CN108728934A - 一种高强度阻燃耐热织带 - Google Patents
一种高强度阻燃耐热织带 Download PDFInfo
- Publication number
- CN108728934A CN108728934A CN201810772970.1A CN201810772970A CN108728934A CN 108728934 A CN108728934 A CN 108728934A CN 201810772970 A CN201810772970 A CN 201810772970A CN 108728934 A CN108728934 A CN 108728934A
- Authority
- CN
- China
- Prior art keywords
- parts
- heat
- flaming
- agent
- strength anti
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000007822 coupling agent Substances 0.000 claims abstract description 23
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 12
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000013078 crystal Substances 0.000 claims abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 5
- 239000004734 Polyphenylene sulfide Substances 0.000 claims abstract description 5
- 239000002216 antistatic agent Substances 0.000 claims abstract description 5
- 239000004917 carbon fiber Substances 0.000 claims abstract description 5
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 5
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 5
- 239000004927 clay Substances 0.000 claims abstract description 5
- 150000002500 ions Chemical class 0.000 claims abstract description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000004048 modification Effects 0.000 claims abstract description 5
- 238000012986 modification Methods 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229920000570 polyether Polymers 0.000 claims abstract description 5
- 229920000069 polyphenylene sulfide Polymers 0.000 claims abstract description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 5
- 150000003457 sulfones Chemical class 0.000 claims abstract description 5
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 16
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000003963 antioxidant agent Substances 0.000 claims description 12
- 230000003078 antioxidant effect Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical group NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 5
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical group 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 4
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 4
