CN108752132A - A kind of the organic fertilizer phosphate fertilizer and its manufacturing method of prevention and control Phosphorus leaching - Google Patents

A kind of the organic fertilizer phosphate fertilizer and its manufacturing method of prevention and control Phosphorus leaching Download PDF

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Publication number
CN108752132A
CN108752132A CN201810658857.0A CN201810658857A CN108752132A CN 108752132 A CN108752132 A CN 108752132A CN 201810658857 A CN201810658857 A CN 201810658857A CN 108752132 A CN108752132 A CN 108752132A
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parts
fertilizer
prevention
organic fertilizer
robiniae
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Inventor
张国印
王凌
刘蕾
贡冬梅
刘雅祯
郜静
李玭
孙秀英
孙世友
茹淑华
徐万强
牛君仿
王锡平
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INSTITUTE OF AGRICULTURAL RESOURCES AND ENVIRONMENT HEBEI ACADEMY OF AGRICULTURE AND FORESTRY SCIENCES
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INSTITUTE OF AGRICULTURAL RESOURCES AND ENVIRONMENT HEBEI ACADEMY OF AGRICULTURE AND FORESTRY SCIENCES
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Priority to CN201810658857.0A priority Critical patent/CN108752132A/en
Publication of CN108752132A publication Critical patent/CN108752132A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching and its manufacturing methods, include the raw material of following parts by weight:8-12 parts of 42-57 parts of pig manure, 24-36 parts of beancake powder, 5-10 parts of eggshell, 6-12 parts of grapefruit flesh, 4-6 parts of urea, 9-16 parts of sodium dihydrogen phosphate, 10-14 parts of nano-graphene, 18-25 parts of plant ash, 6-10 parts of chitin, 8-14 parts of rice bran and robiniae,flos.Raw material sources of the present invention are extensive, by using different preparation processes to different raw materials, act synergistically between different products, the finished product tool of preparation prevents phosphorous loss in organic fertilizer, can improve the utilization rate of fertilizer, increase economic benefit.

Description

A kind of the organic fertilizer phosphate fertilizer and its manufacturing method of prevention and control Phosphorus leaching
Technical field
The present invention relates to fertilizer field, the organic fertilizer phosphate fertilizer and its manufacturing method of specifically a kind of prevention and control Phosphorus leaching.
Background technology
Agricultural is the growth-development law using animals and plants, and the industry of product is obtained by artificial culture.Agricultural belongs to The primary industry, the science for studying agricultural is agronomy.The subject of labour of agricultural is lived animals and plants, and the product of acquisition is plant Object itself.Agricultural provides the basic product of the support development of the national economy and development.With the rapid development of present agricultural science and technology, agriculture The people more and more recognize the importance to apply fertilizers scientifically.
China peasant has the tradition of manure use.The developed countries such as the U.S., West Europe, Japan, also in rise " ecological agriculture Industry ", " organic agriculture " attach great importance to manure use material, and organic fertilizer are defined as the main source of manure of production pollution-free food. Organic fertilizer contains abundant organic matter and various nutrients, has the advantages that quantity is big, source is wide, nutrient is comprehensive, but also deposit It is low in nutrient content, it is not easily decomposed, the shortcomings of fertilizer efficiency is slow.The preparation and use of traditional organic fertilizer are also very inconvenient.Inorganic fertilizer Expect the advantages that fertilizer efficiency is fast with nutrient content height, easy to use, but there are the single deficiencies of nutrient.
The application for developing into fertilizer during agricultural planting of composite fertilizer provides new developing direction.Composite chemical fertilizer is i.e. multiple Hefei refers to the only fertilizer made of chemical method of at least two kinds nutrient amounts of showing in three kinds of nitrogen, phosphorus, potassium nutrients, is multiple One kind of complex fertilizer material has many advantages, such as that nutrient content is high, easy to use, but can increase soil medium-height grass in application of organic fertilizers The content of the organic acids such as acid, lactic acid, citric acid and humic acid, they are easy Ca, Mg, Fe, Al plasma in chelating soil, Reduce the fixation of P.
Invention content
The purpose of the present invention is to provide a kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching and its manufacturing methods, in solution State the problem of being proposed in background technology.
To achieve the above object, the present invention provides the following technical solutions:
A kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, includes the raw material of following parts by weight:42-57 parts of pig manure, beancake powder 24-36 parts, 5-10 parts of eggshell, 6-12 parts of grapefruit flesh, 4-6 parts of urea, 9-16 parts of sodium dihydrogen phosphate, nano-graphene 10-14 Part, 18-25 parts of plant ash, 6-10 parts of chitin, 8-14 parts of rice bran and 8-12 parts of robiniae,flos.
