CN108864790B - 石墨烯复合防锈颜料及其制备方法 - Google Patents
石墨烯复合防锈颜料及其制备方法 Download PDFInfo
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- CN108864790B CN108864790B CN201810632977.3A CN201810632977A CN108864790B CN 108864790 B CN108864790 B CN 108864790B CN 201810632977 A CN201810632977 A CN 201810632977A CN 108864790 B CN108864790 B CN 108864790B
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 172
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 163
- 239000000049 pigment Substances 0.000 title claims abstract description 93
- 239000002131 composite material Substances 0.000 title claims abstract description 58
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000002002 slurry Substances 0.000 claims abstract description 41
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 38
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011787 zinc oxide Substances 0.000 claims abstract description 19
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 16
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 12
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 12
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000002105 nanoparticle Substances 0.000 claims abstract description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 49
- 238000000227 grinding Methods 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 239000011268 mixed slurry Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 claims description 3
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 2
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 2
- 235000014692 zinc oxide Nutrition 0.000 claims 4
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical group [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 59
- 239000011248 coating agent Substances 0.000 abstract description 58
- 230000000694 effects Effects 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 abstract description 5
- 239000002184 metal Substances 0.000 abstract description 5
- 238000002161 passivation Methods 0.000 abstract description 3
- 230000009257 reactivity Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 26
- 239000003973 paint Substances 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 18
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- 238000006243 chemical reaction Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
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- 229910000831 Steel Inorganic materials 0.000 description 8
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- 239000010959 steel Substances 0.000 description 8
- 238000003917 TEM image Methods 0.000 description 6
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- 238000001035 drying Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 239000008199 coating composition Substances 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 231100000252 nontoxic Toxicity 0.000 description 4
- 230000003000 nontoxic effect Effects 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- 238000007865 diluting Methods 0.000 description 3
- -1 dodecyl alcohol ester Chemical class 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N ethyl butylhexanol Natural products CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110437654A (zh) * | 2019-08-08 | 2019-11-12 | 深圳航天科技创新研究院 | 一种水性无机富锌防腐涂料及其制备方法 |
CN110551411B (zh) * | 2019-08-30 | 2020-09-04 | 复旦大学 | 一种磷酸锌/氧化石墨烯复合防腐颜料的制备方法 |
CN110482539B (zh) * | 2019-09-06 | 2021-09-21 | 常州富烯科技股份有限公司 | 强、弱氧化石墨烯的混合浆料及其制备方法、强、弱氧化石墨烯的复合膜及其制备方法 |
CN110760239A (zh) * | 2019-11-05 | 2020-02-07 | 立邦工业涂料(上海)有限公司 | 一种复合纳米材料增强的水性环氧底漆及其制备方法 |
CN111793373A (zh) * | 2020-07-31 | 2020-10-20 | 株洲飞鹿高新材料技术股份有限公司 | 改性石墨烯浆料的制备方法和环氧防腐底漆及其制备方法 |
CN114907710B (zh) * | 2021-02-08 | 2023-06-09 | 深圳贝特瑞钠电新材料科技有限公司 | 一种防锈颜料及其制备方法和涂料及其应用 |
CN113292902B (zh) * | 2021-05-20 | 2022-04-26 | 常州大学 | 改性氧化石墨烯防腐涂料及其制备方法 |
CN115093769A (zh) * | 2022-06-23 | 2022-09-23 | 有研工程技术研究院有限公司 | 一种有机抗氢渗透的涂料及其制备方法和应用 |
CN116023844A (zh) * | 2022-12-29 | 2023-04-28 | 江南大学 | 一种高效型金属表面防锈封闭保护剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105694570A (zh) * | 2016-03-04 | 2016-06-22 | 广西民族大学 | 一种纳米磷酸锌防锈颜料连续生产方法及生产装置 |
CN105838115A (zh) * | 2016-04-27 | 2016-08-10 | 中国科学院上海硅酸盐研究所 | 一种石墨烯基导电珠光颜料的制备方法 |
CN107001818A (zh) * | 2014-10-28 | 2017-08-01 | Ppg工业俄亥俄公司 | 包含石墨烯碳颗粒的黑色颜料 |
CN107286798A (zh) * | 2017-07-10 | 2017-10-24 | 湖南邦弗特新材料技术有限公司 | 一种耐盐雾、耐老化水性涂料及其制备方法 |
Family Cites Families (2)
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KR101372758B1 (ko) * | 2012-12-26 | 2014-03-10 | 주식회사 포스코 | 자기치유제, 상기 자기치유제를 포함하는 코팅 조성물 및 이 코팅 조성물 피막을 갖는 강판 |
CN105008466A (zh) * | 2013-03-08 | 2015-10-28 | 比克化学有限公司 | 提供具有耐腐蚀性的金属基材的方法 |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107001818A (zh) * | 2014-10-28 | 2017-08-01 | Ppg工业俄亥俄公司 | 包含石墨烯碳颗粒的黑色颜料 |
CN105694570A (zh) * | 2016-03-04 | 2016-06-22 | 广西民族大学 | 一种纳米磷酸锌防锈颜料连续生产方法及生产装置 |
CN105838115A (zh) * | 2016-04-27 | 2016-08-10 | 中国科学院上海硅酸盐研究所 | 一种石墨烯基导电珠光颜料的制备方法 |
CN107286798A (zh) * | 2017-07-10 | 2017-10-24 | 湖南邦弗特新材料技术有限公司 | 一种耐盐雾、耐老化水性涂料及其制备方法 |
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