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000011858 nanopowder Substances 0.000 claims description 4
- 150000001451 organic peroxides Chemical class 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- 238000004513 sizing Methods 0.000 claims description 4
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 239000003921 oil Substances 0.000 abstract description 13
- 230000002940 repellent Effects 0.000 abstract description 12
- 239000005871 repellent Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 8
- 239000004519 grease Substances 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- 238000002485 combustion reaction Methods 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- YESRULSVSWLZLT-UHFFFAOYSA-N C(C)O[SiH](OCC)OCC.[Ru].[F] Chemical class C(C)O[SiH](OCC)OCC.[Ru].[F] YESRULSVSWLZLT-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical class CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04D—TRIMMINGS; RIBBONS, TAPES OR BANDS, NOT OTHERWISE PROVIDED FOR
- D04D9/00—Ribbons, tapes, welts, bands, beadings, or other decorative or ornamental strips, not otherwise provided for
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Artificial Filaments (AREA)
Abstract
本发明公开了一种高强度阻燃耐热织带，其由下列重量份数的原料制成：聚苯硫醚砜50~80份、可溶性聚四氟乙烯50~100份、改性聚酯10~20份、碳纳米管2~5份、氯化聚醚20~30份、碳纤维5~10份、碳化硅短纤1~3份、硫酸钙晶须0.5~1份、离子改性黏土1~2份、偶联剂1~2份、抗静电剂2~5份、防老化剂2~5份。本发明处理工艺制得的高强度阻燃耐热织带有耐热阻燃的优点，且性价比高，价格便宜、抗静电、拒水防油、避免油污污染和水渍粘结、化学性能稳定、使用时间长。
Description
技术领域
本发明属于织带生产技术领域，具体涉及一种高强度阻燃耐热织带。
背景技术
织带是以各种纱线为原料制成狭幅状织物或管状织物。带织物品种繁多，广泛用于服饰、鞋材、箱包、工业、农业、军需、交通运输等各产业部门。以前，织带都是手工作坊生产，原料为棉线、麻线。新中国成立后，织带用原料逐渐发展到锦纶、维纶、涤纶、丙纶、氨纶、粘胶等，形成机织、编结、针织三大类工艺技术，织物结构有平纹、斜纹、缎纹、提花、双层、多层、管状和联合组织。
现有的织带强度较低，耐磨性能差。虽然有的织带具有阻燃效果，但阻燃等级较低，无法达到特定环境的使用要求特别是现有的织带因为其本身材料的性质决定了在受到拉力的时候延伸率比较大。
因为织带的应用场合非常广泛，但织带毕竟作为一种由纱线为原料的织物，它的阻燃性能差，尤其是在消防救援中使用的防护带或在生产领域中的输送带，其使用的环境可能会接触到明火，此时织带则容易被引燃，对人员的生命造成威胁，对设备造成破坏；在家庭中，一般的织带一旦遇到火源无法达到阻燃的效果甚至会加速火源的蔓延，增大火灾的危害。
发明内容
本发明的目的是针对现有的问题，提供了一种高强度阻燃耐热织带。
本发明通过以下技术方案实现：
一种高强度阻燃耐热织带，包含有以下的组分：聚苯硫醚砜50~80份、可溶性聚四氟乙烯50~100份、改性聚酯10~20份、碳纳米管2~5份、氯化聚醚20~30份、碳纤维5~10份、碳化硅短纤1~3份、硫酸钙晶须0.5~1份、离子改性黏土1~2份、偶联剂1~2份、抗静电剂2~5份、防老化剂2~5份、拒水抗油剂0.5~1份、清洁添加剂0.5~1份。
进一步的，拒水抗油剂由含氟化合物与酒精1：80~1：60重量比例均匀混合制成，其中含氟化合物为lH，lH，2H，2H-全氟十二烷硫醇、十七氟癸基三乙氧基硅烷、十三氟辛基三乙氧基硅烷中的一种或多种。
