CN108912907A - Potent anti-oxidant quick drying paint of one kind and preparation method thereof - Google Patents

Potent anti-oxidant quick drying paint of one kind and preparation method thereof Download PDF

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Publication number
CN108912907A
CN108912907A CN201810520975.5A CN201810520975A CN108912907A CN 108912907 A CN108912907 A CN 108912907A CN 201810520975 A CN201810520975 A CN 201810520975A CN 108912907 A CN108912907 A CN 108912907A
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CN
China
Prior art keywords
parts
coating
oxidant
quick drying
potent anti
Prior art date
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Pending
Application number
CN201810520975.5A
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Chinese (zh)
Inventor
王和山
王厚国
王和东
殷东楼
殷芳荣
曹文强
张万霞
张萍
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Anhui Kailin New Material Co Ltd
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Anhui Kailin New Material Co Ltd
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Publication date
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Priority to CN201810520975.5A priority Critical patent/CN108912907A/en
Publication of CN108912907A publication Critical patent/CN108912907A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides potent anti-oxidant quick drying paint of one kind and preparation method thereof, is related to coating processing technique field.The coating is made of raw material from the following weight:40-50 parts of acrylic resin, 6-12 parts of epoxy resin, 2-3 parts of graphene, 8-12 parts of butyl acetate, 2-4 parts of polylactide, 4-8 parts of silicone oil, 3-6 parts of zinc oxide, 1-2 parts of titanium dioxide, 1.6-2.8 parts of thio-2 acid dibasic acid esters, 2-2.6 parts of pentalyn, 1.4-1.6 parts of levelling agent, 0.6-1.4 parts of defoaming agent;Coating of the present invention improves the coating film forming dry time, and the present invention, while with high-efficiency antioxidant performance, film forming thickness is high, and protective effect is strong, reduces the number of coating material, effectively reduces cost and reduces manual labor.

