CN108801964A - It is a kind of directly to measure formula gaseous pollutant emission monitoring device - Google Patents

It is a kind of directly to measure formula gaseous pollutant emission monitoring device Download PDF

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Publication number
CN108801964A
CN108801964A CN201811100684.7A CN201811100684A CN108801964A CN 108801964 A CN108801964 A CN 108801964A CN 201811100684 A CN201811100684 A CN 201811100684A CN 108801964 A CN108801964 A CN 108801964A
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gas
module
detection
admission line
pump
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刘建松
刘怡琳
王炜炜
于春燕
吴岳嵩
姚秀红
岳福龄
方红娟
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light

Abstract

Formula gaseous pollutant emission monitoring device is directly measured the invention discloses a kind of, including testing agency, interrupter, extraction sector, calibrating device, blowing mechanism and central processing module, testing agency includes spectral detection module and sensing chamber, interrupter includes admission line and smoke valve, admission line and smoke valve are arranged in flue, it is arranged with smoke filtration cover outside admission line entrance, filter is equipped in admission line, admission line pipe shaft is communicated with standard gas pipeline, purging pipeline is communicated in smoke filtration cover, gas flow controller is equipped in pump-line;The present invention being capable of detection for gaseous contaminants accuracy, and it effectively solves tradition and directly measures the problems such as overproof when field calibration result existing for formula detection device is overproof, environment monitoring compares, and simple operation, it occupies little space, simultaneously, additionally it is possible to accurately measure, calculate the oxygen-containing concentration of emission of gaseous pollutant benchmark of flue gas.

Description

It is a kind of directly to measure formula gaseous pollutant emission monitoring device
Technical field
The present invention relates to gaseous pollutant technical field of measuring equipment, more particularly to a kind of directly measurement formula gaseous pollutant Emission monitoring device.
Background technology
Currently, the increasing with China to environment non-environmental-pollution management, national departments concerned has been formulated stringent Atmosphere pollutants emission standards, in newest environment protectment protection《Stationary source flue gas(SO2,NOX, particulate matter)Discharge connects Continuous monitoring system specifications and detection method》(HJ 76-2017)In, specify gas pollutant CEMS(Flue gas emission is continuous Monitoring system)Type include complete extraction method, the direct method of measurement and dilution three kinds of extraction method.Due to the office of current detection technology Sex-limited, the especially restriction of the detection technique of the gaseous pollutant concentration of emission containing particulate solid, China is existing at present CEMS cannot be quickly detected from fixed pollution source smoke discharge situation, be primarily present following problem:
One, complete extraction method and dilution extraction method are extraction-type CEMS, and extraction-type CEMS is a kind of present the most commonly used inspection Survey method can accurately detect fixed pollution source smoke discharge situation, and still, extraction-type CEMS lag times are long, for example, For thermal power plant denitration CEMS, a length of 8 seconds or so when the reaction that flue gas is exported from ammonia-gas spraying device to denitration, in actual motion, survey It measures result and lags about 220S or even longer than the practical flue gas pollutant state parameter of sample point, and the newest environment in China Protective standard《Stationary source flue gas(SO2,NOX, particulate matter)Discharge continuous Specifications of Monitoring Technology》(HJ 75-2017)In System response time≤200 second of gas pollutant CEMS when calibrating gas verification can only be distinctly claimed.Too because of lag time Long, the existing environmental protection equipment in country thermal power plant cannot achieve automatic adjustment at present, can only use manual adjustment mode, and Due to the long reason manual adjustment of lag and it is unreliable, effect is poor, causes that environmentally friendly parameter is frequently exceeded, spray ammonia is superfluous, cause The subsequent equipment cisco unity malfunction of denitration causes air preheater blocking, deduster failure to cause compressor emergency shutdown, neither ring It protects, it is also not energy-efficient, and security risk is very big.
Based on current existing CEMS technologies, substantially manually operation is completed for adjustment, the control of environmental protection equipment, environmental protection administration Also it can only provide that NOx average values cannot be exceeded in a hour, and power environment protection detection department provides environmentally friendly parameter in one hour No more than 15 times, even under the standard of " the relaxing ", the environmentally friendly parameter of the unit of gaseous contamination source monitoring also frequent frequency It is numerous to be required beyond this standard.
Two, it is in a kind of blowdown place method measured directly directly to measure the CEMS of formula, and spectrum detection device is mounted directly to At measuring point, flue gas is directly detected, detection speed is fast, is conducive to adjust environmental protection equipment, is conducive to control and prevention gaseous pollutant Environmentally friendly parameter is not exceeded.But existing direct measurement formula measuring technique and device cannot meet environmental protection tests requirement, root at present It is frequently overproof when carrying out Site Detection comparison to the CEMS of existing direct measuring according to by environmentally friendly related request, to existing The CEMS of direct measuring it is usually overproof when being calibrated, do not meet environmental protection tests requirement.Now with environmental protection inspection It puts more effort, the higher gaseous contamination source of content of each thermal power plant and particulate solid monitors unit, all eliminates The CEMS for directly measuring formula, is replaced with extraction-type and the CEMS of dilution sampling formula, and the CEMS manufacturers of import brand also provide Do not go out to meet the direct CEMS for measuring formula of environmental protection tests requirement.