As a further solution of the present invention:The organic fertilizer phosphate fertilizer of the prevention and control Phosphorus leaching, including following parts by weight Raw material:49-57 parts of pig manure, 28-36 parts of beancake powder, 6.6-10 parts of eggshell, 8-12 parts of grapefruit flesh, 4.8-6 parts of urea, di(2-ethylhexyl)phosphate 11.5-16 parts of hydrogen sodium, 12-14 parts of nano-graphene, 21-25 parts of plant ash, 7.5-10 parts of chitin, 10-14 parts of rice bran and ocean 9.6-12 parts of sophora flower.
As further scheme of the invention:The organic fertilizer phosphate fertilizer of the prevention and control Phosphorus leaching, including following parts by weight Raw material:54 parts of pig manure, 34 parts of beancake powder, 9.2 parts of eggshell, 11.1 parts of grapefruit flesh, 5.5 parts of urea, 15 parts of sodium dihydrogen phosphate, 11.5 parts of 13.6 parts of nano-graphene, 23.5 parts of plant ash, 9 parts of chitin, 13 parts of rice bran and robiniae,flos.
As further scheme of the invention:The grain size of the nano-graphene is 15-48nm, and the grain size of plant ash is 30-80um。
The manufacturing method of the organic fertilizer phosphate fertilizer for prevention and control Phosphorus leaching, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 33-42 degrees Celsius and pH value are 5-6, by enzyme by step 1 Product enzyme deactivation, filtering, centrifugation are solved, shaddock enzymolysis liquid is obtained;
Robiniae,flos are crushed to 40-60 mesh by step 2, and breakdown products are spent the ethanol water that mass fraction is 45-66% Solution is impregnated 3-5 hours and is centrifuged, and by supernatant liquid filtering, obtains robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran Merge and be added water, the mass fraction for adjusting water is 60-72%, and the compound bacteria that addition accounts for total weight 0.2-0.4% carries out compost Fermentation 18-25 days, it is primary per 16-20 hour turning, obtain tunning;
Eggshell is crushed to 120-150 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution simultaneously And supersonic oscillations are uniform, obtain egg-shell meal suspension;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly simultaneously And it is dried to get to finished product under 35-48 degrees Celsius.
As a further solution of the present invention:The time of the supersonic oscillations is 20-25 minutes, the work(of supersonic oscillations Rate is 240-330W.
As a further solution of the present invention:The mixing velocity of the high mixer is 1800-2400rpm.
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, by different raw materials It using different preparation processes, acts synergistically between different products, the finished product tool of preparation prevents phosphorus element stream in organic fertilizer It loses, the utilization rate of fertilizer can be improved, increase economic benefit.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, includes the raw material of following parts by weight:42 parts of pig manure, beancake powder 24 Part, 5 parts of eggshell, 6 parts of grapefruit flesh, 4 parts of urea, 9 parts of sodium dihydrogen phosphate, 10 parts of nano-graphene, 18 parts of plant ash, chitin 8 parts of 6 parts, 8 parts of rice bran and robiniae,flos.
A kind of manufacturing method of the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 36 degrees Celsius and pH value are 5.4, enzymolysis is produced by step 1 Object enzyme deactivation, filtering, centrifugation obtain shaddock enzymolysis liquid;
Robiniae,flos are crushed to 50 mesh by step 2, and breakdown products, which are spent the ethanol water that mass fraction is 54%, soaks It stain 3.5 hours and centrifuges, by supernatant liquid filtering, obtains robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran Merge and be added water, the mass fraction for adjusting water is 66%, and the compound bacteria that addition accounts for total weight 0.3% carries out compost fermentation 22 It, every 18 hour turnings are primary, obtain tunning;
Eggshell is crushed to 140 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution and is surpassed Sonication is uniform, and the time of supersonic oscillations is 24 minutes, and the power of supersonic oscillations is 280W, obtains egg-shell meal suspension Liquid;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly simultaneously And it is dried to get to finished product under 40 degrees Celsius.
