CN108690249A - A kind of thermal-insulating type modified pearl cotton material preparation method and applications - Google Patents
A kind of thermal-insulating type modified pearl cotton material preparation method and applications Download PDFInfo
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
- B65D65/44—Applications of resilient shock-absorbing materials, e.g. foamed plastics material, honeycomb material
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- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
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- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
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- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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Abstract
The invention discloses a kind of thermal-insulating type modified pearl cotton material preparation method and applications, this method is by calcite, bentonite grinding refinement, then and low density polyethylene (LDPE), acetoacetic acid allyl ester, tricresyl phosphate is added in reaction kettle jointly to react, again by reaction product and isobutyl triethoxy silane, dimethylaminopropylamine carries out microwave treatment, then by treating products with microwaves and tetramethoxy-silicane excessively, epoxidized soybean oil carries out mixing twice and heats maintenance molten condition, then by molecule distillating monoglyceride, ethoxylated alkylamine is heated to molten condition, it is added into the secondary mixing product for being similarly molten condition, insulation reaction simultaneously foams, finally squeeze out while hot, it is cooling, packaging, obtain modified pearl cotton material.The modified pearl cotton material being prepared, thermal coefficient is low, has a good application prospect as packaging material.
Description
Technical field
The present invention relates to field of packaging material, and in particular to a kind of thermal-insulating type modified pearl cotton material preparation method and
It is applied.
Background technology
Packaging material is widely used in the fields such as packing container, packing and decorating, packages printing, packed and transported, for work
Industry production, people's daily life play an important roll.With the industrialized continuous development in China, the type of industrial products and production
The raising year by year of amount, the Year's consumption of packaging material is also increasing, thus, Chinese society to the demand of packaging material drastically
Rise.Pearl cotton is a kind of packaging material of novel environment friendly, it generates countless independence through physical blowing by low density polyethylene (LDPE)
Bubble constitute, overcome common foamed glue it is frangible, deformation, restorative difference disadvantage.Moisture-proof with water proof, shockproof, sound insulation, guarantor
Temperature, plasticity is good, toughness is strong, reconstituted circularly, environmental protection, strong crashworthiness power many advantages, such as, also with good chemical resistance,
It is the ideal substitute of conventional packaging material.Pearl cotton point can be ordinary pearl cotton, without wax pearl cotton, special flat pearl cotton, encryption
Pearl cotton, encryption stiffened pearl cotton, antistatic pearl cotton, PO overlay films pearl cotton, PE laminations pearl cotton, cladded aluminum foil pearl cotton, plating
Color film fitting pearl cotton, pearl cotton, PS plates(Pearl plate), KT plates(Billboard)Fire prevention pearl cotton, pearl cotton build bridge etc..Due to
The application field of packaging material is different, also has different requirements, the insulation of existing EPE packaging material to its own performance
Although performance has some superiority, but still require further improvement, to extend the application range of Pearl wool material.
Invention content
In order to solve the above technical problems, the present invention provides a kind of thermal-insulating type modified pearl cotton material preparation method and its answers
With, this method be by calcite, bentonite grinding refinement, then with low density polyethylene (LDPE), acetoacetic acid allyl ester, tripotassium phosphate
Phenyl ester is added in reaction kettle jointly to react, then reaction product and isobutyl triethoxy silane, dimethylaminopropylamine are carried out
Treating products with microwaves is then carried out mixing twice with tetramethoxy-silicane excessively, epoxidized soybean oil and heats maintenance by microwave treatment
Molecule distillating monoglyceride, ethoxylated alkylamine are then heated to molten condition by molten condition, are added into and are similarly melting
In the secondary mixing product of state, insulation reaction simultaneously foams, and finally squeezes out while hot, is cooling, packaging, obtaining modified pearl cotton material
Material.The modified pearl cotton material being prepared, thermal coefficient is low, has a good application prospect as packaging material.
