CN108823972A - A kind of preparation method of fireproof facing material - Google Patents
A kind of preparation method of fireproof facing material Download PDFInfo
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- CN108823972A CN108823972A CN201810757701.8A CN201810757701A CN108823972A CN 108823972 A CN108823972 A CN 108823972A CN 201810757701 A CN201810757701 A CN 201810757701A CN 108823972 A CN108823972 A CN 108823972A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
- D06M13/453—Phosphates or phosphites containing nitrogen atoms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of preparation methods of fireproof facing material, include the following steps：Step 1：By nylon, cotton according to weight ratio 3:1 by item, spinning, woven fabric, obtain blended yarn weaved fabric, then blended yarn weaved fabric is placed in basalt fibre solution and impregnates 12-18min, then dry again, drying temperature is 105-115r/min, it is then re-fed into nano organic montmorillonite grafting diphenyl phosphoester, fire resistant fluid immersion 12-18min, then is dried, mixed cloth A is obtained.The object of the present invention is to provide a kind of preparation method of fireproof facing material, which is greatly improved compared with prior art, use value with higher and good application prospect.
Description
Technical field
The present invention relates to fabric technical fields, and in particular to a kind of preparation method of fireproof facing material.
Background technique
Fabric is exactly the material for making clothes.As one of clothes three elements, fabric can not only annotate clothes
Style and characteristic, and the expression effect of the color of clothes, moulding is directly controlled, cotton is the general name of all kinds of cotton textiles,
Cotton divides cotton, and the kinds such as people cotton, it is mostly used for fashionable dress, easy dress, underwear and shirt, and its advantages are easily to keep warm,
Soft fit, hygroscopic, gas permeability are favourable, its advantage is that easily contracting, easily wrinkle, in appearance less well-pressed beauty, in wear
It must ironing often；Burlap is one made of the various fibre of flax for textile material fibers such as hemp, flax, ramie, jute, sisal hemp, abaca
Kind cloth is generally used to production easy dress, work dress, and common summer clothing is mostly made with it, and its advantages are that intensity is high, inhale
It is wet, thermally conductive, gas permeability is favourable.Its advantage is that wear is not comfortable, appearance is more coarse, stiff.
Existing Chinese patent literature（Publication number：CN102137895B）Disclose a kind of capstock composition, by the composition
The fabric of preparation, the lamination fabric including the fabric and the composite material including the lamination fabric, wherein the capstock composition contains
There are at least one of the copolymer based on polystyrene and copolymer based on ethylene vinyl acetate, the fabric fire protecting performance
Difference.
Chinese patent literature（Publication number：CN107190404B）Disclose a kind of graphene and biology base fiber knitted fabric
And its production technology, belong to field of textiles, which is single side weft-knitting institutional framework, and fabric face is the C/R containing graphene
Scribbled, reverse side are the sorona biology base fiber composition that wet structure is led containing pipeline, which has antibiosis anti-acarien, antistatic
Radiation protection, but fire protecting performance is poor.
Summary of the invention
In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of preparation method of fireproof facing material, the fabric is anti-
Fiery performance is greatly improved compared with prior art, use value with higher and good application prospect.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention provides a kind of preparation methods of fireproof facing material, include the following steps：
Step 1：By nylon, cotton according to weight ratio 3:1 by obtaining blended yarn weaved fabric, then by blended face at item, spinning, woven fabric
Material, which is placed in basalt fibre solution, impregnates 12-18min, then dries again, drying temperature 105-115r/min is then sent again
Enter nano organic montmorillonite grafting diphenyl phosphoester, fire resistant fluid immersion 12-18min, then dry, obtains mixed cloth A；
Step 2 prepares soaking agent：Epoxidation triglyceride, p-hydroxybenzoic acid isopropyl ester, glycerine are added to magnetic force and stirred
It mixes in device, speed of agitator rises to 115-125r/min, and mixing time 25-35min then adds nano silica, talcum
Powder, small red soil, volcanic mud continue to stir 15-25min to get soaking agent；
Mixed cloth A in step 1 is impregnated in soaking agent 15-25min, is then dried to get fire prevention face by step 3
Material.
