CN108786715A - A kind of adsorption catalyst of ira situ degradation formaldehyde - Google Patents
A kind of adsorption catalyst of ira situ degradation formaldehyde Download PDFInfo
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
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- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
Abstract
The present invention relates to formaldehyde purifying agent technical fields, and in particular to a kind of adsorption catalyst of ira situ degradation formaldehyde, the adsorption catalyst of the ira situ degradation formaldehyde are made of the substance of following parts by weight：5~15 parts by weight of attapulgite, 3~12 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, 5~8 parts by weight of graphene oxide, 3~8 parts by weight of diallyl dimethyl ammoniumchloride, 1~5 parts by weight of foaming agent, 80~150 parts by weight of nylon66 fiber lotion, 10~50 parts by weight of solvent.The adsorption catalyst of the ira situ degradation formaldehyde of the present invention can carry out indoor formaldehyde absorption and catalytic degradation, can persistently, thoroughly purify indoor formaldehyde.
Description
Technical field
The present invention relates to formaldehyde purifying agent technical fields, and in particular to a kind of adsorption catalyst of ira situ degradation formaldehyde.
Background technology
Formaldehyde is one of the major pollutants in volatile organic contaminant (VOCs), especially extensive in environment indoors
In the presence of.Formaldehyde depends on its concentration to the harm of human body, stimulates eye mucous membrane at low concentrations, is breathed in stimulation when concentration is slightly higher
Road causes cough, uncomfortable in chest, headache and nausea, when concentration higher to cause rhinitis, pharyngitis, pulmonary emphysema, lung cancer, or even dead.At present
, through being determined as carcinogenic by the World Health Organization and causing deformed material, the health that the indoor environmental pollution caused by formaldehyde is brought is asked for oneself
Topic has become the new hot spot that the public attractes attention.
Currently, indoor formaldehyde decomposition technique has nature Traditional Method, absorption method, negative aeroion technology law, photocatalysis technology
Method, catalytic oxidation technologies method, wherein based on absorption method, photocatalysis technology method, catalytic oxidation technologies method.Absorption method mainly uses
Activated carbon, activated alumina etc. are adsorbed as adsorbent PARA FORMALDEHYDE PRILLS(91,95), are had as disclosed in patent CN201310425845.0
It is a kind of disclosed in formaldehyde absorbing packet of composite adsorption function and preparation method thereof, patent CN201410511926.7 to be inhaled for formaldehyde
The preparation method of attached modified active carbon fiber.Catalytic oxidation technologies are mainly using the oxygen in air, in the work of catalyst
With it is lower by Formaldehyde decomposition be carbon dioxide and water, outer excitation light source and product cleaning are not needed, as disclosed in CN102658115A
It is a kind of to mix cerium nano-titanium dioxide/activated carbon fibre composite photo-catalyst and preparation method thereof for air purification,
A kind of effective catalyst of eliminating formaldehyde at room temperature disclosed in CN102247842A, can efficient-decomposition low concentration first under ambient temperature and moisture
The catalyst of aldehyde, but the photochemical catalyst pair can formaldehyde transformation efficiency be low, catalyst easy in inactivation.
To sum up, existing Degradation Formaldehyde agent or use absorption method or use catalytic degradation method, to keep indoor formaldehyde inadequate
Thoroughly, and the conversion ratio of formaldehyde is relatively low.
Invention content
It is of the existing technology the purpose of the invention is to overcome the problems, such as, a kind of absorption of ira situ degradation formaldehyde is provided and is urged
Agent, it can adsorb indoor formaldehyde, and can carry out ira situ degradation in absorption point PARA FORMALDEHYDE PRILLS(91,95), have high catalytic efficiency, drop
Solve thorough advantage.
To achieve the goals above, the present invention provides a kind of adsorption catalyst of ira situ degradation formaldehyde, by following parts by weight
Substance be made：5~15 parts by weight of attapulgite, 3~12 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, oxygen
5~8 parts by weight of graphite alkene, 1~5 parts by weight of foaming agent, 80~150 parts by weight of nylon66 fiber lotion, 10~50 parts by weight of solvent.
