KR101718917B1 - Fire extinguishing agent composition and its manufacturing method - Google Patents

Abstract

The present invention relates to an environmentally friendly fire extinguishing agent composition and a method for producing the same. It includes seawater and an ionic solution, thereby preventing the fire from being extinguished by blocking the oxygen by moving to the surface of the combustible material when the fire is extinguished. Do not pollute.

Description

FIELD OF THE INVENTION The present invention relates to a fire extinguishing agent composition and a manufacturing method thereof,

The present invention relates to an environmentally friendly fire extinguishing composition which does not harm the human body and does not pollute the soil as well as extinguishes fire by blocking oxygen by moving to the surface of the combustible material during the fire evolution and a method for producing the same.

Water or a fire extinguishing agent composition is commonly used in the general fire, but in the case of a water extinguishing agent composition, the freezing point is relatively high at 0 ° C, which makes it difficult to use in a cold or winter outdoor environment. In case of secondary damage after digestion is very large, and if it is not shaken more than once every six months when it is managed and handled, it hardens easily and problems are not generated when necessary.

In particular, it is difficult to store in case of a lot of moisture. A fire extinguishing agent, which is an A-grade fire in a general fire, uses a foam fire extinguishing composition, but it has no effect in terms of performance, and there is no satisfactory extinguishing composition in advanced countries.

Generally, the fire-extinguishing agent composition has the best fire extinguishing power for oil fire, which is class B, and is widely used. However, it is in urgent need to develop a fire extinguishing agent composition having excellent fire extinguishing performance because it shows poor fire extinguishing power in A-class fire .

On the other hand, PFOS in the fire-extinguishing agent composition is a fluorine-based compound consisting of carbon and fluorine. It is an environmental hormone substance restricted in use other than the specific use (fire suppression, etc.) according to the Stockholm Convention (international regulations on persistent organic pollutants) In Korea, since April 2011, the use of organic pollutants has been limited by the Persistent Organic Pollutants Control Act.

The toxicity of PFOS is known to have harmful effects such as reproductive toxicity, carcinogenesis, hormonal system and immune system disturbance and birth defects, which are dying immediately after birth. In addition, since hydrolysis, photodegradation and biodegradation do not occur in the sustainability, decomposition is possible only at incineration at a high temperature (1,100), and exposed harmful substances accumulate at a high concentration in association with blood and liver proteins.

In recent years, advanced countries such as the United States and Japan have developed and marketed a neutral-strengthening liquid that is harmless to the human body and has excellent corrosion characteristics for various materials, and is commercially available for the B-class fire. However, there is no strengthening liquid fire extinguishing agent with excellent fire extinguishing performance in Class A fire. In the case of domestic fire extinguishing agent approval and certification standards of the Korea Fire Protection Authority, strengthened liquid fire extinguishing agent is basically approved for the liquidity, so it is strongly basic in the case of fire extinguishing agent composition developed and marketed in Korea, It is being developed as a cooking oil for fire extinguishers.

Although the liquidity of the fortified liquid extinguishing agent composition does not affect the digestive power, secondary damage is caused by digestion of human life or corrosion of a specific part of a conventional automatic extinguishing system, and even if the digestive power is excellent, There was a problem that it could not enter the world market. In view of the global trend, the demand for fire-extinguishing agent composition will increase greatly, but there is a serious problem that the fire-extinguishing agent composition must depend on all imports when the regulations are strengthened for the purpose of corrosion and stability to the human body.

Accordingly, there is a demand for a fire-extinguishing composition which is manufactured to be neutral and not basic, does not corrode equipment such as a fire extinguishing container, and is harmless to the human body and does not pollute the soil.

Korean Patent No. 117936 Korean Patent No. 259512 Korean Patent No. 112862

It is an object of the present invention to provide an environmentally friendly fire extinguishing composition which does not pollute the human body and does not pollute the soil as well as extinguish by blocking oxygen by moving to the surface of the combustible material during the fire evolution.