进一步的，清洁添加剂由纳米无机物1~2份、溶剂20~30份、偶联剂0.5~1份、可溶性聚四氟乙烯13~15份，混合、球磨、分散而成，其中纳米粉体为介孔二氧化硅、冰晶石、氟化铝、氟化钡、氟化镁中的一种或几种构成，粒径为50~100nm，溶剂由丙酮、二氯乙烷、二氯甲烷、甲苯中的一种或多种构成，偶联剂为铝酸酯偶联剂、钛酸酯偶联剂、有机过氧化物偶联剂中的一种或多种构成，将各物质置于球磨机中充分研磨，即得。
进一步的，，所述防老化剂为对苯二胺类防老剂和喹啉类防老剂的混合物，且对苯二胺类防老剂和喹啉类防老剂的质量比为1~3：1~2。
进一步的，将上述各组分置于高速混合机中，共混的同时必须加热320~370℃，待完全干燥后方可取出，使用双螺杆挤出机造粒冷切，再通过双螺杆挤出机熔融挤出并通过纺丝箱喷丝板喷丝，冷却，定型，得到网丝；将网丝织网，即得到高强度阻燃耐热织带。
本发明的有益效果：
本发明提供的一种高强度阻燃耐热织带，本发明相比现有术具有以下优点：本发明采用固液混合加工共混法制得均匀拒水抗油的抗静电高强度阻燃耐热织带，采用氟系聚合物材料可溶性聚四氟乙烯，保证了材料的双疏效果，同时与表面涂层法相比，具有耐摩擦、耐洗涤、等优势。该方法打破了现有高强度阻燃耐热织带拒水抗油效果，只能做成表面涂层的形式，从而拥有良好的耐摩擦、耐洗涤性能，具有自清洁表面，可在含油量高、含水量高的髙炉煤气、电炉、转炉、炭黑、水泥、油炉、垃圾焚烧炉、沥青搅拌等苛刻高要求的领域使用，且均具有良好的应用前景。
具体实施方式
下面用具体实施例说明本发明，但并不是对本发明的限制。
实施例1
一种高强度阻燃耐热织带，包含有以下的组分：聚苯硫醚砜80份、可溶性聚四氟乙烯100份、改性聚酯20份、碳纳米管2份、氯化聚醚30份、碳纤维5份、碳化硅短纤3份、硫酸钙晶须1份、离子改性黏土2份、偶联剂1份、抗静电剂2份、防老化剂2份、拒水抗油剂1份、清洁添加剂1份。
进一步的，拒水抗油剂由含氟化合物与酒精1：80~1：60重量比例均匀混合制成，其中含氟化合物为lH，lH，2H，2H-全氟十二烷硫醇、十七氟癸基三乙氧基硅烷、十三氟辛基三乙氧基硅烷中的一种或多种。
进一步的，清洁添加剂由纳米无机物1份、溶剂30份、偶联剂1份、可溶性聚四氟乙烯15份，混合、球磨、分散而成，其中纳米粉体为介孔二氧化硅、冰晶石、氟化铝、氟化钡、氟化镁中的一种或几种构成，粒径为50~100nm，溶剂由丙酮、二氯乙烷、二氯甲烷、甲苯中的一种或多种构成，偶联剂为铝酸酯偶联剂、钛酸酯偶联剂、有机过氧化物偶联剂中的一种或多种构成，将各物质置于球磨机中充分研磨，即得。
进一步的，，所述防老化剂为对苯二胺类防老剂和喹啉类防老剂的混合物，且对苯二胺类防老剂和喹啉类防老剂的质量比为1~3：1~2。
进一步的，将上述各组分置于高速混合机中，共混的同时必须加热320~370℃，待完全干燥后方可取出，使用双螺杆挤出机造粒冷切，再通过双螺杆挤出机熔融挤出并通过纺丝箱喷丝板喷丝，冷却，定型，得到网丝；将网丝织网，即得到高强度阻燃耐热织带。
实施例2
一种高强度阻燃耐热织带，包含有以下的组分：聚苯硫醚砜80份、可溶性聚四氟乙烯50份、改性聚酯20份、碳纳米管2份、氯化聚醚20份、碳纤维5份、碳化硅短纤3份、硫酸钙晶须1份、离子改性黏土2份、偶联剂1份、抗静电剂2份、防老化剂2份、拒水抗油剂1份、清洁添加剂1份。
进一步的，拒水抗油剂由含氟化合物与酒精1：80~1：60重量比例均匀混合制成，其中含氟化合物为lH，lH，2H，2H-全氟十二烷硫醇、十七氟癸基三乙氧基硅烷、十三氟辛基三乙氧基硅烷中的一种或多种。
进一步的，清洁添加剂由纳米无机物2份、溶剂30份、偶联剂1份、可溶性聚四氟乙烯15份，混合、球磨、分散而成，其中纳米粉体为介孔二氧化硅、冰晶石、氟化铝、氟化钡、氟化镁中的一种或几种构成，粒径为50~100nm，溶剂由丙酮、二氯乙烷、二氯甲烷、甲苯中的一种或多种构成，偶联剂为铝酸酯偶联剂、钛酸酯偶联剂、有机过氧化物偶联剂中的一种或多种构成，将各物质置于球磨机中充分研磨，即得。
进一步的，，所述防老化剂为对苯二胺类防老剂和喹啉类防老剂的混合物，且对苯二胺类防老剂和喹啉类防老剂的质量比为1~3：1~2。
进一步的，将上述各组分置于高速混合机中，共混的同时必须加热320~370℃，待完全干燥后方可取出，使用双螺杆挤出机造粒冷切，再通过双螺杆挤出机熔融挤出并通过纺丝箱喷丝板喷丝，冷却，定型，得到网丝；将网丝织网，即得到高强度阻燃耐热织带。
对比例1
本对比例与实施例2相比，在原料称取步骤中，省去拒水抗油剂成分，除此外的方法步骤均相同。
对比例2
本对比例与实施例2相比，在原料称取步骤中，省去清洁添加剂成分，除此外的方法步骤均相同。
对比例3
本对比例与实施例2相比，在原料称取步骤中，省去可溶性聚四氟乙烯成分，除此外的方法步骤均相同。
表1各实施例和对比例所制备高强度阻燃耐热织带的力学性能
注：由上表1可以看出，本发明公开的高强度阻燃耐热织带的强度得到了明显的提高，同时其断裂伸长率控制较好，与原性能相差无几。拒水防油，效果明显。本发明公开的高强度阻燃耐热织带有抗折、抗拉性好的优点，且性价比高，价格便宜、抗静电、拒水防油、避免油污污染和水渍粘结、化学性能稳定、使用时间长。该高强度阻燃耐热织带具备的、耐温、耐腐蚀等物理特性。