Technical solution:To solve the above-mentioned problems, the invention discloses a kind of thermal-insulating type modified pearl cotton material preparation sides
Method comprises the steps of:
(1)By 5~7 parts of calcite, the grinding refinement of 4~6 parts of bentonite, solid grain size is made to be less than 50 μm, then with it is low close
150~200 parts of polyethylene of degree, 35~45 parts of acetoacetic acid allyl ester, 10~20 parts of tricresyl phosphate are added to reaction jointly
In kettle, improves reaction kettle internal temperature and be stirred reaction to 100~120 DEG C, obtain the first reaction product;
(2)First reaction product and 16~20 parts of isobutyl triethoxy silane, 8~12 parts of dimethylaminopropylamine are placed in microwave
Microwave treatment is carried out in processor, obtains treating products with microwaves;
(3)Treating products with microwaves and 8~10 parts of tetramethoxy-silicane, 2~4 parts of epoxidized soybean oil excessively are added to mixer jointly
In, mixer internal temperature is improved to 180~190 DEG C, at such a temperature internal mixing and plasticizing 40~60 minutes, is then added anti-quiet
0.5~1.5 part of electric agent improves mixer internal temperature to 250 DEG C, and secondary internal mixing and plasticizing 20~30 minutes obtains secondary close
It refines product and heats and maintain molten condition;
(4)15~25 parts of molecule distillating monoglyceride, 5~9 parts of ethoxylated alkylamine are mixed and heated to molten condition, by itself plus
Maintaining temperature in the secondary mixing product for entering to be similarly molten condition, after being uniformly mixed keeps mixture in molten state
In the range of, it is filled with 1~2 part of physical blowing agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80~100 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Further, the step(1)Middle mixed material is preferably stirred with 200~300 revs/min of rate in a kettle
Mix reaction 25~35 minutes.
Further, the step(2)The microwave frequency of middle microwave treatment be 280~300 MHz, processing time be 15~
25 minutes.
Further, the step(3)In antistatic agent to be selected from cationic antistatic agent, anionic antistatic
Any one in agent and non-ionic antistatic agent.
Further, the step(4)In physical blowing agent it is any one in butane, hexane and carbon dioxide
Kind.
At the same time, the invention also discloses thermal-insulating type modified pearl cotton materials made from above-mentioned preparation method as packaging
The application of material.
Compared with prior art, the present invention advantage is:
(1)The present invention thermal-insulating type modified pearl cotton material preparation method be by calcite, bentonite grinding refinement, then with it is low
Density polyethylene, acetoacetic acid allyl ester, tricresyl phosphate are added in reaction kettle jointly to react, then by reaction product with it is different
Butyl triethoxysilane, dimethylaminopropylamine carry out microwave treatment, then by treating products with microwaves with cross tetramethoxy-silicane,
Epoxidized soybean oil carries out mixing twice and heats maintenance molten condition, then by molecule distillating monoglyceride, ethoxylated alkylamine
It is heated to molten condition, is added into the secondary mixing product for being similarly molten condition, insulation reaction simultaneously foams, while hot finally
It squeezes out, is cooling, packaging, obtaining modified pearl cotton material.The modified pearl cotton material being prepared, thermal coefficient is low, as
Packaging material has a good application prospect.
(2)Present invention employs dimethylaminopropylamine, molecule distillating monoglyceride, ethoxylated alkylamines to participate in preparing heat preservation
Type modified pearl cotton material has carried out effective performance boost to modified pearl cotton material, although these materials are not answered for the first time
For in modified pearl cotton material, but it is aided with corresponding processing mode after amount combination according to a certain ratio, to being finally prepared
Modified pearl cotton material bring increasing substantially in performance, this is never to report in previous research,
For realizing that it is conclusive that the technique effect of the present invention plays the role of.