Another object of the present invention is to provide a method for manufacturing the environmentally friendly fire extinguishing agent composition.

To achieve the above object, the present invention provides an eco-friendly fire extinguishing composition, which can include seawater and an ionic solution.

The extinguishing agent composition may further contain a silicate metal salt.

The extinguishing agent composition may further contain a metal carbonate.

The extinguishing agent composition may further contain a water-soluble surfactant.

The environmentally friendly fire extinguishing composition may be contained in an amount of 0.001 to 1 part by weight per 100 parts by weight of seawater.

The ionic solution may be at least one selected from the group consisting of trihexyltetradecylphosphonium cation, N, N-dimethyl-N, N-di (3,3-dimethylbutyl) ammonium cation, bis (trifluoromethyl) imide anion, An anion, an alkyl carboxylate anion, a carbonate anion, chloride anion, hydrogen carbonate anion, sulfate anion, hydrogen sulfate anion, silicate anion, methanesulfonate anion, And a tetrafluoroborate anion. Among these, at least one selected from the group consisting of tetrafluoroborate anions and tetrafluoroborate anions.

The ionic solution may be a trihexyltetradecylphosphonium-based cation.

The silicate metal salt may be contained in an amount of 1 to 40 parts by weight based on 100 parts by weight of seawater.

The metal carbonate may be contained in an amount of 5 to 35 parts by weight based on 100 parts by weight of seawater.

The water-soluble surfactant may be contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of seawater.

The silicate metal salt may be at least one selected from the group consisting of sodium silicate, potassium silicate, lithium silicate and ammonium silicate.

The metal carbonate may be at least one selected from the group consisting of potassium carbonate, sodium carbonate, magnesium carbonate, cobalt carbonate and sodium bicarbonate.

The water-soluble surfactant may be C8 to C14 alkyl polyglucoside.

According to another aspect of the present invention, there is provided a method of manufacturing an environmentally friendly fire extinguishing agent composition, comprising: (A) mixing seawater and an ionic solution; (B) adding a metal silicate and a metal carbonate to the mixture and mixing at room temperature; And (C) adding and mixing a water-soluble surfactant to the mixture mixed in the step (B).

Since the fire extinguishing agent composition of the present invention is neutral, it does not corrode the fire extinguishing facilities such as the fire extinguishing container and does not produce precipitates, so that the fire extinguishing performance is not deteriorated.

In addition, the extinguishing agent composition of the present invention is not only harmful to the human body and does not pollute the soil because it completely blocks the oxygen by forming a membrane such as a salt membrane and an inorganic material film by moving to the surface of the combustible material during the fire evolution, It is possible to prevent the secondary damage due to the extinguishing agent composition.

In addition, the extinguishing agent composition of the present invention is excellent in fire-extinguishing performance and can be used not only for oil-fired oil of grade B but also for forest fires of class A-grade.

In addition, it is eco-friendly because it does not use highly toxic chemicals such as freezing point depressants and rust inhibitors.

The present invention relates to an environmentally friendly fire extinguishing composition which does not pollute the human body and does not pollute the soil as well as extinguish by blocking the oxygen by moving to the surface of the combustible material during the fire evolution, and a method for manufacturing the same.

Hereinafter, the present invention will be described in detail.

The extinguishing agent composition of the present invention includes seawater and an ionic solution, and may further contain at least one member selected from the group consisting of a silicate metal salt, a metal carbonate salt, and a water-soluble surfactant.

sea water

The seawater is seawater having a salt concentration of 3.5% or more, preferably 3.5 to 3.9%, and is liquefied in the event of a fire to absorb the heat of the combustible material to help digest it.

Ionic solution

The ionic solution is not vaporized by fire evolution and forms a film on the surface of the combustible material to block the contact with oxygen, thereby extinguishing and extinguishing the fire. Especially, it is used together with seawater, To form a salt film as an active ingredient.

