CN108739857A - 一种养殖场用泡沫型消毒剂及其制备方法与应用 - Google Patents

一种养殖场用泡沫型消毒剂及其制备方法与应用 Download PDF

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Publication number
CN108739857A
CN108739857A CN201810739109.5A CN201810739109A CN108739857A CN 108739857 A CN108739857 A CN 108739857A CN 201810739109 A CN201810739109 A CN 201810739109A CN 108739857 A CN108739857 A CN 108739857A
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China
Prior art keywords
disinfectant
parts
foam
farm
sodium
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CN201810739109.5A
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Inventor
王庆福
胡鹏飞
黄静
戴多亮
梁世仁
吴有林
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Jiangxi Aoxin Biotechnology Co Ltd
Fujian Aonong Biological Technology Group Co Ltd
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Jiangxi Aoxin Biotechnology Co Ltd
Fujian Aonong Biological Technology Group Co Ltd
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Priority to CN201810739109.5A priority Critical patent/CN108739857A/zh
Publication of CN108739857A publication Critical patent/CN108739857A/zh
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Abstract

本发明涉及一种养殖场用泡沫型消毒剂及其制备方法与应用，每100重量份的消毒剂包括以下重量份的组分：活性氯5‑10份、醛类5‑10份、发泡剂25‑40份、强化剂1‑2.5份、缓冲剂0.1‑0.5份，余量为水；制备时，按比例称取各组分并混合均匀即可；将消毒剂与水按照1:100‑1000的体积比混合，用于养殖场消毒。与现有技术相比，本发明消毒剂通过高压泡沫喷射器喷出泡沫，发泡倍数达100倍以上，可对消毒面全覆盖，不留死角与空白，使消毒剂均匀分布，可延长消毒剂与消毒面接触时间，从而增强消毒效果，同时可节约用水，适用于养殖场圈舍、器具等清洗与消毒。

