CN108837371A - For the water-based extinguishing agent and preparation method thereof of electric power storage Pool fire - Google Patents

For the water-based extinguishing agent and preparation method thereof of electric power storage Pool fire Download PDF

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Publication number
CN108837371A
CN108837371A CN201810950440.1A CN201810950440A CN108837371A CN 108837371 A CN108837371 A CN 108837371A CN 201810950440 A CN201810950440 A CN 201810950440A CN 108837371 A CN108837371 A CN 108837371A
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CN
China
Prior art keywords
fire
parts
water
power storage
electric power
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201810950440.1A
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Chinese (zh)
Inventor
程潇
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Shanghai Yongyi Fire Fighting Equipment Co Ltd
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Individual
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Priority to CN201810950440.1A priority Critical patent/CN108837371A/en
Publication of CN108837371A publication Critical patent/CN108837371A/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0028Liquid extinguishing substances
    • A62D1/0035Aqueous solutions
    • A62D1/0042"Wet" water, i.e. containing surfactant
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0071Foams
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/06Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses a kind of water-based extinguishing agents for electric power storage Pool fire, are prepared by the raw material of following weight proportion:130-160 parts of hc-surfactant, 32-42 parts of fire retardant, 100-125 parts of empgen BB, 12-20 parts of agent for capturing, 80-95 parts of preservative, 100-120 parts of betaine type fluorine-containing surfactant, 500-535 parts of deionized water.Water-based extinguishing agent for electric power storage Pool fire of the invention, the spot fire that will lead to electric short circuit and electric leakage initiation when E class fire and fire extinguishing or other fortuitous casualties cannot be put out by overcoming traditional water-based extinguishing agent, and the extinguishing chemical attack time is shorter, extinguishing effect is more preferable.The invention also discloses a kind of preparation methods of water-based extinguishing agent for electric power storage Pool fire.