Such an ionic solution uses a substance having a specific gravity of 1.0 or less, preferably 0.8 to 0.9 for excellent digestive power, and the digestive power may be lowered when an ionic solution heavier than water is used.

The content of the ionic solution is 0.001 to 1 part by weight, preferably 0.001 to 0.1 part by weight based on 100 parts by weight of seawater. If the content of the ionic solution is less than the lower limit value, the digestive power may be lowered. If the content is above the upper limit value, the environment may be problematic.

The ionic solution is not particularly limited as long as the specific gravity is 1.0 or less, but preferably trihexyltetradecylphosphonium cation, N, N-dimethyl-N, N-di (3,3-dimethylbutyl) A carboxylate anion, a carboxylate anion, a carbonate anion, a chloride anion, a hydrogen carbonate anion, a sulfate anion, a hydrogen sulfate anion, a silicate anion, a methane anion, a carboxylate anion, Sulfonate anion, sulfonate anion, trifluoromethanesulfonate anion, hexafluorophosphate anion and tetrafluoroborate anion, and more preferably trihexyltetradecylphosphonium, A cation and / or a chloride anion.

Silicate metal salt

The silicate metal salt may be applied over the film formed by the ionic solution to completely block the contact of the combustible material with oxygen. For example, a silicate inorganic film is formed on the salt film formed by the reaction of the seawater and the ionic solution to completely block the oxygen contact of the combustible material, and also to help the metal carbonate to extinguish the flame or the fire source.

Specifically, when the metal silicate is injected into a fire source during fire-fighting, the coated surface to which the fire-extinguishing composition is applied is swollen at 400 ° C to block oxygen from entering the fire source, and at a temperature of 1000 ° C or higher, By changing the composition to a liquid phase, the materials are firmly bonded to each other to form a water film to block oxygen from entering the source.

The content of the silicate metal salt is 1 to 40 parts by weight, preferably 5 to 25 parts by weight, based on 100 parts by weight of seawater. When the content of the silicate metal salt is less than the lower limit, the silicate inorganic film may not be formed, and when the content exceeds the upper limit, the economical efficiency is lowered.

The silicate metal salt is not particularly limited as long as the silicate acid is a metal in which the hydrogen atom thereof is substituted with a metal, and preferably at least one selected from the group consisting of sodium silicate, potassium silicate, lithium silicate and ammonium silicate.

Metal carbonate salt

The carbonic acid metal salt is not burnt even when brought into contact with a flame or a fire source but rather is extinguished and flame-retarded as well as a silicate formed by a salt film formed by an ionic solution and a silicate metal salt It helps to keep the inorganic film for a long time.

The content of the metal carbonate salt is 5 to 35 parts by weight, preferably 10 to 25 parts by weight based on 100 parts by weight of seawater. When the content of the metal carbonate salt is less than the lower limit value, the flame or the fire source can not be extinguished or flame-retarded and the salt film and the silicate inorganic film can not be maintained for a long time. When the content is above the upper limit, precipitates are generated in the extinguishing agent composition, .

The carbonic acid metal salt is not particularly limited as long as it is a substance in which a carbonate and a metal are combined, but is preferably at least one selected from the group consisting of potassium carbonate, sodium carbonate, magnesium carbonate, cobalt carbonate and sodium bicarbonate.

Water-soluble surfactant

The water-soluble surfactant is a natural non-ionic water-soluble surfactant prepared from a vegetable raw material, and the surface tension of the extinguishing agent composition is lowered to 33 dyne / cm or less so that the extinguishing agent composition easily penetrates to the deep portion of the combustible material The deep portion can be effectively digested.

The water-soluble surfactant is combined with an electrolyte such as a salt of seawater, so that the surface tension can be adjusted to a desired value. Thus, the weight ratio of the seawater to the water-soluble surfactant is very important for obtaining a desired surface tension value.