Description

Potent anti-oxidant quick drying paint of one kind and preparation method thereof
Technical field
The present invention relates to coating processing technique fields, and in particular to the potent anti-oxidant quick drying paint of one kind and its preparation side Method.
Background technique
Coating (paint), our usually described paint are only one such.Finger is coated on body surface certain Under the conditions of can form film and play a class I liquid I of protection, decoration or other specific functions (insulation, antirust, mould proof, heat-resisting etc.) Or solid material.Because the coating of early stage is mostly using vegetable oil as primary raw material, therefore also referred to as paint.Present synthetic resin has replaced Vegetable oil, therefore referred to as coating.
The main function of coating is exactly to protect coated product, and the performance of coating and service life longer are protected under normal circumstances The service life of the product of shield is longer, so the antioxygenic property of coating is one very important performance;In addition coating makes With in the process in order to reach ideal protecting effect, often using the method for being superimposed coating repeatedly, but now on the market Drying time is slow after coating most coated, and distance uses long period, influences the efficiency of production and processing.
Summary of the invention
In view of the shortcomings of the prior art, the present invention provides potent anti-oxidant quick drying paint of one kind and preparation method thereof, improve The coating film forming dry time, and the present invention, while with high-efficiency antioxidant performance, film forming thickness is high, protective effect By force, the number for reducing coating material effectively reduces cost and reduces manual labor.
In order to achieve the above object, technical solution of the present invention is achieved by the following technical programs:
A kind of potent anti-oxidant quick drying paint, the coating are made of raw material from the following weight:Acrylic resin 40-50 Part, 6-12 parts of epoxy resin, 2-3 parts of graphene, 8-12 parts of butyl acetate, 2-4 parts of polylactide, 4-8 parts of silicone oil, zinc oxide 3- 6 parts, 1-2 parts of titanium dioxide, 1.6-2.8 parts of thio-2 acid dibasic acid esters, 2-2.6 parts of pentalyn, levelling agent 1.4-1.6 Part, 0.6-1.4 parts of defoaming agent.
Preferably, a kind of potent anti-oxidant quick drying paint, the coating are made of raw material from the following weight:Acrylic acid tree 45 parts of rouge, 9 parts of epoxy resin, 2.5 parts of graphene, 10 parts of butyl acetate, 3 parts of polylactide, 6 parts of silicone oil, 4.5 parts of zinc oxide, 1.5 parts of titanium dioxide, 2.2 parts of thio-2 acid dibasic acid esters, 2.3 parts of pentalyn, 1.5 parts of levelling agent, 1 part of defoaming agent.
Preferably, the levelling agent is carboxymethyl cellulose;The defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of preparation method of potent anti-oxidant quick drying paint, the preparation method comprises the following steps:
(1) acrylic resin and epoxy resin are mixed, takes the deionized water of latter times of volume parts of mixing, is heated to 50-55 DEG C, then mixed resin is poured into deionized water, it is spare to obtain hybrid resin by the uniform velocity stirring 40-60min;
(2) butyl acetate, polylactide, silicone oil, thio-2 acid dibasic acid esters and pentalyn are poured into blender Middle mixing, it is spare to obtain mixed slurry;
(3) by graphene, zinc oxide and titanium dioxide mix after be placed in together in the hybrid resin in above-mentioned steps (1) In dispersion cylinder, 30-40min is stirred, then levelling agent and defoaming agent are poured into dispersion cylinder, stirs 60-70min;
(4) mixed slurry in above-mentioned steps (2) is poured into the dispersion cylinder in step (3), is warming up to 35-40 DEG C, it is even Speed stirring 2-3h, obtains coating of the present invention.
The present invention provides potent anti-oxidant quick drying paint of one kind and preparation method thereof, and advantage is compared with prior art:
(1) present invention uses acrylic resin for base-material, cooperates via epoxy resin modification and various additives addition, The film forming speed that coating of the present invention can effectively be promoted, reaches the effect of rapid-curing cutback.
(2) it is added with thio-2 acid dibasic acid esters and pentalyn in coating of the present invention, can promote the anti-of coating Oxidation effectiveness, and with polylactide complex reaction, greatly promote its performance, reach that dosage is minimum, and antioxidant effect is most Good state.
(3) present invention is added with graphene and butyl acetate while promoting coating overall performance, with thio-2 acid Dibasic acid esters cooperates the adhesiveness for increasing coating together, while increasing the thickness of coating film forming.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below with reference to the embodiment of the present invention pair Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is a part of the invention Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making wound Every other embodiment obtained under the premise of the property made labour, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of potent anti-oxidant quick drying paint, the coating are made of raw material from the following weight:40 parts of acrylic resin, 6 parts of epoxy resin, 2 parts of graphene, 8 parts of butyl acetate, 2 parts of polylactide, 4 parts of silicone oil, 3 parts of zinc oxide, 1 part of titanium dioxide, 1.6 parts of thio-2 acid dibasic acid esters, 2 parts of pentalyn, 1.4 parts of levelling agent, 0.6 part of defoaming agent.
The levelling agent is carboxymethyl cellulose;The defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of preparation method of potent anti-oxidant quick drying paint, the preparation method comprises the following steps:
(1) acrylic resin and epoxy resin are mixed, takes the deionized water of latter times of volume parts of mixing, is heated to 50-55 DEG C, then mixed resin is poured into deionized water, it is spare to obtain hybrid resin by the uniform velocity stirring 40-60min;
(2) butyl acetate, polylactide, silicone oil, thio-2 acid dibasic acid esters and pentalyn are poured into blender Middle mixing, it is spare to obtain mixed slurry;
(3) by graphene, zinc oxide and titanium dioxide mix after be placed in together in the hybrid resin in above-mentioned steps (1) In dispersion cylinder, 30-40min is stirred, then levelling agent and defoaming agent are poured into dispersion cylinder, stirs 60-70min;
(4) mixed slurry in above-mentioned steps (2) is poured into the dispersion cylinder in step (3), is warming up to 35-40 DEG C, it is even Speed stirring 2-3h, obtains coating of the present invention.
Embodiment 2:
A kind of potent anti-oxidant quick drying paint, the coating are made of raw material from the following weight:50 parts of acrylic resin, 12 parts of epoxy resin, 3 parts of graphene, 12 parts of butyl acetate, 4 parts of polylactide, 8 parts of silicone oil, 6 parts of zinc oxide, titanium dioxide 2 Part, 2.8 parts of thio-2 acid dibasic acid esters, 2.6 parts of pentalyn, 1.6 parts of levelling agent, 1.4 parts of defoaming agent.
The levelling agent is carboxymethyl cellulose;The defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of preparation method of potent anti-oxidant quick drying paint, the preparation method comprises the following steps:
(1) acrylic resin and epoxy resin are mixed, takes the deionized water of latter times of volume parts of mixing, is heated to 50-55 DEG C, then mixed resin is poured into deionized water, it is spare to obtain hybrid resin by the uniform velocity stirring 40-60min;
(2) butyl acetate, polylactide, silicone oil, thio-2 acid dibasic acid esters and pentalyn are poured into blender Middle mixing, it is spare to obtain mixed slurry;
(3) by graphene, zinc oxide and titanium dioxide mix after be placed in together in the hybrid resin in above-mentioned steps (1) In dispersion cylinder, 30-40min is stirred, then levelling agent and defoaming agent are poured into dispersion cylinder, stirs 60-70min;
(4) mixed slurry in above-mentioned steps (2) is poured into the dispersion cylinder in step (3), is warming up to 35-40 DEG C, it is even Speed stirring 2-3h, obtains coating of the present invention.
Embodiment 3:
A kind of potent anti-oxidant quick drying paint, the coating are made of raw material from the following weight:45 parts of acrylic resin, 9 parts of epoxy resin, 2.5 parts of graphene, 10 parts of butyl acetate, 3 parts of polylactide, 6 parts of silicone oil, 4.5 parts of zinc oxide, titanium dioxide 1.5 parts, 2.2 parts of thio-2 acid dibasic acid esters, 2.3 parts of pentalyn, 1.5 parts of levelling agent, 1 part of defoaming agent.
The levelling agent is carboxymethyl cellulose;The defoaming agent is polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of preparation method of potent anti-oxidant quick drying paint, the preparation method comprises the following steps:
(1) acrylic resin and epoxy resin are mixed, takes the deionized water of latter times of volume parts of mixing, is heated to 50-55 DEG C, then mixed resin is poured into deionized water, it is spare to obtain hybrid resin by the uniform velocity stirring 40-60min;
(2) butyl acetate, polylactide, silicone oil, thio-2 acid dibasic acid esters and pentalyn are poured into blender Middle mixing, it is spare to obtain mixed slurry;
(3) by graphene, zinc oxide and titanium dioxide mix after be placed in together in the hybrid resin in above-mentioned steps (1) In dispersion cylinder, 30-40min is stirred, then levelling agent and defoaming agent are poured into dispersion cylinder, stirs 60-70min;
(4) mixed slurry in above-mentioned steps (2) is poured into the dispersion cylinder in step (3), is warming up to 35-40 DEG C, it is even Speed stirring 2-3h, obtains coating of the present invention.
Embodiment 4
The selection resulting coating of above-described embodiment 1-3 is experimental group, detects the drying time of every group of coating, when artificial ageing Between, as a result as shown in the table:
As seen from the above table, that coating of the present invention can be dried within 2 hours, and have the antioxidant effect chatted.
It should be noted that, in this document, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, those skilled in the art should understand that:It still can be to aforementioned each implementation Technical solution documented by example is modified or equivalent replacement of some of the technical features;And these modification or Replacement, the spirit and scope for technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution.

