CN108785142B - Mascara and preparation method thereof - Google Patents
Mascara and preparation method thereof Download PDFInfo
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- CN108785142B CN108785142B CN201811123220.8A CN201811123220A CN108785142B CN 108785142 B CN108785142 B CN 108785142B CN 201811123220 A CN201811123220 A CN 201811123220A CN 108785142 B CN108785142 B CN 108785142B
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- 238000002360 preparation method Methods 0.000 title abstract description 10
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical class O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 66
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 34
- 239000000440 bentonite Substances 0.000 claims abstract description 34
- 239000000919 ceramic Substances 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 23
- 229940119170 jojoba wax Drugs 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000004166 Lanolin Substances 0.000 claims abstract description 21
- 235000019388 lanolin Nutrition 0.000 claims abstract description 21
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 20
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 20
- ZHALDANPYXAMJF-UHFFFAOYSA-N octadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCC[NH+](CCO)CCO.CCCCCCCCCCCCCCCCCC([O-])=O ZHALDANPYXAMJF-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229940029614 triethanolamine stearate Drugs 0.000 claims abstract description 20
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 20
- 229940046009 vitamin E Drugs 0.000 claims abstract description 20
- 239000011709 vitamin E Substances 0.000 claims abstract description 20
- 239000006229 carbon black Substances 0.000 claims abstract description 19
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 11
- 239000012266 salt solution Substances 0.000 claims abstract description 6
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 22
- 239000000243 solution Substances 0.000 claims description 18
- 229910001404 rare earth metal oxide Inorganic materials 0.000 claims description 10
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 3
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 3
- 210000000720 eyelash Anatomy 0.000 abstract description 39
- 230000000694 effects Effects 0.000 abstract description 18
- 230000008569 process Effects 0.000 abstract description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 9
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 abstract description 9
- 125000004344 phenylpropyl group Chemical group 0.000 abstract description 9
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 abstract description 9
- 238000009776 industrial production Methods 0.000 abstract description 5
- 238000005054 agglomeration Methods 0.000 abstract description 4
- 230000002776 aggregation Effects 0.000 abstract description 4
- 239000002537 cosmetic Substances 0.000 abstract description 3
- 239000002245 particle Substances 0.000 description 12
- -1 phenylpropyl dimethyl siloxy silicate ester Chemical class 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 150000001767 cationic compounds Chemical class 0.000 description 2
- 229910001411 inorganic cation Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- XJWSAJYUBXQQDR-UHFFFAOYSA-M dodecyltrimethylammonium bromide Chemical group [Br-].CCCCCCCCCCCC[N+](C)(C)C XJWSAJYUBXQQDR-UHFFFAOYSA-M 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000003862 health status Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical group [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to mascara and a preparation method thereof, and belongs to the technical field of cosmetics. The raw materials of the mascara comprise 12-15 parts by weight of modified bentonite, 4-5 parts by weight of triethanolamine-stearate, 4-5 parts by weight of phenylpropyl dimethyl siloxy silicate, 25-30 parts by weight of jojoba oil, 20-25 parts by weight of wool wax, 4-5 parts by weight of far infrared ceramic powder, 3-4 parts by weight of vitamin E and 8-10 parts by weight of carbon black; the modified bentonite is obtained by modifying bentonite with quaternary ammonium salt solution. The mascara has the advantages of reasonable formula, low cost, good makeup effect, no agglomeration and no makeup removal, and can effectively relieve the condition that eyelashes are easy to fall off in the makeup removal process of the mascara. The preparation method comprises the steps of mixing the raw materials according to the proportion, and the method is simple and quick and is suitable for industrial production.
Description
Technical Field
The invention relates to the technical field of cosmetics, and particularly relates to mascara and a preparation method thereof.
Background
Mascara is a cosmetic applied to eyelashes in order to thicken, lengthen, curl, and darken the color of the eyelashes. The traditional mascara can make eyelashes hard and sticky after being used, and make up is easy to be removed, thereby reducing the using effect.