Embodiment 2
A kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, includes the raw material of following parts by weight:49 parts of pig manure, beancake powder 28 Part, 6.6 parts of eggshell, 8 parts of grapefruit flesh, 4.8 parts of urea, 11.5 parts of sodium dihydrogen phosphate, 12 parts of nano-graphene, plant ash 21 Part, 7.5 parts of chitin, 10 parts of rice bran and 9.6 parts of robiniae,flos.The grain size of nano-graphene is 24nm, and the grain size of plant ash is 60um。
A kind of manufacturing method of the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 40 degrees Celsius and pH value are 5.8, enzymolysis is produced by step 1 Object enzyme deactivation, filtering, centrifugation obtain shaddock enzymolysis liquid;
Robiniae,flos are crushed to 40 mesh by step 2, and breakdown products, which are spent the ethanol water that mass fraction is 64%, soaks It stain 5 hours and centrifuges, by supernatant liquid filtering, obtains robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran Merge and be added water, the mass fraction for adjusting water is 64%, and the compound bacteria that addition accounts for total weight 0.2% carries out compost fermentation 24 It, every 18 hour turnings are primary, obtain tunning;
Eggshell is crushed to 120 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution and is surpassed Sonication is uniform, obtains egg-shell meal suspension;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly simultaneously And it is dried to get to finished product under 44 degrees Celsius.
Embodiment 3
A kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, includes the raw material of following parts by weight:54 parts of pig manure, beancake powder 34 Part, 9.2 parts of eggshell, 11.1 parts of grapefruit flesh, 5.5 parts of urea, 15 parts of sodium dihydrogen phosphate, 13.6 parts of nano-graphene, plant ash 11.5 parts of 23.5 parts, 9 parts of chitin, 13 parts of rice bran and robiniae,flos.
A kind of manufacturing method of the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 36 degrees Celsius and pH value are 6, by enzymolysis product by step 1 Enzyme deactivation, filtering, centrifugation obtain shaddock enzymolysis liquid;
Robiniae,flos are crushed to 60 mesh by step 2, and breakdown products, which are spent the ethanol water that mass fraction is 55%, soaks It stain 4 hours and centrifuges, by supernatant liquid filtering, obtains robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran Merge and be added water, the mass fraction for adjusting water is 68%, and the compound bacteria that addition accounts for total weight 0.4% carries out compost fermentation 24 It, every 20 hour turnings are primary, obtain tunning;
Eggshell is crushed to 140 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution and is surpassed Sonication is uniform, and the time of supersonic oscillations is 24 minutes, and the power of supersonic oscillations is 3200W, obtains egg-shell meal suspension Liquid;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly simultaneously And it is dried to get to finished product under 45 degrees Celsius.
Embodiment 4
A kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, includes the raw material of following parts by weight:57 parts of pig manure, beancake powder 36 Part, 10 parts of eggshell, 12 parts of grapefruit flesh, 6 parts of urea, 16 parts of sodium dihydrogen phosphate, 14 parts of nano-graphene, 25 parts of plant ash, first 12 parts of 10 parts of shell element, 14 parts of rice bran and robiniae,flos.The grain size of nano-graphene is 33nm, and the grain size of plant ash is 70um.
A kind of manufacturing method of the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 40 degrees Celsius and pH value are 5.5, enzymolysis is produced by step 1 Object enzyme deactivation, filtering, centrifugation obtain shaddock enzymolysis liquid;
Robiniae,flos are crushed to 40 mesh by step 2, and breakdown products, which are spent the ethanol water that mass fraction is 50%, soaks It stain 5 hours and centrifuges, by supernatant liquid filtering, obtains robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran Merge and be added water, the mass fraction for adjusting water is 68%, and the compound bacteria that addition accounts for total weight 0.4% carries out compost fermentation 25 It, every 16 hour turnings are primary, obtain tunning;
Eggshell is crushed to 130 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution and is surpassed Sonication is uniform, and the time of supersonic oscillations is 24 minutes, and the power of supersonic oscillations is 300W, obtains egg-shell meal suspension Liquid;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly simultaneously And it is dried to get to finished product under 44 degrees Celsius.
Comparative example 1
Except without containing eggshell, remaining raw material and manufacturing method are same as Example 2.
Comparative example 2
Except without containing robiniae,flos, remaining raw material and manufacturing method are same as Example 4.
Comparative example 3
Except without containing robiniae,flos and eggshell, remaining raw material and manufacturing method are same as Example 3.
Comparative example 4
Using commercially available composite fertilizer as a comparison case 4.
The product of the product of embodiment 1-4 and comparative example 1-4 are used for green cucumber, it is identical in soil and environmental condition The same area is divided into 8 groups, and the product of the product and comparative example 1-4 of embodiment 1-4 is respectively adopted in 1-8 groups, and 1-8 groups are in plantation cucumber Apply equivalent fertilizer before, phosphorous measurement is carried out to soil at cucumber rhizome after one month, the results are shown in Table 1.