Specific implementation mode
Embodiment 1
(1)By 5 parts of calcite, the grinding refinement of 4 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
150 parts of alkene, 35 parts of acetoacetic acid allyl ester, 10 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 25 minutes with 200 revs/min of rate to 100 DEG C, obtains the first reaction product;
(2)First reaction product and 16 parts of isobutyl triethoxy silane, 8 parts of dimethylaminopropylamine are placed in microwave treater
Microwave treatment is carried out, microwave frequency is 280 MHz, and processing time is 15 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 8 parts of tetramethoxy-silicane, 2 parts of epoxidized soybean oil excessively are added in mixer jointly, it will be close
Mill internal temperature is improved to 180 DEG C, at such a temperature internal mixing and plasticizing 40 minutes, and cationic antistatic agent 0.5 is then added
Part, mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 20 minutes obtains secondary mixing product and heats maintenance
In molten condition;
(4)15 parts of molecule distillating monoglyceride, 5 parts of ethoxylated alkylamine are mixed and heated to molten condition, are added into same
In the secondary mixing product of molten condition, temperature to be maintained to the range for keeping mixture to be in molten state after being uniformly mixed
It is interior, it is filled with 1 part of butane foaming agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Embodiment 2
(1)By 6 parts of calcite, the grinding refinement of 5 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
175 parts of alkene, 40 parts of acetoacetic acid allyl ester, 15 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 30 minutes with 250 revs/min of rate to 110 DEG C, obtains the first reaction product;
(2)First reaction product and 18 parts of isobutyl triethoxy silane, 10 parts of dimethylaminopropylamine are placed in microwave treater
Middle carry out microwave treatment, microwave frequency are 290 MHz, and processing time is 20 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 9 parts of tetramethoxy-silicane, 3 parts of epoxidized soybean oil excessively are added in mixer jointly, it will be close
Mill internal temperature is improved to 185 DEG C, at such a temperature internal mixing and plasticizing 50 minutes, and 1 part of anionic antistatic agent is then added,
Mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 25 minutes, obtain secondary mixing product and heating maintain it is molten
Melt state;
(4)20 parts of molecule distillating monoglyceride, 7 parts of ethoxylated alkylamine are mixed and heated to molten condition, are added into same
In the secondary mixing product of molten condition, temperature to be maintained to the range for keeping mixture to be in molten state after being uniformly mixed
It is interior, it is filled with 1.5 parts of hexane foaming agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
90 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Embodiment 3
(1)By 7 parts of calcite, the grinding refinement of 6 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
200 parts of alkene, 45 parts of acetoacetic acid allyl ester, 20 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 35 minutes with 300 revs/min of rate to 120 DEG C, obtains the first reaction product;
(2)First reaction product and 20 parts of isobutyl triethoxy silane, 12 parts of dimethylaminopropylamine are placed in microwave treater
Middle carry out microwave treatment, microwave frequency are 300 MHz, and processing time is 25 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 10 parts of tetramethoxy-silicane, 4 parts of epoxidized soybean oil excessively are added in mixer jointly, it will
Mixer internal temperature is improved to 190 DEG C, and internal mixing and plasticizing 60 minutes, are then added non-ionic antistatic agent at such a temperature
1.5 parts, mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 30 minutes obtains secondary mixing product and heats dimension
It holds in molten condition;
(4)25 parts of molecule distillating monoglyceride, 9 parts of ethoxylated alkylamine are mixed and heated to molten condition, are added into same
In the secondary mixing product of molten condition, temperature to be maintained to the range for keeping mixture to be in molten state after being uniformly mixed
It is interior, it is filled with 2 parts of carbon dioxide foaming agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
100 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Comparative example 1
(1)By 5 parts of calcite, the grinding refinement of 4 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
150 parts of alkene, 35 parts of acetoacetic acid allyl ester, 10 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 25 minutes with 200 revs/min of rate to 100 DEG C, obtains the first reaction product;
(2)16 parts of first reaction product and isobutyl triethoxy silane are placed in microwave treater and carry out microwave treatment, it is micro-
Wave frequency rate is 280 MHz, and processing time is 15 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 8 parts of tetramethoxy-silicane, 2 parts of epoxidized soybean oil excessively are added in mixer jointly, it will be close
Mill internal temperature is improved to 180 DEG C, at such a temperature internal mixing and plasticizing 40 minutes, and cationic antistatic agent 0.5 is then added