Disclosure of Invention
The invention aims to provide the mascara, which has the advantages of reasonable formula, low cost, good makeup effect, no agglomeration and no makeup removal, and can effectively relieve the condition that eyelashes are easy to fall off in the makeup removal process of the mascara.
The second purpose of the present invention is to provide a method for preparing the above mascara, which is simple and fast and suitable for industrial production.
The technical problem to be solved by the invention is realized by adopting the following technical scheme:
the invention provides mascara, which comprises the following raw materials, by weight, 12-15 parts of modified bentonite, 4-5 parts of triethanolamine-stearate, 4-5 parts of phenylpropyl dimethyl siloxy silicate ester, 25-30 parts of jojoba oil, 20-25 parts of wool wax, 4-5 parts of far infrared ceramic powder, 3-4 parts of vitamin E and 8-10 parts of carbon black; the modified bentonite is obtained by modifying bentonite with quaternary ammonium salt solution.
The invention also provides a preparation method of the mascara, which comprises the following steps: mixing the raw materials according to the proportion.
The mascara and the preparation method thereof provided by the preferred embodiment of the invention have the beneficial effects that:
the mascara provided by the preferred embodiment of the invention has the advantages of reasonable formula, low cost, good makeup effect, no caking and no makeup removal, and can effectively relieve the condition that eyelashes are easy to fall off during makeup removal of the mascara. The preparation method comprises the steps of mixing the raw materials according to the proportion, and the method is simple and quick and is suitable for industrial production.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
Hereinafter, mascara and a method for preparing the same according to embodiments of the present invention will be described in detail.
The mascara comprises, by weight, 12-15 parts of modified bentonite, 4-5 parts of triethanolamine-stearate, 4-5 parts of phenylpropyl dimethyl siloxy silicate, 25-30 parts of jojoba oil, 20-25 parts of wool wax, 4-5 parts of far infrared ceramic powder, 3-4 parts of vitamin E and 8-10 parts of carbon black. The modified bentonite is obtained by modifying bentonite with quaternary ammonium salt solution.
In some embodiments, the raw material of mascara may include 14-15 parts by weight of modified bentonite, 4-4.5 parts by weight of triethanolamine-stearate, 4.5-5 parts by weight of phenylpropyldimethylsilanyloxysilicate, 26-28 parts by weight of jojoba oil, 22-24 parts by weight of wool wax, 4.5-5 parts by weight of far infrared ceramic powder, 3.5-4 parts by weight of vitamin E, and 9-10 parts by weight of carbon black.
In some particularly preferred embodiments, the raw material of mascara may include 15 parts by weight of modified bentonite, 4.5 parts by weight of triethanolamine-stearate, 5 parts by weight of phenylpropyldimethylsilanyloxysilicate, 28 parts by weight of jojoba oil, 23 parts by weight of wool wax, 5 parts by weight of far infrared ceramic powder, 4 parts by weight of vitamin E, and 10 parts by weight of carbon black.
Under the preferable proportion, the raw materials are more appropriately mixed, so that the mascara has stronger water resistance and is not easy to agglomerate.
In this application, modified bentonite obtains for the bentonite after quaternary ammonium salt solution is modified, and the bentonite after the modification has reduced the hydrophilicity of bentonite, can effectively adjust the mobility and the waterproof nature of mascara, avoids the mascara to appear taking off the phenomenon of making up and making up with flowers under meeting water or sweat condition.
Alternatively, the carbon chain of the quaternary amine salt may have 10 to 18 carbon atoms. In some embodiments, cetyl trimethylammonium bromide is selected as the quaternary ammonium salt. In the process of modifying the bentonite, the cetyl trimethyl ammonium bromide can fully enlarge the interlayer spacing of the bentonite, improve the replacement degree of inorganic cations and reduce the hydrophilicity of the bentonite.