Description

一种养殖场用泡沫型消毒剂及其制备方法与应用
技术领域
本发明属于消毒剂技术领域，涉及一种养殖场用泡沫型消毒剂及其制备方法与应用。
背景技术
当前，随着我国畜牧养殖业的集约化发展，养殖环境的消毒已成为越来越重要的疾病防控手段。优良的消毒剂，合理的消毒方法，能有效降低动物的发病率。尤其是对于病毒性疾病，由于目前缺乏行之有效的治疗药物，所以消毒预防显得尤为重要。
目前市场上消毒剂的种类繁多，有酸碱类消毒剂、活性氧类消毒剂、酚类消毒剂、碘类消毒剂等，不同消毒剂消毒机理不同，消毒效力也不同。在生产实践中，这些常用的消毒剂在使用时存在一些不足之处，主要为：如果采用泼洒方式消毒，消毒液在消毒面呈点状或斑片状分布，会导致消毒剂扩散不均匀，消毒不彻底；如果采用浸泡方式消毒，则用水量大，造成很大浪费。
发明内容
本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种养殖场用泡沫型消毒剂及其制备方法与应用。
本发明的目的可以通过以下技术方案来实现：
一种养殖场用泡沫型消毒剂，每100重量份的消毒剂包括以下重量份的组分：活性氯5-10份、醛类5-10份、发泡剂25-40份、强化剂1-2.5份、缓冲剂0.1-0.5份，余量为水。
进一步地，所述的活性氯包括复合二氧化氯、次氯酸钠、二氯异氰尿酸钠、三氯异氰尿酸钠、溴氯海因中的一种或更多种。活性氯除了具有消毒功能外，还可吸附、分解氨气、硫化氢、二氧化硫等刺激性气体，达到净化空气的效果，解决养殖场普遍存在的气味不良的问题。
进一步地，所述的醛类为戊二醛。为了减缓或降低病原体对消毒剂的耐药性，提高消毒剂消毒效果，达到高效、广谱效果，将活性氯、戊二醛等多种消毒活性成分进行复配，提高消毒剂的消毒效果。
进一步地，所述的发泡剂包括烷基多糖苷、茶皂素、皂角素、烷基葡萄糖酰胺、松香聚氧乙烯酯、脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚羧酸钠、十二烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠或季铵盐中的一种或更多种。发泡剂除了具有发泡功能之外，还可以改变病原体细胞膜的表面张力和通透性，增强消毒效果；发泡剂还可以去除油污，达到清洁效果。
进一步地，所述的强化剂包括吐温-80、丙二醇、甘油、正十二醇、海藻酸钠、草酸钠、三氯化铁、月桂酸、三乙醇胺、聚丙烯酰胺或月桂酰胺中的一种或更多种。强化剂可增强泡沫强度，提高气泡稳定性，延长泡沫破灭半衰期。
进一步地，所述的缓冲剂包括NaHCO3、Na2CO3、Na2HPO4或NaH2PO4中的一种或更多种。
缓冲剂的作用如下：
1、稀释后的消毒剂溶液pH值变化会影响消毒剂消毒功效，而不同地区水质不同，会影响消毒剂pH值。相同的消毒剂，相同使用方法，但临床效果却不一样，出现这种情况多与稀释用水有关。本发明消毒剂中的缓冲剂，可以将溶液pH值维持在一定范围，以达到以下两种目的：一是缓冲稀释用水对消毒剂pH值的影响，使消毒剂充分发挥效果；二是降低水质对溶液发泡性能及泡沫稳定性的影响；
2、缓冲剂还可以稳定消毒剂在储存过程中的pH值，提高产品质量稳定性。
一种养殖场用泡沫型消毒剂的制备方法，该方法为：按比例称取各组分并混合均匀，即制得所述的消毒剂。
一种养殖场用泡沫型消毒剂的应用，将消毒剂与水按照1:100-1000的体积比混合，用于养殖场消毒。消毒剂除具有消毒作用外，还具有净味、清洗功能。
进一步地，将消毒剂与水混合后，通过高压泡沫喷射器喷出泡沫。本发明消毒剂与高压泡沫喷射器配合使用，发泡倍数达100倍以上，泡沫半衰期≥15min，可对消毒面全覆盖，不留死角与空白，使消毒剂均匀分布，可延长消毒剂与消毒面接触时间，从而增强消毒效果，同时可节约用水。此外，本发明消毒剂还具有净味、清洗功效，适用于养殖场圈舍、器具等清洗与消毒。
本发明消毒剂具有高倍数发泡能力，且泡沫维持时间长，主要机理如下：
1、使用的发泡剂为表面活性剂，且可选用多种发泡剂进行复合，能高效降低液体表面张力，故发泡性能强；
2、发泡剂含量高，达25-40％；
3、消毒剂通过高压泡沫喷射器，与空气充分混合，然后被高压空气喷出，形成丰富泡沫；
4、消毒剂中含强化剂，可增强泡沫强度，提高气泡稳定性，延长泡沫破灭半衰期。
与现有技术相比，本发明具有以下特点：
1)消毒剂具有净化空气(活性氯作用)、消毒(活性氯、醛类、发泡剂综合作用)、洗涤(发泡剂作用)等多重作用，满足生产实践中的多元化需求；
2)消毒剂可以吸附、分解氨气、硫化氢、二氧化硫等刺激性气体，净化养殖场圈舍空气；
3)消毒功能是活性氯、醛类、发泡剂(与醛类具有协同杀菌作用)三种成分消毒功能的综合，消毒剂中的活性氯、戊二醛协同杀菌，既增强了消毒剂的消毒效果，还可减缓耐药性的产生；同时，通过发泡剂改变细菌细胞膜表面张力和通透性，协助活性氯和戊二醛进入菌体内，更进一步强化消毒效果；发泡剂还可去除油脂，对消毒面具有清洁功能；
4)消毒剂具有高倍数发泡能力，且泡沫维持时间长，可对消毒面全覆盖，使消毒剂分布均匀，且消毒时间长，有效提升了消毒效果；
5)消毒剂在使用时，单位面积用水量小，可节约水资源；
6)消毒剂使用后可进行生物降解，不污染环境。
具体实施方式
下面结合具体实施例对本发明进行详细说明。本实施例以本发明技术方案为前提进行实施，给出了详细的实施方式和具体的操作过程，但本发明的保护范围不限于下述的实施例。
实施例1：
一种养殖场用高泡沫型消毒剂，其以重量份数计，每100份消毒剂由以下成分组成：戊二醛5份，复合二氧化氯5份，癸甲溴铵5份，脂肪醇聚氧乙烯醚(AEO-7)0.5份，脂肪醇聚氧乙烯醚磺酸钠25份，吐温-80 1.5份，Na2HPO4 0.1份，NaH2PO40.1份，余量为水。按比例称取各原料，溶解、混合均匀，密封灌装即得。