Part, mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 20 minutes obtains secondary mixing product and heats maintenance
In molten condition;
(4)15 parts of molecule distillating monoglyceride, 5 parts of ethoxylated alkylamine are mixed and heated to molten condition, are added into same
In the secondary mixing product of molten condition, temperature to be maintained to the range for keeping mixture to be in molten state after being uniformly mixed
It is interior, it is filled with 1 part of butane foaming agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Comparative example 2
(1)By 5 parts of calcite, the grinding refinement of 4 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
150 parts of alkene, 35 parts of acetoacetic acid allyl ester, 10 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 25 minutes with 200 revs/min of rate to 100 DEG C, obtains the first reaction product;
(2)First reaction product and 16 parts of isobutyl triethoxy silane, 8 parts of dimethylaminopropylamine are placed in microwave treater
Microwave treatment is carried out, microwave frequency is 280 MHz, and processing time is 15 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 8 parts of tetramethoxy-silicane, 2 parts of epoxidized soybean oil excessively are added in mixer jointly, it will be close
Mill internal temperature is improved to 180 DEG C, at such a temperature internal mixing and plasticizing 40 minutes, and cationic antistatic agent 0.5 is then added
Part, mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 20 minutes obtains secondary mixing product and heats maintenance
In molten condition;
(4)Ethoxylated alkylamine is heated to molten condition for 5 parts, is added into the secondary mixing product for being similarly molten condition
In, temperature is maintained after being uniformly mixed and keeps mixture in the range of molten state, fourth is filled with into molten mixture
1 part of alkane foaming agent, makes molten mixture fully foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
Comparative example 3
(1)By 5 parts of calcite, the grinding refinement of 4 parts of bentonite, solid grain size is made to be less than 50 μm, then and low density polyethylene
150 parts of alkene, 35 parts of acetoacetic acid allyl ester, 10 parts of tricresyl phosphate are added in reaction kettle jointly, are improved inside reaction kettle
Temperature is stirred to react 25 minutes with 200 revs/min of rate to 100 DEG C, obtains the first reaction product;
(2)First reaction product and 16 parts of isobutyl triethoxy silane, 8 parts of dimethylaminopropylamine are placed in microwave treater
Microwave treatment is carried out, microwave frequency is 280 MHz, and processing time is 15 minutes, obtains treating products with microwaves;
(3)Treating products with microwaves and 8 parts of tetramethoxy-silicane, 2 parts of epoxidized soybean oil excessively are added in mixer jointly, it will be close
Mill internal temperature is improved to 180 DEG C, at such a temperature internal mixing and plasticizing 40 minutes, and cationic antistatic agent 0.5 is then added
Part, mixer internal temperature is improved to 250 DEG C, secondary internal mixing and plasticizing 20 minutes obtains secondary mixing product and heats maintenance
In molten condition;
(4)Molecule distillating monoglyceride is mixed and heated to molten condition for 15 parts, is added into and is similarly the secondary close of molten condition
It refines in product, temperature is maintained after being uniformly mixed and keeps mixture in the range of molten state, into molten mixture
It is filled with 1 part of butane foaming agent, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
It is 100 mm × 100 that specification, which is respectively prepared, in the modified pearl cotton material obtained of embodiment 1-3 and comparative example 1-3
The sheet material of the mm of mm × 1 tests its thermal coefficient according to heat-flow meter method, and testing standard is ASTM C518, and test equipment is moral
The resistance to import instrument of speeding of state, model:HFM436, test result are as shown in table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| Thermal coefficient(w/mK) | 0.25 | 0.23 | 0.24 | 0.28 | 0.30 | 0.27 |
The present invention thermal-insulating type modified pearl cotton material preparation method be by calcite, bentonite grinding refinement, then with it is low close
Degree polyethylene, acetoacetic acid allyl ester, tricresyl phosphate are added in reaction kettle and react jointly, then by reaction product and isobutyl
Ethyl triethoxy silicane alkane, dimethylaminopropylamine carry out microwave treatment, then by treating products with microwaves and tetramethoxy-silicane, ring excessively
Oxygen soybean oil carries out mixing twice and heats maintenance molten condition, then adds molecule distillating monoglyceride, ethoxylated alkylamine
Heat is added into molten condition in the secondary mixing product for being similarly molten condition, and insulation reaction simultaneously foams, and finally squeezes while hot
Go out, cool down, pack, obtains modified pearl cotton material.The modified pearl cotton material being prepared, thermal coefficient is low, as packet
Package material has a good application prospect.Also, present invention employs dimethylaminopropylamine, molecule distillating monoglyceride, ethyoxyls
