CN108864885A - A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator - Google Patents

A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator Download PDF

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Publication number
CN108864885A
CN108864885A CN201810289316.5A CN201810289316A CN108864885A CN 108864885 A CN108864885 A CN 108864885A CN 201810289316 A CN201810289316 A CN 201810289316A CN 108864885 A CN108864885 A CN 108864885A
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China
Prior art keywords
parts
kitchen ventilator
cathode electrophoresis
electrophoresis dope
pure water
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Pending
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CN201810289316.5A
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Chinese (zh)
Inventor
刘树飞
郭晓猛
胡中源
董立志
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201810289316.5A priority Critical patent/CN108864885A/en
Publication of CN108864885A publication Critical patent/CN108864885A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4473Mixture of polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4488Cathodic paints
    • C09D5/4492Cathodic paints containing special additives, e.g. grinding agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to technical field of coatings, specifically disclose a kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator.The cathode electrophoresis dope suitable for kitchen ventilator, the raw material components including following mass fraction:Mill base 10%-20%, lotion 30%-50%, pure water 40%-60%;The mill base includes following components according to the mass fraction:10-35 parts of fluorine richness epoxy resin, environmentally friendly cosolvent 5-15 parts, 1-6 parts of neutralizer, 0.1-0.5 parts of surfactant, 25-40 parts of pure water, 5-30 parts of kaolin, 4-20 parts of pigment;The lotion includes following components according to the mass fraction:30-40 parts of fluorine richness epoxy resin, 2-8 parts of emulsifier, 1-8 parts of neutralizer, 30-50 parts of pure water.Cathode electrophoresis dope provided by the invention suitable for kitchen ventilator has stronger throwing power, good water-fast, oil resistant chemical property, and more environmentally-friendly.