The content of the water-soluble surfactant is 0.1 to 10 parts by weight, preferably 0.1 to 5 parts by weight, based on 100 parts by weight of seawater. If the content of the water-soluble surfactant is less than the lower limit, a desired surface tension can not be obtained. If the content exceeds the upper limit, the surfactant is not dissolved and remains as a suspended material.

Examples of the water-soluble surfactant include C8 to C14 alkyl polyglucosides. When the carbon number is from C1 to C13, a desired surface tension can not be obtained and the formation of a salt film and an inorganic film can be prevented.

In addition, the present invention can provide a method for manufacturing an environmentally friendly fire extinguishing agent composition.

The method for preparing the extinguishing agent composition of the present invention comprises the steps of (A) mixing sea water and an ionic solution; (B) adding a metal silicate and a metal carbonate to the mixture and mixing at room temperature; And (C) adding and mixing a water-soluble surfactant to the mixture mixed in the step (B).

First, in the step (A), the seawater and the ionic solution are mixed at room temperature of 23 to 27 ° C for 0.5 to 2 hours.

If the reaction temperature is lower than the lower limit value, a salt film may not be formed on the combustible material. If the reaction temperature is higher than the upper limit value, the formed salt film may not be maintained for a long time.

 When the reaction time is less than the lower limit, a salt film may not be formed, and when the reaction time exceeds the upper limit, a large amount of impurities may be produced.

Next, in step (B), a metal silicate and a metal carbonate are added to the mixture obtained in step (A), and the mixture is mixed at room temperature of 23 to 27 ° C for 0.5 to 5 hours.

If the reaction temperature is lower than the lower limit, it may be difficult to form a silicate inorganic film. If the reaction temperature is higher than the upper limit, the digestibility may be lowered due to changes in the components.

In addition, when the reaction time is less than the lower limit, precipitates may be formed in the extinguishing agent composition. If the reaction time exceeds the upper limit, the effect can not be further improved, which is not economical.

Next, in step (C), a water-soluble surfactant is added to the mixture mixed in step (B), and the mixture is mixed at 23 to 27 ° C at room temperature for 0.5 to 2 hours.

When the water-soluble surfactant is added after step (A), the desired surface tension can not be obtained, so that it is preferably added after step (B).

When the reaction temperature and the reaction time are out of the above range, desired surface tension can not be obtained.

By containing seawater, the extinguishing agent composition of the present invention can lower the freezing point of the extinguishing agent composition without using a freezing point depressant, so that the extinguishing agent composition contained in the extinguishing container can be easily frozen even when the outside temperature is low as in the winter season.

In addition, since the extinguishing agent composition of the present invention contains an ionic solution, it does not require the use of a fluorochemical surfactant (PFOS), which is environmentally friendly. In addition, by including the silicate metal salt and the metal carbonate, it is not necessary to use a chemical substance having high toxicity such as benzotriazole and molybdenum compound used as a rust preventing agent, so that environmental pollution caused by heavy metals is not generated.

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the present invention. Such variations and modifications are intended to be within the scope of the appended claims.

Example 1. Seawater + ionic solution

100 parts by weight of seawater and 0.001 part by weight of trihexyltetradecylphosphonium ([P6, 6, 6, 14]) having a specific gravity of 0.867 were added and stirred at room temperature for 30 minutes to prepare an extinguishing agent composition.

Example 2. Seawater + ionic solution + metal silicate

5.5 parts by weight of sodium silicate and 2 parts by weight of lithium silicate were mixed at room temperature and stirred for 1 hour to prepare an extinguishing agent composition.

Example  3. Seawater + ionic solution + metal carbonate salt

Except that 10 parts by weight of potassium carbonate was mixed at room temperature and stirred for 1 hour to prepare an extinguishing agent composition.

