CN108771038A - A kind of broiler fodder improving chicken flavor - Google Patents

A kind of broiler fodder improving chicken flavor Download PDF

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Publication number
CN108771038A
CN108771038A CN201810687162.5A CN201810687162A CN108771038A CN 108771038 A CN108771038 A CN 108771038A CN 201810687162 A CN201810687162 A CN 201810687162A CN 108771038 A CN108771038 A CN 108771038A
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coupling agent
vitamin
solution
aluminate coupling
oyster shell
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CN201810687162.5A
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Inventor
王清华
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Pubei Qinghua Ecological Chicken Cooperatives
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Pubei Qinghua Ecological Chicken Cooperatives
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Priority to CN201810687162.5A priority Critical patent/CN108771038A/en
Publication of CN108771038A publication Critical patent/CN108771038A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K50/00—Feeding-stuffs specially adapted for particular animals
    • A23K50/70—Feeding-stuffs specially adapted for particular animals for birds
    • A23K50/75—Feeding-stuffs specially adapted for particular animals for birds for poultry
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/10—Animal feeding-stuffs obtained by microbiological or biochemical processes
    • A23K10/16—Addition of microorganisms or extracts thereof, e.g. single-cell proteins, to feeding-stuff compositions
    • A23K10/18—Addition of microorganisms or extracts thereof, e.g. single-cell proteins, to feeding-stuff compositions of live microorganisms
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/20—Animal feeding-stuffs from material of animal origin
    • A23K10/22—Animal feeding-stuffs from material of animal origin from fish
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/20—Animal feeding-stuffs from material of animal origin
    • A23K10/26—Animal feeding-stuffs from material of animal origin from waste material, e.g. feathers, bones or skin
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K10/00—Animal feeding-stuffs
    • A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
    • A23K10/37—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from waste material
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/105—Aliphatic or alicyclic compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/158—Fatty acids; Fats; Products containing oils or fats
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/163—Sugars; Polysaccharides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/174—Vitamins
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/20—Inorganic substances, e.g. oligoelements
    • A23K20/22—Compounds of alkali metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
    • Y02P60/87—Re-use of by-products of food processing for fodder production

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Physiology (AREA)
  • Health & Medical Sciences (AREA)
  • Biotechnology (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Microbiology (AREA)
  • Botany (AREA)
  • Mycology (AREA)
  • Birds (AREA)
  • Biochemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Fodder In General (AREA)

Abstract

It is calculated by mass the invention discloses a kind of broiler fodder improving chicken flavor, it is made of following component：Corn 45.0-55.0%, wheat bran 10.0-15.0%, tapioca starch 8.0-10.0%, fish meal 7.0-9.0%, red date powder 7.0-9.0%, grease 1.0-3.0%, antioxidant 1.0-2.0%, oyster shell whiting 3.0-5.0%, green tea 0.1-0.3%, Herba Andrographitis 0.2-0.4%, Radix zanthoxyli 0.2-0.4%, multi-vitamins 1.5-2.5%, glucose 0.4-0.6%, allicin 0.4-0.6%, probiotics 1.0-2.5%, sodium bicarbonate 0.1-0.3%.