实施例2：
一种养殖场用高泡沫型消毒剂，其以重量份数计，每100份消毒剂由以下成分组成：戊二醛5份，复合二氧化氯5份，癸甲溴铵5份，皂角素15份，脂肪醇聚氧乙烯醚(AEO-7)10份，脂肪醇聚氧乙烯醚磺酸钠15份，十二烷基苯磺酸钠8份，正十二烷1.5份，海藻酸钠0.2份，Na2HPO4 0.1份，NaH2PO4 0.1份，余量为水。按比例称取各原料，溶解、混合均匀，密封灌装即得。
实施例3：
一种养殖场用高泡沫型消毒剂，其以重量份数计，每100份消毒剂由以下成分组成：戊二醛5份，次氯酸钠10份，烷基多糖苷15份，松香聚氧乙烯酯10份，脂肪醇聚氧乙烯醚硫酸钠15份，丙二醇2.5份，Na2HPO4 0.1份，余量为水。按比例称取各原料，溶解、混合均匀，密封灌装即得。
实施例4：
取实施例1-3所配制的消毒剂，分别与自来水按1:100的体积比稀释，并用高压泡沫喷射器喷成泡沫，待泡沫稳定后，用已知质量(记为W)和体积(记为V)的容器盛满泡沫，刮平，称质量(记为W1)，待泡沫体积缩减到1/2时，记录时间(泡沫半衰期，记为T)，发泡倍数N＝V/(W1-W)。每种消毒剂测量3次，取平均值，具体结果见下表。
消毒剂样品 发泡倍数N(平均值) 泡沫半衰期T(平均值)
实施例1 117.7 17.7
实施例2 197.3 29.3
实施例3 135.3 22
由以上试验数据可知，实施例1-3所配制的消毒剂，发泡倍数均大于100，泡沫半衰期均大于15min。
实施例5：
对实施例1-3所配制的消毒剂进行消毒效果实验室验证。
取上述消毒剂样品以及市售戊二醛溶液(戊二醛质量体积比为5％，g/mL)，分别在无菌环境下用灭菌去离子水按1:1000的体积比稀释。取大肠杆菌标准菌(CVCC2081)培养斜面，制成1×104cfu/mL的菌悬液。将菌悬液与稀释后的消毒剂各取1mL(空白对照组用生理盐水)，混合，37℃静置30min，0.22μm滤膜过滤，收集滤膜上的活菌，稀释成50mL，取100μL涂布平板，37℃倒置培养24h，每组各做5个平行，计数，各组菌落数平均值如下表。
组别 菌落数(CFU)
空白对照组 15.8
实施例1样品组 2.4
实施例2样品组 0.8
实施例3样品组 1.4
5％戊二醛溶液组 5.6
以上各组间平均值差异显著(P＜0.05)。经比较可知，实施例1-3所配制的消毒剂对大肠杆菌杀菌效果显著，且优于5％戊二醛溶液。
实施例6：
在同一养殖场不同圈舍，分别使用实施例1-3所配制的消毒剂以及市售戊二醛溶液(戊二醛质量体积比为5％，g/mL)进行消毒试验。不同圈舍均使用相同消毒方式和相同剂量消毒剂(按面积折算)。消毒前分别在各圈舍5个不同区域(离地面30cm高度)使用集菌仪收集空气中微生物，消毒后1小时采用同样方式再收集一次。将各圈舍消毒前后所收集微生物洗涤、培养，计数，计算空气中微生物浓度。结果统计如下表：
由以上试验结果可以看出，各圈舍消毒后空气中微生物量均有明显降低，且实施例1-3所配制的消毒剂比5％戊二醛溶液消毒效果更加明显。
实施例7：
一种养殖场用泡沫型消毒剂，每100重量份的消毒剂包括以下重量份的组分：活性氯5份、醛类10份、发泡剂25份、强化剂2.5份、缓冲剂0.1份，余量为水。
其中，活性氯为次氯酸钠；醛类为戊二醛；发泡剂为茶皂素；强化剂为丙二醇；缓冲剂为Na2CO3。
该消毒剂的制备方法为：按比例称取各组分并混合均匀，即制得消毒剂。
将消毒剂与水按照1:700的体积比混合，通过高压泡沫喷射器喷出泡沫，用于养殖场消毒。
实施例8：
一种养殖场用泡沫型消毒剂，每100重量份的消毒剂包括以下重量份的组分：活性氯10份、醛类5份、发泡剂40份、强化剂1份、缓冲剂0.5份，余量为水。
其中，活性氯包括复合二氧化氯及二氯异氰尿酸钠；醛类为戊二醛；发泡剂包括烷基多糖苷及皂角素；强化剂包括吐温-80及甘油；缓冲剂包括NaHCO3及Na2HPO4。
该消毒剂的制备方法为：按比例称取各组分并混合均匀，即制得消毒剂。
将消毒剂与水按照1:500的体积比混合，通过高压泡沫喷射器喷出泡沫，用于养殖场消毒。
实施例9：
一种养殖场用泡沫型消毒剂，每100重量份的消毒剂包括以下重量份的组分：活性氯7份、醛类8份、发泡剂30份、强化剂2份、缓冲剂0.2份，余量为水。
其中，活性氯包括三氯异氰尿酸钠及溴氯海因；醛类为戊二醛；发泡剂包括烷基葡萄糖酰胺、松香聚氧乙烯酯及脂肪醇聚氧乙烯醚；强化剂包括正十二醇、海藻酸钠、草酸钠及三氯化铁；缓冲剂为NaH2PO4。
该消毒剂的制备方法为：按比例称取各组分并混合均匀，即制得消毒剂。
将消毒剂与水按照1:1000的体积比混合，通过高压泡沫喷射器喷出泡沫，用于养殖场消毒。
实施例10：
一种养殖场用泡沫型消毒剂，每100重量份的消毒剂包括以下重量份的组分：活性氯9份、醛类6份、发泡剂35份、强化剂1.5份、缓冲剂0.4份，余量为水。
其中，活性氯为二氯异氰尿酸钠；醛类为戊二醛；发泡剂包括脂肪醇聚氧乙烯醚羧酸钠、十二烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠及季铵盐；强化剂包括月桂酸、三乙醇胺、聚丙烯酰胺及月桂酰胺；缓冲剂包括NaHCO3及NaH2PO4。
该消毒剂的制备方法为：按比例称取各组分并混合均匀，即制得消毒剂。
将消毒剂与水按照1:100的体积比混合，通过高压泡沫喷射器喷出泡沫，用于养殖场消毒。
上述的对实施例的描述是为便于该技术领域的普通技术人员能理解和使用发明。熟悉本领域技术的人员显然可以容易地对这些实施例做出各种修改，并把在此说明的一般原理应用到其他实施例中而不必经过创造性的劳动。因此，本发明不限于上述实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。