Existing direct measurement formula gas pollutant measuring technique causes existing due to there is the technical bottleneck for being difficult to overcome The direct basic function for measuring formula gas pollutant measuring device do not meet environmental protection tests requirement, and technical bottleneck includes mainly Following several respects:
(1)The environment that the CEMS devices of directly measurement formula carry out when gaseous pollutant continuously monitors residing for measuring point is extremely severe, example Such as, the temperature of the flue gas of thermal power plant's denitration CEMS measuring points is up to 370 more and spends, and dust-laden is larger, for example, using the cigarette of wet desulphurization Air humidity degree is larger, and CEMS devices are affected by environment.The detection probe for directly measuring the CEMS devices of formula is mounted directly to fume pipe In road, when using standard gas to CEMS device normalizations, standard gas enters flue gas inspection channel, and standard gas is mixed with flue gas, and when calibration enters The gas of sense channel is the mixed gas of the uncertain standard gas of mixed proportion and flue gas rather than standard gas, it is calibrating the result is that Uncertain, when directly resulting in environmentally friendly field calibration, calibration result is overproof, does not meet environmental protection supervision cigarette requirement;Therefore it directly surveys The CEMS devices of amount formula generally use following methods to demarcate:It is inserted into the optical path and filter glass similar in pollutant absorption characteristic Or " material object " eyeglass calculates calibration result using operation, because eyeglass and eyeglass in kind with standard gas detected status is inconsistent makes It is overproof at environmentally friendly live contrastive detection result.
(2)Existing direct measurement formula measuring technique and device in environmentally friendly live contrasting detection experiment, newly into it is micro Flue gas was mixed with the flue gas of the upper period in filter interior sluggishness space, and mixed flue gas enters Yang Qi sensing chamber, As a result the instantaneous and real-time concentration that gaseous pollutant cannot be characterized, cannot detect the maximum value of gaseous pollutant;It is right with environmental protection It is overproof when being compared than the master meter testing result of monitoring, environmental protection tests requirement cannot be met.
(3)The minimum discharge of national requirements environmental protection at present, the accuracy of detection of CEMS want that minimum discharge requirement can be met;It is existing It directly measures formula gas pollutant measuring technique and the range of device is all larger, the requirement of minimum discharge accuracy of detection cannot be met. The light that spectrum analysis is emitted is longer in the indoor stroke of detection, then the accuracy of spectrum analysis is higher, increases light and is examining Minimum discharge testing requirements could be met by surveying indoor stroke, but if directly increasing the length of Yang Qi sensing chamber, long-term high Under the working environment of temperature, nature creep and sag bent occur for sensing chamber, influence the normal light path of light, the stability of instrument compared with Difference;Meanwhile directly measurement formula measuring device need to be tested at the scene, the increase of sensing chamber's length can cause the increase of volume, It is not easy to execute-in-place.
(4)According to《Fossil-fuel power plant atmospheric pollutant emission standard》The concentration of emission of gaseous pollutant need to be according to actual measurement oxygen content It is converted to benchmark oxygen content concentration, environmental protection administration is examined by the benchmark oxygen content concentration of gaseous pollutant;It directly surveys at present The measuring point of amount type gaseous pollutant emission monitoring device, the measuring point of oxygen content concentration detection apparatus are arranged in different positions, and Independent detection, and due to current existing direct measurement formula gaseous pollutant emission monitoring device, measurement of oxygen content device itself Basic function just do not meet environmental protection tests requirement, cause the content of the gaseous pollutant detected and gaseous pollutant oxygen amount Value is within the same period, the oxygen-containing concentration of emission of benchmark for the gaseous pollutant that cannot accurately calculate sample gas.
In conclusion although the CEMS for directly measuring formula has many advantages, such as, in terms of above-mentioned basic function Problem causes to be unable to reach environmental protection tests requirement, therefore, how to solve existing superseded direct measurement formula gaseous contamination The technical bottleneck of object measuring technique designs the direct measurement formula gas pollutant monitoring device for meeting environmental protection tests requirement CEMS meets environmental protection equipment operation adjust automatically needs, realizes the perfection of environment monitoring and environmental protection equipment operation automatically controlled In conjunction with, be of great significance to disposal of pollutants analyte detection, control field, and the detection technique in the field can be brought it is great into Step.
Invention content
Formula gaseous pollutant emission monitoring device is directly measured the object of the present invention is to provide a kind of, it being capable of gaseous pollutant Accuracy in detection, and effectively solve the problems, such as that overproof big and sample gas purity existing for traditional directly measurement formula detection device is low, it carries High measurement accuracy, and simple operation, occupy little space, simultaneously, additionally it is possible to which the accurate gaseous pollutant benchmark for calculating sample gas contains Oxygen concentration of emission.
The technical solution adopted by the present invention is:
It is a kind of directly to measure formula gaseous pollutant emission monitoring device, including testing agency, interrupter, extraction sector, calibration Mechanism, blowing mechanism and central processing module;
Testing agency includes sensing chamber, is equipped on the left of sensing chamber and the spectral detection module that be connected to inside sensing chamber, detection interior Equipped with principal reflection mirror, spectral detection module is oppositely arranged with principal reflection mirror;The spectral detection module includes light source module and light Spectrum receives analysis module;
Interrupter includes the admission line of communication with detection room right end and the smoke valve in admission line inlet, air inlet pipe is arranged Road and smoke valve are arranged in flue, and smoke filtration cover is arranged with outside admission line entrance, filter is equipped in admission line;
Extraction sector includes pump-line, extraction valve and aspiration pump, pump-line entrance communication with detection room left part, pump-line Outlet connection aspiration pump, extraction valve are arranged in pump-line;
Calibrating device includes standard gas pipeline and the standard gas intake valve that is arranged on standard gas pipeline, and the connection of standard gas pipeline air-inlet end is external Standard air source, standard gas pipeline outlet side are connected to admission line, and standard gas pipeline outlet side is between smoke valve and filter;
Blowing mechanism includes purging pipeline, the purging gentle body flow controller of intake valve, the external mark of purging pipeline inlet end connection Quasi- air source, scavenging conduit road outlet side are stretched into flue and are connected to inside smoke filtration cover, and purging intake valve is arranged on purging pipeline, Gas flow controller is arranged on pump-line;
Light source module controlled end connects the light source control end of central processing module, in the communication terminal connection of spectrum acquisition analysis module The spectrum analysis communication terminal of processing module, gas flow controller communication terminal is entreated to connect central processing module flow communication terminal, in Processing module pumping control terminal is entreated to connect aspiration pump controlled end.
