CN108933248A - 一种锂离子电池负极材料尖晶石型球形高熵氧化物材料的制备方法 - Google Patents
一种锂离子电池负极材料尖晶石型球形高熵氧化物材料的制备方法 Download PDFInfo
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- CN108933248A CN108933248A CN201810815366.2A CN201810815366A CN108933248A CN 108933248 A CN108933248 A CN 108933248A CN 201810815366 A CN201810815366 A CN 201810815366A CN 108933248 A CN108933248 A CN 108933248A
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- lithium ion
- ion battery
- high entropy
- battery negative
- entropy oxide
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- 239000000463 material Substances 0.000 title claims abstract description 41
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011651 chromium Substances 0.000 claims abstract description 8
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 239000012279 sodium borohydride Substances 0.000 claims abstract description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims abstract description 5
- 229910002651 NO3 Inorganic materials 0.000 claims abstract description 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 3
- 150000003891 oxalate salts Chemical class 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 150000003839 salts Chemical class 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 2
- 239000007791 liquid phase Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000004615 ingredient Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- FBHNJVAPQXOPOB-UHFFFAOYSA-L [Na+].[Na+].OS(=O)S(O)=O.[O-]S(=O)S([O-])=O Chemical compound [Na+].[Na+].OS(=O)S(O)=O.[O-]S(=O)S([O-])=O FBHNJVAPQXOPOB-UHFFFAOYSA-L 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000006479 redox reaction Methods 0.000 abstract 1
- 238000006722 reduction reaction Methods 0.000 abstract 1
- 229910052596 spinel Inorganic materials 0.000 description 6
- 239000011029 spinel Substances 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 5
- 239000007773 negative electrode material Substances 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- UPWOEMHINGJHOB-UHFFFAOYSA-N oxo(oxocobaltiooxy)cobalt Chemical compound O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 description 2
- -1 thio sulphur Chemical compound 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910016287 MxOy Inorganic materials 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052927 chalcanthite Inorganic materials 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- NNGHIEIYUJKFQS-UHFFFAOYSA-L hydroxy(oxo)iron;zinc Chemical compound [Zn].O[Fe]=O.O[Fe]=O NNGHIEIYUJKFQS-UHFFFAOYSA-L 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 238000009766 low-temperature sintering Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052987 metal hydride Inorganic materials 0.000 description 1
- 238000001451 molecular beam epitaxy Methods 0.000 description 1
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/364—Composites as mixtures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/523—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron for non-aqueous cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Compounds Of Iron (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
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CN201810815366.2A CN108933248B (zh) | 2018-07-23 | 2018-07-23 | 一种锂离子电池负极材料尖晶石型球形高熵氧化物材料的制备方法 |
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CN108933248A true CN108933248A (zh) | 2018-12-04 |