Preferably, basalt fibre fineness is 12-18um in the basalt fibre solution.
Preferably, basalt fibre fineness is 15um in the basalt fibre solution.
Preferably, basalt fibre accounting is 6-14% in the basalt fibre solution.
Preferably, basalt fibre accounting is 10% in the basalt fibre solution.
Preferably, the nano organic montmorillonite grafting diphenyl phosphoester preparation method is to be placed in nano montmorillonite
Ultrasonic disperse is carried out in ionized water, is dispersed 6-12min, is then sequentially added pentaerythrite, gamma-aminopropyl-triethoxy thereto
Silane, speed of agitator rise to 105-115r/min, and mixing time 25-35min then adds diphenyl phosphoester, continue
15-25min is stirred, azodiisobutyronitrile is eventually adding, 8-14min is reacted to get nano organic montmorillonite and is grafted diphenylphosphine
Acid esters.
Preferably, the nano montmorillonite partial size is 10-20nm.
Preferably, the nano montmorillonite, diphenyl phosphoester substance mass ratio be（5-9）:3.
Preferably, the nano montmorillonite, diphenyl phosphoester substance mass ratio be 7:3.
Preferably, the fire resistant fluid is carbamidophosphoric acid salt GUP, epoxy Linseed oil according to weight ratio 4:The mixing of 1 composition
Object.
Compared with prior art, the present invention has following beneficial effect：
（1）The present invention first prepares blended yarn weaved fabric, is then impregnated using fire-resistant fluid, the fire line of fabric is improved, using nanometer
Organo montmorillonite is grafted diphenyl phosphoester processing, and nano organic montmorillonite has lamellar structure, and diphenyl phosphoester has resistance
Fire protecting performance is fired, after grafting, can be uniformly dispersed in the coating, improve the compatibility of material, then enhances the fire resisting of fabric
Performance.
（2）The soaking agent that nano silica is formed has unique gap structure, and porosity is big, by be added talcum powder,
Small red soil, volcanic mud inorganic filler, the combination solution of formation can further improve flameproof effect.
（3）It is obtained from embodiment 3 and comparative example 1-3, relative to comparative example 3, char length reduces the embodiment of the present invention 3
7mm, reduced rate 38.8%, using nano organic montmorillonite grafting diphenyl phosphoester processing, char length improves 2mm, adopts
It is handled with soaking agent, 7mm can be improved.
Specific embodiment
Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows
So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention
Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to
In the scope of protection of the invention.
Embodiment 1.
A kind of preparation method of fireproof facing material of the present embodiment, includes the following steps：
Step 1：By nylon, cotton according to weight ratio 3:1 by obtaining blended yarn weaved fabric, then by blended face at item, spinning, woven fabric
Material, which is placed in basalt fibre solution, impregnates 12min, then dries again, drying temperature 105r/min is then re-fed into nanometer
Organo montmorillonite is grafted diphenyl phosphoester, fire resistant fluid impregnates 12min, then dries, and obtains mixed cloth A；
Step 2 prepares soaking agent：Epoxidation triglyceride, p-hydroxybenzoic acid isopropyl ester, glycerine are added to magnetic force and stirred
It mixes in device, speed of agitator rises to 115r/min, mixing time 25min, then adds nano silica, talcum powder, small red
Mud, volcanic mud continue to stir 15min to get soaking agent；
Mixed cloth A in step 1 is impregnated in soaking agent 15min, is then dried to get fireproof facing material by step 3.
Basalt fibre fineness is 12um in the basalt fibre solution of the present embodiment.
Basalt fibre accounting is 6% in the basalt fibre solution of the present embodiment.
