CN108864751B - Blue-black mixture with high coloring and washing fastness - Google Patents
Blue-black mixture with high coloring and washing fastness Download PDFInfo
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- CN108864751B CN108864751B CN201810892342.7A CN201810892342A CN108864751B CN 108864751 B CN108864751 B CN 108864751B CN 201810892342 A CN201810892342 A CN 201810892342A CN 108864751 B CN108864751 B CN 108864751B
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- blue
- disperse
- cooch
- black mixture
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8276—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester groups
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a blue-black mixture with high coloring and high washing fastness, and particularly relates to the field of dye mixtures, wherein the blue-black mixture is prepared by mixing the following components in percentage by mass: 1-30% of disperse blue (I), 0-30% of disperse violet (II), 1-40% of disperse orange (III) and an auxiliary agent; the structures of the disperse blue (I), the disperse violet (II) and the disperse orange (III) are as follows in sequence:
Description
Technical Field
The invention belongs to the field of dye mixtures, and particularly relates to a blue-black mixture with high coloring and high washing fastness.
Background
With the development of polyester fiber, superfine fiber appears, which has the characteristics of soft hand feeling, comfortable wearing and the like, and has become a textile raw material for textile enterprises at home and abroad, but because of the superfine diameter and the large surface area, the washing fastness and the dye uptake of common disperse dye are poor;
wherein, the dye uptake of the automobile bus disperse black WW-KS and the disperse dark blue W-RS is only about 80%, the dye uptake is improved by the patents with domestic publication numbers of CN103421347A and CN102352125A, but the dye uptake is only about 85%, and the low dye uptake means that more dyes enter sewage, thereby increasing much burden for the treatment of three wastes.
Disclosure of Invention
In view of the above disadvantages, the present invention provides a high-coloring high-washing fastness blue-black mixture, and a disperse blue-black mixture with high coloring rate and high washing fastness for dyeing and printing polyester fabrics.
The invention provides the following technical scheme:
the blue-black mixture with high coloring and high washing fastness is prepared by mixing the following components in percentage by mass: 1-30% of disperse blue (I), 0-30% of disperse violet (II), 1-40% of disperse orange (III) and an auxiliary agent;
the disperse blue (I) has the following structure:
When R is1、R2When one of them is alkyl, the other is ester group, but it can be ester group at the same time;
the disperse violet (II) has the following structure:
in the formula R3Is one of hydrogen and methoxy
And when R is4、R5When one of them is an alkyl group, the other must be an ester group, but may be both ester groups;
the dispersed orange (III) has the following structure:
R6comprises the following steps:
-CH2COOCH3、-CH2COOC2H5、-CH(CH3)COOCH3、-CH(CH3)COOC2H5、-CH2COOCH2COCH3、-CH2COOCH2one of CN.
Preferably, disperse blue (IR) R1、R2is-C2H5、CH2COOCH3、-CH2COOC2H5、-CH(CH3)COOCH3One of (1) and (b).
Preferably, disperse violet (II) R4、R5is-C2H5、CH2COOCH3、-CH2COOC2H5、-CH(CH3)COOCH3One of (1) and (b).
Preferably, R6Is CH2COOCH3And CH2COOCH2COCH3One of (1) and (b).
Preferably, the dye is prepared by mixing the following components in percentage by mass, 10-30% of disperse blue, 5-25% of disperse violet,
1-30% of dispersing orange and the balance of auxiliary agent.
Preferably, the auxiliary agent is a mixture of lignin and MF.
Preferably, the dyeing and printing method is applied to dyeing and printing of terylene and blended fabrics.
The disperse blue (I) structure is one or more of the following structures, the following structure numbers are I-1, I-2, I-3, I-4 and I-5 in sequence, sigma is a solubility parameter, and the specific structure and sigma are as follows:
the disperse violet (II) is one or more of the following components, the following structure numbers are sequentially II-1, II-2, II-3, II-4 and II-5, sigma is a solubility parameter, and the specific structure sum sigma is as follows:
the dispersing orange (III) is one or two of the following, the following structure numbers are III-1 and III-2 in sequence, sigma is a solubility parameter, and the specific structure sum sigma is as follows:
the invention has the beneficial effects that:
(1) in the structures of the disperse blue (I), the disperse violet (II) and the disperse orange (III), the solubility parameter of the dye is between 10.4 and 11.2, and particularly the selected dye; the solubility parameter is quite close to that of terylene, so the selected compounds of the invention have better coloring rate;
(2) the dyes of formula (I), formula (II) and formula (III) all have ester groups in the structure, and easily form-CH in the alkali washing process of dyeing post-treatment2COO negative ions and meta chlorine of azo groups are replaced by hydroxyl to form sodium phenolate under alkaline, so that loose colors on the surface of the fabric are easy to wash away, and better washing fastness can be obtained, therefore, the disperse black dye mixture has high dyeing rate and high washing fastness.
Detailed Description
The manufacturing method of the invention is as follows:
the raw materials are mixed uniformly according to the proportion, and are sanded and sprayed to obtain the disperse blue-black dye mixture.
