CN108808445A - A kind of shared VCSEL and HBT integrated morphologies and production method - Google Patents

A kind of shared VCSEL and HBT integrated morphologies and production method Download PDF

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CN108808445A
CN108808445A CN201810713719.8A CN201810713719A CN108808445A CN 108808445 A CN108808445 A CN 108808445A CN 201810713719 A CN201810713719 A CN 201810713719A CN 108808445 A CN108808445 A CN 108808445A
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gaas
shaped
vcsel
algaas
layers
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王智勇
周广正
李颖
兰天
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Beijing University of Technology
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Beijing University of Technology
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/10Construction or shape of the optical resonator, e.g. extended or external cavity, coupled cavities, bent-guide, varying width, thickness or composition of the active region
    • H01S5/18Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities
    • H01S5/183Surface-emitting [SE] lasers, e.g. having both horizontal and vertical cavities having only vertical cavities, e.g. vertical cavity surface-emitting lasers [VCSEL]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/06Arrangements for controlling the laser output parameters, e.g. by operating on the active medium
    • H01S5/062Arrangements for controlling the laser output parameters, e.g. by operating on the active medium by varying the potential of the electrodes
    • H01S5/06203Transistor-type lasers

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Bipolar Transistors (AREA)
  • Semiconductor Lasers (AREA)

Abstract

A kind of shared VCSEL and HBT integrated morphologies and production method, belong to compound semiconductor materials and device arts.VCSEL and HBT shares N-shaped InGaP emitter region, the base areas p-type GaAs and N-shaped GaAs collecting zones in the structure, and VCSEL is connected in vertical direction formation with HBT to reduce chip area.It is etched to N-shaped InGaP corrosion barrier layers using wet etching, it recycles wet oxidation to form annular oxidation to limit to provide electric current and light field, it is sequentially etched N-shaped InGaP corrosion barrier layers, N-shaped GaAs collecting zones and the base areas p-type GaAs again, successively base electrode and emitter electrode are made in the base areas p-type GaAs and N-shaped InGaP emitter region, it recycles BCB to fill etching groove, then makes the faces VCSEL p electrode.VCSEL connects in vertical direction formation with HBT and reduces chip area.