The nano organic montmorillonite grafting diphenyl phosphoester preparation method of the present embodiment is to be placed in nano montmorillonite
Ultrasonic disperse is carried out in ionized water, is dispersed 6min, is then sequentially added pentaerythrite, gamma-aminopropyl-triethoxy silicon thereto
Alkane, speed of agitator rise to 105r/min, and mixing time 25min then adds diphenyl phosphoester, continue to stir 15min,
It is eventually adding azodiisobutyronitrile, 8min is reacted to get nano organic montmorillonite and is grafted diphenyl phosphoester.
The nano montmorillonite partial size of the present embodiment is 10nm.
The nano montmorillonite of the present embodiment, the mass ratio of diphenyl phosphoester substance are 5:3.
The fire resistant fluid of the present embodiment is carbamidophosphoric acid salt GUP, epoxy Linseed oil according to weight ratio 4:The mixing of 1 composition
Object.
Embodiment 2.
A kind of preparation method of fireproof facing material of the present embodiment, includes the following steps：
Step 1：By nylon, cotton according to weight ratio 3:1 by obtaining blended yarn weaved fabric, then by blended face at item, spinning, woven fabric
Material, which is placed in basalt fibre solution, impregnates 18min, then dries again, drying temperature 115r/min is then re-fed into nanometer
Organo montmorillonite is grafted diphenyl phosphoester, fire resistant fluid impregnates 18min, then dries, and obtains mixed cloth A；
Step 2 prepares soaking agent：Epoxidation triglyceride, p-hydroxybenzoic acid isopropyl ester, glycerine are added to magnetic force and stirred
It mixes in device, speed of agitator rises to 125r/min, mixing time 35min, then adds nano silica, talcum powder, small red
Mud, volcanic mud continue to stir 25min to get soaking agent；
Mixed cloth A in step 1 is impregnated in soaking agent 25min, is then dried to get fireproof facing material by step 3.
Basalt fibre fineness is 18um in the basalt fibre solution of the present embodiment.
Basalt fibre accounting is 14% in the basalt fibre solution of the present embodiment.
The nano organic montmorillonite grafting diphenyl phosphoester preparation method of the present embodiment is to be placed in nano montmorillonite
Ultrasonic disperse is carried out in ionized water, is dispersed 12min, is then sequentially added pentaerythrite, gamma-aminopropyl-triethoxy silicon thereto
Alkane, speed of agitator rise to 115r/min, and mixing time 35min then adds diphenyl phosphoester, continue to stir 25min,
It is eventually adding azodiisobutyronitrile, 14min is reacted to get nano organic montmorillonite and is grafted diphenyl phosphoester.
The nano montmorillonite partial size of the present embodiment is 20nm.
The nano montmorillonite of the present embodiment, the mass ratio of diphenyl phosphoester substance are 3:1.
The fire resistant fluid of the present embodiment is carbamidophosphoric acid salt GUP, epoxy Linseed oil according to weight ratio 4:The mixing of 1 composition
Object.
Embodiment 3.
A kind of preparation method of fireproof facing material of the present embodiment, includes the following steps：
Step 1：By nylon, cotton according to weight ratio 3:1 by obtaining blended yarn weaved fabric, then by blended face at item, spinning, woven fabric
Material, which is placed in basalt fibre solution, impregnates 15min, then dries again, drying temperature 110r/min is then re-fed into nanometer
Organo montmorillonite is grafted diphenyl phosphoester, fire resistant fluid impregnates 15min, then dries, and obtains mixed cloth A；
Step 2 prepares soaking agent：Epoxidation triglyceride, p-hydroxybenzoic acid isopropyl ester, glycerine are added to magnetic force and stirred
It mixes in device, speed of agitator rises to 120r/min, mixing time 30min, then adds nano silica, talcum powder, small red
Mud, volcanic mud continue to stir 20min to get soaking agent；
Mixed cloth A in step 1 is impregnated in soaking agent 20min, is then dried to get fireproof facing material by step 3.
Basalt fibre fineness is 15um in the basalt fibre solution of the present embodiment.
Basalt fibre accounting is 10% in the basalt fibre solution of the present embodiment.