Claims (5)

1. a kind of potent anti-oxidant quick drying paint, which is characterized in that the coating is made of raw material from the following weight:Acrylic acid 40-50 parts of resin, 6-12 parts of epoxy resin, 2-3 parts of graphene, 8-12 parts of butyl acetate, 2-4 parts of polylactide, silicone oil 4-8 Part, 3-6 parts of zinc oxide, 1-2 parts of titanium dioxide, 1.6-2.8 parts of thio-2 acid dibasic acid esters, 2-2.6 parts of pentalyn, stream Flat agent 1.4-1.6 parts, 0.6-1.4 parts of defoaming agent.
2. the potent anti-oxidant quick drying paint of one kind according to claim 1, which is characterized in that the coating is by following weight The raw material of part is made:45 parts of acrylic resin, 9 parts of epoxy resin, 2.5 parts of graphene, 10 parts of butyl acetate, 3 parts of polylactide, 6 parts of silicone oil, 4.5 parts of zinc oxide, 1.5 parts of titanium dioxide, 2.2 parts of thio-2 acid dibasic acid esters, 2.3 parts of pentalyn, stream 1.5 parts of flat agent, 1 part of defoaming agent.
3. the potent anti-oxidant quick drying paint of one kind according to claim 1, it is characterised in that:The levelling agent is carboxymethyl Cellulose.
4. the potent anti-oxidant quick drying paint of one kind according to claim 1, it is characterised in that:The defoaming agent is polyoxy second Alkene polyoxy propyl alcohol amidogen ether.
5. a kind of preparation method of potent anti-oxidant quick drying paint, which is characterized in that the preparation method comprises the following steps:
(1) acrylic resin and epoxy resin are mixed, takes the deionized water of latter times of volume parts of mixing, is heated to 50-55 DEG C, then mixed resin is poured into deionized water, it is spare to obtain hybrid resin by the uniform velocity stirring 40-60min;
(2) butyl acetate, polylactide, silicone oil, thio-2 acid dibasic acid esters and pentalyn are poured into blender and is mixed Stirring is closed, it is spare to obtain mixed slurry;
(3) by graphene, zinc oxide and titanium dioxide mix after be placed in dispersion together in the hybrid resin in above-mentioned steps (1) In cylinder, 30-40min is stirred, then levelling agent and defoaming agent are poured into dispersion cylinder, stirs 60-70min;
(4) mixed slurry in above-mentioned steps (2) is poured into the dispersion cylinder in step (3), is warming up to 35-40 DEG C, at the uniform velocity stirs 2-3h is mixed, coating of the present invention is obtained.
CN201810520975.5A 2018-05-28 2018-05-28 Potent anti-oxidant quick drying paint of one kind and preparation method thereof Pending CN108912907A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201810520975.5A CN108912907A (en) 2018-05-28 2018-05-28 Potent anti-oxidant quick drying paint of one kind and preparation method thereof

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Publication Number Publication Date
CN108912907A true CN108912907A (en) 2018-11-30

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115537081A (en) * 2022-09-28 2022-12-30 哈尔滨市雪鹰工程材料有限公司 Soft film toughened colored drawing coating

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129727A (en) * 2017-06-30 2017-09-05 合肥博创机械制造有限公司 A kind of production technology of engineering machinery coating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107129727A (en) * 2017-06-30 2017-09-05 合肥博创机械制造有限公司 A kind of production technology of engineering machinery coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国大百科全书总编辑委员会《化学》编辑委员会: "《中国大百科全书 化学I》", 28 February 1989, 中国大百科全书出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115537081A (en) * 2022-09-28 2022-12-30 哈尔滨市雪鹰工程材料有限公司 Soft film toughened colored drawing coating

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Application publication date: 20181130