Description

A kind of shared VCSEL and HBT integrated morphologies and production method
Technical field
The invention belongs to compound semiconductor materials and device arts, specifically design a kind of vertical cavity surface-emitting laser The structure of device (VCSEL) and Heterojunction Bipolar Transistors (HBT).
Background technology
VCSEL is a kind of emergent light perpendicular to the semiconductor laser of substrate surface, is had the following advantages:Circular light spot It is easy to fiber coupling;Threshold current is small, and low energy consumption;Chamber length can realize single longitudinal mode operation;With higher relaxation oscillation frequency It can obtain larger modulation bandwidth;Testing cost can be saved with On-wafer measurement.Main devices of the HBT as laser modulation circuit One of part has many advantages, such as that power density is high, current gain is big, phase noise is low and the linearity is good.Typically by VCSEL and drive Dynamic circuit separates, and this considerably increases costs.It is in Unexamined Publication patent application 104752952, VCSEL is simple with HBT It is integrated VCSEL and HBT form parallel-connection structure on the same substrate, be unfavorable for reducing chip area cost.Therefore by VCSEL With HBT shared structures, and VCSEL and HBT connect in vertical direction formation can reduce chip area, reduce cost.In U.S.'s public affairs It opens and provides a kind of HBT and VCSEL integrated morphologies in patent application 1993/5216686, but due to no InGaP corrosion barrier layers, Therefore etching depth is difficult control, and yield rate is relatively low;And non-oxidation limiting layer, good electric current and light field limitation cannot be provided.
Invention content
The purpose of the present invention is to provide a kind of shared VCSEL and HBT integrated morphologies and production method, reduce and integrate core Piece area improves yield rate, reduces cost.
The present invention is in order to achieve the above object, the technical solution used is as follows:
A kind of sharing VCSEL and HBT integrated morphologies, it is characterised in that:VCSEL and HBT has shared N-shaped InGaP and emits Area, the base areas p-type GaAs and N-shaped GaAs collecting zones, structure are followed successively by p-type GaAs cap layers, p-type AlGaAs/ from top to bottom AlGaAs upper DBR, Al0.98Ga0.02As oxide layers and AlxOyComposite layer, InGaAs/AlGaAs Quantum Well, upper and lower limiting layer, N-shaped The cylindrical structure of InGaP corrosion barrier layers, N-shaped GaAs collecting zones composition, Al0.98Ga0.02As oxide layers and AlxOyComposite layer: Al0.98Ga0.02As oxide layers are circle center, AlxOyIn Al0.98Ga0.02As oxide layer outer shrouds;The lower layer of N-shaped GaAs collecting zones according to It is secondary that the side of the base areas p-type GaAs is longer than N-shaped GaAs collecting zones for the base areas p-type GaAs, N-shaped InGaP emitter region, thereon for Base electrode;The side of N-shaped InGaP emitter region is longer than the base areas p-type GaAs, there is emitter electrode thereon;N-shaped InGaP hairs The downward lower layer for penetrating area is followed successively by DBR under unintentional doping AlGaAs/AlAs, unintentional doping GaAs buffer layers, semi-insulating GaAs substrates;The upper surface of DBR fills material other than N-shaped InGaP emitter region for planarization under unintentional doping AlGaAs/AlAs Expect BCB, planarizing fill material BCB upwards the upper surface of flushed with p-type GaAs cap layers;Upward in planarizing fill material BCB Above with the faces p electrode is equipped in p-type GaAs cap layers.
In said program, the unintentional doping GaAs buffer layers be used to inhibit dislocation in half-insulating GaAs substrate to Extend in epitaxial layer, thickness is preferably 1000nm.
In said program, DBR under the unintentional doping AlGaAs/AlAs, by 30.5 couples of λ0/ 4 optical thicknesses Al0.12Ga0.88As/AlAs is constituted, and overall thickness is preferably 3988nm, doping concentration 2e18cm-3
In said program, the N-shaped InGaP emitter region thickness is preferably 196nm, doping concentration 2e18cm-3
In said program, the base areas the p-type GaAs thickness is preferably 59nm, doping concentration 1e19cm-3
In said program, the N-shaped GaAs collecting zone thickness is preferably 118nm, doping concentration 1e18cm-3
In said program, the N-shaped InGaP corrosion barrier layers, InGaP has different corrosion rates from GaAs, Play the role of selective corrosion.The thickness on the barrier layer is preferably 65nm, doping concentration 2e18cm-3
In said program, the limiting layer up and down is by Al0.60Ga0.40As materials are constituted, and thickness is preferably 110nm.
In said program, the InGaAs/AlGaAs Quantum Well photoluminescence wavelength ratio λ0Small 10-20nm, including 4 couples In0.10Ga0.90As/Al0.37Ga0.63As materials, thickness are preferably 45nm.
In said program, the Al0.98Ga0.02As oxide layers, it is characterised in that:Oxide layer is through wet process oxidation technology oxygen After change, electric current and light field restriction effect are played, oxidated layer thickness is preferably 30nm.
In said program, DBR is by 22.5 couples of λ on the p-type AlGaAs/AlGaAs0/ 4 optical thicknesses Al0.12Ga0.88As/Al0.90Ga0.10As is constituted, and overall thickness is preferably 2942nm, doping concentration 2e18cm-3
In said program, the GaAs cap layers thickness is preferably 50nm, doping concentration 1e20cm-3
The specific preparation process of shared VCSEL and HBT integrated morphologies described above includes following:
(1) the MOCVD unintentional doping GaAs buffer layers of extension, unintentional doping successively is utilized on half-insulating GaAs substrate DBR under AlGaAs/AlAs, N-shaped InGaP emitter region, the base areas p-type GaAs, N-shaped GaAs collecting zones, N-shaped InGaP corrosion barrier layers, Lower limit layer, InGaAs/AlGaAs Quantum Well, upper limiting layer, Al0.98Ga0.02DBR in As oxide layers, p-type AlGaAs/AlGaAs With p-type GaAs cap layers;
(2) N-shaped InGaP corrosion barrier layers are etched to using wet etching;Recycle wet oxidation formed annular oxidation with Electric current and light field limitation are provided;
(3) it is sequentially etched N-shaped InGaP corrosion barrier layers, N-shaped GaAs collecting zones and the base areas p-type GaAs again;Successively in p-type The base areas GaAs and N-shaped InGaP emitter region make base electrode and emitter electrode;