Through the above technical solutions, foaming agent is added in the present invention in nylon66 fiber lotion first, and carry out electrostatic spinning and
Calcining, obtains porous carbon fiber, ultrasonic after then mixing porous carbon fiber with attapulgite and organic titanate, can make recessed
Convex stick soil enters with organic titanate in the hole of porous carbon fiber, then carries out closing thermal response, organic titanate is made to decompose
Nano-titanium dioxide is generated, i.e., is generated in the hole of porous carbon fiber nano-titanium dioxide modified recessed with catalytic performance
Modified porous carbon fiber is finally reacted with diallyl dimethyl ammoniumchloride, makes to change by convex stick soil, i.e., modified porous carbon fiber
Property porous carbon fiber carry positive charge, then will to wait for that the modified porous carbon fiber of positive charge is stirred with negatively charged graphite oxide anti-
It answers, modified porous carbon fiber is further modified using graphene oxide, improves the performance of its catalytic degradation formaldehyde.This hair
The adsorption catalyst of bright ira situ degradation formaldehyde contains abundant pore structure, and specific surface area is high, being capable of formaldehyde adsorption；And hole
In nano-titanium dioxide modified attapulgite can PARA FORMALDEHYDE PRILLS(91,95) decomposed, to have the function that decomposition in situ formaldehyde, tool
There is the characteristics of high catalytic efficiency.
Specific implementation mode
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The present invention provides a kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：Concave convex rod
Native 5~15 parts by weight, 3~12 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, 5~8 weight of graphene oxide
Part, 3~8 parts by weight of diallyl dimethyl ammoniumchloride, 1~5 parts by weight of foaming agent, 80~150 parts by weight of nylon66 fiber lotion,
10~50 parts by weight of solvent.Under optimum condition, the adsorption catalyst of the ira situ degradation formaldehyde, by the substance system of following parts by weight
At：6~12 parts by weight of attapulgite, 5~10 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, graphene oxide 5
~8 parts by weight, 3~8 parts by weight of diallyl dimethyl ammoniumchloride, 1~5 parts by weight of foaming agent, nylon66 fiber lotion 100~
120 parts by weight, 10~50 parts by weight of solvent.
The present invention also provides a kind of preparation methods of the adsorption catalyst of the ira situ degradation formaldehyde, include the following steps：
(1) foaming agent is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, by nylon
66 fibers calcine 2~4h at 300~450 DEG C, obtain porous carbon fiber；
(2) in a solvent after mixing by porous carbon fiber, attapulgite, silane coupling agent and organic titanate, surpass
15~30min of sound, then 3~6h of sealing reaction at 80~120 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber 15~30min of ultrasonic disperse in a solvent, diallyl dimethyl is then added
Ammonium chloride continues 30~45min of ultrasound, is subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation formaldehyde
Adsorption catalyst.
Foaming agent is added in the present invention in nylon66 fiber lotion first, and carries out electrostatic spinning and calcining, obtains porous carbon fiber
It ties up, under optimum condition, the electrostatic spinning process is：30~50kV of supply voltage, spinning temperature are 25~35 DEG C, relative humidity
60~75%；Multi needle spinneret unit syringe needle 25~35cm of spacing, spinneret unit syringe needle quantity are 60~90；The foaming agent
Selected from least one of azo-compound, sulfonyl hydrazines compound, nitroso compound and carbonate.
Contain abundant pore structure in attapulgite, the formaldehyde of air can be adsorbed, in order to improve the ratio of attapulgite
Surface area further includes the modification of attapulgite, the modification process of the attapulgite under optimum condition, in the present invention
For：After attapulgite grinding uniformly, 200 mesh sieve is crossed, 3~6h is then calcined at 300~500 DEG C.