Description

A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator
Technical field
The present invention relates to technical field of coatings more particularly to a kind of cathode electrophoresis dopes and its preparation suitable for kitchen ventilator Method.
Background technique
Since cathode electrophoresis dope comes out, no matter in terms of coating itself or coating application technology, all achieve many Progress, is proposed many products and new application technology, and so far, almost 100% application ability cathode electrophoresis applies primer for automobiles Material.
Electrophoretic coating is the water paint that developed earliest, it be mainly characterized by coating efficiency high, economic, safety, Pollute it is small, convenient for automation size produce.After decades of development, product constantly updates, newest ability cathode electrophoresis Coating requires the characteristics such as higher throwing power, lower P/B, better edge coverage effect.
Kitchen ventilator majority oleic series spraying paint, wherein viscous oil effect is not poor for oleic series dip painting, easy to pollute, difficult It cleans.This method solves corner angle inside and outside kitchen ventilator by electrophoretic painting and is not easy coating, and the heavy-polluted problem of acrylic coating, makes It by current oil paint production interchange is water paint with this coating, it is more environmentally friendly.
Summary of the invention
The problems such as, environmental pollution poor for existing kitchen ventilator oleic series dip painting oil preventing performance weighs, the present invention provide A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
A kind of cathode electrophoresis dope suitable for kitchen ventilator, the raw material components including following mass fraction:Mill base 10%- 20%, lotion 30%-50%, pure water 40%-60%;
The mill base includes following components according to the mass fraction:10-35 parts of fluorine richness epoxy resin, environmentally friendly cosolvent 5-15 Part, 1-6 parts of neutralizer, 0.1-0.5 parts of surfactant, 25-40 parts of pure water, 5-30 parts of kaolin, 4-20 parts of pigment;
The lotion includes following components according to the mass fraction:30-40 parts of fluorine richness epoxy resin, 2-8 parts of emulsifier, in With 1-8 parts of agent, 30-50 parts of pure water.
Compared with the existing technology, the cathode electrophoresis dope provided by the invention suitable for kitchen ventilator, using fluorine richness epoxy Main material of the resin as lotion and mill base, so that electrophoretic coating not only has stronger throwing power, what is be provided simultaneously with is good Water-fast, oil resistant chemical property, and functional group reactions in the fluorine and epoxy resin in PVDF resinoid form reticular structure, Keep the paint film to be formed uniform, glossiness is high, there are the Corrosion Protections such as non-stick, hardness is high, adhesive force is strong, acid-fast alkali-proof, this Outside, keep coating more environmentally-friendly with environmentally friendly cosolvent.
Further, the present invention also provides the preparation methods of the cathode electrophoresis dope suitable for kitchen ventilator.The preparation Method includes the following steps:
(1) each component is weighed according to the raw material proportioning of the cathode electrophoresis dope suitable for kitchen ventilator;
(2) by the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, pigment and pure water Mixing treatment, milled processed are carried out, mill base is obtained;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment, obtain lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment, obtain the cathode electrophoresis dope suitable for kitchen ventilator.
Compared with the existing technology, the preparation method of the cathode electrophoresis dope provided by the invention suitable for kitchen ventilator, technique Simply, easy to operate, it is environmentally protective, securely and reliably.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
The embodiment of the present invention provides a kind of cathode electrophoresis dope suitable for kitchen ventilator.This is suitable for the cathode electricity of kitchen ventilator Swimming coating, including the following raw material components of mass fraction:Raw material components including following mass fraction:Mill base 10%-20%, cream Liquid 30%-50%, pure water 40%-60%;
The mill base includes following components according to the mass fraction:10-35 parts of fluorine richness epoxy resin, environmentally friendly cosolvent 5-15 Part, 1-6 parts of neutralizer, 0.1-0.5 parts of surfactant, 25-40 parts of pure water, 5-30 parts of kaolin, 4-20 parts of pigment;
The lotion includes following components according to the mass fraction:30-40 parts of fluorine richness epoxy resin, 2-8 parts of emulsifier, in With 1-8 parts of agent, 30-50 parts of pure water.
Preferably, the fluorine richness epoxy resin by one or both of PVDF resinoid combination and epoxy resin into Obtained by row secondary synthesis or physical blending, be provided simultaneously with epoxy resin water-fast chemical resistance and PVDF resinoid it is resistance to Oil, corrosion resistance improve oil resistant, the corrosion resistance of coating paint film.
Preferably, the environmentally friendly cosolvent be isopropanol, sec-butyl alcohol, propylene glycol monomethyl ether, in butyl at least One kind keeps coating more environmentally-friendly.
Preferably, the neutralizer is at least one of lactic acid, acetic acid, and the pH environment of adjusting coating system makes mill base Or lotion is more stable.
Preferably, the surfactant is that propylene oxide is condensed species nonionic surfactant or polyoxyethylene nonyl phenyl second Alkene ether nonionic surfactant, acid and alkali-resistance improve the corrosion resistance of coating.
Preferably, the emulsifier be at least one of induced by alkyl hydroxybenzene polyoxyethylene ether, nonylphenol class polyoxyethylene ether, Improve the various surface tension constituted between phase in lotion, forms uniform and stable lotion, anti-settling.
Preferably, the pigment is one of carbon black, phthalocyanine blue, titanium dioxide, for deploying different types of mill base.