(4) it recycles BCB to fill etching groove, makes the faces VCSEL p electrode.
The present invention beneficial outcomes be:
It can be seen from the above technical proposal that shared VCSEL provided by the invention and HBT integrated morphologies, are conventional VCSEL and HBT has shared N-shaped InGaP emitter region, the base areas p-type GaAs and N-shaped GaAs collecting zones, and VCSEL and HBT is in vertical side Chip area is reduced to series connection is formed;InGaP corrosion barrier layers play the role of selective corrosion, reduce etching technics Difficulty improves yield rate.
Description of the drawings
The above-mentioned and/or additional aspect and advantage of the present invention will become in the description from combination following accompanying drawings to embodiment Obviously and it is readily appreciated that, wherein:
Fig. 1 is the structural schematic diagram of the shared VCSEL and HBT devices of the embodiment of the present invention.
Fig. 2 is the epitaxial structure schematic diagram of the embodiment of the present invention.
Fig. 3 is structural schematic diagram of the embodiment through primary etching and wet oxidation.
Fig. 4 is the structural schematic diagram that etched embodiment, vapor deposition and sputtering make base electrode and emitter electrode thickness.
DBR under half-insulating GaAs substrate 101, unintentional doping GaAs buffer layers 102, unintentional doping AlGaAs/AlAs 103, N-shaped InGaP emitter region 104, the base areas p-type GaAs 105, N-shaped GaAs collecting zones 106, N-shaped InGaP corrosion barrier layers 107, Upper and lower limiting layer 108, InGaAs/AlGaAs Quantum Well 109, Al0.98Ga0.02In As oxide layers 110, p-type AlGaAs/AlGaAs DBR 111, p-type GaAs cap layers 112, AlxOy201, planarizing fill material BCB 301, base electrode 401, emitter electrode The faces 402 and p electrode 403.
Specific implementation mode
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, and is only used for explaining the present invention, and is not considered as limiting the invention.
A kind of shared VCSEL and HBT structure provided according to embodiments of the present invention below with reference to Fig. 1 descriptions.It includes: DBR 103, N-shaped under half-insulating GaAs substrate 101, unintentional doping GaAs buffer layers 102, unintentional doping AlGaAs/AlAs InGaP emitter region 104, the base areas p-type GaAs 105, N-shaped GaAs collecting zones 106, N-shaped InGaP corrosion barrier layers 107, up and down limitation Layer 108, InGaAs/AlGaAs Quantum Well 109, Al0.98Ga0.02DBR 111, p in As oxide layers 110, p-type AlGaAs/AlGaAs Type GaAs cap layers 112, AlxOy201, planarizing fill material BCB 301, base electrode 401, emitter electrode 402 and the faces p electricity Pole 403.
The present invention also provides a kind of methods making shared VCSEL and HBT, include the following steps:
Step 1:As shown in Fig. 2, half-insulating GaAs substrate is positioned in MOCVD boards, successively each epitaxial layer.Exist first H in 600 DEG C -800 DEG C2The above-mentioned epitaxial wafer surface 20min~40min of high-temperature cleaning in atmosphere, and it is passed through AsH3, remove surface Water.TMGa and AsH are passed through into MOCVD3, grow GaAs buffer layers;Thickness is 1000nm.TMGa, TMAl are passed through into MOCVD And AsH3, grow lower DBR, thickness 3988nm, doping concentration 2e18cm-3;It is passed through TMIn, TMGa, PH3And Si2H4, growth hair Penetrate area, thickness 196nm, doping concentration 2e18cm-3;It is passed through TMGa, AsH3And CBr4, growth emitter region, thickness 59nm, Doping concentration is 1e19cm-3;It is passed through TMIn, TMGa, PH3And Si2H6, grow corrosion barrier layer, thickness 65nm, doping concentration For 1e18cm-3;It is passed through TMGa, TMAl and AsH3, grow lower limit layer, thickness 110nm;Be passed through TMIn, TMGa, TMAl and AsH3, grown quantum trap, thickness 45nm, photoluminescence wavelength ratio λ0Small 10-20nm, wherein λ0For excitation wavelength;It is passed through TMGa, TMAl and AsH3, grow upper limiting layer, thickness 110nm;It is passed through TMGa, TMAl, AsH3And CBr4, grow lower oxidation Layer, thickness 30nm, doping concentration 2e18cm-3;It is passed through TMGa, TMAl, AsH3And CBr4, DBR in growth, thickness is 2942nm, doping concentration 2e18cm-3;It is passed through TMGa, AsH3And CBr4, cap layers, thickness 30nm are grown, doping concentration is 1e20cm-3
Step 2:Through photoetching and wet etching, epitaxial layer is etched to InGaP corrosion barrier layers, forms the first table top, platform A diameter of 20-30 μm of face.Epitaxial wafer is placed in oxidation furnace, N is passed through2And H2O, the temperature inside oxidation furnace are 400 DEG C -450 DEG C, oxide layer aoxidizes inwards from side, forms the Al of insulationxOy, the size of oxide-aperture is 5 μm -8 μm, as shown in Figure 3.
Step 3:Through photoetching and wet etching, it is etched to collecting zone, recycles ICP to be etched to base area, utilizes magnetron sputtering Make base electrode;It recycles wet etching to be etched to emitter, makes emitter electrode using electron beam evaporation technique, such as scheme Shown in 4.
Step 4:It is coated using non-photosensitivity BCB materials, is then cured in anaerobic baking oven, utilize SiO2It carries out Mask etches BCB figures using ICP, then etches BCB again until base electrode and emitter electrode;Utilize magnetron sputtering system Make the faces p electrode, as shown in Figure 1.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " illustrative examples ", The description of " example ", " specific example " or " some examples " etc. means specific features described in conjunction with this embodiment or example, knot Structure, material or feature are included at least one embodiment or example of the invention.In the present specification, to above-mentioned term Schematic representation may not refer to the same embodiment or example.Moreover, specific features, structure, material or the spy of description Point can be combined in any suitable manner in any one or more of the embodiments or examples.
Although an embodiment of the present invention has been shown and described, it will be understood by those skilled in the art that:Not In the case of being detached from the principle of the present invention and objective a variety of change, modification, replacement and modification can be carried out to these embodiments, this The range of invention is limited by claim and its equivalent.