Claims (9)

1.一种养殖场用泡沫型消毒剂，其特征在于，每100重量份的消毒剂包括以下重量份的组分：活性氯5-10份、醛类5-10份、发泡剂25-40份、强化剂1-2.5份、缓冲剂0.1-0.5份，余量为水。
2.根据权利要求1所述的一种养殖场用泡沫型消毒剂，其特征在于，所述的活性氯包括复合二氧化氯、次氯酸钠、二氯异氰尿酸钠、三氯异氰尿酸钠、溴氯海因中的一种或更多种。
3.根据权利要求1所述的一种养殖场用泡沫型消毒剂，其特征在于，所述的醛类为戊二醛。
4.根据权利要求1所述的一种养殖场用泡沫型消毒剂，其特征在于，所述的发泡剂包括烷基多糖苷、茶皂素、皂角素、烷基葡萄糖酰胺、松香聚氧乙烯酯、脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯醚羧酸钠、十二烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠或季铵盐中的一种或更多种。
5.根据权利要求1所述的一种养殖场用泡沫型消毒剂，其特征在于，所述的强化剂包括吐温-80、丙二醇、甘油、正十二醇、海藻酸钠、草酸钠、三氯化铁、月桂酸、三乙醇胺、聚丙烯酰胺或月桂酰胺中的一种或更多种。
6.根据权利要求1所述的一种养殖场用泡沫型消毒剂，其特征在于，所述的缓冲剂包括NaHCO3、Na2CO3、Na2HPO4或NaH2PO4中的一种或更多种。
7.一种如权利要求1至6任一项所述的养殖场用泡沫型消毒剂的制备方法，其特征在于，该方法为：按比例称取各组分并混合均匀，即制得所述的消毒剂。
8.一种如权利要求1至6任一项所述的养殖场用泡沫型消毒剂的应用，其特征在于，将消毒剂与水按照1:100-1000的体积比混合，用于养殖场消毒。
9.根据权利要求8所述的一种养殖场用泡沫型消毒剂的应用，其特征在于，将消毒剂与水混合后，通过高压泡沫喷射器喷出泡沫。
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CN110583646A (zh) * 2019-09-19 2019-12-20 江西农业大学 一种养鸡场用泡沫型微酸性电解水消毒剂
CN111363635A (zh) * 2020-04-02 2020-07-03 西南科技大学 用于放射性污染去污的防冻泡沫去污剂的制备及使用方法
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CN114106936A (zh) * 2021-12-10 2022-03-01 广东腾骏药业股份有限公司 一种养殖场用带消毒功能的发泡型清洁剂
CN114668011A (zh) * 2022-03-31 2022-06-28 濮阳宏业环保技术研究院有限公司 一种鞋袜除臭喷雾剂及其应用
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