The implementation of the preparation method 1:
12g of disperse blue (I-1), 10g of disperse violet (II 1), 17g of disperse orange (III-1), an auxiliary agent MF20g, 85A41g lignin and 200g of water are put together, sand milled and spray dried to obtain the disperse black dye mixture;
the preparation method 2 to 18 is implemented to prepare the following components in proportion:
the experimental demonstration is as follows:
respectively taking 1g of products obtained by implementing the manufacturing methods 1-18 and 1g of samples of patents CN103421347A and CN102352125A, respectively numbering the samples as a comparison sample 1 and a comparison sample 2, dispersing the comparison samples in 500ml of water, uniformly mixing, respectively taking 20ml of dispersion liquid and 80ml of water, adjusting pH to 4-5 by using acetic acid, adding 2g of polyester fabric for dyeing, carrying out dyeing treatment according to a national standard GB/T2394-2006 method, testing the washing fastness according to GB/T3921-2008, and carrying out the dyeing rate according to GB/T9337-2001; the test results of the dye uptake of the washing fastness are shown in the following table:
examples | Washing fastness is 60 DEG C | Dye uptake |
1 | 5 | 92.5% |
2 | 5 | 93% |
3 | 5 | 93.6% |
4 | 5 | 91.7% |
5 | 5 | 94% |
6 | 5 | 93.3% |
7 | 5 | 93% |
8 | 5 | 93.4% |
9 | 5 | 93% |
10 | 5 | 93.7% |
11 | 5 | 93% |
12 | 5 | 93.8% |
13 | 5 | 94.5% |
14 | 5 | 94% |
15 | 5 | 93.5% |
16 | 5 | 93.5% |
17 | 5 | 93% |
18 | 5 | 92.8% |
Comparative sample 1 | 5 | 83.5% |
Comparative sample 2 | 5 | 82.5% |
The dyeing process of the dye can be regarded as a process of dissolving the dye on chemical fibers, the dye uptake can be judged by solubility parameters, generally, the closer the solubility parameter of the dye is to the solubility parameter of the terylene (sigma is 10.8, the better the dye uptake and fastness within 10.8 +/-0.5 is shown by research), the better the dye uptake is, the better the dye is fixed on the fabric, and the same can be understood from similar compatibility. Meanwhile, the dye entering the inside can be analyzed under the action of the dispersing agent, so that the dye is dissociated out of the inside of the fabric, and the difference between the fixing and analyzing capabilities determines the dyeing rate of the dye.
From the above table, it can be seen that the disperse blue-black of the invention is used for dyeing terylene and blended fabrics thereof, and has excellent washing fastness, and the dyeing rate is greatly improved and is greatly higher than that of a contrast group.
The following is a related structure:
WW-KS disperse Black structures
The related structure of patent CN103421347A is as follows:
purple sigma 11.78
Red sigma 11.77
Golden yellow sigma 12.78
Yellow sigma 12.73
The related structure of patent CN102352125A is as follows:
although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art will understand that changes can be made in the embodiments described above, and equivalents may be substituted for elements thereof. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (7)
1. The blue-black mixture with high coloring and high washing fastness is prepared by mixing the following components in percentage by mass: 1-30% of disperse blue (I), 0-30% of disperse violet (II), 1-40% of disperse orange (III) and an auxiliary agent;
the disperse blue (I) has the following structure:
in the formula R1,R2Is composed of
When R is1、R2When one of them is an alkyl group, the other is an ester group, except that R1、R2May be simultaneously an ester group;
the disperse violet (II) has the following structure:
in the formula R3Is one of hydrogen and methoxy
R4,R5Is composed of
And when R is4、R5When one of them is an alkyl group, the other must be an ester group, but may be both ester groups;
the dispersed orange (III) has the following structure:
R6comprises the following steps:
-CH2COOCH3、-CH2COOC2H5、-CH(CH3)COOCH3、-CH(CH3)COOC2H5、-CH2COOCH2COCH3、-CH2COOCH2one of CN.
2. The high color and high wash fastness blue-black mixture according to claim 1, characterized in that: formula (I) R1、R2is-C2H5、CH2COOCH3、CH2COOC2H5、-CH(CH3)COOCH3One of (1) and (b).
3. The high color and high wash fastness blue-black mixture according to claim 1, characterized in that: formula (II) R4、R5is-C2H5、CH2COOCH3、-CH2COOC2H5、-CH(CH3)COOCH3One of (1) and (b).
4. The high color and high wash fastness blue-black mixture according to claim 1, characterized in that: formula (III) R6Is CH2COOCH3、CH2COOCH2COCH3One of (1) and (b).
5. The high color and high wash fastness blue-black mixture according to claim 1, characterized in that: the dye is prepared by mixing the following components in percentage by mass, 10-30% of disperse blue (I), 5-25% of disperse violet (II), 1-30% of disperse orange (III) and the balance of auxiliary agents.
6. The high coloring and high washing fastness blue-black mixture according to claim 1 or 5, characterized in that: the auxiliary agent is a mixture of lignin and a dispersing agent MF.
7. The high color and high wash fastness blue-black mixture according to claim 1, characterized in that: it is used for dyeing and printing terylene and blended fabrics.
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CN108864751A CN108864751A (en) | 2018-11-23 |
CN108864751B true CN108864751B (en) | 2020-04-14 |
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CN114437563B (en) * | 2022-01-28 | 2023-10-24 | 杭州吉华江东化工有限公司 | Disperse blue-to-black dye mixture and preparation method and application thereof |
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DE102007045364A1 (en) * | 2007-09-22 | 2009-04-02 | Dystar Textilfarben Gmbh & Co. Deutschland Kg | Azo dyes for dyeing and printing hydrophobic materials |
DE102009028780A1 (en) * | 2009-08-21 | 2011-02-24 | Dystar Colours Deutschland Gmbh | Disperse dye mixtures, their preparation and use |
DE102011008683A1 (en) * | 2011-01-15 | 2012-07-19 | Dystar Colours Distribution Gmbh | Disperse dye mixtures, their preparation and use |
CN102775809B (en) * | 2012-08-09 | 2014-07-02 | 江苏之江化工有限公司 | Cyano-containing azo disperse dye |
EP2995653A1 (en) * | 2014-09-15 | 2016-03-16 | DyStar Colours Distribution GmbH | High wet-fast disperse dyes and mixtures thereof |
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