Claims (10)

1. a kind of sharing VCSEL and HBT integrated morphologies, it is characterised in that:VCSEL and HBT have shared N-shaped InGaP emitter region, The base areas p-type GaAs and N-shaped GaAs collecting zones, structure are followed successively by p-type GaAs cap layers, on p-type AlGaAs/AlGaAs from top to bottom DBR、Al0.98Ga0.02As oxide layers and AlxOyComposite layer, InGaAs/AlGaAs Quantum Well, upper and lower limiting layer, N-shaped InGaP are rotten Lose barrier layer, the cylindrical structure that N-shaped GaAs collecting zones form, Al0.98Ga0.02As oxide layers and AlxOyComposite layer: Al0.98Ga0.02As oxide layers are circle center, AlxOyIn Al0.98Ga0.02As oxide layer outer shrouds;The lower layer of N-shaped GaAs collecting zones according to It is secondary that the side of the base areas p-type GaAs is longer than N-shaped GaAs collecting zones for the base areas p-type GaAs, N-shaped InGaP emitter region, thereon for Base electrode;The side of N-shaped InGaP emitter region is longer than the base areas p-type GaAs, there is emitter electrode thereon;N-shaped InGaP hairs The downward lower layer for penetrating area is followed successively by DBR under unintentional doping AlGaAs/AlAs, unintentional doping GaAs buffer layers, semi-insulating GaAs substrates;The upper surface of DBR fills material other than N-shaped InGaP emitter region for planarization under unintentional doping AlGaAs/AlAs Expect BCB, planarizing fill material BCB upwards the upper surface of flushed with p-type GaAs cap layers;Upward in planarizing fill material BCB Above with the faces p electrode is equipped in p-type GaAs cap layers.
2. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:Described is unintentional Doping GaAs buffer layers are used to inhibit to extend in the dislocation epitaxial layers in half-insulating GaAs substrate, and thickness is preferably 1000nm.
3. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:Described is unintentional DBR under AlGaAs/AlAs is adulterated, by 30.5 couples of λ0The Al of/4 optical thicknesses0.12Ga0.88As/AlAs is constituted, and overall thickness is preferably 3988nm, doping concentration 2e18cm-3
4. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:The N-shaped InGaP emitter region thickness is preferably 196nm, doping concentration 2e18cm-3;The base areas the p-type GaAs thickness is preferably 59nm, Doping concentration is 1e19cm-3
5. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:The N-shaped GaAs collecting zone thickness is preferably 118nm, doping concentration 1e18cm-3
6. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:The N-shaped InGaP corrosion barrier layers, InGaP have different corrosion rates from GaAs, play the role of selective corrosion;The barrier layer Thickness be preferably 65nm, doping concentration 2e18cm-3
7. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:The bound Preparative layer is by Al0.60Ga0.40As materials are constituted, and thickness is preferably 110nm.
8. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:Described InGaAs/AlGaAs Quantum Well photoluminescence wavelength ratio λ0Small 10-20nm, including 4 couples of In0.10Ga0.90As/Al0.37Ga0.63As materials Material, thickness is preferably 45nm.
9. a kind of sharing VCSEL described in accordance with the claim 1 and HBT integrated morphologies, it is characterised in that:Described Al0.98Ga0.02As oxide layers, oxide layer play electric current and light field restriction effect after wet process oxidation technology aoxidizes, aoxidize thickness Degree is preferably 30nm;DBR is by 22.5 couples of λ on the p-type AlGaAs/AlGaAs0/ 4 optical thickness Al0.12Ga0.88As/ Al0.90Ga0.10As is constituted, and overall thickness is preferably 2942nm, doping concentration 2e18cm-3;The GaAs cap layers thickness is preferably 50nm, doping concentration 1e20cm-3
10. claim 1-9 any one of them sharing VCSEL obtain preparation method with HBT integrated morphologies, which is characterized in that Specific preparation process includes following:
(1) the MOCVD unintentional doping GaAs buffer layers of extension, unintentional doping successively is utilized on half-insulating GaAs substrate DBR under AlGaAs/AlAs, N-shaped InGaP emitter region, the base areas p-type GaAs, N-shaped GaAs collecting zones, N-shaped InGaP corrosion barrier layers, Lower limit layer, InGaAs/AlGaAs Quantum Well, upper limiting layer, Al0.98Ga0.02DBR in As oxide layers, p-type AlGaAs/AlGaAs With p-type GaAs cap layers;
(2) N-shaped InGaP corrosion barrier layers are etched to using wet etching;Wet oxidation is recycled to form annular oxidation to provide Electric current and light field limitation;
(3) it is sequentially etched N-shaped InGaP corrosion barrier layers, N-shaped GaAs collecting zones and the base areas p-type GaAs again;Successively in p-type GaAs Base area and N-shaped InGaP emitter region make base electrode and emitter electrode;
(4) it recycles BCB to fill etching groove, makes the faces VCSEL p electrode.
CN201810713719.8A 2018-07-03 2018-07-03 A kind of shared VCSEL and HBT integrated morphologies and production method Pending CN108808445A (en)