The nano organic montmorillonite grafting diphenyl phosphoester preparation method of the present embodiment is to be placed in nano montmorillonite
Ultrasonic disperse is carried out in ionized water, is dispersed 9min, is then sequentially added pentaerythrite, gamma-aminopropyl-triethoxy silicon thereto
Alkane, speed of agitator rise to 110r/min, and mixing time 30min then adds diphenyl phosphoester, continue to stir 20min,
It is eventually adding azodiisobutyronitrile, 11min is reacted to get nano organic montmorillonite and is grafted diphenyl phosphoester.
The nano montmorillonite partial size of the present embodiment is 15nm.
The nano montmorillonite of the present embodiment, the mass ratio of diphenyl phosphoester substance are 7:3.
The fire resistant fluid of the present embodiment is carbamidophosphoric acid salt GUP, epoxy Linseed oil according to weight ratio 4:The mixing of 1 composition
Object.
Comparative example 1.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that using nano organic montmorillonite grafting two
Phenyl phosphate ester processing.
Comparative example 2.
It is essentially identical with the material and preparation process of embodiment 3, it has only the difference is that not handled using soaking agent.
Comparative example 3.
Using Chinese patent literature（Publication number：CN102137895B）Disclose a kind of raw material of embodiment 1 in capstock composition
And method.
Embodiment 3 and comparative example 1-3 the performance test results are as follows
| Char length（mm） | |
| Embodiment 3 | 11 |
| Comparative example 1 | 13 |
| Comparative example 2 | 16 |
| Comparative example 3 | 18 |
It is obtained from embodiment 3 and comparative example 1-3, for the embodiment of the present invention 3 relative to comparative example 3, char length reduces 7mm, drop
Low rate is 38.8%, and using nano organic montmorillonite grafting diphenyl phosphoester processing, char length improves 2mm, using immersion
Agent processing, can improve 7mm.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (10)
1. a kind of preparation method of fireproof facing material, which is characterized in that include the following steps：
Step 1：By nylon, cotton according to weight ratio 3:1 by obtaining blended yarn weaved fabric, then by blended face at item, spinning, woven fabric
Material, which is placed in basalt fibre solution, impregnates 12-18min, then dries again, drying temperature 105-115r/min is then sent again
Enter nano organic montmorillonite grafting diphenyl phosphoester, fire resistant fluid immersion 12-18min, then dry, obtains mixed cloth A；
Step 2 prepares soaking agent：Epoxidation triglyceride, p-hydroxybenzoic acid isopropyl ester, glycerine are added to magnetic force and stirred
It mixes in device, speed of agitator rises to 115-125r/min, and mixing time 25-35min then adds nano silica, talcum
Powder, small red soil, volcanic mud continue to stir 15-25min to get soaking agent；
Mixed cloth A in step 1 is impregnated in soaking agent 15-25min, is then dried to get fire prevention face by step 3
Material.
2. a kind of preparation method of fireproof facing material according to claim 1, which is characterized in that the basalt fibre solution
Middle basalt fibre fineness is 12-18um.
3. a kind of preparation method of fireproof facing material according to claim 2, which is characterized in that the basalt fibre solution
Middle basalt fibre fineness is 15um.
4. a kind of preparation method of fireproof facing material according to claim 1, which is characterized in that the basalt fibre solution
Middle basalt fibre accounting is 6-14%.
5. a kind of preparation method of fireproof facing material according to claim 4, which is characterized in that the basalt fibre solution
Middle basalt fibre accounting is 10%.
6. a kind of preparation method of fireproof facing material according to claim 1, which is characterized in that the nano organic montmorillonite
Grafting diphenyl phosphoester preparation method is that nano montmorillonite is placed in deionized water to carry out ultrasonic disperse, disperses 6-12min,
Pentaerythrite, gamma-aminopropyl-triethoxy-silane are then sequentially added thereto, and speed of agitator rises to 105-115r/min, stirs
Mixing the time is 25-35min, then adds diphenyl phosphoester, continues to stir 15-25min, is eventually adding two isobutyl of azo
Nitrile reacts 8-14min to get nano organic montmorillonite and is grafted diphenyl phosphoester.