In order to reduce decaying when light transmission, spectral detection precision is improved, further, the light source module passes through hair Fiber unit communication with detection room is penetrated, the spectrum acquisition analysis module passes through mirror based fiber optica unit communication with detection room, launching fiber Unit is arranged between light source module and principal reflection mirror, and mirror based fiber optica unit is arranged in principal reflection mirror and spectrum acquisition analysis module Between;Launching fiber unit includes diversing lens and transmitting light-conductive optic fibre, and diversing lens and transmitting light-conductive optic fibre are along light source module Emit and set gradually to the optical path direction of principal reflection mirror, mirror based fiber optica unit includes mirror lens and reflection light optical fiber, reflection The optical path direction that lens and reflection light optical fiber are reflected towards spectrum acquisition analysis module along principal reflection mirror is set gradually.
Indoor distance is being detected in order to increase light in the case where not lengthening sensing chamber's length, it is further, described Detection interior is additionally provided with subreflector, and subreflector is located on the left of principal reflection mirror and is oppositely arranged with principal reflection mirror.
In order to consider pressure and temperature effect in spectrum analysis, accuracy of analysis, further, the inspection are improved Surveying mechanism, to further include setting detecting indoor temperature sensor and pressure sensor, temperature sensor and pressure sensor it is defeated Outlet is separately connected spectrum acquisition analysis module signal input part.
Further include that setting exists further in order to realize the detection of oxygen concentration in sample gas on same complete equipment Oxygen detection module on pump-line, oxygen detection module output end connect the detection signal input part of central processing module; When testing agency is detected the gas pollutant content in high-temperature sample gas, oxygen detection module is to the oxygen content with equally gas Directly detected, testing agency carry out standard gas calibration when, standard gas simultaneously into oxygen detection module to oxygen detection module into Rower is fixed.
Further, the admission line is equipped with NOXConverter, NOXConverter is arranged in standard gas pipeline outlet side and mistake Between filter.
Further, the smoke valve uses check-valves or stock control valve.
Further, the aspiration pump is using air ejector of emanating, and air ejector of emanating is equipped with compressed air inlet, sample gas is taken out Suction inlet and the outlet of sample gas, compressed air inlet are connected to external air source, and sample gas pump orifice is connected to exhaust tube, sample gas outlet outlet Pipeline, outlet pipe are connected to inside flue.
Further, the light of the light source module transmitting is ultraviolet light.
Root further, when being demarcated with standard gas, open, and smoke valve is closed, in standard gas and filter mantle by standard gas intake valve Flue gas isolation, flue gas cannot mix into admission line with standard gas, and standard gas will not leak into flue from admission line.
The invention has the advantages that:
(1)By the way that interrupter is arranged, when sample gas enters sensing chamber by admission line, smoke valve is opened, and is ensureing flue gas circulation just Often, when carrying out standard gas calibration, sensing chamber's smoke valve is closed, when realizing standard gas calibration, calibrating gas and flue gas it is complete every From having kept away and exempted from sample gas and be mixed into standard gas to cause calibration inaccurate, ensured the accuracy of calibration result, environmentally friendly scene is made to carry out sample gas Calibration result is accurate and unique when calibration, and then ensures that the present invention disclosure satisfy that the requirement of environmental protection tests;
(2)The structure for stretching into sample gas filter mantle in flue and by admission line is set by the way that smoke filtration to be provide with, is increased ensureing While big filtering traffic, prevent resistance from being had an impact to sample throughput, meanwhile, admission line is arranged in smoke filtration cover It is interior, have compressed filter mantle internal gas sluggishness space;
(3)By the way that blowing mechanism is arranged, detects that the gas flow of pump-line is less than in gas flow controller and limit threshold value When blowback cleaning is carried out to smoke filtration cover in time, avoiding smoke filtration from covering on, long-time service is lower to be blocked and then influences sample air-flow Amount further ensures sample gas accuracy of detection, meanwhile, blowing mechanism coordinates the use of smoke valve, gas stream when can avoid purging Entering sensing chamber makes detection interior gas mixing cause sample gas testing result inaccurate;
(4)By the way that optical link module is arranged between spectral detection module and sensing chamber, not only by spectral detection module and inspection Survey is isolated between room, avoids detecting indoor high-temperature gas damage spectral detection module, ensures that equipment safety is used and improved Service life of equipment, while the decaying in light transmission is reduced, ensure the accuracy of Spectroscopic analysis results;
(5)By the way that subreflector is arranged, the light source that light source module is launched is set to pass through between speculum and subreflector multiple Spectrum acquisition analysis module is entered back into after reflection, under the premise of not increasing sensing chamber's length, increases light in sensing chamber's sample Light path in gas improves the accuracy of detection of the present invention;
(6)By the way that heat safe oxygen detection module is arranged, make sample gas without processing such as coolings with regard to directly carrying out oxygen-containing measurement Amount makes the actual oxygen magnitude that the gaseous pollutant content of detection is converted with the oxygen-containing concentration of emission of participation benchmark within the same period, And can realize that the when of being calibrated to detection for gaseous contaminants apparatus function synchronizes and lambda sensor is calibrated, convenient for more accurately calculating sample The oxygen-containing concentration of emission of the benchmark of pollutant in gas.
