CN108653027A - A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica - Google Patents
A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica Download PDFInfo
- Publication number
- CN108653027A CN108653027A CN201810718612.2A CN201810718612A CN108653027A CN 108653027 A CN108653027 A CN 108653027A CN 201810718612 A CN201810718612 A CN 201810718612A CN 108653027 A CN108653027 A CN 108653027A
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- CN
- China
- Prior art keywords
- amino acid
- dioxane
- hair shampoo
- transparent hair
- silica
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of amino acid transparent hair shampoos and preparation method without dioxane and silica, and formula includes guar hydroxypropyltrimonium ammonium chloride, palmitamide trimonium chloride, amino acid surfactant, amino acid conditioner, acidity agent, moisturizer, thickener, nonionic surfactant, preservative, essence and water.The present invention, as major ingredient, not only has good biological degradability and mildness, but also substantially increase safety of the cosmetics to human body itself using sarcosine lipid surfactants.In addition, flesh amino acid lipoid table lives in having assigns fat agent performance well, has flushing compliance due to without separately adding the conditioners such as silica.Compared with existing shampoo, shampoo color and luster of the present invention is sparkling and crystal-clear bright, environmental-friendly, has more preferable safety, higher usage experience sense.
Description
Technical field
The present invention relates to shampoo technical fields, and in particular to a kind of amino acid without dioxane and silica is transparent to be washed
Hair-care shampoo and preparation method.
Background technology
Dioxanes, organic compound, alias dioxane, Isosorbide-5-Nitrae-dioxane, colourless liquid, slightly fragrance are main to use
Make solvent, emulsifier, detergent etc..Dioxanes category micro-virus kind, it is irritant to skin, eye and respiratory system, and may
Liver, kidney and nervous system are damaged, when acute poisoning may lead to death.
Contained dioxanes is the by-product in main surfactant, shower cream in shower cream and shampoo in cosmetics
Alkyl is oxidized easily in the fabrication process with main surfactant in shampoo, generates Isosorbide-5-Nitrae-dioxanes by-product, therefore
The overwhelming majority washes away class cosmetics and contains 1,4- dioxanes.1,4- dioxanes is the nonionic emulsifier (polyoxy in skin care item
Ethylene ethers), the by-product in shower cream and shampoo in the raw material containing polyoxyethylene ether structure.In general, polyoxy second
The class cosmetics that wash away of the raw material making of alkene ether structure all contain 1,4- dioxanes.
Dioxanes is by sucking, eating, percutaneous absorbtion entrance will produce anesthesia and stimulation in vivo, and be accumulated in body
It is interior, eye and upper respiratory tract stimulation are easily caused when contacting a large amount of steams, are often accompanied by dizziness, headache, drowsiness, Nausea and vomiting etc..
It sucks for a long time, liver, skin lesion can be caused, or even uremia occurs, it is irritant to skin, eye and respiratory system, and can
Liver, kidney and nervous system can be damaged, when acute poisoning may lead to death, be classified as carcinogen by the U.S..
Invention content
In order to solve human-body safety health problem of the existing shampoo caused by by-product Isosorbide-5-Nitrae-dioxanes, this hair
It is bright that a kind of amino acid transparent hair shampoo and preparation method without dioxane and silica are provided.
The purpose of the present invention will be realized by following technical method：A kind of amino acid without dioxane and silica is transparent to be washed
Hair-care shampoo, including guar hydroxypropyltrimonium ammonium chloride, palmitamide trimonium chloride, amino acid surface activity
Agent, amino acid conditioner, acidity agent, moisturizer, thickener, nonionic surfactant, preservative, essence and water.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, based on mass fraction, institute
State guar hydroxypropyltrimonium ammonium chloride 0.1~0.5%, palmitamide trimonium chloride 0.5~1.5%, amino
Acid surfaces activating agent 30~40%, amino acid conditioner 1~2%, acidity agent 0.5~1%, moisturizer 2~3%, thickener 0.5
~1%, nonionic surfactant 15~20, preservative 0~1%, essence 0~0.5%, remaining as water.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the amino acid surface
Activating agent includes Hamposyl L, cocoyl amino acid sodium, ceteth -20, N-methyltaurine sodium, taurine, day
Winter propylhomoserin and dipropylene glycol.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the amino acid conditioning
Agent includes cocoyl amino acid sodium, N-methyltaurine sodium, PEG-120 methyls dioleate, ceteth -20, ox
Sulfonic acid, aspartic acid, alanine, arginine, dipropylene glycol and sodium benzoate.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the acidity agent are lemon
Lemon acid.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the moisturizer are tea
The mass ratio of seed oil and ethoxy urea, tea-seed oil and ethoxy urea is 1：10.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the thickener are first
Base glucoside polyoxyethylene (120) ether dioleate.