Description

A kind of broiler fodder improving chicken flavor
Technical field
The invention belongs to technical field of animal, and in particular to a kind of broiler fodder improving chicken flavor.
Background technology
Chicken is a kind of food materials common and important in daily life, no matter stewing Baoshang or marinated quick-fried all has solely Special deliciousness and splendid Dietotherapy health are worth, and due to the huge market demand, chicken supply at present relies primarily on broiler breeding field, Broiler breeding field cultural technique is ripe, and growth of meat chicken is fast, benefits apparent.
It needs to provide energy using a large amount of cereal in broiler fodder, the protein level needed is also higher.In daily ration of broiler High-grade maize and beans cypress are often used to ensure its normal growth.But in recent years, with the high speed development of aquaculture, feedstuff industry pair The demand of corn and beans cypress increases.Corn, beans cypress price be in history a high position, substantially increase feed cost.Due to The problems such as breeding process intensive degree is high, and chicken group is high there are incidence, has buried the hidden danger of medicament residue, while in order to accelerate Growth of meat chicken usually feeding concentrated feed, causes the quality of chicken to be had a greatly reduced quality, also adds aquaculture cost, to obtain high-quality Chicken, realize efficient green cultivation, it is necessary to focus on the preparation of feed, battalion should be provided according to each growth phase feature of broiler chicken Rational feed is supported, the use of chemical classes drug is avoided, prevents medicament residue problem, to which maximizing the benefits will be cultivated.
Current broiler chicken is mostly to use intensive breeding way, and eaten by broilers is man-made feeds, this feed ingredient Dull, nutritional deficiency, the meat and meat flavour of chicken substantially reduce, and What is more, some culturists arbitrarily make in broiler fodder With substances such as additive and hormones, but also the quality of chicken is absolutely unsafe.And traditional free-ranging broiler chicken, jade can be freely eaten The natural foods such as rice, forage and insect, food source enrich, chicken taste giving off a strong fragrance extensively, thus fast-selling continuous on the market, supply It should not ask, quite be liked by citizen.In face of this situation, the trophic level of existing broiler chicken how is promoted, improves the wind of chicken Taste gets liking for consumer, it has also become the key issues of current expert and scholar's research.
Invention content
For overcome the deficiencies in the prior art, the present invention is intended to provide a kind of broiler fodder improving chicken flavor, is added Specific process of surface treatment can effectively prevent oyster shell whiting reunion using different coupling agents to oyster shell whiting secondary surface treatment, and Enhance the bond strength of oyster shell whiting and feed.
To achieve the above object, the technical solution adopted by the present invention is as follows：
A kind of broiler fodder improving chicken flavor, it is calculated by mass, it is made of following component：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, then again by adding silane coupling agent Secondary surface treatment is carried out, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, Aluminate coupling The mass concentration of aluminate coupling agent is 30-40% in agent solution, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent is mixed to form with absolute ethyl alcohol, silane coupler solution The mass concentration of middle silane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, finally Vacuum drying can recycle ethyl alcohol.
Further, calculated by mass, it is made of following component：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, then again by adding silane coupling agent Secondary surface treatment is carried out, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, Aluminate coupling The mass concentration of aluminate coupling agent is 30-40% in agent solution, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent is mixed to form with absolute ethyl alcohol, silane coupler solution The mass concentration of middle silane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, finally Vacuum drying can recycle ethyl alcohol.
The present invention
The corn supplements the nutrition needed for animal, such as carrotene, vitamin A, vitamin B, vitamin B2.
The wheat bran supplements the nutrition needed for animal, such as vitamin E, vitamin B.
The tapioca starch supplements the nutrition needed for animal and heat, such as protein, carbohydrate.
The fish meal, the protein and amino acid of effect supplement animal.
The grease, grease are divided into animal raw fat and vegetative grease, and the metabolizable energy value of vegetative grease is 34.3- The metabolizable energy value of 36.8MJ/kg, animal raw fat are 29.7-35.6MJ/kg, and grease is added in mixed feed can reduce ash simultaneously Dirt reduces feed waste, reduces the abrasion of feed mixing machine and granulator, improves the utilization rate of equipment, promote pellet at Type, grease can also provide essential fatty acid, improve the absorption of liposoluble vitamin.
The antioxidant is one kind in BHA, BHT, PG, TBHQ, TP, vitamin E.
The oyster shell whiting, effect are the calcium carbonate supplemented needed for animal, and mesh number is 300-600 mesh, is conducive to chicken and disappears Change.
The green tea, effect are dissolved aging object in animal body, adjustment and promotion animal body tissue function, are promoted dynamic Object health benefit.
The Herba Andrographitis, effect is clearing heat and detoxicating, and mesh number is 400 mesh or more.
Gas, desinsection are changed in the Radix zanthoxyli, effect anti-inflammatory, and mesh number is 400 mesh or more.
The multi-vitamins, every kilogram of multi-vitamins active ingredient are：3-Hydroxyretinol 0g, vitamin D330g, dimension Raw element E100g, vitamin K360g, vitamin B1100g, vitamin B2100g, vitamin B6100g, vitamin B1250g, niacin 80g, folic acid 80g, calcium pantothenate 80g, biotin 30g, inositol 60g, vitamin C 100g.
The allicin, mesh number are 650 mesh or more, and effect has antibacterial work to more clock Gram-positives and negative bacterium With.
The probiotics, mesh number are 650 mesh or more, effect can it is digested to animal intestinal tract, there are whole intestines to act on, can make The excrement of animal reaches environmental and ecological effect.
The sodium bicarbonate, effect are to adjust acid excessive, indigestion in animal body.
A kind of broiler fodder improving chicken flavor of the present invention, preparation method are：Carrying out Crushing of Ultrafine to raw material makes It is pelletized at 80 DEG C, so that its gelatinization degree is reached 90% and obtain 100% by 30 mesh standard sieves.
Compared with prior art, the invention has the advantages that：