Example 4. Seawater + Ionic Solution + Carbonate + Surfactant

The same procedure as in Example 1 was carried out except that 0.2 parts by weight of C10 alkylpolyglucoside was added and stirred at room temperature for 30 minutes to prepare an extinguishing agent composition.

Example 5. Seawater + ionic solution + metal silicate + metal carbonate + surfactant

5.5 parts by weight of sodium silicate, 2 parts by weight of lithium silicate and 10 parts by weight of potassium carbonate were added and stirred at room temperature for 1 hour. Then, 0.2 part by weight of C10 alkylpolyglucoside was added thereto, Lt; / RTI > for one minute to prepare an extinguishing agent composition.

Comparative Example 1. Conventional fire extinguisher composition

10 parts by weight of potassium carbonate, 5 parts by weight of ammonium monophosphate, 2.5 parts by weight of sodium bicarbonate, 7 parts by weight of ammonia sulfate, 10 parts by weight of fluoroalkyl polyethoxylate (fluorochemical surfactant), 10 parts by weight of ethylene glycol, 0.5 parts by weight of tripolyphosphate, 0.5 parts by weight of hexametaphosphate 1 weight of citric acid and distilled water were added thereto to prepare an extinguishing agent composition having a total weight of 100 parts by weight.

Comparative Example 2. General tap water

The fire extinguishing agent composition was prepared in the same manner as in Example 1 except that general tap water was used instead of seawater.

<Test Example>

The extinguishing agent compositions prepared according to the above Examples and Comparative Examples were allowed to stand for 24 hours and then used for the test.

Test Example 1. Measurement of physical properties

In order to evaluate the physical properties of the extinguishing agent compositions prepared according to Examples 1 to 5 and Comparative Examples 1 and 2, the following measurements were made in accordance with the type approval of the extinguishing agent, the test standards, and the test specification.

(1) The surface tension of the extinguishing agent composition is measured after setting the liquid temperature to 20 ± 0.5 ° C using a Du Noy surface tensiometer in the cutting fluid test method, and the surface tension is 33 dyne / cm or less do.

(2) The pH was measured after adjusting the liquid temperature to 20 ± 0.5 ° C using a pH meter (OVIBOND).

(3) The degree of biodegradation was performed according to OECD 301A.

(4) When the fire extinguisher is operated under normal conditions, the radiant strengthening liquid shall be flame retardant and its freezing point shall be not higher than -20 ℃. In this case, the solidification point was measured by injecting 10 mL of a sample taken in a test tube having an inner diameter of 18 mm, placing the thermometer, cooling the sample in a bathtub, cooling the sample with a thermometer while stirring, When the solution became transparent, the temperature was read and repeated three times, and the average value of the results of the test was taken as a solidifying point.

(5) The specific gravity was measured at 20 ± 2 ° C using a specific gravity sludge system or a sickle sickle which is a method of measuring the specific gravity of a chemical product.

The physical properties of the extinguishing agent composition prepared in Examples 1 to 4 and Comparative Examples 1 to 3, which were measured by the physical property measuring method described above, are shown in Table 1 below.

division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Test Methods Surface tension (20 ° C)
(dyne / cm) 34 34 35 28 27 18 40 KS M2525 pH 7.4 7.9 7.3 7.7 7.7 7.0 10.1 KS M0011 Biodegradability 50 48 47 47 45 40 41 OECD 301A Freezing point
(° C) -25 or less -27 or less -27 or less -28 or less -28 or less -below 10 -0 or less - importance
(20 DEG C) 1.1 1.1 1.1 1.2 1.2 1.1 1.0 -

As shown in Table 1 above, the extinguishing agent compositions prepared according to Examples 1 to 5 of the present invention were measured in accordance with the type approval and testing regulations of the extinguishing agent, It is confirmed that the specific gravity is close to water. It was confirmed that the degree of biodegradation was higher than that of Comparative Example 1 using a fluorochemical surfactant, which was low.

On the other hand, the extinguishing agent composition prepared according to Comparative Example 2 had a high surface tension and a high freezing point.