Claims (4)
1.一种高强度阻燃耐热织带，其特征在于，包含有以下的组分：聚苯硫醚砜50~80份、可溶性聚四氟乙烯50~100份、改性聚酯10~20份、碳纳米管2~5份、氯化聚醚20~30份、碳纤维5~10份、碳化硅短纤1~3份、硫酸钙晶须0.5~1份、离子改性黏土1~2份、偶联剂1~2份、抗静电剂2~5份、防老化剂2~5份。
2.如权利1所述的一种高强度阻燃耐热织带，其特征在于，清洁添加剂由纳米无机物1~2份、溶剂20~30份、偶联剂0.5~1份、可溶性聚四氟乙烯13~15份，混合、球磨、分散而成，其中纳米粉体为介孔二氧化硅、冰晶石、氟化铝、氟化钡、氟化镁中的一种或几种构成，粒径为50~100nm，溶剂由丙酮、二氯乙烷、二氯甲烷、甲苯中的一种或多种构成，偶联剂为铝酸酯偶联剂、钛酸酯偶联剂、有机过氧化物偶联剂中的一种或多种构成，将各物质置于球磨机中充分研磨，即得。
3.如权利1所述的一种高强度阻燃耐热织带，其特征在于，所述防老化剂为对苯二胺类防老剂和喹啉类防老剂的混合物，且对苯二胺类防老剂和喹啉类防老剂的质量比为1~3：1~2。
4.如权利1所述的一种高强度阻燃耐热织带，其特征在于，将上述各组分置于高速混合机中，共混的同时必须加热320~370℃，待完全干燥后方可取出，使用双螺杆挤出机造粒冷切，再通过双螺杆挤出机熔融挤出并通过纺丝箱喷丝板喷丝，冷却，定型，得到网丝；将网丝织网，即得到高强度阻燃耐热织带。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810772970.1A CN108728934A (zh) | 2018-07-14 | 2018-07-14 | 一种高强度阻燃耐热织带 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810772970.1A CN108728934A (zh) | 2018-07-14 | 2018-07-14 | 一种高强度阻燃耐热织带 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108728934A true CN108728934A (zh) | 2018-11-02 |
Family
ID=63926830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810772970.1A Pending CN108728934A (zh) | 2018-07-14 | 2018-07-14 | 一种高强度阻燃耐热织带 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108728934A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294128A (zh) * | 2018-09-28 | 2019-02-01 | 安徽省永欣织带有限公司 | 一种柔性绝缘导热织带 |
| US20220033168A1 (en) * | 2020-08-03 | 2022-02-03 | Maria Grenier | Heat-resistant portable storage unit |
| CN114703562A (zh) * | 2022-03-09 | 2022-07-05 | 杭州惠丰化纤有限公司 | 一种超细抗静电涤棉复合丝及其制备方法与抗静电面料 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1464008A (zh) * | 2002-06-07 | 2003-12-31 | 四川大学 | 纳米粒子增韧聚芳硫醚复合材料及其制备方法 |
| CN105348796A (zh) * | 2015-12-17 | 2016-02-24 | 重庆可益荧新材料有限公司 | 碳纤维增强聚苯硫醚复合材料及其制备方法 |
| CN107841105A (zh) * | 2016-09-20 | 2018-03-27 | 河南智联寰宇知识产权运营有限公司 | 耐热阻燃聚乳酸石墨烯复合材料及其制备方法 |
| CN108102369A (zh) * | 2017-12-28 | 2018-06-01 | 浙江大学台州研究院 | 耐高温耐磨高填充复合材料及其制备方法 |
| CN109294128A (zh) * | 2018-09-28 | 2019-02-01 | 安徽省永欣织带有限公司 | 一种柔性绝缘导热织带 |
-
2018
- 2018-07-14 CN CN201810772970.1A patent/CN108728934A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1464008A (zh) * | 2002-06-07 | 2003-12-31 | 四川大学 | 纳米粒子增韧聚芳硫醚复合材料及其制备方法 |
| CN105348796A (zh) * | 2015-12-17 | 2016-02-24 | 重庆可益荧新材料有限公司 | 碳纤维增强聚苯硫醚复合材料及其制备方法 |