1, oyster shell whiting is easy to reunite when in use due to relatively thin, causes to disperse in feed uneven, influences feed Performance.Inventor develops specific process of surface treatment, using different coupling agents to the secondary surface of oyster shell whiting through studying for a long period of time Processing can effectively prevent oyster shell whiting reunion, and enhance the bond strength of oyster shell whiting and feed.The present invention is first passed through using Aluminate Coupling agent carries out one-time surface processing to oyster shell whiting, can effectively improve the dispersibility between oyster shell whiting and the dispersion in organic matter Property, then secondary surface treatment, aluminate coupling agent and silane coupling agent synergy are carried out by adding silane coupling agent again Oyster shell whiting can be effectively wrapped up, can effectively solve the problems, such as that oyster shell whiting is reunited in this way, and surface-active base is provided to oyster shell whiting Group enhances the bond strength of oyster shell whiting and feed, improves the availability of oyster shell whiting in this way, improve the performance of feed, Last vacuum drying can recycle ethyl alcohol, and aluminate coupling agent used in the present invention, silane coupling agent, and dosage is considerably less, Experiment shows not will produce safety problem.
2, the metabolizable energy value of wheat is about the 90% of corn, and protein content is that more can increase chicken since wheat contains and disappear Change the soluble polysaccharide araboxylan of road chyme stickiness, this so that chicken is relatively low to the utilization rate of nutrient in wheat, to The digestibility and feed conversion rate of nutrient are reduced, wheat bran is commonly called as wheat bran, is wheat processing into the byproduct during flour.And The present invention can increase cladding, immixture of other raw materials to wheat bran, increase wheat bran by the way that processed oyster shell whiting is added Utilization rate.Food reaches chicken gizzard, and gizzard is commonly called as chicken gizzard, is the place that chicken digests food into chicken row, chicken gizzard is very tough and tensile, inside has The cutin skin of one layer of yellow, the food that chicken ate mix specially treated oyster shell whiting start to digest in chicken gizzard, the muscle of chicken gizzard By strong contraction, under the firmly wriggling of chicken gizzard, rub food jointly, will eat tripe in this way for the membrane of a chicken's gizzard and oyster shell whiting In corn, wheat bran, tapioca starch etc. grind, food is thoroughly digested and assimilated.
3, fish meal is larger with source difference quality discrepancy because processing, and the protein content of high-quality fish meal is generally 55-65%, Protein digestibility is 90% or more, and fish meal lysine, methionine, cystine and tryptophane are high, and digestibility is also high.Fish Powder is also good mineral origin, and calcium, phosphorus content are abundant, ratio is suitable, and phosphorus is essentially all using phosphorus, trace elements of selenium It is all higher with Zn content, it is rich in VitAVitE and B family vitamin, especially contains and does not have in vegetable protein feed Some vitamin Bs12.But when fish meal dosage is excessively high, cost was not only increased but also egg and chicken can be made to generate fishy smell, so in chicken feed Fish meal dosage is no more than 10%, and fish meal dosage of the present invention can be more than 10%, is because by the way that processed shell is added Powder can increase cladding, immixture of other raw materials to fish meal, can reduce egg and chicken generates fishy smell.
Specific implementation mode
With specific embodiment, the invention will be further described below, but the invention is not limited in these embodiments.
Embodiment 1
A kind of broiler fodder improving chicken flavor, calculates, is made of following component by percentage to the quality：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, then again by adding silane coupling agent Secondary surface treatment is carried out, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, Aluminate coupling The mass concentration of aluminate coupling agent is 30-40% in agent solution, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent is mixed to form with absolute ethyl alcohol, silane coupler solution The mass concentration of middle silane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, finally Vacuum drying can recycle ethyl alcohol.
Preparation method is：Carrying out Crushing of Ultrafine to raw material makes it pelletize at 80 DEG C, make it 100% by 30 mesh standard sieves Gelatinization degree reaches 90% and obtains.
Embodiment 2
A kind of broiler fodder improving chicken flavor, is made of following component：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, then again by adding silane coupling agent Secondary surface treatment is carried out, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, Aluminate coupling The mass concentration of aluminate coupling agent is 30-40% in agent solution, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent is mixed to form with absolute ethyl alcohol, silane coupler solution The mass concentration of middle silane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, finally Vacuum drying can recycle ethyl alcohol.
Preparation method is：Carrying out Crushing of Ultrafine to raw material makes it pelletize at 80 DEG C, make it 100% by 30 mesh standard sieves Gelatinization degree reaches 90% and obtains.
Embodiment 3
A kind of broiler fodder improving chicken flavor, is made of following component：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, then again by adding silane coupling agent Secondary surface treatment is carried out, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, Aluminate coupling The mass concentration of aluminate coupling agent is 30-40% in agent solution, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent is mixed to form with absolute ethyl alcohol, silane coupler solution The mass concentration of middle silane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, finally Vacuum drying can recycle ethyl alcohol.
Preparation method is：Carrying out Crushing of Ultrafine to raw material makes it pelletize at 80 DEG C, make it 100% by 30 mesh standard sieves Gelatinization degree reaches 90% and obtains.
Comparative example
A kind of broiler fodder improving chicken flavor, is made of following component：
Experimental example：
This experiment selects 200 weight close to the 10-15 Day-old Broiler Chickens of health, feeds 4 weeks, by randomized complete-block design It is divided into test group and control group, every group of 5 repetitions each repeat 20 chickens.The above diet is fed respectively.
Test result is as shown in table 1：
Influence of 1 different feeds of table to broiler performance index
Experiment shows：The result of embodiment 3 is substantially better than comparative example.