By way of reference, the modified bentonite described above can be obtained, for example, in the following manner, taking cetyltrimethylammonium bromide as an example: mixing bentonite and hexadecyl trimethyl ammonium bromide solution, water bathing, filtering, collecting filtrate, removing bromide ions, and oven drying.
In this application, every 100g of bentonite is modified with 90-100mmoL of cetyltrimethylammonium bromide solution. In this ratio, the cetyltrimethylammonium bromide solution is beneficial for the inorganic cations (including K) contained in the bentonite+、Na+、Ca2+And Mg2+Etc.) to be more completely replaced, so that the hydrophilic structure contained in the mascara is changed into a hydrophobic structure, thereby improving the water resistance of the mascara.
Triethanolamine-stearate is mainly used for adjusting the dispersibility and wettability of the mascara in the application, so that the mascara can be uniformly dispersed on eyelashes, the dried thickness is more consistent, and the phenomenon of agglomeration and agglomeration is avoided.
The phenylpropyl dimethyl siloxy silicate can play a role in shaping and film forming, provides a waterproof capsule for mascara, resists sweat and water, and can be matched with triethanolamine-stearate to further improve the dispersibility of the mascara.
Jojoba oil and wool wax are used herein primarily to improve the adhesion strength of mascara. The jojoba oil is vegetable oil, has good penetration and high stability, can resist strong light, and does not stimulate eyelashes. Wool wax is animal oil, has strong water-in-oil type emulsifying capacity, is stable at high temperature and has strong viscosity. After the jojoba oil is matched with the wool wax, the adhesion degree of mascara and eyelashes can be improved, the makeup is more durable and stable, and the phenomenon of makeup removal or makeup removal after long-time brushing is avoided.
On bearing, mascara in this application combines waterproof nature and adhesion strength to improve its stability on the eyelashes jointly, improves the result of making up, avoids the condition such as caking, make up or make up by removing.
However, the mascara may be easily peeled off during makeup removal after the adhesive strength of the mascara is improved. The mascara of this application still contains far infrared ceramic powder and vitamin E in the raw materials, through the two cooperation, can effectively improve the toughness and the dense degree of eyelash, avoids it to drop at the makeup removal in-process.
Wherein, the far infrared ceramic powder can absorb external heat, releases the far infrared easily absorbed by the human body, and this part far infrared can act on the eyelashes and be absorbed by the eyelashes, increases the vitality and the metabolism of eyelash tissue, improves the health status of eyelashes, such as toughness and thickness degree etc..
In some embodiments, the far infrared ceramic powder has an average particle size of not more than 10 μm, which is small in size and can rapidly absorb heat and act on eyelashes.
Vitamin E can effectively avoid factors such as ultraviolet rays or air pollution to cause eyelash toughness to reduce on the one hand, and on the other hand can improve the texture of eyelashes, makes them become dense, thereby improves the stability of eyelashes in the mascara makeup removing process.
It is worth saying that the jojoba oil in the raw material is rich in vitamin D and protein, and can permeate into eyelash tissues to achieve the effect of moistening and caring eyelash.
In other embodiments, the raw material may further include 0.5 to 1 part by weight of a rare earth oxide and 0.5 to 1 part by weight of a transition metal oxide. The rare earth element ions and the transition metal element ions have an activating and catalyzing effect, and can capture photocatalytic electrons, so that the far infrared ceramic powder can generate more electrons and holes, and the infrared radiation capability of the far infrared ceramic powder is improved.
Alternatively, the rare earth oxide may include La2O3And Sm2O3At least one of (1). The transition metal oxide may comprise TiO2And Pd2O3At least one of (1). The rare earth oxide and the transition metal oxide have good effect of improving the infrared radiation capability of the far infrared ceramic powder.
Carbon black is mainly used as a pigment of mascara, providing color to the mascara.