Description of the drawings
Fig. 1 is the structural schematic diagram of embodiment one;
Fig. 2 is the structural schematic diagram of embodiment one in a state of use;
Fig. 3 is the structural schematic diagram of embodiment two;
Fig. 4 is the structural schematic diagram of embodiment two in a state of use;
Fig. 5 is the structural schematic diagram of embodiment three
Fig. 6 is the structural schematic diagram of embodiment three in a state of use;
The structural schematic diagram of Fig. 7 example IVs;
Fig. 8 is the structural schematic diagram of example IV in a state of use.
Reference sign:
1, sensing chamber;2, spectrum acquisition analysis module;3, light source module;4, extraction valve;5, pump-line;6, gas flow controls Device;7, aspiration pump;8, intake valve is purged;9, pipeline is purged;10, standard gas pipeline;11, standard gas intake valve;12, smoke filtration cover; 13, principal reflection mirror;14, check-valves;15, admission line;16, filter;17, mounting flange;18, walling of flue;19, NOx is converted Device;20, subreflector;21, temperature sensor;22, pressure sensor;23, launching fiber unit;24, stock control valve; 25, launching fiber unit;26, sealing sleeve pipe;27, outlet pipe;28, oxygen detection module.
Specific implementation mode
The present invention includes testing agency, interrupter, extraction sector, calibrating device, blowing mechanism and central processing module;
Testing agency includes sensing chamber 1, and 1 left side of sensing chamber is equipped with the spectral detection module being connected to inside sensing chamber 1, sensing chamber Principal reflection mirror 13 is equipped in 1, spectral detection module is oppositely arranged with principal reflection mirror 13;The spectral detection module includes light source die Block 3 and spectrum acquisition analysis module 2;
Interrupter includes the admission line 15 of 1 right end of communication with detection room, and admission line 15 stretches into walling of flue 18 and is arranged in flue It is interior, and 15 inlet of admission line is arranged with smoke filtration cover 12, admission line 15 is interior to be equipped with cigarette successively along air current flow direction Air valve and filter 16, filter 16 use nonplanar convex-concave structure, increased tolerance;The smoke valve uses check-valves 14 Or stock control valve 24;
Extraction sector includes pump-line 5, and 5 entrance communication with detection room of pump-line, 1 left part, the outlet of pump-line 5, which is equipped with, takes out Air pump 7, pump-line 5 is interior to be equipped with extraction valve 4;
Calibrating device includes standard gas pipeline 10 and the standard gas intake valve 11 that is arranged on standard gas pipeline 10,10 inlet end of standard gas pipeline Be connected to external perimysium reference air source, 10 outlet side of standard gas pipeline be connected to admission line 15,10 outlet side of standard gas pipeline be located at smoke valve with Between filter 16;
Blowing mechanism includes purging pipeline 9, purging intake valve 8 and gas flow controller 6, and purging 9 inlet end of pipeline connection is outer Ministerial standard air source, 9 outlet side of purging pipeline are stretched into flue and are connected to inside smoke filtration cover 12, and the purging setting of intake valve 8 is being blown It sweeps on pipeline 9, gas flow controller 6 is arranged on pump-line 5;
3 controlled end of light source module connects the light source control end of central processing module, the communication terminal connection of spectrum acquisition analysis module 2 The spectrum analysis communication terminal of central processing module, 6 communication terminal of gas flow controller connect central processing module flow communication terminal, Central processing module is evacuated control terminal and connects 7 controlled end of aspiration pump.
For a better understanding of the present invention, technical scheme of the present invention is described further below in conjunction with the accompanying drawings.
Embodiment one:
As depicted in figs. 1 and 2, the present embodiment include testing agency, interrupter, extraction sector, calibrating device, blowing mechanism and Central processing module;
Testing agency includes sensing chamber 1, and 1 right end of sensing chamber stretches into flue and sensing chamber 1 is fixed on cigarette by mounting flange 17 On road wall 18,1 left end of sensing chamber is connected to extraction sector, and 1 right end of sensing chamber is respectively communicated with interrupter and calibrating device.Sensing chamber 1 left side is equipped with the spectral detection module being connected to inside sensing chamber 1, and spectral detection module includes light source module 3 and spectrum acquisition Analysis module 2, is equipped with principal reflection mirror 13 in sensing chamber 1, principal reflection mirror 13 be located at 1 right end of sensing chamber and with spectral detection module phase To setting, principal reflection mirror 13 preferably uses three angle mirrors.Wherein, spectrum acquisition analysis module 2 includes for receiving reflection light Laser pick-off module and analyzer for carrying out spectrum analysis.
Interrupter is arranged in flue and for being filtered to sample gas, interrupter includes 1 right end of communication with detection room Admission line 15,15 inlet of admission line is arranged with smoke filtration cover 12, and 15 entrance of admission line positioned at right end is set There are flue gas hair, smoke valve that electrically-controlled valve or the check-valves 14 with one-way flow function, the present embodiment is used preferably to use non-return The circulating direction of valve 14, check-valves 14 is that is, consistent with sample gas circulating direction, the air inlet being located on the left of check-valves 14 from right to left Filter 16 is equipped in pipeline 15.
Smoke filtration cover 12 preferably uses radial section for the metal powder sintered filter element of ellipse, oval under same volume Type column structure has the surface area of bigger, therefore can be effectively increased the filter area of smoke filtration cover 12, makes smoke filtration The ventilatory capacity of cover 12 can reach 0.8L/min, under the premise of not increasing resistance, can increase in this way smoke filtration cover 12 surface area, Increase through-current capacity, simultaneously, moreover it is possible to reduce 16 internal gas sluggishness space of filter.