It is ultrasonic after porous carbon fiber is mixed with attapulgite and organic titanate, attapulgite and organic titanium can be made
Acid esters enters in the hole of porous fibre, then carries out closing thermal response, so that organic titanate is decomposed and generates nano-titanium dioxide,
Then nano silicon dioxide and attapulgite are generated in acting in the hole of porous carbon fiber for silane coupling agent with urging
Change the nano-titanium dioxide modified attapulgite of performance；Under optimum condition, the organic titanate is selected from tetraethyl titanate, metatitanic acid
At least one of four methyl esters, tetraisopropyl titanate, tetrabutyl titanate, tetra-n-butyl titanate.
Under optimum condition, the silane coupling agent is selected from Silane coupling agent KH550, silane coupling agent KH560, silane coupled
Agent KH570, silane coupling agent KH580, silane coupling agent KH590, silane coupling agent KH792, silane coupling agent KBM602, silane
At least one of coupling agent A151 and silane coupling A 171.
In the present invention, modified porous carbon fiber is reacted with diallyl dimethyl ammoniumchloride, makes modified porous carbon fiber
Dimension carries positive charge, then the modified porous carbon fiber for waiting for positive charge is stirred to react with negatively charged graphite oxide, using oxygen
Graphite alkene is further modified modified porous carbon fiber, improves the performance of its catalytic degradation formaldehyde.
It is further preferred that the solvent is selected from acetone, n,N-Dimethylformamide, N-Methyl pyrrolidone, N, N- bis-
Methylacetamide, N, N- diethylformamides, ethyl alcohol, acetic acid, ethyl acetate, chloroform, tetrahydrofuran, petroleum ether, dimethyl are sub-
At least one of sulfone and water.
The adsorption catalyst of the ira situ degradation formaldehyde of the present invention contains abundant pore structure, and specific surface area is high, can inhale
Attached formaldehyde；And the nano-titanium dioxide modified attapulgite in hole can PARA FORMALDEHYDE PRILLS(91,95) decomposed, to reach decomposition in situ
The effect of formaldehyde, has the characteristics that high catalytic efficiency.
The present invention will be described in detail by way of examples below.
Embodiment 1
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：10 parts by weight of attapulgite,
8 parts by weight of tetraethyl titanate, silane coupling agent KH5803.5 parts by weight, 6 parts by weight of graphene oxide, diallyl dimethyl
5 parts by weight of ammonium chloride, 3 parts by weight of sodium carbonate, 100 parts by weight of nylon66 fiber lotion, 50 parts by weight of water.
The preparation method of the adsorption catalyst of the ira situ degradation formaldehyde, includes the following steps：
(1) sodium carbonate is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, described quiet
Electrospinning process is：Supply voltage 50kV, spinning temperature are 35 DEG C, relative humidity 75%；Multi needle spinneret unit syringe needle spacing
35cm, spinneret unit syringe needle quantity are 90；
Nylon 66 fiber is calcined into 3h at 350 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 5h at 400 DEG C；
In water after mixing by porous carbon fiber, attapulgite, silane coupling agent KH580 and tetraethyl titanate, surpass
15~30min of sound, then 3~6h of sealing reaction at 80~120 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber 15~30min of ultrasonic disperse in water, diallyl dimethyl chlorine is then added
Change ammonium, continue 30~45min of ultrasound, be subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation formaldehyde
Adsorption catalyst.
Embodiment 2
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：12 parts by weight of attapulgite,
10 parts by weight of tetramethoxy titanate ester, silane coupling agent KH5903.2 parts by weight, 6 parts by weight of graphene oxide, polydiene dimethylamine
6 parts by weight of ammonium chloride, N, 3 parts by weight of N '-dinitrosopentamethlyene tetramines, 120 parts by weight of nylon66 fiber lotion, 50 weight of ethyl alcohol
Measure part.