| CN107841105A (zh) * | 2016-09-20 | 2018-03-27 | 河南智联寰宇知识产权运营有限公司 | 耐热阻燃聚乳酸石墨烯复合材料及其制备方法 |
| CN108102369A (zh) * | 2017-12-28 | 2018-06-01 | 浙江大学台州研究院 | 耐高温耐磨高填充复合材料及其制备方法 |
| CN109294128A (zh) * | 2018-09-28 | 2019-02-01 | 安徽省永欣织带有限公司 | 一种柔性绝缘导热织带 |
Non-Patent Citations (1)
| Title |
|---|
| 王文广 主编: "《聚合物改性原理》", 31 March 2018, 中国轻工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109294128A (zh) * | 2018-09-28 | 2019-02-01 | 安徽省永欣织带有限公司 | 一种柔性绝缘导热织带 |
| US20220033168A1 (en) * | 2020-08-03 | 2022-02-03 | Maria Grenier | Heat-resistant portable storage unit |
| CN114703562A (zh) * | 2022-03-09 | 2022-07-05 | 杭州惠丰化纤有限公司 | 一种超细抗静电涤棉复合丝及其制备方法与抗静电面料 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Liu et al. | Functionalization of cotton with carbon nanotubes | |
| CN108728934A (zh) | 一种高强度阻燃耐热织带 | |
| EP2412850B1 (en) | Amorphous polyetherimide fiber and heat-resistant fabric | |
| JP2019007120A (ja) | 耐摩耗性と耐切傷性を備える超高分子量ポリエチレンファイバーの調製方法 | |
| CN107557966A (zh) | 一种复合阻燃材料及制备方法 | |
| CN110396748B (zh) | 一种耐高温纱线、复合面料及防护面料 | |
| CN102634904A (zh) | 一种具有阻燃及抗熔滴性能的涤纶纤维混纺或交织织物 | |
| TWI385206B (zh) | 無融滴阻燃母粒、用以製備該阻燃母粒的組成物與方法以及包含該阻燃母粒的阻燃物 | |
| CN105113254A (zh) | 一种玄武岩纤维防火布的制备方法 | |
| CN106149084B (zh) | 一种石墨烯、uhmwpe复合纤维及其制备方法和应用 | |
| US11447895B2 (en) | Fire retardant nylon fibers and methods for making them | |
| CN110387739B (zh) | 一种具有石墨烯涂层的电焊防护服面料的制备方法及制得的电焊防护服面料 | |
| WO2018066438A1 (ja) | 遮炎性織物 | |
| CN108728930A (zh) | 一种拒水防油抗静电织带 | |
| CN103451757A (zh) | 一种具有抗静电、耐酸碱、隔热阻燃特性的纤维 | |
| JP6087533B2 (ja) | 耐熱性有機繊維 | |
| CN110158174B (zh) | 一种阻燃剂、阻燃合成纤维及其制造方法 | |
| Zhang et al. | Zinc hydroxystannate microencapsulated to improve its safety and application to flame-retardant, smoke-suppressed polyvinyl chloride composites | |
| CN105088794A (zh) | 一种玄武岩纤维防火布 | |
| CN102634896A (zh) | 一种阻燃抗滴落的混纺织物及其制备方法 | |
| TWI385205B (zh) | 無鹵低磷阻燃母粒、用以製備該阻燃母粒的組成物與方法以及包含該阻燃母粒的阻燃物 | |
| JP2012036511A (ja) | 難燃性布帛およびそれを用いてなる防護衣 | |
| JP2007254915A (ja) | 難燃性に優れたメタ型芳香族ポリアミド繊維 | |
| CN108914242A (zh) | 一种耐高温抗熔滴的石墨烯纤维材料及其制备方法 | |
| CN101857985A (zh) | 一种氢氧化镁及氢氧化铝pbt/pet复合纤维及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181102 |
|
| RJ01 | Rejection of invention patent application after publication |