Claims (5)

1. a kind of broiler fodder improving chicken flavor, which is characterized in that it is calculated by mass, it is made of following component：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, is then carried out again by adding silane coupling agent Secondary surface treatment, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, and aluminate coupling agent is molten The mass concentration of aluminate coupling agent is 30-40% in liquid, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent and absolute ethyl alcohol are mixed to form, silicon in silane coupler solution The mass concentration of alkane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, and last is true Empty drying can recycle ethyl alcohol.
2. a kind of broiler fodder improving chicken flavor according to claim 1, it is characterised in that：It is calculated by mass, by Following component is made：
The oyster shell whiting first carries out one-time surface processing with aluminate coupling agent, is then carried out again by adding silane coupling agent Secondary surface treatment, specifically：
The aluminate coupling agent solution is the solution that aluminate coupling agent is mixed to form with absolute ethyl alcohol, and aluminate coupling agent is molten The mass concentration of aluminate coupling agent is 30-40% in liquid, and the dosage of aluminate coupling agent is the 0.3- of oyster shell whiting weight 0.5%；
The silane coupler solution is the solution that silane coupling agent and absolute ethyl alcohol are mixed to form, silicon in silane coupler solution The mass concentration of alkane coupling agent is 30-40%, and the dosage of silane coupling agent is the 0.1-0.3% of oyster shell whiting weight, and last is true Empty drying can recycle ethyl alcohol.
3. a kind of broiler fodder improving chicken flavor according to claim 1 or 2, it is characterised in that：The antioxygen Agent is one kind in BHA, BHT, PG, TBHQ, TP, vitamin E.
4. a kind of broiler fodder improving chicken flavor according to claim 1 or 2, it is characterised in that：The shell Powder, mesh number are 300-600 mesh.
5. a kind of broiler fodder improving chicken flavor according to claim 1 or 2, it is characterised in that：Described is compound Vitamin, every kilogram of multi-vitamins active ingredient are：3-Hydroxyretinol 0g, vitamin D330g, vitamin e1 00g, vitamin K360g, vitamin B1100g, vitamin B2100g, vitamin B6100g, vitamin B1250g, niacin 80g, folic acid 80g, pantothenic acid Calcium 80g, biotin 30g, inositol 60g, vitamin C 100g.
CN201810687162.5A 2018-06-28 2018-06-28 A kind of broiler fodder improving chicken flavor Pending CN108771038A (en)

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CN103897434A (en) * 2014-04-19 2014-07-02 芮城新泰纳米材料有限公司 Method for preparing special nano calcium carbonate for plastic master batch
CN104938834A (en) * 2015-06-12 2015-09-30 广西南丹益康牧业开发有限公司 Feed for meat chicken
CN106689783A (en) * 2016-12-05 2017-05-24 防城港市百胜农产品科技有限公司 Broiler feed and preparation method thereof
CN106519773A (en) * 2016-12-08 2017-03-22 浩力森化学科技（江苏）有限公司 Preparation method of wet modified inorganic filler and cathode electrophoretic coating

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Title
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李星等: "铝酸酯复合偶联剂改性碳酸钙的性能研究", 《云南化工》 *
王训遒等: "复合偶联剂改性纳米CaCO_3工艺研究 ", 《化工矿物与加工》 *
邓正荣等: "改性超细重质碳酸钙在硬质PVC中的应用 ", 《聚氯乙烯》 *
郑永军等: "复合偶联表面处理CaCO_3的新工艺研究 ", 《辽宁化工》 *
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