(1) N is added in nylon66 fiber lotion, N '-dinitrosopentamethlyene tetramines are uniformly mixed, and then electrostatic spinning obtains
To nylon 66 fiber, the electrostatic spinning process is：Supply voltage 50kV, spinning temperature are 35 DEG C, relative humidity 75%；Spininess
Head spinneret unit syringe needle spacing 35cm, spinneret unit syringe needle quantity are 90；
Nylon 66 fiber is calcined into 2.5h at 400 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 5h at 350 DEG C；
In ethanol after mixing by porous carbon fiber, attapulgite, silane coupling agent KH590 and tetramethoxy titanate ester,
15~30min of ultrasound, then the sealing reaction 4h at 100 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber 15~30min of ultrasonic disperse in ethanol, diallyl dimethyl is then added
Ammonium chloride continues 30~45min of ultrasound, is subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation formaldehyde
Adsorption catalyst.
Embodiment 3
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：6 parts by weight of attapulgite,
5 parts by weight of tetra-n-butyl titanate, silane coupling agent KH7923.8 parts by weight, 5.5 parts by weight of graphene oxide, polydiene propyl two
4 parts by weight of ammonio methacrylate, 2 parts by weight of 4,4- oxobenzenesulfonyl hydrazide, 100 parts by weight of nylon66 fiber lotion, 40 weight of petroleum ether
Part.
(1) 4,4- oxobenzenesulfonyl hydrazide is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon
66 fibers, the electrostatic spinning process are：Supply voltage 50kV, spinning temperature are 35 DEG C, relative humidity 75%；Multi needle spinneret
Unit syringe needle spacing 35cm, spinneret unit syringe needle quantity are 90；
Nylon 66 fiber is calcined into 2.5h at 350 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 4h at 400 DEG C；
Porous carbon fiber, attapulgite, silane coupling agent KH792 and tetra-n-butyl titanate are uniformly mixed in petroleum ether
Afterwards, 15~30min of ultrasound, then the sealing reaction 3h at 120 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber in petroleum ether 15~30min of ultrasonic disperse, then be added polydiene dimethylamine
Ammonium chloride continues 30~45min of ultrasound, is subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation first
The adsorption catalyst of aldehyde.
Embodiment 4
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：15 parts by weight of attapulgite,
3 parts by weight of tetrabutyl titanate, silane coupling agent KH5704 parts by weight, 5 parts by weight of graphene oxide, diallyl dimethyl
8 parts by weight of ammonium chloride, 1 parts by weight of sodium carbonate, 150 parts by weight of nylon66 fiber lotion, 50 parts by weight of water.
(1) sodium carbonate is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, described quiet
Electrospinning process is：Supply voltage 30kV, spinning temperature are 25 DEG C, relative humidity 60%；Multi needle spinneret unit syringe needle spacing
25cm, spinneret unit syringe needle quantity are 60；
Nylon 66 fiber is calcined into 4h at 450 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 3h at 500 DEG C；
In water after mixing by porous carbon fiber, attapulgite, silane coupling agent KH570 and tetrabutyl titanate,
15~30min of ultrasound, then the sealing reaction 6h at 80 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber 15~30min of ultrasonic disperse in water, diallyl dimethyl chlorine is then added
Change ammonium, continue 30~45min of ultrasound, be subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation formaldehyde
Adsorption catalyst.
Embodiment 5
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：5 parts by weight of attapulgite,
12 parts by weight of tetra-n-butyl titanate, silane coupling agent KH5703 parts by weight, 8 parts by weight of graphene oxide, polydiene dimethylamine
3 parts by weight of ammonium chloride, 5 parts by weight of sodium carbonate, 80 parts by weight of nylon66 fiber lotion, 10 parts by weight of tetrahydrofuran.