Description

For the water-based extinguishing agent and preparation method thereof of electric power storage Pool fire
Technical field
The present invention relates to extinguishing chemical technical field, especially a kind of water-based extinguishing agent and its preparation for electric power storage Pool fire Method.
Background technique
Tradition compounding synergetic A, B class water-based extinguishing agent, the heat absorption cooling carried out by the collaboration of various fire-extinguishing function concurrently components, Asphyxia is watered down, isolation covering, inhibits the effects of blocking pyric chain and quickly puts out solid matter such as timber, cotton, hair, fiber crops, paper And its A class fire and liquid or fusible solid of product, as gasoline, kerosene, diesel oil, crude oil, methanol, ethyl alcohol, pitch, The B class fire of the substances such as paraffin, and form fire-resistant heat-insulating flame-proof in combustible surface by various anti-re-ignition function ingredients and cover Cap rock and play anti-re-ignition efficiency.Effect but above-mentioned extinguishing chemical initial stage on fire for electric appliance does not put out a fire, traditional extinguishing chemical go out It will lead to electric short circuit when fiery and electric leakage cause spot fire or other fortuitous casualties, bring safety hidden to personnel's evacuation of suing and labouring Suffer from.
Chinese patent CN201710350557.1 discloses a kind of compounding concertedness A, B, E class water-based extinguishing agent, the fire extinguishing Agent is by hc-surfactant, ammonium polyphosphate, Cocoalkyl glycine betaine, cationic hydroxyethyl cellulose polymer, dodecyl Imidazoles beautiful jade, fluorinated surfactant and deionized water are made, and 36KV electrification below can be also put out while putting out A, B class fire E class fire, but the extinguishing chemical extinguishing effect is not obvious enough, it is long there are attack time the disadvantages of.
Summary of the invention
To solve problems of the prior art, the present invention provides a kind of water-based extinguishing agents for electric power storage Pool fire And preparation method thereof.
The technical solution adopted by the present invention is that:
A kind of water-based extinguishing agent for electric power storage Pool fire, is prepared by the raw material of following weight proportion:
170-180 parts of hc-surfactant, 38-42 parts of fire retardant, 120-125 parts of empgen BB, agent for capturing 12-20 parts, 100-105 parts of preservative, 5-8 parts of betaine type fluorine-containing surfactant, 520-555 parts of deionized water.
Preferably, the hc-surfactant is lauryl sodium sulfate.
Preferably, the fire retardant is the composition of one or both of ammonium sulfate and boric acid.
Preferably, the fire retardant is the composition of ammonium sulfate and boric acid in mass ratio 4: 1.
Preferably, the agent for capturing is isopropanol.
Preferably, the preservative is Kathon CG.
A kind of preparation method of the water-based extinguishing agent as described above for electric power storage Pool fire, includes the following steps:
A, the raw material of formula ratio is weighed respectively;
B, fire retardant is added into deionized water, stirring stood 2 hours after 2.5 hours;
C, agent for capturing, preservative, hc-surfactant, empgen BB are sequentially added, is stirred 4 hours;
D, betaine type fluorine-containing surfactant is added into mixed liquor obtained by step c, stirs 1.5 hours, test solution Conductivity≤50us/cm;
E, it is packed and stored.
Working principle of the present invention is as follows:
1, inhibition, when chance fire scene temperature, which reaches 200-300 DEG C, spends, the fiery metaphosphoric acid of generation at once of this extinguishing chemical chance, Pyrophosphoric acid, polyoxyethylene macromolecular organic compound element prevent fire burning and sprawling, extinguish fire rapidly;
2, using physics extinguishing property, extinguishing chemical is ejected on comburant, that is, formed quenchable film block oxygen into Enter, stops up comburant and put out;
3, penetration and extension are strong, and product is can destroy rapidly hydrone surface tension and refine the side of hydrone simultaneously Formula allows it to have faster flow conductivity and penetration, can quickly radiate rapidly after the heat absorption of fire source deep inside, at the first time will be hot Source is converted into vapor, and powerful extension wraps up extinguishing chemical rapidly, covers, diffusing to bigger region;
4, free chain reaction is interrupted:Free radical is that unburned comburant generates in combustion, become cigarette and The toxic gases such as coal smoke, this extinguishing chemical and comburant occur chemical reaction and form polymeric material in fire extinguishing procedure, the polymeric material Can effectively inhibit or block burning free radical generation, destroy pyric chain, prevent burning, inhibit chain reaction do not generate cigarette and Toxin;
5, electrical isolation fire extinguishing:Product self-conductance rate is extremely low and can destroy hydrone surface tension and thin simultaneously rapidly The mode for changing hydrone, the foam for forming its small adhesion block the propagation of electricity, reach it and put out 36KV or less electrification class fire The effect of calamity.
The beneficial effects of the invention are as follows:
Water-based extinguishing agent provided by the invention for electric power storage Pool fire, penetration and extension are strong, and can interrupt burning Free chain reaction in object combustion process, the foam of formation are overlying on comburant surface with insulating effect, inhibition with Physics fire extinguishing combine, overcome traditional water-based extinguishing agent cannot put out E class fire and fire extinguishing when will lead to electric short circuit and The spot fire or other fortuitous casualties that electric leakage causes, and the extinguishing chemical attack time is shorter, extinguishing effect is more preferable.
Specific embodiment
Raw material, equipment used in the specific embodiment of the invention are known product, are obtained by purchase commercial product.
Embodiment 1
A kind of water-based extinguishing agent for electric power storage Pool fire, is prepared by the raw material of following weight proportion:
130 parts of hc-surfactant, 32 parts of fire retardant, 100 parts of empgen BB, 12 parts of agent for capturing, preservative 80 parts, 100 parts of betaine type fluorine-containing surfactant, 500 parts of deionized water.
The hc-surfactant is lauryl sodium sulfate.
The fire retardant is ammonium sulfate and boric acid in mass ratio 4:1 composition.
The agent for capturing is isopropanol.
The preservative is Kathon CG.
Embodiment 2
A kind of water-based extinguishing agent for electric power storage Pool fire, is prepared by the raw material of following weight proportion:
145 parts of hc-surfactant, 37 parts of fire retardant, 122 parts of empgen BB, 16 parts of agent for capturing, preservative 87 parts, 110 parts of betaine type fluorine-containing surfactant, 517 parts of deionized water.
The hc-surfactant is lauryl sodium sulfate.
The fire retardant is ammonium sulfate and boric acid in mass ratio 4:1 composition.
The agent for capturing is isopropanol.
The preservative is Kathon CG.
Embodiment 3
A kind of water-based extinguishing agent for electric power storage Pool fire, is prepared by the raw material of following weight proportion:
160 parts of hc-surfactant, 42 parts of fire retardant, 125 parts of empgen BB, 20 parts of agent for capturing, preservative 95 parts, 120 parts of betaine type fluorine-containing surfactant, 535 parts of deionized water.
The hc-surfactant is lauryl sodium sulfate.
The fire retardant is ammonium sulfate and boric acid in mass ratio 4:1 composition.
The agent for capturing is isopropanol.
The preservative is Kathon CG.
Embodiment 4
A kind of preparation side for the water-based extinguishing agent being directed to electric power storage Pool fire as described in embodiment 1-3 any embodiment Method includes the following steps:
A, the raw material of formula ratio is weighed respectively;
B, fire retardant is added into deionized water, stirring stood 2 hours after 2.5 hours;
C, agent for capturing, preservative, hc-surfactant, empgen BB are sequentially added, is stirred 4 hours;
D, betaine type fluorine-containing surfactant is added into mixed liquor obtained by step c, stirs 1.5 hours, test solution Conductivity≤50us/cm;
E, it is packed and stored.
A specific embodiment of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention Protect range.