By using smoke filtration cover 12 made of metal powder sintered filter element, and section by smoke filtration cover 12 radially Face is set as non-circular, do not increase 12 internal volume of smoke filtration cover under the premise of, so that it may increase 12 table of smoke filtration cover Area, increase sample air-flow flux, ensure newly into a large amount of flue gases the gas in sluggish space all can be cemented out rapidly, Make gas in sensing chamber 1 it is all newly into flue gas, and then ensure that testing result is capable of the instantaneous of accurate characterization gaseous pollutant And real-time concentration, so that the present invention is consistent with master meter testing result when carrying out environmentally friendly contrastive detection, meets ring Protect the requirement of detection;
Extraction sector includes pump-line 5, and 5 entrance communication with detection room of pump-line, 1 left part, the outlet of pump-line 5, which is equipped with, takes out Air pump 7, pump-line 5 is interior to be equipped with extraction valve 4;
Calibrating device includes standard gas pipeline 10 and the standard gas intake valve 11 that is arranged on standard gas pipeline 10,10 inlet end of standard gas pipeline It is connected to external perimysium reference air source, 10 outlet side of standard gas pipeline is connected to admission line 15, and 10 outlet side of standard gas pipeline is located at check-valves 14 Between filter 16;
Blowing mechanism includes purging pipeline 9, purging intake valve 8 and gas flow controller 6, and purging 9 inlet end of pipeline connection is outer Ministerial standard air source, 9 outlet side of purging pipeline are stretched into flue and are connected to inside smoke filtration cover 12, and the purging setting of intake valve 8 is being blown It sweeps on pipeline 9, gas flow controller 6 is arranged on pump-line 5.
3 controlled end of light source module connects the light source control end of central processing module, the communication terminal of spectrum acquisition analysis module 2 The spectrum analysis communication terminal of central processing module is connected, it is logical that 6 communication terminal of gas flow controller connects central processing module flow End is interrogated, central processing module is evacuated control terminal and connects 7 controlled end of aspiration pump.
The operation principle of embodiment one is:
When sample gas detects, extraction valve 4 and aspiration pump 7 are opened, and standard gas intake valve 11 and purging intake valve 8 are closed, smoke filtration cover Negative-pressure sucking is generated in 12, the sample gas in flue enters smoke filtration cover 12, passed through successively after filtering out the solid particulate matter in flue gas After crossing back valve 14, admission line 15 and filter 16, clean contains gas pollutant SO2、NOXSample gas by sensing chamber 1 into Enter sensing chamber 1 and carry out spectral detection, is discharged subsequently into pump-line 5, gas flow controller 6, and by aspiration pump 7.
The spectral-analysis process of the present embodiment is:The light that light source module 3 sends out ultraviolet band enters sensing chamber 1, light Enter spectrum acquisition detection module after the reflection of principal reflection mirror 13, due to the SO in sample gas2、NOXIt can 1 light of absorption detecting room In characteristic wave bands, spectrum acquisition analysis module 2 to the spectrum of the light after being absorbed by gas pollutant carry out analysis obtain gas Body pollution object concentration.
Preferably using integrated spectrum acquisition module and spectroanalysis instrument, spectrum acquisition module receives anti-spectral detection module Irradiating light beam carries out gaseous pollutant analysis by spectrometer.
When standard gas is demarcated, extraction valve 4 and standard gas intake valve 11 are opened, and aspiration pump 7, purging intake valve 8 are closed, in standard gas pressure Under force effect, standard gas enters standard gas pipeline 10, and since smoke valve uses check-valves 14, check-valves 14 closes under the effect of standard gas pressure It closes, standard gas will not leak into flue from admission line 15, and flue gas cannot enter admission line 15 since check-valves 14 is closed; Standard gas enters sensing chamber 1 after filter 16, and spectral detection module carries out spectrum analysis and carries out parameter calibration, and standard gas finally flows It is discharged through pump-line 5 and gas flow controller 6.Interval of calibration according to《Stationary source flue gas(SO2, NOX, particle Object)Discharge continuous Specifications of Monitoring Technology》(HJ 75-2017)It is required that setting, primary per interior at least automatic Calibration calibration for 24 hours.
The spectrum analysis and process for carrying out parameter calibration is:The ultraviolet band light that light source module 3 is sent out enters sensing chamber 1, spectral detection module, the SO in calibrating gas are entered after the reflection of principal reflection mirror 132、NOXIn 1 light of absorption detecting room Characteristic wave bands, spectral detection module analyze the spectrum of the light after being absorbed by gas pollutant, obtain calibrating gas Pollutant concentration, then the indicating value of adjustment spectrum acquisition analysis module 2, makes 2 indicating value of spectrum acquisition analysis module and standard value one It causes, completes calibration process.
It is detected in above-mentioned sample gas and in the process, gas flow controller 6 detects the gas flow in pump-line 5 in real time, When flow value, which is less than, limits threshold value, it was demonstrated that stopping state occurs in smoke filtration cover 12, at this point, extraction valve 4, aspiration pump 7, standard gas Intake valve 11 is turned off, and purging intake valve 8 is opened, and external compression air source enters via purging pipeline 9 inside smoke filtration cover 12, And smoke filtration cover 12 is purged from inside to outside, 12 surface dirt of removal smoke filtration cover.The value of flow restriction threshold value need to ensure Stablized by the flue gas flow of monitoring device, is met simultaneously《Stationary source flue gas(SO2, NOX, particulate matter)The continuous prison of discharge Examining system technology requires and detection method》(HJ 76-2017)" influence of sample introduction changes in flow rate " technical indicator meet the requirements.
Embodiment two:
As shown in Figure 3 and Figure 4, the difference between this embodiment and the first embodiment lies in:
Temperature sensor 21 and pressure sensor 22 are equipped in sensing chamber 1, sensing chamber 1 is interior to be equipped with principal reflection mirror 13 in right part, On the admission line 15 that 1 left part of sensing chamber is connected to equipped with subreflector 20 corresponding with principal reflection mirror 13,1 right end of sensing chamber certainly Right-to-left is equipped with check-valves 14, NOx converters 19 and filter 16 successively, and NOx converters 19 are located at 10 outlet side of standard gas pipeline Between filter 16.