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Cited By (5)

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CN108736316A (en) * 2018-06-08 2018-11-02 北京嘉圣光通科技有限公司 Make the method and vertical cavity surface emitting laser of vertical cavity surface emitting laser
CN111162451A (en) * 2019-12-26 2020-05-15 浙江博升光电科技有限公司 Bottom emitting vertical cavity surface emitting laser
CN111628022A (en) * 2019-02-28 2020-09-04 中国科学院物理研究所 GaAs-based photoelectric device and preparation method of array thereof
CN112563378A (en) * 2020-12-11 2021-03-26 西安立芯光电科技有限公司 Manufacturing method of oxidation intensifying diode
CN117594644A (en) * 2024-01-18 2024-02-23 常州承芯半导体有限公司 Semiconductor device and method of forming the same

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CN104752952A (en) * 2015-03-11 2015-07-01 北京工业大学 GaAs-based HBT and vertical-cavity surface emitting laser
CN105070751A (en) * 2015-08-18 2015-11-18 成都嘉石科技有限公司 Gaas hbt device
CN208767611U (en) * 2018-07-03 2019-04-19 北京工业大学 A kind of shared VCSEL and HBT integrated morphology

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CN104319626A (en) * 2014-10-11 2015-01-28 北京工业大学 Microwave carrier directly modulated vertical-cavity surface-emitting laser
CN104752952A (en) * 2015-03-11 2015-07-01 北京工业大学 GaAs-based HBT and vertical-cavity surface emitting laser
CN105070751A (en) * 2015-08-18 2015-11-18 成都嘉石科技有限公司 Gaas hbt device
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108736316A (en) * 2018-06-08 2018-11-02 北京嘉圣光通科技有限公司 Make the method and vertical cavity surface emitting laser of vertical cavity surface emitting laser
CN111628022A (en) * 2019-02-28 2020-09-04 中国科学院物理研究所 GaAs-based photoelectric device and preparation method of array thereof
CN111628022B (en) * 2019-02-28 2022-07-15 中国科学院物理研究所 GaAs-based photoelectric device and preparation method of array thereof
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CN112563378A (en) * 2020-12-11 2021-03-26 西安立芯光电科技有限公司 Manufacturing method of oxidation intensifying diode
CN112563378B (en) * 2020-12-11 2022-02-25 西安立芯光电科技有限公司 Manufacturing method of oxidation intensifying diode
CN117594644A (en) * 2024-01-18 2024-02-23 常州承芯半导体有限公司 Semiconductor device and method of forming the same
CN117594644B (en) * 2024-01-18 2024-05-28 常州承芯半导体有限公司 Semiconductor device and method of forming the same

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