Cathode electrophoresis dope provided in an embodiment of the present invention suitable for kitchen ventilator, using fluorine richness epoxy resin as cream The main material of liquid and mill base, so that electrophoretic coating not only has stronger throwing power, the good water-fast, oil resistant being provided simultaneously with Chemical property, and functional group reactions in the fluorine and epoxy resin in PVDF resinoid form reticular structure, make the paint to be formed Film is uniform, and glossiness is high, has the Corrosion Protections such as non-stick, hardness is high, adhesive force is strong, acid-fast alkali-proof, in addition, helping with environmental protection Solvent keeps coating more environmentally-friendly.
The present invention still further provides this and is applicable under the premise of providing the cathode electrophoresis dope for being suitable for kitchen ventilator In the preparation method of the cathode electrophoresis dope of kitchen ventilator.
In one embodiment, which includes the following steps:
(1) each component is weighed according to the raw material proportioning of the cathode electrophoresis dope suitable for kitchen ventilator;
(2) by the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, pigment and pure water Mixing treatment, milled processed are carried out, mill base is obtained;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment, obtain lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment, obtain the cathode electrophoresis dope suitable for kitchen ventilator.
Explanation is further explained to above-mentioned preparation method below:
Preferably, in step (4), the mixing speed of the mixing treatment is 500-2500rpm, is sufficiently stirred, obtains body It is uniform cathode electrophoresis dope.
Preferably, the fineness of grind of the milled processed is≤10um, guarantees the homogeneity of mill base.
This method preparation process is simple, easy to operate, environmentally protective, securely and reliably.
The cathode electrophoresis dope suitable for kitchen ventilator and its preparation side that embodiment provides in order to better illustrate the present invention Method is illustrated below by embodiment is further.
Embodiment 1
A kind of cathode electrophoresis dope suitable for kitchen ventilator, the raw material components including following mass fraction:Mill base 20%, cream Liquid 30%, pure water 50%;
The mill base includes following components according to the mass fraction:18 parts of fluorine richness epoxy resin, 5 parts of environmentally friendly cosolvent, in With 1 part of agent, 0.4 part of surfactant, 30 parts of pure water, 22.6 parts of kaolin, 9 parts of carbon black;
The lotion includes following components according to the mass fraction:40 parts of fluorine richness epoxy resin, 6 parts of emulsifier, neutralizer 3 Part, 50 parts of pure water.
Cathode electrophoresis dope preparation method suitable for kitchen ventilator includes the following steps:
(1) each component is weighed according to the raw material proportioning of the cathode electrophoresis dope suitable for kitchen ventilator;
(2) by the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, carbon black and pure water Mixing treatment 10-20min, milled processed are carried out to fineness≤15um, obtains mill base;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment 30-60min, obtained Lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment 10-30min with 1000-1500rpm, are suitable for The cathode electrophoresis dope of kitchen ventilator.
Embodiment 2
A kind of cathode electrophoresis dope suitable for kitchen ventilator, the raw material components including following mass fraction:Mill base 10%, cream Liquid 40%, pure water 40%;
The mill base includes following components according to the mass fraction:30 parts of fluorine richness epoxy resin, 15 parts of environmentally friendly cosolvent, in With 5 parts of agent, 0.5 part of surfactant, 40 parts of pure water, 28 parts of kaolin, 6 parts of carbon black;
The lotion includes following components according to the mass fraction:35 parts of fluorine richness epoxy resin, 4 parts of emulsifier, neutralizer 6 Part, 45 parts of pure water.
Cathode electrophoresis dope preparation method suitable for kitchen ventilator includes the following steps:
(1) each component is weighed according to the raw material proportioning of the cathode electrophoresis dope suitable for kitchen ventilator;
(2) by the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, carbon black and pure water Mixing treatment 10-20min, milled processed are carried out to fineness≤15um, obtains mill base;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment 30-60min, obtained Lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment 10-30min with 1000-1500rpm, are suitable for The cathode electrophoresis dope of kitchen ventilator.
Embodiment 3
A kind of cathode electrophoresis dope suitable for kitchen ventilator, the raw material components including following mass fraction:Mill base 15%, cream Liquid 50%, pure water 50%;
The mill base includes following components according to the mass fraction:35 parts of fluorine richness epoxy resin, 13 parts of environmentally friendly cosolvent, in With 6 parts of agent, 0.5 part of surfactant, 35 parts of pure water, 15 parts of kaolin, 4 parts of carbon black;
The lotion includes following components according to the mass fraction:30 parts of fluorine richness epoxy resin, 2 parts of emulsifier, neutralizer 4 Part, 30 parts of pure water.
Cathode electrophoresis dope preparation method suitable for kitchen ventilator includes the following steps:
(1) each component is weighed according to the raw material proportioning of the cathode electrophoresis dope suitable for kitchen ventilator;
(2) by the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, carbon black and pure water Mixing treatment 10-20min, milled processed are carried out to fineness≤15um, obtains mill base;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment 30-60min, obtained Lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment 10-30min with 1000-1500rpm, are suitable for The cathode electrophoresis dope of kitchen ventilator.
The characteristic for the cathode electrophoresis dope suitable for kitchen ventilator that embodiment provides in order to better illustrate the present invention, below The test that cathode electrophoresis dope suitable for kitchen ventilator prepared by embodiment 1,2,3 is carried out to corresponding performance, as a result such as 1 institute of table Show.
Table 1
As can be seen from Table 1, the cathode electrophoresis dope suitable for kitchen ventilator of preparation of the embodiment of the present invention, hardness of paint film Height has excellent anticorrosive property, oil resistivity, non-stick etc..
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Made any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention within mind and principle.

