CN108676592A - 一种环保节能玫瑰汽车尾气清净剂及其制备方法 - Google Patents
一种环保节能玫瑰汽车尾气清净剂及其制备方法 Download PDFInfo
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Abstract
本发明公开一种环保节能玫瑰汽车尾气清净剂及其制备方法,属于汽车尾气排放处理技术领域,包括下述的组分:马达法提高剂,烷基酚类辛烷值提高剂,烷基磷酸酯,二甲苯,环烷烃为,助燃剂,玫瑰精油,烷基化汽油35~45份,石脑油,芳烃,C9~C12烯烃。本发明中的汽车尾气清净剂能够充分将汽油中的组分燃烧,提升动力,诱导期达到7179min。本发明的成品与普通汽油混溶后,碳氢化合物低于国家规定的限值28.5倍,一氧化碳低于国家规定的限值20倍。
Description
技术领域
本发明涉及汽车尾气排放处理技术领域,特别涉及一种环保节能玫瑰汽车尾气清净剂及其制备方法。
背景技术
目前我国生产的车用汽油都添加甲基叔丁基醚(MTBE)、锰剂(MMT)来提高汽油辛烷值,炼油厂为降低汽油中的硫、芳烃以及烯烃等杂质的含量,在加氢过程中不得不损耗部分芳烃,使长链变为短链,异构烷烃减少,辛烷值下降,导致汽油的燃烧效率相应降低。MTBE作为汽油抗爆组分,能显著提高辛烷值。据测算,汽油中如加入10%的MTBE,可使辛烷值提高1.8~2.0个单位。随着我国油品质量的不断升级,为补偿或增加汽油辛烷值,我国炼油企业普遍采用在汽油中添加MTBE来解决,添加量也从上世纪90年代的平均0.4%逐渐提高到2008年的3.1%,目前甚至已高达13%。
但是,MTBE具有一定毒性,20世纪70年代末开始研究其毒性,研究发现它易于水融合,可渗入土壤,破坏地下水质,MTBE主要经呼吸道吸收,也可以经皮肤和消化道吸收,动物在高浓度的MTBE可致癌。对小鼠麻醉浓度为1毫克,致死浓度为1.6毫克。MTBE即使在很低的浓度也会造成水质恶臭。自1973年起,美国各地陆续出台政策限制在汽油中使用MTBE,美国环保署已将MTBE列为人类可致癌物质。美国2004年起全停止使用MTBE,澳大利亚也与2004年起禁用MTBE。欧洲国家相继停止使用MTBE,周边国家韩国日本也与90年代末全面停止使用MTBE。
总之,MTBE是目前四乙基铅的替代品,在中国广泛应用于汽油中,直接导致雾霾、肺癌及呼吸道的罪魁祸首,MTBE会导致汽油中的烯烃、芳烃等燃烧不完全从尾气排出,浪费20%-30%的汽油组分,加重汽车尾气对空气的污染。
因此,开发出汽车尾气清净剂用以快速提升空气质量、消除雾霾天气迫在眉捷。
发明内容
本发明提供了一种环保节能玫瑰汽车尾气清净剂,解决现有的车用汽油中由于添加了甲基叔丁基醚而引起的环境污染问题。
为解决上述技术问题,本发明采用的技术方案为:
一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:
马达法提高剂0.0016~0.0048份,烷基酚类辛烷值提高剂0.0032~0.0048份,烷基磷酸酯0.0008~0.0016份,二甲苯0.00064~0.00128份,环烷烃为0.0016~0.0024份,助燃剂0.0016~0.0024份,玫瑰精油0.001~0.002份,烷基化汽油35~45份,石脑油18~25份,芳烃15~20份,C9~C12烯烃18~22份。
其中,优选地,所述烷基酚类辛烷值提高剂为邻异丙基酚、4-乙基-2-甲基酚、4,5-二甲基2-乙基酚中任意一种或几种。
其中,优选地,所述烷基磷酸酯为十二烷基磷酸酯、十四烷基磷酸酯或十八烷基磷酸酯。
其中,优选地,所述烷基化汽油为高度分支的异构烷烃。所述的马达法提高剂为蓖麻油。所述助燃剂为过氧化异丙苯、过氧化叔丁基醚或硝酸辛酯。
一种环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
本发明的有益效果:
(1)本发明中的汽车尾气清净剂能够充分将汽油中的组分燃烧,提升动力,节油最高达到40%以上,添加本发明的清净剂后,诱导期达到7179min,超过GB19592-2004车用汽油清净剂质量标准9倍以上。
(2)本发明的成品与普通汽油混溶后,尾气中各排放物依据GB18285-2005、DB371657-200b检测方法检测,碳氢化合物低于国家规定的限值28.5倍,一氧化碳低于国家规定的限值20倍。
具体实施方式
下面将结合本发明具体实施例,对本发明的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
下述实施例中,采用的烷基化汽油为高度分支的异构烷烃。
实施例1