Claims (7)

1. a kind of water-based extinguishing agent for electric power storage Pool fire, which is characterized in that be prepared by the raw material of following weight proportion 's:
130-160 parts of hc-surfactant, 32-42 parts of fire retardant, 100-125 parts of empgen BB, agent for capturing 12-20 Part, 80-95 parts of preservative, 100-120 parts of betaine type fluorine-containing surfactant, 500-535 parts of deionized water.
2. the water-based extinguishing agent according to claim 1 for electric power storage Pool fire, which is characterized in that the hydrocarbon surface is living Property agent be lauryl sodium sulfate.
3. the water-based extinguishing agent according to claim 1 for electric power storage Pool fire, which is characterized in that the fire retardant is sulphur The composition of one or both of sour ammonium and boric acid.
4. the water-based extinguishing agent according to claim 3 for electric power storage Pool fire, which is characterized in that the fire retardant is sulphur Sour ammonium and boric acid in mass ratio 4:1 composition.
5. the water-based extinguishing agent according to claim 1 for electric power storage Pool fire, which is characterized in that the agent for capturing is different Propyl alcohol.
6. the water-based extinguishing agent according to claim 1 for electric power storage Pool fire, which is characterized in that the preservative is card Pine.
7. a kind of preparation method of the water-based extinguishing agent as claimed in any one of claims 1 to 6 for electric power storage Pool fire, special Sign is, includes the following steps:
A, the raw material of formula ratio is weighed respectively;
B, fire retardant is added into deionized water, stirring stood 2 hours after 2.5 hours;
C, agent for capturing, preservative, hc-surfactant, empgen BB are sequentially added, is stirred 4 hours;
D, betaine type fluorine-containing surfactant is added into mixed liquor obtained by step c, stirs 1.5 hours, test solution conductance Rate≤50us/cm;
E, it is packed and stored.
CN201810950440.1A 2018-08-20 2018-08-20 For the water-based extinguishing agent and preparation method thereof of electric power storage Pool fire Pending CN108837371A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109364410A (en) * 2018-11-22 2019-02-22 程潇 A kind of electronic extinguishing device
CN109364395A (en) * 2018-11-22 2019-02-22 程潇 A kind of electronic extinguishing device on vehicle
CN109939410A (en) * 2019-04-25 2019-06-28 杜洋西 Dedicated extinguishing chemical of lithium battery and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06218075A (en) * 1993-01-25 1994-08-09 G T L:Kk Water-based fire extinguishing agent
CN101417166A (en) * 2008-11-14 2009-04-29 中国科学技术大学 Gas-solid composite powder base fire-extinguishing agent and preparation method thereof
CN103520870A (en) * 2013-10-17 2014-01-22 中国人民武装警察部队学院 Multifunctional water-based extinguishing agent and preparation method thereof
CN106964098A (en) * 2017-05-18 2017-07-21 四川威利安特消防科技有限公司 A kind of preparation method for compounding synergetic A, B, E class water-based extinguishing agent
CN107890620A (en) * 2017-11-13 2018-04-10 上海应用技术大学 A kind of environmentally friendly fine spray extinguishment additive agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06218075A (en) * 1993-01-25 1994-08-09 G T L:Kk Water-based fire extinguishing agent
CN101417166A (en) * 2008-11-14 2009-04-29 中国科学技术大学 Gas-solid composite powder base fire-extinguishing agent and preparation method thereof
CN103520870A (en) * 2013-10-17 2014-01-22 中国人民武装警察部队学院 Multifunctional water-based extinguishing agent and preparation method thereof
CN106964098A (en) * 2017-05-18 2017-07-21 四川威利安特消防科技有限公司 A kind of preparation method for compounding synergetic A, B, E class water-based extinguishing agent
CN107890620A (en) * 2017-11-13 2018-04-10 上海应用技术大学 A kind of environmentally friendly fine spray extinguishment additive agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109364410A (en) * 2018-11-22 2019-02-22 程潇 A kind of electronic extinguishing device
CN109364395A (en) * 2018-11-22 2019-02-22 程潇 A kind of electronic extinguishing device on vehicle
CN109939410A (en) * 2019-04-25 2019-06-28 杜洋西 Dedicated extinguishing chemical of lithium battery and preparation method thereof

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Effective date of registration: 20181130

Address after: Room J1085, 2nd Floor, 5358 Huyi Highway, Jiading District, Shanghai 201800

Applicant after: Shanghai Yongyi Fire Fighting Equipment Co., Ltd.

Address before: 611800 No. 12, 4th Floor, Unit 2, Building No. 179, Lower Baitiao Hebei Road, Xujia Town, Chengdu City, Sichuan Province

Applicant before: Cheng Xiao

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