Change alkylamine participation and prepare thermal-insulating type modified pearl cotton material, effective performance boost has been carried out to modified pearl cotton material, though
These right materials are not first Application in modified pearl cotton material, but are aided with corresponding place after amount combination according to a certain ratio
Reason mode brings increasing substantially in performance to the modified pearl cotton material being finally prepared, this is previous
It is never to report in research, for realizing that it is conclusive that the technique effect of the present invention plays the role of.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (6)
1. a kind of thermal-insulating type modified pearl cotton material preparation method, which is characterized in that comprise the steps of:
(1)By 5~7 parts of calcite, the grinding refinement of 4~6 parts of bentonite, solid grain size is made to be less than 50 μm, then with it is low close
150~200 parts of polyethylene of degree, 35~45 parts of acetoacetic acid allyl ester, 10~20 parts of tricresyl phosphate are added to reaction jointly
In kettle, improves reaction kettle internal temperature and be stirred reaction to 100~120 DEG C, obtain the first reaction product;
(2)First reaction product and 16~20 parts of isobutyl triethoxy silane, 8~12 parts of dimethylaminopropylamine are placed in microwave
Microwave treatment is carried out in processor, obtains treating products with microwaves;
(3)Treating products with microwaves and 8~10 parts of tetramethoxy-silicane, 2~4 parts of epoxidized soybean oil excessively are added to mixer jointly
In, mixer internal temperature is improved to 180~190 DEG C, at such a temperature internal mixing and plasticizing 40~60 minutes, is then added anti-quiet
0.5~1.5 part of electric agent improves mixer internal temperature to 250 DEG C, and secondary internal mixing and plasticizing 20~30 minutes obtains secondary close
It refines product and heats and maintain molten condition;
(4)15~25 parts of molecule distillating monoglyceride, 5~9 parts of ethoxylated alkylamine are mixed and heated to molten condition, by itself plus
Maintaining temperature in the secondary mixing product for entering to be similarly molten condition, after being uniformly mixed keeps mixture in molten state
In the range of, it is filled with 1~2 part of physical blowing agent into molten mixture, molten mixture is made fully to foam;
(5)Molten mixture after foaming is injected in extruder while hot, sets extruder temperature as 150 DEG C, screw speed is
80~100 revs/min, extruder pressure is 50 MPa, and modified pearl cotton material is obtained after extruded, cooling, packaging.
2. thermal-insulating type modified pearl cotton material preparation method according to claim 1, which is characterized in that the step(1)
Middle mixed material is preferably stirred to react 25~35 minutes with 200~300 revs/min of rate in a kettle.
3. thermal-insulating type modified pearl cotton material preparation method according to claim 1, which is characterized in that the step(2)
The microwave frequency of middle microwave treatment is 280~300 MHz, and processing time is 15~25 minutes.
4. thermal-insulating type modified pearl cotton material preparation method according to claim 1, which is characterized in that the step(3)
In antistatic agent it is arbitrary in cationic antistatic agent, anionic antistatic agent and non-ionic antistatic agent
It is a kind of.
5. thermal-insulating type modified pearl cotton material preparation method according to claim 1, which is characterized in that the step(4)
In any one in butane, hexane and carbon dioxide of physical blowing agent.
6. according to thermal-insulating type modified pearl cotton material made from any one of the claim 1-5 preparation methods as packaging material
Application.
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| CN201810572582.9A CN108690249A (en) | 2018-06-06 | 2018-06-06 | A kind of thermal-insulating type modified pearl cotton material preparation method and applications |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1343739A (en) * | 2000-09-20 | 2002-04-10 | 中国石油化工股份有限公司 | Radiation cross-linked millipore polyethene material and its preparing process |
| CN1343738A (en) * | 2000-09-20 | 2002-04-10 | 中国石油化工股份有限公司 | Chemically cross-linked millipore polyethene material and its preparing process |
| CN1464891A (en) * | 2000-03-17 | 2003-12-31 | 陶氏环球技术公司 | Polyolefin foam useful for sound and thermal insulation |
| CN104974368A (en) * | 2014-04-04 | 2015-10-14 | 中国石油化工股份有限公司 | Preparation method of antistatic polypropylene foamed beads |
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2018
- 2018-06-06 CN CN201810572582.9A patent/CN108690249A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1464891A (en) * | 2000-03-17 | 2003-12-31 | 陶氏环球技术公司 | Polyolefin foam useful for sound and thermal insulation |
| CN1343739A (en) * | 2000-09-20 | 2002-04-10 | 中国石油化工股份有限公司 | Radiation cross-linked millipore polyethene material and its preparing process |
| CN1343738A (en) * | 2000-09-20 | 2002-04-10 | 中国石油化工股份有限公司 | Chemically cross-linked millipore polyethene material and its preparing process |
| CN104974368A (en) * | 2014-04-04 | 2015-10-14 | 中国石油化工股份有限公司 | Preparation method of antistatic polypropylene foamed beads |
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