Principal reflection mirror 13 includes x three angle mirrors being set up in parallel, and subreflector 20 includes the x-1 triangles being set up in parallel Mirror, three angle mirrors of principal reflection mirror 13 are towards left setting, and three angle mirrors of subreflector 20 are towards right setting, i-th three of subreflector 20 Angle mirror lower half and i-th of three angle mirror first halves of principal reflection mirror 13 are oppositely arranged, i=1,2 ... ..., x-1;Light is in principal reflection Transmittance process between mirror 13 and subreflector 20 is:The light that light source module 3 is sent out injects the 1st triangle of principal reflection mirror 13 Mirror, light is reflexed to the 1st three angle mirrors of subreflector 20 by the 1st three angle mirrors of principal reflection mirror 13, then by subreflector 20 the 1st three angle mirrors reflex to the 2nd three angle mirrors of principal reflection mirror 13, until xth -1 of the light by subreflector 20 After three angle mirrors 20 reflex to x-th of three angle mirrors of principal reflection mirror 13, light is finally reflected by x-th of three angle mirrors of principal reflection mirror 13 To the spectrum acquisition analysis module 2 in left side.
Light source module 3 passes through mirror based fiber optica by 23 communication with detection room 1 of launching fiber unit, spectrum acquisition analysis module 2 25 communication with detection room 1 of unit, launching fiber unit 23 are arranged between light source module 3 and principal reflection mirror 13, mirror based fiber optica unit 25 are arranged between principal reflection mirror 13 and spectrum acquisition analysis module 2;Launching fiber unit 23 includes that diversing lens and transmitting are led Light optical fiber, diversing lens and transmitting light-conductive optic fibre, which emit along light source module 3 to the optical path direction of principal reflection mirror 13, to be set gradually, instead It includes mirror lens and reflection light optical fiber to penetrate fiber unit 25, and mirror lens and reflection light optical fiber are reflected along principal reflection mirror 13 It is set gradually to the optical path direction of spectrum acquisition analysis module 2.
The operation principle of embodiment two is:
When sample gas detects, extraction valve 4 and aspiration pump 7 are opened, and standard gas intake valve 11 and purging intake valve 8 are closed, smoke filtration cover Negative-pressure sucking is generated in 12, the sample gas in flue enters smoke filtration cover 12, passed through successively after filtering out the solid particulate matter in flue gas After crossing admission line 15, NOx converters 19 and filter 16, clean contains gas pollutant SO2、NOXSample gas pass through detection Room 1 enters sensing chamber 1 and carries out spectral detection, is discharged subsequently into pump-line 5 and by aspiration pump 7.
The spectral-analysis process of the present embodiment is:Light source module 3 sends out the light of ultraviolet band, the light warp of ultraviolet band By sensing chamber 1 and propagated on principal reflection mirror 13 by transmitting light unit, then principal reflection mirror 13 and subreflector 20 it Between carry out multiple reflections after, the light of final ultraviolet band enters spectrum acquisition detection module via mirror based fiber optica unit 25, by SO in sample gas2、NOXCharacteristic wave bands in 1 light of meeting absorption detecting room, spectrum acquisition analysis module 2 is to by gas pollutant The spectrum of light after absorption is analyzed, and the temperature signal and pressure sensor 22 that are detected according to temperature sensor 21 detect Pressure signal, analyzed via spectroanalysis instrument and obtain gas pollutant concentration.
When standard gas is demarcated, extraction valve 4 and standard gas intake valve 11 are opened, and aspiration pump 7 and purging intake valve 8 are closed, check-valves 14 since non-return acts on, and standard gas can not leak into flue from admission line 15, and flue gas can not enter admission line 15;It is marking Under air pressure force effect, external standard gas air source successively via after standard gas pipeline 10 and filter 16 enter sensing chamber 1, spectral detection mould Block carries out spectrum analysis and carries out parameter calibration, and standard gas is discharged after finally flowing through pump-line 5 and gas flow controller 6.
Embodiment three:
As shown in Figure 5 and Figure 6, the difference between this embodiment and the first embodiment lies in:
1 excircle of sensing chamber is arranged with sealing sleeve pipe 26, and 26 outer diameter of sealing sleeve pipe is not less than 12 maximum outside diameter of smoke filtration cover;Inspection It surveys and is equipped with temperature sensor 21 and pressure sensor 22 in room 1, it is left that temperature sensor 21 and pressure sensor 22 are located at sensing chamber 1 End is respectively used to the temperature and pressure of sample gas in detection sensing chamber 1.
Smoke valve in the present embodiment uses stock control valve 24, stock control valve 24 to include valve body, valve rod and hold Row device, 15 entrance of admission line extend downwardly, and valve body is arranged in 15 inlet of admission line, and actuator is located at outside walling of flue 18, Valve body and actuator are rotatablely connected by valve rod, realize actuator long-distance control valve body, the outlet side of aspiration pump 7 passes through outlet Pipeline 27 is connected to inside flue.
Light source module 3 passes through mirror based fiber optica by 23 communication with detection room 1 of launching fiber unit, spectrum acquisition analysis module 2 25 communication with detection room 1 of unit, launching fiber unit 23 are arranged between light source module 3 and principal reflection mirror 13, mirror based fiber optica unit 25 are arranged between principal reflection mirror 13 and spectrum acquisition analysis module 2;Launching fiber unit 23 includes that diversing lens and transmitting are led Light optical fiber, diversing lens and transmitting light-conductive optic fibre, which emit along light source module 3 to the optical path direction of principal reflection mirror 13, to be set gradually, instead It includes mirror lens and reflection light optical fiber to penetrate fiber unit 25, and mirror lens and reflection light optical fiber are reflected along principal reflection mirror 13 It is set gradually to the optical path direction of spectrum acquisition analysis module 2.