In the makeup process, the mascara is effectively relieved, and the condition that eyelashes fall off easily caused by the makeup removing process is avoided.
In addition, the present application also provides a method for preparing the mascara, which may include, for example, the following steps: mixing the raw materials according to the proportion.
Specifically, when the raw materials do not contain rare earth oxides and transition metal oxides, the modified bentonite, triethanolamine stearate, phenylpropyldimethylsilanyloxysilicate, far infrared ceramic powder, vitamin E and carbon black can be mixed according to the proportion, and then the mixture is mixed with jojoba oil and wool wax.
When the raw materials contain rare earth oxide and transition metal oxide, the far infrared ceramic powder, the rare earth oxide and the transition metal oxide are mixed according to the proportion, then the mixture is mixed with modified bentonite, triethanolamine-stearate, phenylpropyl dimethyl siloxy silicate, vitamin E and carbon black, and finally the mixture is mixed with jojoba oil and wool wax.
The preparation method is simple and quick, and is suitable for industrial production.
The features and properties of the present invention are described in further detail below with reference to examples.
Example 1
First, 12 parts by weight of modified bentonite, 4 parts by weight of triethanolamine-stearate, 4 parts by weight of phenylpropyl dimethyl siloxysilicate, 4 parts by weight of far infrared ceramic powder with an average particle size of 10 μm, 3 parts by weight of vitamin E and 8 parts by weight of carbon black are mixed, and then, the mixture is mixed with 25 parts by weight of jojoba oil and 20 parts by weight of wool wax to obtain mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 2
Firstly, 13 parts by weight of modified bentonite, 5 parts by weight of triethanolamine-stearate, 4 parts by weight of phenylpropyl dimethyl siloxysilicate, 4.2 parts by weight of far infrared ceramic powder with the average particle size of 10 mu m, 3.2 parts by weight of vitamin E and 8.5 parts by weight of carbon black are mixed, and then the mixture is mixed with 30 parts by weight of jojoba oil and 25 parts by weight of wool wax to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 3
First, 14 parts by weight of modified bentonite, 4 parts by weight of triethanolamine-stearate, 4.5 parts by weight of phenylpropyl dimethyl siloxy silicate, 4.5 parts by weight of far infrared ceramic powder with the average particle size of 10 mu m, 3.5 parts by weight of vitamin E and 9 parts by weight of carbon black are mixed, and then, 26 parts by weight of jojoba oil and 22 parts by weight of wool wax are mixed to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 4
First, 14.5 parts by weight of modified bentonite, 4.2 parts by weight of triethanolamine-stearate, 4.8 parts by weight of phenylpropyl dimethyl siloxy silicate, 4.8 parts by weight of far infrared ceramic powder having an average particle size of 10 μm, 3.8 parts by weight of vitamin E and 9.5 parts by weight of carbon black were mixed, and then, 27 parts by weight of jojoba oil and 24 parts by weight of wool wax were mixed to obtain mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 5
Firstly, 15 parts by weight of modified bentonite, 4.5 parts by weight of triethanolamine-stearate, 5 parts by weight of phenylpropyl dimethyl siloxysilicate, 5 parts by weight of far infrared ceramic powder with the average particle size of 10 mu m, 4 parts by weight of vitamin E and 10 parts by weight of carbon black are mixed, and then, the mixture is mixed with 28 parts by weight of jojoba oil and 23 parts by weight of wool wax to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 6
First, 5 parts by weight of far infrared ceramic powder having an average particle diameter of 10 μm and 0.8 part by weight of La were mixed2O3And 1 part by weight of TiO2Then mixing with 15 weight parts of modified bentonite, 4.5 weight parts of triethanolamine-stearate, 5 weight parts of phenylpropyl dimethyl siloxy silicate, 4 weight parts of vitamin E and 10 weight parts of carbon black, and finally mixing with 28 weight parts of jojoba oil and 23 weight parts of wool wax to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 7
First, 5 parts by weight of far infrared ceramic powder having an average particle diameter of 10 μm and 1 part by weight of La were mixed2O3And 0.8 part by weight of TiO2Then mixing with 15 weight parts of modified bentonite, 4.5 weight parts of triethanolamine-stearate, 5 weight parts of phenylpropyl dimethyl siloxy silicate, 4 weight parts of vitamin E and 10 weight parts of carbon black, and finally mixing with 28 weight parts of jojoba oil and 23 weight parts of wool wax to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 8
First, 5 parts by weight of far infrared ceramic powder having an average particle diameter of 10 μm and 0.5 part by weight of La were mixed2O3And 0.5 part by weight of TiO2Then mixing with 15 weight parts of modified bentonite, 4.5 weight parts of triethanolamine-stearate, 5 weight parts of phenylpropyl dimethyl siloxy silicate, 4 weight parts of vitamin E and 10 weight parts of carbon black, and finally mixing with 28 weight parts of jojoba oil and 23 weight parts of wool wax to obtain the mascara.