(1) sodium carbonate is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, described quiet
Electrospinning process is：Supply voltage 30kV, spinning temperature are 25 DEG C, relative humidity 60%；Multi needle spinneret unit syringe needle spacing
25cm, spinneret unit syringe needle quantity are 60；
Nylon 66 fiber is calcined into 2h at 300 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 6h at 300 DEG C；
Porous carbon fiber, attapulgite, silane coupling agent KH570 and tetra-n-butyl titanate are mixed in tetrahydrofuran
After even, 15~30min of ultrasound, then the sealing reaction 3h at 100 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber in tetrahydrofuran 15~30min of ultrasonic disperse, polydiene propyl two is then added
Ammonio methacrylate continues 30~45min of ultrasound, is subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation
The adsorption catalyst of formaldehyde.
Comparative example 1
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：10 parts by weight of attapulgite,
Silane coupling agent KH5803.5 parts by weight, 6 parts by weight of graphene oxide, 5 parts by weight of diallyl dimethyl ammoniumchloride, carbonic acid
3 parts by weight of sodium, 100 parts by weight of nylon66 fiber lotion, 50 parts by weight of water.
The preparation method of the adsorption catalyst of the ira situ degradation formaldehyde, includes the following steps：
(1) sodium carbonate is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, described quiet
Electrospinning process is：Supply voltage 50kV, spinning temperature are 35 DEG C, relative humidity 75%；Multi needle spinneret unit syringe needle spacing
35cm, spinneret unit syringe needle quantity are 90；
Nylon 66 fiber is calcined into 3h at 350 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 5h at 400 DEG C；
In water after mixing by porous carbon fiber, attapulgite, silane coupling agent KH580,15~30min of ultrasound,
Then 3~6h of sealing reaction at 80~120 DEG C, obtains modified porous carbon fiber；
(3) by modified porous carbon fiber 15~30min of ultrasonic disperse in water, diallyl dimethyl chlorine is then added
Change ammonium, continue 30~45min of ultrasound, be subsequently added into graphene oxide, after stirring 30~45min, obtains ira situ degradation formaldehyde
Adsorption catalyst.
Comparative example 2
A kind of adsorption catalyst of ira situ degradation formaldehyde, is made of the substance of following parts by weight：10 parts by weight of attapulgite,
8 parts by weight of tetraethyl titanate, silane coupling agent KH5803.5 parts by weight, 5 parts by weight of diallyl dimethyl ammoniumchloride, carbonic acid
3 parts by weight of sodium, 100 parts by weight of nylon66 fiber lotion, 50 parts by weight of water.
The preparation method of the adsorption catalyst of the ira situ degradation formaldehyde, includes the following steps：
(1) sodium carbonate is added in nylon66 fiber lotion to be uniformly mixed, then electrostatic spinning obtains nylon 66 fiber, described quiet
Electrospinning process is：Supply voltage 50kV, spinning temperature are 35 DEG C, relative humidity 75%；Multi needle spinneret unit syringe needle spacing
35cm, spinneret unit syringe needle quantity are 90；
Nylon 66 fiber is calcined into 3h at 350 DEG C, obtains porous carbon fiber；
(2) by after attapulgite grinding uniformly, 200 mesh sieve is crossed, then calcines 5h at 400 DEG C；
In water after mixing by porous carbon fiber, attapulgite, silane coupling agent KH580 and tetraethyl titanate, surpass
15~30min of sound, then 3~6h of sealing reaction at 80~120 DEG C, obtains modified porous carbon fiber.
Experiment test：
The purification of the adsorption catalyst PARA FORMALDEHYDE PRILLS(91,95) of ira situ degradation formaldehyde in 1-5 of the embodiment of the present invention and comparative example 1-2
It can evaluate and be carried out in the straight type polytetrafluoroethylene (PTFE) pipe reactor of Φ 20mm, long 200mm, by the adsorption catalyst of ira situ degradation formaldehyde
Be added polytetrafluoroethylene (PTFE) pipe reactor in, then by polytetrafluoroethylene (PTFE) pipe reactor be evacuated to pressure be -1.0KPa, then to
Unstripped gas is injected in polytetrafluoroethylene (PTFE) pipe reactor to normal pressure, tests the adsorption catalyst pair of ira situ degradation formaldehyde under different time
The purifying rate of formaldehyde, unstripped gas group become：Concentration of formaldehyde 6ppm, remaining is air.Reaction carries out under 25 DEG C of atmospheric pressure environments, real
Test that the results are shown in Table 1.