7. a kind of preparation method of fireproof facing material according to claim 6, which is characterized in that the nano montmorillonite partial size
For 10-20nm.
8. a kind of preparation method of fireproof facing material according to claim 6, which is characterized in that the nano montmorillonite, two
The mass ratio of phenyl phosphate ester substance is（5-9）:3.
9. a kind of preparation method of fireproof facing material according to claim 8, which is characterized in that the nano montmorillonite, two
The mass ratio of phenyl phosphate ester substance is 7:3.
10. a kind of preparation method of fireproof facing material according to claim 1, which is characterized in that the fire resistant fluid is urea groups
Phosphate GUP, epoxy Linseed oil are according to weight ratio 4:The mixture of 1 composition.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810757701.8A CN108823972A (en) | 2018-07-11 | 2018-07-11 | A kind of preparation method of fireproof facing material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810757701.8A CN108823972A (en) | 2018-07-11 | 2018-07-11 | A kind of preparation method of fireproof facing material |
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| CN108823972A true CN108823972A (en) | 2018-11-16 |
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| CN201810757701.8A Withdrawn CN108823972A (en) | 2018-07-11 | 2018-07-11 | A kind of preparation method of fireproof facing material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110936691A (en) * | 2019-11-25 | 2020-03-31 | 绍兴柯桥区归零纺织品有限公司 | Fireproof laser embroidery fabric and manufacturing method thereof |
Citations (6)
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| CN102358784A (en) * | 2011-08-25 | 2012-02-22 | 贵州省复合改性聚合物材料工程技术研究中心 | Preparation method for nano-montmorillonite modified organophosphate nucleating agent |
| CN103266468A (en) * | 2013-05-30 | 2013-08-28 | 东华大学 | Flame retardant conditioning method of intumescent flame retardant system on pure cotton fabrics |
| CN104191737A (en) * | 2014-09-18 | 2014-12-10 | 江苏红豆实业股份有限公司 | Method for preparing special composite fabric based on flame-retarded basalt fiber |
| CN105239253A (en) * | 2015-11-13 | 2016-01-13 | 深圳市名仕度服饰有限公司 | Durable flame-retardant cloth and preparation method thereof |
| CN105802436A (en) * | 2016-05-18 | 2016-07-27 | 湖南浩盛消防科技有限公司 | Nano expanding type transparent fireproof paint and preparation method thereof |
| CN106996038A (en) * | 2017-04-18 | 2017-08-01 | 芜湖升星纺织品有限公司 | A kind of production technology of fire-proof function fabric |
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- 2018-07-11 CN CN201810757701.8A patent/CN108823972A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102358784A (en) * | 2011-08-25 | 2012-02-22 | 贵州省复合改性聚合物材料工程技术研究中心 | Preparation method for nano-montmorillonite modified organophosphate nucleating agent |
| CN103266468A (en) * | 2013-05-30 | 2013-08-28 | 东华大学 | Flame retardant conditioning method of intumescent flame retardant system on pure cotton fabrics |
| CN104191737A (en) * | 2014-09-18 | 2014-12-10 | 江苏红豆实业股份有限公司 | Method for preparing special composite fabric based on flame-retarded basalt fiber |
| CN105239253A (en) * | 2015-11-13 | 2016-01-13 | 深圳市名仕度服饰有限公司 | Durable flame-retardant cloth and preparation method thereof |
| CN105802436A (en) * | 2016-05-18 | 2016-07-27 | 湖南浩盛消防科技有限公司 | Nano expanding type transparent fireproof paint and preparation method thereof |
| CN106996038A (en) * | 2017-04-18 | 2017-08-01 | 芜湖升星纺织品有限公司 | A kind of production technology of fire-proof function fabric |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110936691A (en) * | 2019-11-25 | 2020-03-31 | 绍兴柯桥区归零纺织品有限公司 | Fireproof laser embroidery fabric and manufacturing method thereof |
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