The modified bentonite is obtained by modifying bentonite with hexadecyl trimethyl ammonium bromide quaternary ammonium salt. Each 100g of bentonite was modified with 90mmoL of cetyltrimethylammonium bromide solution.
Example 9
This example differs from example 8 in that: the rare earth oxide contains 0.25 part by weight of La2O3And 0.25 part by weight of Sm2O3In a mixture of transition metal oxides containing 0.25 parts by weight of TiO2And 0.25 parts by weight of Pd2O3A mixture of (a).
Example 10
This example differs from example 5 in that: the quaternary ammonium salt is dodecyl trimethyl ammonium bromide.
Example 11
This example differs from example 5 in that: the quaternary ammonium salt is octadecyl trimethyl ammonium bromide.
Example 12
This example differs from example 5 in that: each 100g of bentonite was modified with 100mmoL of cetyltrimethylammonium bromide solution.
Example 13
This example differs from example 5 in that: each 100g of bentonite was modified with 95mmoL of cetyltrimethylammonium bromide solution.
Example 14
This example differs from example 5 in that: the average grain diameter of the far infrared ceramic powder is 5 μm.
Test example 1
The above examples 1 to 14 were repeated to obtain sufficient mascara. 300 female subjects were randomly selected and divided into 15 groups of 20 subjects on average. The first 1 to 14 groups were treated as test groups 1 to 14 with the mascaras obtained in examples 1 to 14, respectively, and the 15 group was treated as a control group with commercially available Kazilan micro-relief large-eye double-ended mascara. The mascara was applied 3 times for both the test and control groups using the same application method. The number of people who had mascara clumping and makeup removal in each of the test and control groups was compared while maintaining the same outdoor environment (temperature of 28 degrees celsius) for 8 hours. The number of people who showed eyelash fallout in each of the test group and the control group was compared according to the same makeup removing method. The results are shown in Table 1.
TABLE 1 measurement results
| The number of caking persons (human) | Number of people who take off makeup | Eyelash falloff number (person) | |
| Test group 1 | 3 | 6 | 6 |
| Test group 2 | 4 | 6 | 5 |
| Test group 3 | 3 | 4 | 5 |
| Test group 4 | 3 | 4 | 5 |
| Test group 5 | 2 | 3 | 4 |
| Test group 6 | 2 | 3 | 2 |
| Test group 7 | 2 | 2 | 2 |
| Test group 8 | 2 | 3 | 3 |
| Test group 9 | 2 | 3 | 1 |
| Test group 10 | 3 | 3 | 4 |
| Test group 11 | 2 | 3 | 4 |
| Test group 12 | 1 | 2 | 4 |
| Test group 13 | 0 | 2 | 4 |
| Test group 14 | 2 | 3 | 2 |
| Control group | 6 | 10 | 12 |
As can be seen by comparing the test groups 1-14 with the control group, the test groups 1-14 have better effects than the control group in terms of preventing caking and preventing makeup loss and reducing eyelash falling off of users during makeup removal, especially in terms of preventing makeup loss and eyelash falling off. The mascara provided by the application has a better makeup effect than the existing mascara, does not cake and does not make up, and can effectively relieve the condition that eyelashes fall off in the makeup removing process of the mascara.