Preferably, a kind of amino acid transparent hair shampoo without dioxane and silica, the non-ionic surface
Activating agent is alkyl glycosides and cocamidopropyl propyl amide hydroxy sulfo lycine, alkyl glycosides and cocamidopropyl propyl amide hydroxy sulfo lycine
Mass ratio be 9：7.
A kind of preparation method of the amino acid transparent hair shampoo without dioxane and silica, weighs pure water and is placed in beaker
In, guar hydroxypropyltrimonium ammonium chloride is added and is uniformly dispersed, heats while stirring, acidity agent is added, until completely molten
Solution adds amino acid surfactant at clear solution, and stirring makes it completely dissolved, and is then warming up to 90 DEG C, sequentially adds
Tea-seed oil, thickener, palmitamide trimonium chloride and amino acid conditioner, insulated and stirred 90 minutes, until completely molten
When being cooled to 60 DEG C, nonionic surfactant is added at starting to cool down after clear solution in solution, when being cooled to 50 DEG C, adds successively
Enter ethoxy urea, preservative and essence, stirs evenly.
Compared with prior art, the present invention has following advantageous effect：The present invention uses sarcosine lipoid surface-active
Agent not only has good biological degradability and mildness, but also substantially increase cosmetics to human body itself as major ingredient
Safety.In addition, flesh amino acid lipoid table lives in having assigns fat agent performance well, because without separately adding the conditioners such as silica
And has flushing compliance.For existing shampoo, shampoo color and luster of the present invention it is sparkling and crystal-clear it is bright, environment is friendly
It is good, there is more preferable safety, higher usage experience sense.
Specific implementation mode
To more fully understand the present invention, further specific elaboration is made to the present invention below by following embodiment, but not
Limitation of the invention is can be regarded as, some are nonessential according to made by foregoing invention content for those skilled in the art
It improves and adjusts, be also considered as being within the scope of the present invention.
Embodiment 1
A kind of amino acid transparent hair shampoo without dioxane and silica, including guar hydroxypropyltrimonium chlorination
Amine, palmitamide trimonium chloride, amino acid surfactant, amino acid conditioner, acidity agent, moisturizer, thickening
Agent, nonionic surfactant, preservative, essence and water, the mass fraction such as following table of component：
The amino acid surfactant include Hamposyl L, cocoyl amino acid sodium, ceteth -20,
N-methyltaurine sodium, taurine, aspartic acid and dipropylene glycol.
The amino acid conditioner includes cocoyl amino acid sodium, N-methyltaurine sodium, two oil of PEG-120 methyls
Acid esters, ceteth -20, taurine, aspartic acid, alanine, arginine, dipropylene glycol and sodium benzoate.
The acidity agent is citric acid.
The moisturizer is tea-seed oil and ethoxy urea, and the mass fraction of tea-seed oil is 0.2%, the quality point of ethoxy urea
Number is 2%.
The thickener is methyl glucoside polyoxyethylene (120) ether dioleate.
The nonionic surfactant is alkyl glycosides and cocamidopropyl propyl amide hydroxy sulfo lycine, the matter of alkyl glycosides
Score 9% is measured, the mass fraction of cocamidopropyl propyl amide hydroxy sulfo lycine is 7%.
A kind of preparation method of the amino acid transparent hair shampoo without dioxane and silica, weighs pure water and is placed in beaker
In, guar hydroxypropyltrimonium ammonium chloride is added and is uniformly dispersed, heats while stirring, acidity agent is added, until completely molten
Solution adds amino acid surfactant at clear solution, and stirring makes it completely dissolved, and is then warming up to 90 DEG C, sequentially adds
Tea-seed oil, thickener, palmitamide trimonium chloride and amino acid conditioner, insulated and stirred 90 minutes, until completely molten
When being cooled to 60 DEG C, nonionic surfactant is added at starting to cool down after clear solution in solution, when being cooled to 50 DEG C, adds successively
Enter ethoxy urea, preservative and essence, stirs evenly.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (9)
1. a kind of amino acid transparent hair shampoo without dioxane and silica, it is characterised in that：Including guar gum hydroxypropyl three
Methyl chloride amine, palmitamide trimonium chloride, amino acid surfactant, amino acid conditioner, acidity agent, moisturizing
Agent, thickener, nonionic surfactant, preservative, essence and water.
2. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
Based on mass fraction, the guar hydroxypropyltrimonium ammonium chloride 0.1~0.5%, palmitamide trimonium chloride
0.5~1.5%, amino acid surfactant 30~40%, amino acid conditioner 1~2%, acidity agent 0.5~1%, moisturizer 2
~3%, thickener 0.5~1%, nonionic surfactant 15~20, preservative 0~1%, essence 0~0.5%, remaining as
Water.
3. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The amino acid surfactant includes Hamposyl L, cocoyl amino acid sodium, ceteth -20, methyl ox sulphur
Sour sodium, taurine, aspartic acid and dipropylene glycol.
4. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The amino acid conditioner includes cocoyl amino acid sodium, N-methyltaurine sodium, PEG-120 methyls dioleate, whale
Ceryl alcohol polyethers -20, taurine, aspartic acid, alanine, arginine, dipropylene glycol and sodium benzoate.
5. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The acidity agent is citric acid.
6. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The moisturizer is tea-seed oil and ethoxy urea, and the mass ratio of tea-seed oil and ethoxy urea is 1：10.
7. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The thickener is methyl glucoside polyoxyethylene (120) ether dioleate.
8. a kind of amino acid transparent hair shampoo without dioxane and silica according to claim 1, it is characterised in that：
The nonionic surfactant is alkyl glycosides and cocamidopropyl propyl amide hydroxy sulfo lycine, alkyl glycosides and coconut oleoyl amine third
The mass ratio of base hydroxy sulfo lycine is 9：7.
9. a kind of preparation method of amino acid transparent hair shampoo without dioxane and silica according to claim 1,
It is characterized in that：It weighs pure water to be placed in beaker, guar hydroxypropyltrimonium ammonium chloride is added and is uniformly dispersed, in heating
Acidity agent is added in stirring, until being completely dissolved into clear solution, adds amino acid surfactant, stirring keeps it completely molten
Solution, is then warming up to 90 DEG C, sequentially adds tea-seed oil, thickener, palmitamide trimonium chloride and amino acid conditioning
When being cooled to 60 DEG C, non-ionic surface is added until starting to cool down after being completely dissolved into clear solution in agent, insulated and stirred 90 minutes
Activating agent when being cooled to 50 DEG C, sequentially adds ethoxy urea, preservative and essence, stirs evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810718612.2A CN108653027A (en) | 2018-07-03 | 2018-07-03 | A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810718612.2A CN108653027A (en) | 2018-07-03 | 2018-07-03 | A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108653027A true CN108653027A (en) | 2018-10-16 |
Family
ID=63772740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810718612.2A Pending CN108653027A (en) | 2018-07-03 | 2018-07-03 | A kind of amino acid transparent hair shampoo and preparation method without dioxane and silica |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108653027A (en) |
Citations (9)
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|---|---|---|---|---|
| CN102552069A (en) * | 2011-12-31 | 2012-07-11 | 广州市浪奇实业股份有限公司 | Bath foam |
| CN102885740A (en) * | 2012-10-22 | 2013-01-23 | 广州立白企业集团有限公司 | Hair cleanser containing no dioxane residue and preparation method of hair cleanser |
| CN103356408A (en) * | 2013-08-06 | 2013-10-23 | 珀莱雅化妆品股份有限公司 | Conditioning shampoo composition free of sulfates and dioxan |
| CN103381137A (en) * | 2013-07-31 | 2013-11-06 | 朱耀灯 | Natural softening moisturizing shampoo composition |
| CN105997553A (en) * | 2016-07-22 | 2016-10-12 | 广州百孚润化工有限公司 | Liquid shampoo containing amino acid surfactant and preparation method thereof |
| CN106420461A (en) * | 2016-10-12 | 2017-02-22 | 广州丹奇日用化工厂有限公司 | Application of herbal extract composition in liquid shampoo with function of scalp nursing |
| CN106580726A (en) * | 2016-11-11 | 2017-04-26 | 珠海伊斯佳科技股份有限公司 | Silicone-oil-free liquid shampoo containing amino acid and preparation method of silicone-oil-free liquid shampoo |
| CN106726919A (en) * | 2016-12-16 | 2017-05-31 | 广东宝贝儿婴童用品股份有限公司 | A kind of infant's amino acid herb composition and its preparation without diox |
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-
2018
- 2018-07-03 CN CN201810718612.2A patent/CN108653027A/en active Pending
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| CN103381137A (en) * | 2013-07-31 | 2013-11-06 | 朱耀灯 | Natural softening moisturizing shampoo composition |
| CN103356408A (en) * | 2013-08-06 | 2013-10-23 | 珀莱雅化妆品股份有限公司 | Conditioning shampoo composition free of sulfates and dioxan |
| CN105997553A (en) * | 2016-07-22 | 2016-10-12 | 广州百孚润化工有限公司 | Liquid shampoo containing amino acid surfactant and preparation method thereof |
| CN106420461A (en) * | 2016-10-12 | 2017-02-22 | 广州丹奇日用化工厂有限公司 | Application of herbal extract composition in liquid shampoo with function of scalp nursing |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20181016 |