Table 1
The phosphorus content of 5-7 groups is slightly above 8 groups of phosphorus content as can be seen from Table 1, and the phosphorus content of 1-4 groups is far above 5-7 The phosphorus content of group, the i.e. phosphorus content of 1-4 groups are far above 8 groups of phosphorus content, illustrate that the product of the present invention can effectively prevent phosphorus element stream It loses.
Raw material sources of the present invention are extensive, by using different preparation processes to different raw materials, between different products It acts synergistically, the finished product tool of preparation prevents phosphorous loss in organic fertilizer, can improve the utilization rate of fertilizer, increases economic effect Benefit.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (7)

1. a kind of organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching, which is characterized in that include the raw material of following parts by weight:Pig manure 42-57 Part, 24-36 parts of beancake powder, 5-10 parts of eggshell, 6-12 parts of grapefruit flesh, 4-6 parts of urea, 9-16 parts of sodium dihydrogen phosphate, nanometer stone 8-12 parts of black alkene 10-14 parts, 18-25 parts of plant ash, 6-10 parts of chitin, 8-14 parts of rice bran and robiniae,flos.
2. the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching according to claim 1, which is characterized in that including following parts by weight Raw material:49-57 parts of pig manure, 28-36 parts of beancake powder, 6.6-10 parts of eggshell, 8-12 parts of grapefruit flesh, 4.8-6 parts of urea, di(2-ethylhexyl)phosphate 11.5-16 parts of hydrogen sodium, 12-14 parts of nano-graphene, 21-25 parts of plant ash, 7.5-10 parts of chitin, 10-14 parts of rice bran and ocean 9.6-12 parts of sophora flower.
3. the organic fertilizer phosphate fertilizer of prevention and control Phosphorus leaching according to claim 1, which is characterized in that including following parts by weight Raw material:54 parts of pig manure, 9.2 parts of eggshell, 11.1 parts of grapefruit flesh, 5.5 parts of urea, 15 parts of sodium dihydrogen phosphate, is received 34 parts of beancake powder 11.5 parts of 13.6 parts of graphene of rice, 23.5 parts of plant ash, 9 parts of chitin, 13 parts of rice bran and robiniae,flos.
4. according to the organic fertilizer phosphate fertilizer of any prevention and control Phosphorus leachings of claim 1-3, which is characterized in that the nanometer stone The grain size of black alkene is 15-48nm, and the grain size of plant ash is 30-80um.
5. a kind of manufacturing method of the organic fertilizer phosphate fertilizer as described in any one of claims 1-3 for prevention and control Phosphorus leaching, special Sign is, is as follows:
Grapefruit flesh is squeezed into juice and is digested in the environment of 33-42 degrees Celsius and pH value are 5-6, enzymolysis is produced by step 1 Object enzyme deactivation, filtering, centrifugation obtain shaddock enzymolysis liquid;
Robiniae,flos are crushed to 40-60 mesh by step 2, and breakdown products are spent the ethanol water that mass fraction is 45-66% It impregnates 3-5 hours and centrifuges, by supernatant liquid filtering, obtain robiniae,flos extracting solution;
Step 3 mixes pig manure, beancake powder, urea, humic acid, sodium dihydrogen phosphate, shaddock enzymolysis liquid, chitin and rice bran simultaneously And water is added, the mass fraction for adjusting water is 60-72%, and the compound bacteria that addition accounts for total weight 0.2-0.4% carries out compost fermentation It is 18-25 days, primary per 16-20 hour turning, obtain tunning;
Eggshell is crushed to 120-150 mesh, obtains egg-shell meal by step 4, and egg-shell meal is added in robiniae,flos extracting solution and is surpassed Sonication is uniform, obtains egg-shell meal suspension;
Step 5, by nano-graphene, tunning, egg-shell meal suspension and plant ash high-speed mixer and mixing uniformly and It is dried to get to finished product under 35-48 degrees Celsius.
6. the manufacturing method of the organic fertilizer phosphate fertilizer according to claim 5 for prevention and control Phosphorus leaching, which is characterized in that institute The time for stating supersonic oscillations is 20-25 minutes, and the power of supersonic oscillations is 240-330W.
7. the manufacturing method of the organic fertilizer phosphate fertilizer according to claim 5 for prevention and control Phosphorus leaching, which is characterized in that institute The mixing velocity for stating high mixer is 1800-2400rpm.
CN201810658857.0A 2018-06-25 2018-06-25 A kind of the organic fertilizer phosphate fertilizer and its manufacturing method of prevention and control Phosphorus leaching Pending CN108752132A (en)

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Application publication date: 20181106