The operation principle of embodiment three is:
When sample gas detects, stock control valve 24, extraction valve 4 and aspiration pump 7 are opened, standard gas intake valve 11 and purging intake valve 8 It closes, negative-pressure sucking is generated in smoke filtration cover 12, the sample gas in flue enters smoke filtration cover 12, after filtering out solid particulate matter Sample gas successively pass through stock control valve 24, admission line 15 and filter 16, then, clean contains gas pollutant SO2、NOXSample gas by sensing chamber 1 enter sensing chamber 1 carry out spectral detection, subsequently into pump-line 5, gas flow control Device 6 is simultaneously discharged into flue by the extraction of aspiration pump 7, avoids pollution air.
It is detected in above-mentioned sample gas and in the process, gas flow controller 6 detects the gas flow in pump-line 5 in real time, When flow value, which is less than, limits threshold value, it was demonstrated that stopping state occurs in smoke filtration cover 12, at this point, by stock control valve 24 and mark Gas intake valve 11 is closed, and purging intake valve 8 is opened, and external compression air source enters via purging pipeline 9 inside smoke filtration cover 12, And smoke filtration cover 12 is purged from inside to outside, 12 surface dirt of removal smoke filtration cover.The value of flow restriction threshold value need to ensure Stablized by the flue gas flow of monitoring device, is met simultaneously《Stationary source flue gas(SO2, NOX, particulate matter)The continuous prison of discharge Examining system technology requires and detection method》(HJ 76-2017)" influence of sample introduction changes in flow rate " technical indicator meet the requirements.
The spectral-analysis process of the present embodiment is:Light source module 3 sends out the light of ultraviolet band, the light warp of ultraviolet band It crosses after principal reflection mirror 13 reflects and enters spectrum acquisition detection module, due to the SO in sample gas2、NOXThe feature in inspection light can be absorbed Wave band, spectrum acquisition analysis module 2 analyze the spectrum of the light after being absorbed by gas pollutant, and according to temperature sensing The pressure signal that the temperature signal and pressure sensor 22 that device 21 detects detect is analyzed via spectroanalysis instrument and obtains gas dirt Contaminate object concentration.
When standard gas is demarcated, extraction valve 4, aspiration pump 7 and standard gas intake valve 11 are opened, and stock control valve 24 is closed, flue gas Valve is that stock control valve 24 is closed, and standard gas can not leak into flue from admission line 15, and flue gas equally cannot Into admission line 15;Under the swabbing action that aspiration pump 7 generates, external standard gas air source is successively via standard gas pipeline 10 and filtering Enter sensing chamber 1 after device 16, spectral detection module carries out spectrum analysis and carries out parameter calibration, and standard gas is finally successively by pumping Pipeline 5, gas flow controller 6 and aspiration pump 7, are finally discharged by aspiration pump 7 in flue.
Example IV:
As shown in Figure 7 and Figure 8, the present embodiment and embodiment three difference lies in:
Smoke valve uses check-valves 14, check-valves 14 to be arranged in the inlet of 15 right end of admission line, air inlet in the present embodiment And sample pipeline 15 be connected to by check-valves 14 and the inside of smoke filtration cover 12, and the circulating direction of check-valves 14 is from right to left, i.e., Gas circulating direction is consistent, is located in the admission line 15 in 14 left side of check-valves and is equipped with filter 16.
Pump-line 5 is equipped with oxygen detection module 28, and oxygen detection module 28 is between extraction valve 4 and aspiration pump 7 And for detecting oxygen concentration in sample gas in real time, the detection signal that 28 output end of oxygen detection module connects central processing module is defeated Enter end.
Using air ejector of emanating, air ejector of emanating goes out aspiration pump 7 equipped with compressed air inlet, sample gas pump orifice and sample gas Mouthful, compressed air inlet is connected to external pressure air source, and sample gas pump orifice is connected to exhaust tube, sample gas outlet outlet pipe 27.
The operation principle of example IV is:
When sample gas detects, check-valves 14, extraction valve 4 and aspiration pump 7 are opened, and standard gas intake valve 11 and purging intake valve 8 are closed, cigarette Negative-pressure sucking is generated in gas filter mantle 12, the sample gas in flue enters smoke filtration cover 12, filters out the solid particulate matter in flue gas Sample gas afterwards passes through check-valves 14, admission line 15 and filter 16 successively, and then, clean contains gas pollutant SO2、NOX Sample gas enter sensing chamber 1 carry out spectral detection, then flow sequentially through into pump-line 5, oxygen detection module 28 and gas Flow controller 6 is finally discharged by aspiration pump 7 in flue, avoids pollution air.
The spectral-analysis process of the present embodiment is:Light source module 3 sends out the light of ultraviolet band, the light warp of ultraviolet band It crosses after principal reflection mirror 13 reflects and enters spectrum acquisition detection module, due to the SO in sample gas2、NOXIn 1 light of meeting absorption detecting room Characteristic wave bands, spectrum acquisition analysis module 2 analyzes the spectrum of the light after being absorbed by gas pollutant, and according to temperature Degree, pressure and oxygen content data, analyze via spectroanalysis instrument and obtain gas pollutant concentration;At the same time, oxygen detection Module 28 analyzes the oxygen content in the sample gas of high temperature, obtains oxygen concentration.