As can be seen by comparing the test groups 1 to 5, the mascara in the test group 5 has better anti-caking and makeup-removal-preventing effects than those in the mascara in the test groups 1 to 4, and the number of people who fall off eyelashes after makeup removal is less, which indicates that the ratio of the raw materials in the mascara in the test group 5 is better than that in the mascara in the test groups 1 to 4.
As can be seen by comparing the test group 5 with the test groups 6 to 9, the test groups 6 to 9 have better effect than the test group 5 in relieving the eyelash falling off of the mascara in the makeup removing process, which shows that the raw materials contain certain rare earth oxides and transition metal oxides, which are beneficial to improving the toughness of the eyelashes of users and reducing the eyelash falling off in the makeup removing process.
As can be seen by comparing the test group 5 with the test groups 12-13, the test groups 12 and 13 have better effects on preventing caking and preventing makeup loss than the test group 5, which indicates that different dosages of cetyl trimethyl ammonium bromide have direct influence on the anti-caking and makeup loss effects of mascara.
Comparing the test group 5 with the test group 14, the test group 14 has a better effect in relieving eyelash falling off of mascara in makeup removing process than the test group 5, which shows that the smaller the average particle size of the far infrared ceramic powder is, the better the toughness of eyelash of the user is, and the condition of eyelash falling off in makeup removing process is reduced.
Test example 2
Comparative groups 1 to 3 were set, wherein comparative group 1 was distinguished from test group 5 in that the quaternary ammonium salt was octaalkyltrimethylammonium bromide, comparative group 2 was distinguished from test group 5 in that 50mmoL of cetyltrimethylammonium bromide solution was used per 100g of bentonite, and comparative group 3 was distinguished from test group 5 in that the average particle diameter of the far-infrared ceramic powder was 20 μm. Then, 60 female test subjects were randomly selected, and the female test subjects were divided into 3 groups of 20 subjects on average. The 3 groups of users applied mascara obtained from the comparative groups 1 to 3, respectively. The number of people who had mascara clumping and makeup removal in each of test group 5 and comparative groups 1 to 3 was compared using the test method and test conditions in test example 1. The number of people who showed eyelash fallout in each of the test group 5 and the comparative groups 1 to 3 was compared according to the same makeup removing method. The results are shown in Table 2.
TABLE 2 measurement results
| The number of caking persons (human) | Number of people who take off makeup | Eyelash falloff number (person) | |
| Test group 5 | 2 | 3 | 4 |
| Comparative group 1 | 5 | 8 | 4 |
| Comparison ofGroup 2 | 4 | 6 | 4 |
| Comparative group 3 | 2 | 3 | 8 |
As can be seen from the comparison of the test group 5 and the comparison group 1, the quaternary ammonium salt adopts octaalkyltrimethylammonium bromide which has poorer effects of preventing caking and preventing makeup loss on mascara than hexadecyltrimethylammonium bromide; it can be seen from the comparison of test 5 and comparison 2 that the mass of cetyltrimethylammonium bromide less than 80% of the ion exchange capacity of bentonite reduces the anti-caking and anti-makeup effects of the mascara; it can be seen from the comparison of the test group 5 and the comparison group 3 that the far infrared ceramic powder has a poorer effect of improving the toughness of the eyelashes of the user when the average particle size exceeds 10 μm, but can reduce the eyelash falling off in the makeup removing process compared with the comparison group.