CN108933248B CN108933248B (zh) | 2021-02-09 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109748303A (zh) * | 2019-03-19 | 2019-05-14 | 大连交通大学 | 高纯球形镁铝尖晶石纳米粉体的制备方法 |
CN110556536A (zh) * | 2019-09-19 | 2019-12-10 | 安徽工业大学 | 用于锂离子电池的六元高熵氧化物材料及制备方法 |
CN110600724A (zh) * | 2019-09-19 | 2019-12-20 | 安徽工业大学 | 一种锂离子电池用五元过渡-非过渡高熵氧化物负极材料 |
CN111333124A (zh) * | 2020-03-06 | 2020-06-26 | 西安交通大学 | 一种空心结构的尖晶石型介孔高熵氧化物纳米球及其制备方法和应用 |
CN111348910A (zh) * | 2020-03-10 | 2020-06-30 | 南昌航空大学 | 一种六元尖晶石型铁钴铬锰镍铜系高熵氧化物及其粉体制备方法 |
CN111620681A (zh) * | 2020-06-16 | 2020-09-04 | 湖南大学 | 一种高熵氧化物材料的制备方法 |
CN113461415A (zh) * | 2021-07-19 | 2021-10-01 | 中国科学院兰州化学物理研究所 | 一种水热法制备高熵氧化物材料(MAlFeCuMg)3O4的方法 |
CN113621988A (zh) * | 2021-08-11 | 2021-11-09 | 东北大学秦皇岛分校 | 一种高效氧析出高熵非晶氧化物纳米催化剂及其制备方法和应用 |
CN114618522A (zh) * | 2020-12-11 | 2022-06-14 | 中国科学院大连化学物理研究所 | 金属氧化物负载的高熵合金制备及合成丙酸甲酯的方法 |
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CN106756417A (zh) * | 2016-12-20 | 2017-05-31 | 安徽工业大学 | 一种可控制备CoCrCuFeNi高熵合金粉体的方法 |
CN107824801A (zh) * | 2017-11-15 | 2018-03-23 | 安徽工业大学 | 一种不同形貌非晶态CoCrCuFeNi高熵合金粉体的制备方法 |
CN107994228A (zh) * | 2017-12-25 | 2018-05-04 | 中国工程物理研究院电子工程研究所 | 一种锂离子电池五元高熵氧化物纳米薄膜及其制备和应用 |
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2018
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CN106756417A (zh) * | 2016-12-20 | 2017-05-31 | 安徽工业大学 | 一种可控制备CoCrCuFeNi高熵合金粉体的方法 |
CN107824801A (zh) * | 2017-11-15 | 2018-03-23 | 安徽工业大学 | 一种不同形貌非晶态CoCrCuFeNi高熵合金粉体的制备方法 |
CN107994228A (zh) * | 2017-12-25 | 2018-05-04 | 中国工程物理研究院电子工程研究所 | 一种锂离子电池五元高熵氧化物纳米薄膜及其制备和应用 |
Non-Patent Citations (2)
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ABHISHEK SARKARA ET.AL: "Nanocrystalline multicomponent entropy stabilised transition metal oxides", 《JOURNAL OF THE EUROPEAN CERAMIC SOCIETY》 * |
JULIUSZ DA˛BROWA ET.AL: "Synthesis and microstructure of the (Co,Cr,Fe,Mn,Ni)3O4 high entropy oxide characterized by spinel structure", 《MATERIALS LETTERS》 * |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109748303B (zh) * | 2019-03-19 | 2022-02-08 | 大连交通大学 | 高纯球形镁铝尖晶石纳米粉体的制备方法 |
CN109748303A (zh) * | 2019-03-19 | 2019-05-14 | 大连交通大学 | 高纯球形镁铝尖晶石纳米粉体的制备方法 |
CN110556536A (zh) * | 2019-09-19 | 2019-12-10 | 安徽工业大学 | 用于锂离子电池的六元高熵氧化物材料及制备方法 |
CN110600724A (zh) * | 2019-09-19 | 2019-12-20 | 安徽工业大学 | 一种锂离子电池用五元过渡-非过渡高熵氧化物负极材料 |
CN110600724B (zh) * | 2019-09-19 | 2022-08-02 | 安徽工业大学 | 一种锂离子电池用五元过渡-非过渡高熵氧化物负极材料 |
CN110556536B (zh) * | 2019-09-19 | 2022-06-14 | 安徽工业大学 | 用于锂离子电池的六元高熵氧化物材料及制备方法 |
CN111333124A (zh) * | 2020-03-06 | 2020-06-26 | 西安交通大学 | 一种空心结构的尖晶石型介孔高熵氧化物纳米球及其制备方法和应用 |
CN111348910A (zh) * | 2020-03-10 | 2020-06-30 | 南昌航空大学 | 一种六元尖晶石型铁钴铬锰镍铜系高熵氧化物及其粉体制备方法 |
CN111348910B (zh) * | 2020-03-10 | 2022-08-12 | 南昌航空大学 | 一种六元尖晶石型铁钴铬锰镍铜系高熵氧化物及其粉体制备方法 |
CN111620681A (zh) * | 2020-06-16 | 2020-09-04 | 湖南大学 | 一种高熵氧化物材料的制备方法 |
CN114618522A (zh) * | 2020-12-11 | 2022-06-14 | 中国科学院大连化学物理研究所 | 金属氧化物负载的高熵合金制备及合成丙酸甲酯的方法 |
CN114618522B (zh) * | 2020-12-11 | 2023-06-20 | 中国科学院大连化学物理研究所 | 金属氧化物负载的高熵合金制备及合成丙酸甲酯的方法 |
CN113461415A (zh) * | 2021-07-19 | 2021-10-01 | 中国科学院兰州化学物理研究所 | 一种水热法制备高熵氧化物材料(MAlFeCuMg)3O4的方法 |
CN113621988A (zh) * | 2021-08-11 | 2021-11-09 | 东北大学秦皇岛分校 | 一种高效氧析出高熵非晶氧化物纳米催化剂及其制备方法和应用 |
CN113621988B (zh) * | 2021-08-11 | 2022-07-08 | 东北大学秦皇岛分校 | 一种高效氧析出高熵非晶氧化物纳米催化剂及其制备方法和应用 |
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