Claims (10)

1. a kind of cathode electrophoresis dope suitable for kitchen ventilator, which is characterized in that the raw material components including following mass fraction:Color Starch 10%-20%, lotion 30%-50%, pure water 40%-60%;
The mill base includes following components according to the mass fraction:10-35 parts of fluorine richness epoxy resin, environmentally friendly cosolvent 5-15 parts, 1-6 parts of neutralizer, 0.1-0.5 parts of surfactant, 25-40 parts of pure water, 5-30 parts of kaolin, 4-20 parts of pigment;
The lotion includes following components according to the mass fraction:30-40 parts of fluorine richness epoxy resin, 2-8 parts of emulsifier, neutralizer 1-8 parts, 30-50 parts of pure water.
2. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:The fluorine richness asphalt mixtures modified by epoxy resin Rouge is carried out obtained by secondary synthesis or physical blending by the combination of one or both of PVDF resinoid and epoxy resin.
3. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:It is described environmental protection cosolvent be At least one of isopropanol, sec-butyl alcohol, propylene glycol monomethyl ether, butyl.
4. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:The neutralizer is cream At least one of acid, acetic acid.
5. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:The surfactant is Propylene oxide is condensed species nonionic surfactant or nonylphenol polyoxyethylene ether class nonionic surfactant.
6. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:The emulsifier is alkyl At least one of phenols polyoxyethylene ether, nonylphenol class polyoxyethylene ether.
7. being suitable for the cathode electrophoresis dope of kitchen ventilator as described in claim 1, it is characterised in that:The pigment be carbon black, One of phthalocyanine blue, titanium dioxide.
8. a kind of preparation method of the cathode electrophoresis dope suitable for kitchen ventilator, it is characterised in that:Include the following steps:
(1) it is weighed respectively according to the raw material proportioning for the cathode electrophoresis dope for being suitable for kitchen ventilator as described in any one of claim 1~7 Component;
(2) the fluorine richness epoxy resin, environmentally friendly solvent, neutralizer, surfactant, kaolin, pigment and pure water are carried out Mixing treatment, milled processed, obtain mill base;
(3) the fluorine richness epoxy resin, emulsifier, neutralizer and pure water are subjected to mixing treatment, obtain lotion;
(4) mill base, lotion and pure water are subjected to mixing treatment, obtain the cathode electrophoresis dope suitable for kitchen ventilator.
9. the preparation method suitable for the cathode electrophoresis dope of kitchen ventilator as claimed in claim 8, it is characterised in that:Step (4) in, the mixing speed of the mixing treatment is 500-2500rpm.
10. the preparation method suitable for the cathode electrophoresis dope of kitchen ventilator as claimed in claim 8, it is characterised in that:It is described The fineness of grind of milled processed is≤10um.
CN201810289316.5A 2018-04-03 2018-04-03 A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator Pending CN108864885A (en)

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Application Number Priority Date Filing Date Title
CN201810289316.5A CN108864885A (en) 2018-04-03 2018-04-03 A kind of cathode electrophoresis dope and preparation method thereof suitable for kitchen ventilator

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4095201A1 (en) * 2021-05-28 2022-11-30 Axalta Coating Systems GmbH Cathodic electrocoating composition having reduced volatile organic compounds

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1400255A (en) * 2002-09-06 2003-03-05 华南理工大学 Low surface energy cathodic electrophoretic coating material and its preparation method
CN105949942A (en) * 2016-05-05 2016-09-21 义乌潘季涂料股份有限公司 Oleophobic cathode electrophoresis coating
CN106243311A (en) * 2016-08-03 2016-12-21 广东科德环保科技股份有限公司 A kind of aqueous epoxy resin emulsion and preparation method thereof, cathode electrophoresis dope
CN106752816A (en) * 2016-12-02 2017-05-31 浩力森化学科技(江苏)有限公司 With high durable, salt fog performance electrophoretic coating high and preparation method
CN107573836A (en) * 2017-08-23 2018-01-12 河北晨阳工贸集团有限公司 It is a kind of suitable for cathode electrophoresis dope of groove pipe fitting and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1400255A (en) * 2002-09-06 2003-03-05 华南理工大学 Low surface energy cathodic electrophoretic coating material and its preparation method
CN105949942A (en) * 2016-05-05 2016-09-21 义乌潘季涂料股份有限公司 Oleophobic cathode electrophoresis coating
CN106243311A (en) * 2016-08-03 2016-12-21 广东科德环保科技股份有限公司 A kind of aqueous epoxy resin emulsion and preparation method thereof, cathode electrophoresis dope
CN106752816A (en) * 2016-12-02 2017-05-31 浩力森化学科技(江苏)有限公司 With high durable, salt fog performance electrophoretic coating high and preparation method
CN107573836A (en) * 2017-08-23 2018-01-12 河北晨阳工贸集团有限公司 It is a kind of suitable for cathode electrophoresis dope of groove pipe fitting and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4095201A1 (en) * 2021-05-28 2022-11-30 Axalta Coating Systems GmbH Cathodic electrocoating composition having reduced volatile organic compounds

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