When standard gas is demarcated, extraction valve 4, aspiration pump 7 and standard gas intake valve 11 are opened, and check-valves 14 and purging intake valve 8 close It closes, under the one-way flow effect of check-valves 14, standard gas can not leak into flue from admission line 15, and flue gas is not due to bearing Pressure effect equally cannot be introduced into admission line 15, ensure that the pure of sample gas;External standard gas air source is successively via standard gas pipeline 10 It carries out spectrum analysis into sensing chamber 1, spectral detection module with after filter 16 and simultaneously carries out parameter calibration, then, standard gas enters Pump-line 5, oxygen detection module 28, gas flow controller 6 and aspiration pump 7, are finally discharged into flue via aspiration pump 7.With This simultaneously, oxygen detection module 28 carries out oxygen content analysis and calibration.
Finally it should be noted that:The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although Present invention has been described in detail with reference to the aforementioned embodiments, it will be understood by those of ordinary skill in the art that, still may be used To modify to the technical solution recorded in previous embodiment, either which part or all technical features are equal It replaces, and these modifications or replacements, the model for technical solution of the embodiment of the present invention that it does not separate the essence of the corresponding technical solution It encloses.

Claims (10)

1. a kind of directly measuring formula gaseous pollutant emission monitoring device, it is characterised in that:Including testing agency, interrupter, Extraction sector, calibrating device, blowing mechanism and central processing module;
Testing agency includes sensing chamber, is equipped on the left of sensing chamber and the spectral detection module that be connected to inside sensing chamber, detection interior Equipped with principal reflection mirror, spectral detection module is oppositely arranged with principal reflection mirror;The spectral detection module includes light source module and light Spectrum receives analysis module;
Interrupter includes the admission line of communication with detection room right end and the smoke valve in admission line inlet, air inlet pipe is arranged Road and smoke valve are arranged in flue, and smoke filtration cover is arranged with outside admission line entrance, filter is equipped in admission line;
Extraction sector includes pump-line, extraction valve and aspiration pump, pump-line entrance communication with detection room left part, pump-line Outlet connection aspiration pump, extraction valve are arranged in pump-line;
Calibrating device includes standard gas pipeline and the standard gas intake valve that is arranged on standard gas pipeline, and the connection of standard gas pipeline air-inlet end is external Standard air source, standard gas pipeline outlet side are connected to admission line, and standard gas pipeline outlet side is between smoke valve and filter;
Blowing mechanism includes purging pipeline, the purging gentle body flow controller of intake valve, the external mark of purging pipeline inlet end connection Quasi- air source, scavenging conduit road outlet side are stretched into flue and are connected to inside smoke filtration cover, and purging intake valve is arranged on purging pipeline, Gas flow controller is arranged on pump-line;
Light source module controlled end connects the light source control end of central processing module, in the communication terminal connection of spectrum acquisition analysis module The spectrum analysis communication terminal of processing module, gas flow controller communication terminal is entreated to connect central processing module flow communication terminal, in Processing module pumping control terminal is entreated to connect aspiration pump controlled end.
2. direct measurement formula gaseous pollutant emission monitoring device according to claim 1, it is characterised in that:The light source Module passes through mirror based fiber optica unit communication with detection by launching fiber unit communication with detection room, the spectrum acquisition analysis module Room, launching fiber unit are arranged between light source module and principal reflection mirror, and mirror based fiber optica unit is arranged in principal reflection mirror and spectrum Between reception analysis module;Launching fiber unit includes diversing lens and transmitting light-conductive optic fibre, the guide-lighting light of diversing lens and transmitting Fibre, which emits along light source module to the optical path direction of principal reflection mirror, to be set gradually, and mirror based fiber optica unit includes that mirror lens and reflection are led The optical path direction that light optical fiber, mirror lens and reflection light optical fiber are reflected towards spectrum acquisition analysis module along principal reflection mirror is set successively It sets.
3. direct measurement formula gaseous pollutant emission monitoring device according to claim 2, it is characterised in that:The detection Interior is additionally provided with subreflector, and subreflector is located on the left of principal reflection mirror and is oppositely arranged with principal reflection mirror.
4. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:It is described Testing agency further includes that setting is detecting indoor temperature sensor and pressure sensor, temperature sensor and pressure sensor Output end is separately connected spectrum acquisition analysis module signal input part.
5. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:Also wrap The oxygen detection module being arranged on pump-line is included, oxygen detection module output end connects the detection signal of central processing module Input terminal;When testing agency is detected the gas pollutant content in high-temperature sample gas, oxygen detection module is to the same as equally gas Oxygen content directly detected, testing agency carry out standard gas calibration when, standard gas simultaneously into oxygen detection module to oxygen examine Module is surveyed to be demarcated.
6. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:It is described Admission line is equipped with NOXConverter, NOXConverter is arranged between standard gas pipeline outlet side and filter.
7. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:It is described Smoke valve uses check-valves or stock control valve.
8. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:It is described For aspiration pump using air ejector of emanating, it is empty that air ejector of emanating is equipped with compressed air inlet, sample gas pump orifice and the outlet of sample gas, compression Gas entrance is connected to external air source, and sample gas pump orifice is connected to exhaust tube, sample gas outlet outlet pipe, and outlet pipe is connected to flue It is internal.
9. direct measurement formula gaseous pollutant emission monitoring device according to claim 1 or 2, it is characterised in that:It is described The light of light source module transmitting is ultraviolet light.
10. a kind of directly measurement formula gaseous pollutant emission monitoring device according to claim 1 or claim 2, it is characterised in that:With When standard gas is demarcated, standard gas intake valve is opened, and smoke valve is closed, and standard gas is isolated with the flue gas in filter mantle, and flue gas cannot be into Enter admission line to mix with standard gas, standard gas will not leak into flue from admission line.
CN201811100684.7A 2018-09-20 2018-09-20 It is a kind of directly to measure formula gaseous pollutant emission monitoring device Pending CN108801964A (en)

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