Test Example  2. Measurement of Flame Retardation Effect

The extinguishing agent compositions prepared according to Examples 1 to 5 and Comparative Examples 1 and 2 were coated once on the surfaces of paper and wooden boards, dried and ignited.

As a result, the paper and the wood flame retarded with the extinguishing agent compositions of Examples 1 to 5 were flame-treated with the extinguishing agent composition of Comparative Examples 1 and 2, The trees were burned with paper and wood for 7 and 60 seconds, respectively, after the flames spread.

As a result, it was confirmed that the extinguishing agent compositions of Examples 1 to 5 of the present invention had a considerably excellent flame retarding effect.

Test Example  3. Measurement of digestion performance

144 pcs of dry pine and duck tree with width X length 3cmX3cm and length 0.9 m are stacked outdoors in a grid shape 1.5m height and it is sprinkled with a little oil and it is ignited, , The extinguishing agent compositions prepared according to Examples 1 to 5 and Comparative Examples 1 and 2 were used for evolution. Also, there should be no recurrence within 2 minutes after the digestion is completed.

division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Digestion time
(second) 61 50 51 40 30 50 100 The amount of the composition (L) 3.4 2.8 2.8 2.2 1.7 2.8 5.6

As shown in Table 2 above, it was confirmed that the extinguishing agent compositions prepared according to Examples 1 to 5 of the present invention can rapidly evolve fire in a small amount.

On the other hand, the extinguishing agent composition of Comparative Example 2 was able to evolve fire only by using a large amount of composition for a long time.

Claims (14)

Seawater, ionic solution, silicate metal salt, metal carbonate salt, and water-soluble surfactant. delete delete delete The eco-friendly fire extinguishing composition according to claim 1, wherein the environmentally friendly fire extinguishing agent composition contains 0.001 to 1 part by weight of an ionic solution per 100 parts by weight of seawater. The ionic liquid according to claim 1, wherein the ionic solution is selected from the group consisting of trihexyltetradecylphosphonium cation, N, N-dimethyl-N, N-di (3,3-dimethylbutyl) ammonium cation, bis (trifluoromethyl) A carboxylate anion, a carboxylate anion, an alkyl carboxylate anion, a carbonate anion, a chloride anion, a hydrogen carbonate anion, a sulfate anion, a hydrogen sulfate anion, a silicate anion, a methanesulfonate anion, a trifluoromethanesulfonate anion , A hexafluorophosphate anion, and a tetrafluoroborate anion. 2. The eco-friendly digestive pharmaceutical composition according to claim 1, The environmentally friendly digestive composition according to claim 1, wherein the ionic solution is a trihexyltetradecylphosphonium-based cation. The eco-friendly digestive composition according to claim 1, wherein the silicate metal salt is contained in an amount of 1 to 40 parts by weight based on 100 parts by weight of seawater. The eco-friendly digestive composition according to claim 1, wherein the metal carbonate salt is contained in an amount of 5 to 35 parts by weight based on 100 parts by weight of seawater. The eco-friendly digestive composition according to claim 1, wherein the water-soluble surfactant is contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of seawater. The eco-friendly digestive composition according to claim 1, wherein the silicate metal salt is at least one selected from the group consisting of sodium silicate, potassium silicate, lithium silicate and ammonium silicate. The eco-friendly digestive composition according to claim 1, wherein the metal carbonate is at least one selected from the group consisting of potassium carbonate, sodium carbonate, magnesium carbonate, cobalt carbonate and sodium bicarbonate. The eco-friendly digestive composition according to claim 1, wherein the water-soluble surfactant is a C8 to C14 alkyl polyglucoside. (A) mixing seawater and an ionic solution;
(B) adding a metal silicate and a metal carbonate to the mixture and mixing at room temperature; And
(C) adding a water-soluble surfactant to the mixture mixed in the step (B) and mixing the mixture.