本实施例提供一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:马达法提高剂0.0032份,邻异丙基酚0.0040份,十二烷基磷酸酯0.0012份,二甲苯0.00096份,环烷烃为0.002份,助燃剂0.002份,玫瑰精油0.0016份,烷基化汽油40份,石脑油20份,芳烃18份,C9~C12烯烃20份。
本实施例环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
实施例2
本实施例提供一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:马达法提高剂0.0016份,4-乙基-2-甲基酚0.0048份,十八烷基磷酸酯0.0008份,二甲苯0.00128份,环烷烃为0.00164份,助燃剂0.0024份,玫瑰精油0.001份,烷基化汽油45份,石脑油18份,芳烃20份,C9~C12烯烃18份。
本实施例环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
实施例3
本实施例提供一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:马达法提高剂0.0048份,4-乙基-2-甲基酚0.0032份,十八烷基磷酸酯0.0016份,二甲苯0.00064份,环烷烃为0.0024份,助燃剂0.0016份,玫瑰精油0.002份,烷基化汽油35份,石脑油25份,芳烃15份,C9~C12烯烃22份。
本实施例环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
实施例4
本实施例提供一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:马达法提高剂0.0036份,4,5-二甲基2-乙基酚0.0042份,烷基磷酸酯0.0012份,二甲苯0.00086份,十四环烷烃为0.0021份,助燃剂0.0022份,玫瑰精油0.0018份,烷基化汽油41份,石脑油19份,芳烃18份,C9~C12烯烃21份。
本实施例环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
实施例5
本实施例提供一种环保节能玫瑰汽车尾气清净剂,包括下述重量份的组分:马达法提高剂0.002份,4,5-二甲基2-乙基酚0.004份,十四烷基磷酸酯0.001份,二甲苯0.0009份,环烷烃为0.002份,助燃剂0.002份,玫瑰精油0.001份,烷基化汽油40份,石脑油20份,芳烃18份,C9~C12烯烃22份。
本实施例环保节能玫瑰汽车尾气清净剂的制备方法,包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
应用实施例
实施例1制得的环保节能玫瑰汽车尾气清净剂与普通汽油混溶后,尾气中各排放物依据GB1318285-2005、DB371657-200b检测方法检测,检测结果如下表所示。
以2010年生产的奥迪A4车(属于第一类轻型汽车)试验:
表中排气中一氧化碳(CO)的体积分数以“%”表示;
排气中碳氢化合物(HC)的体积分数以“10-6”表示,体积分数值按正己烷当量;另外,空白指的是未添加本发明环保节能玫瑰汽车尾气清净剂的普通汽油。
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (5)
1.一种环保节能玫瑰汽车尾气清净剂,其特征在于包括下述重量份的组分:马达法提高剂0.0016~0.0048份,烷基酚类辛烷值提高剂0.0032~0.0048份,烷基磷酸酯0.0008~0.0016份,二甲苯0.00064~0.00128份,环烷烃为0.0016~0.0024份,助燃剂0.0016~0.0024份,玫瑰精油0.001~0.002份,烷基化汽油35~45份,石脑油18~25份,芳烃15~20份,C9~C12烯烃18~22份。
2.根据权利要求1所述的一种环保节能玫瑰汽车尾气清净剂,其特征在于:所述烷基酚类辛烷值提高剂为邻异丙基酚、4-乙基-2-甲基酚、4,5-二甲基2-乙基酚中任意一种或几种。
3.根据权利要求1所述的一种环保节能玫瑰汽车尾气清净剂,其特征在于:所述烷基磷酸酯为十二烷基磷酸酯、十四烷基磷酸酯或十八烷基磷酸酯。
4.根据权利要求1所述的一种环保节能玫瑰汽车尾气清净剂,其特征在于:所述烷基化汽油为高度分支的异构烷烃。
5.一种权利要求1~4任一项所述的环保节能玫瑰汽车尾气清净剂的制备方法,其特征在于包括以下步骤:
(1)取烷基酚类辛烷值提高剂和烷基磷酸酯混合均匀;
(2)在严格避光的条件下,取马达法提高剂、二甲苯、环烷烃、助燃剂、玫瑰精油、烷基化汽油、石脑油、芳烃和C9~C12烯烃加入步骤(1)所得的混合物中,混合均匀,即得。
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