Table 1：Adsorber catalyst purge performance in embodiment 1-5 and comparative example 1-2
The preferred embodiment of the present invention has been described above in detail, and still, the present invention is not limited thereto.In the skill of the present invention
In art conception range, technical scheme of the present invention can be carried out a variety of simple variants, including each technical characteristic with it is any its
Its suitable method is combined, and it should also be regarded as the disclosure of the present invention for these simple variants and combination, belongs to
Protection scope of the present invention.
Claims (6)
1. a kind of adsorption catalyst of ira situ degradation formaldehyde, which is characterized in that be made of the substance of following parts by weight：Attapulgite
5~15 parts by weight, 3~12 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, 5~8 parts by weight of graphene oxide,
It is 3~8 parts by weight of diallyl dimethyl ammoniumchloride, 1~5 parts by weight of foaming agent, 80~150 parts by weight of nylon66 fiber lotion, molten
10~50 parts by weight of agent.
2. the adsorption catalyst of ira situ degradation formaldehyde according to claim 1, which is characterized in that by the object of following parts by weight
Matter is made：6~12 parts by weight of attapulgite, 5~10 parts by weight of organic titanate, 3~4 parts by weight of silane coupling agent, oxidation stone
5~8 parts by weight of black alkene, 3~8 parts by weight of diallyl dimethyl ammoniumchloride, 1~5 parts by weight of foaming agent, nylon66 fiber lotion
100~120 parts by weight, 10~50 parts by weight of solvent.
3. the adsorption catalyst of ira situ degradation formaldehyde according to claim 1, which is characterized in that the organic titanate choosing
From at least one of tetraethyl titanate, tetramethoxy titanate ester, tetraisopropyl titanate, tetrabutyl titanate, tetra-n-butyl titanate.
4. the adsorption catalyst of ira situ degradation formaldehyde according to claim 1, which is characterized in that the silane coupling agent choosing
From Silane coupling agent KH550, silane coupling agent KH560, silane coupling agent KH570, silane coupling agent KH580, silane coupling agent
In KH590, silane coupling agent KH792, silane coupling agent KBM602, silane coupling A 151 and silane coupling A 171 at least
It is a kind of.
5. the adsorption catalyst of ira situ degradation formaldehyde according to claim 1, which is characterized in that the foaming agent is selected from even
At least one of nitrogen compound, sulfonyl hydrazines compound, nitroso compound and carbonate.
6. the adsorption catalyst of ira situ degradation formaldehyde according to claim 1, which is characterized in that the solvent is selected from third
Ketone, N,N-dimethylformamide, N-Methyl pyrrolidone, DMAC N,N' dimethyl acetamide, ethyl alcohol, acetic acid, ethyl acetate, tetrahydrochysene furan
It mutters, at least one of dimethyl sulfoxide (DMSO) and water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810423130.4A CN108786715A (en) | 2018-05-05 | 2018-05-05 | A kind of adsorption catalyst of ira situ degradation formaldehyde |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810423130.4A CN108786715A (en) | 2018-05-05 | 2018-05-05 | A kind of adsorption catalyst of ira situ degradation formaldehyde |
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| CN113083242A (en) * | 2021-03-31 | 2021-07-09 | 广州市绿新环保科技有限公司 | Novel material capable of releasing negative ions and removing formaldehyde and preparation method thereof |
| CN114011476A (en) * | 2021-11-08 | 2022-02-08 | 四川大学 | Adsorption-catalytic decomposition integrated titanium dioxide and application thereof |
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| CN114011476A (en) * | 2021-11-08 | 2022-02-08 | 四川大学 | Adsorption-catalytic decomposition integrated titanium dioxide and application thereof |
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Application publication date: 20181113 |