seed is dried, moisture content 4%, shelling purification, being crushed to granularity is 45 mesh, is put into extraction kettle, and temperature is arranged
It is 60 DEG C, pressure 35MPa is extracted, and 45min is extracted into, and temperature is then adjusted to 35 DEG C, pressure 15MPa, extracts paulownia
Oil, it is spare；
2, preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, in 36kHz ultrasound 40
Minute, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 36kHz ultrasound
40 minutes, obtain mixture B；
(3) tung oil is uniformly mixed with pigment, in 36kHz ultrasound 40 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 65 DEG C of rotary evaporation in vacuo to water content be 10%, floor paint；
(5) spray bottle is packed, and obtains finished product.
Through detecting, quality and technical index is as follows:
Claims (10)
1. a kind of environmentally protective floor paint, which is characterized in that the raw material including following parts by weight:
50~80 parts of epoxy resin；
10~15 parts of pigment；
15~20 parts of pittosporum tobira；
5~10 parts of graphene；
5~10 parts of tung oil；
5~8 parts of aggregate；
3~5 parts of Glycerin；
1~3 part of thickener；
2~3 parts of defoaming agent；
1~3 part of levelling agent；
Water surplus；
The production method of the environmentally protective floor paint, steps are as follows:
Early-stage preparations:
(1) pre-processing is carried out to aggregate, so that fineness of aggregate modulus is 2.4~2.8, it is spare；
(2) leaf of pittosporum tobira, shell or seed are dipped in deionized water, impregnate 35~40h, filtering, squeezing filter residue is squeezed
Pressed liquor and filtered fluid are mixed to get pittosporum tobira extracting solution by liquid, spare, and the mass ratio of the pittosporum tobira and the deionized water is 1:
2~1:5；
(3) paulownia seed to be dried, moisture content is 1%~4%, and shelling purification, being crushed to granularity is 35~45 mesh, it puts into extraction kettle,
It is 40~60 DEG C that temperature, which is arranged, and pressure is 25~35MPa, is extracted, is extracted into 35~45min, temperature is then adjusted to 25
~35 DEG C, pressure is 10~15MPa, extracts tung oil, spare；
Preparation process:
(1) epoxy resin is uniformly mixed with pittosporum tobira extracting solution, adds Glycerin, be uniformly mixed, it is super in 36~38kHz
Sound 35~40 minutes, obtain mixture A；
(2) graphene is uniformly mixed with aggregate, adds thickener, defoaming agent, levelling agent, be uniformly mixed, in 36~38kHz
Ultrasound 35~40 minutes, obtains mixture B；
(3) tung oil is uniformly mixed with pigment, in 36~38kHz ultrasound 35~40 minutes, obtains mixture C；
(4) A, B, C be uniformly mixed, in 60~65 DEG C of rotary evaporation in vacuo to water content be 9~10%, floor paint；
(5) spray bottle is packed, and obtains finished product.
2. environmentally protective floor paint according to claim 1, which is characterized in that the epoxy resin selects Bisphenol F epoxy
Resin, hydrogenated bisphenol A epoxy resin, methylol bisphenol A-type, weight ratio 1:3:1.
3. environmentally protective floor paint according to claim 1, which is characterized in that the pigment is titanium dioxide or phthalocyanine green.
4. environmentally protective floor paint according to claim 1, which is characterized in that the pittosporum tobira selects the extraction of oriental variegated coralbean leaf
Liquid.
5. environmentally protective floor paint according to claim 1, which is characterized in that the graphene, the piece diameter of graphene are 5
~30um, thickness are 30~200m2/g less than 10 layers, specific surface area less than 20 nanometers, the number of plies.
6. environmentally protective floor paint according to claim 1, which is characterized in that the tung oil, using microwave to tung oil into
Row drying, by moisture evaporating completely, moisture content is 1%~3%.
7. environmentally protective floor paint according to claim 1, which is characterized in that the aggregate is by natural gravel, tree
Any 3 kinds of composition described above in skin, clinker, rice husk, old wheel rouge, concrete regenerating fragment, waste plastics or cullet.
8. environmentally protective floor paint according to claim 1, which is characterized in that the thickener thickens for DSX 3551
Agent.
9. environmentally protective floor paint according to claim 1, which is characterized in that the defoaming agent is polypropylene glycol or poly-
Acrylic acid.
10. environmentally protective floor paint according to claim 1, which is characterized in that the levelling agent is levelling agent BYK-
320, levelling agent BYK-354 and levelling agent EFKA 3772 is mixed according to weight ratio 3:1:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017770.1A CN108977002A (en) | 2018-09-03 | 2018-09-03 | A kind of environmentally protective floor paint and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811017770.1A CN108977002A (en) | 2018-09-03 | 2018-09-03 | A kind of environmentally protective floor paint and its production method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108977002A true CN108977002A (en) | 2018-12-11 |
Family
ID=64548327
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811017770.1A Pending CN108977002A (en) | 2018-09-03 | 2018-09-03 | A kind of environmentally protective floor paint and its production method |
Country Status (1)
| Country | Link |
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| CN (1) | CN108977002A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113337185A (en) * | 2021-07-28 | 2021-09-03 | 哈尔滨市雪鹰工程材料有限公司 | Temperature difference resistant floor paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008169398A (en) * | 2008-02-14 | 2008-07-24 | Kaneka Corp | Curable coating composition for floor and method for forming coating film for floor by using the same |
| CN104845491A (en) * | 2015-04-30 | 2015-08-19 | 宁波墨西科技有限公司 | Graphene composite floor coating and preparation method thereof |
| CN108148460A (en) * | 2018-01-18 | 2018-06-12 | 广东洁达涂料有限公司 | A kind of aqueous floor paint |
-
2018
- 2018-09-03 CN CN201811017770.1A patent/CN108977002A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008169398A (en) * | 2008-02-14 | 2008-07-24 | Kaneka Corp | Curable coating composition for floor and method for forming coating film for floor by using the same |
| CN104845491A (en) * | 2015-04-30 | 2015-08-19 | 宁波墨西科技有限公司 | Graphene composite floor coating and preparation method thereof |
| CN108148460A (en) * | 2018-01-18 | 2018-06-12 | 广东洁达涂料有限公司 | A kind of aqueous floor paint |
Non-Patent Citations (1)
| Title |
|---|
| 李国华: "《建筑材料》", 30 September 2013, 中国建材工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113337185A (en) * | 2021-07-28 | 2021-09-03 | 哈尔滨市雪鹰工程材料有限公司 | Temperature difference resistant floor paint |
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Application publication date: 20181211 |