In conclusion, the mascara provided by the preferred embodiment of the invention has the advantages of reasonable formula, low cost, good makeup effect, no caking and no makeup removal, and can effectively relieve the condition that eyelashes are easy to fall off during makeup removal of the mascara. The preparation method comprises the steps of mixing the raw materials according to the proportion, and the method is simple and quick and is suitable for industrial production.
The embodiments described above are some, but not all embodiments of the invention. The detailed description of the embodiments of the present invention is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Claims (4)
1. A kind of mascara, characterized by, according to the part by weight, its raw materials are modified bentonite of 12-15 parts by weight, triethanolamine-stearate of 4-5 parts by weight, phenylpropyl dimethyl silyl oxylsilicate of 4-5 parts by weight, jojoba oil of 25-30 parts by weight, wool wax of 20-25 parts by weight, far infrared ceramic powder of 4-5 parts by weight, vitamin E of 3-4 parts by weight and carbon black of 8-10 parts by weight; the modified bentonite is obtained by modifying bentonite with quaternary ammonium salt solution;
the quaternary ammonium salt solution is cetyl trimethyl ammonium bromide solution; modifying every 100g of bentonite by using 90-100mmoL of the hexadecyl trimethyl ammonium bromide solution;
the average grain diameter of the far infrared ceramic powder is not more than 10 mu m;
the raw material also comprises 0.5-1 weight part of rare earth oxide and 0.5-1 weight part of transition metal oxide; the rare earth oxide comprises La2O3And Sm2O3At least one of; the transition metal oxide comprises TiO2And Pd2O3At least one of (1).
2. The mascara according to claim 1, wherein said raw materials comprise 14-15 parts by weight of said modified bentonite, 4-4.5 parts by weight of said triethanolamine-stearate, 4.5-5 parts by weight of said phenylpropyldimethylsilanyloxysilicate, 26-28 parts by weight of said jojoba oil, 22-24 parts by weight of said wool wax, 4.5-5 parts by weight of said far infrared ceramic powder, 3.5-4 parts by weight of said vitamin E, and 9-10 parts by weight of said carbon black.
3. A mascara according to claim 2, wherein said raw materials are 15 parts by weight of said modified bentonite, 4.5 parts by weight of said triethanolamine stearate, 5 parts by weight of said phenylpropyldimethylsilanyloxysilicate, 28 parts by weight of said jojoba oil, 23 parts by weight of said wool wax, 5 parts by weight of said far infrared ceramic powder, 4 parts by weight of said vitamin E and 10 parts by weight of said carbon black.
4. A method of preparing mascara according to any one of claims 1-3, comprising the steps of: mixing the raw materials according to the proportion.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104398397A (en) * | 2014-11-04 | 2015-03-11 | 广州卡迪莲化妆品有限公司 | Application of methyl glucose ether to improve cosmetic brightness |
| JP2017132732A (en) * | 2016-01-29 | 2017-08-03 | 株式会社伊勢半 | Eyelashes cosmetics |
| JP2017190300A (en) * | 2016-04-13 | 2017-10-19 | 株式会社シャネル化粧品技術開発研究所 | (f+w)/o type emulsion and a cosmetic composition containing the same |
| CN108379103A (en) * | 2018-05-23 | 2018-08-10 | 吴玉婷 | A kind of long-acting eyelashes ointment preparation |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104398397A (en) * | 2014-11-04 | 2015-03-11 | 广州卡迪莲化妆品有限公司 | Application of methyl glucose ether to improve cosmetic brightness |
| JP2017132732A (en) * | 2016-01-29 | 2017-08-03 | 株式会社伊勢半 | Eyelashes cosmetics |
| JP2017190300A (en) * | 2016-04-13 | 2017-10-19 | 株式会社シャネル化粧品技術開発研究所 | (f+w)/o type emulsion and a cosmetic composition containing the same |
| CN108379103A (en) * | 2018-05-23 | 2018-08-10 | 吴玉婷 | A kind of long-acting eyelashes ointment preparation |
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