CN108638251A - 一种木质工艺品的处理方法 - Google Patents

一种木质工艺品的处理方法 Download PDF

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CN108638251A
CN108638251A CN201810441424.XA CN201810441424A CN108638251A CN 108638251 A CN108638251 A CN 108638251A CN 201810441424 A CN201810441424 A CN 201810441424A CN 108638251 A CN108638251 A CN 108638251A
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wood artwork
processing method
wood
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solution
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高恒东
胡佳佳
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Wuhu Chuangyuan New Materials Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/08—Impregnating by pressure, e.g. vacuum impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16—Inorganic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/026—Wholly aromatic polyamines
    • C08G73/0266—Polyanilines or derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/20—Removing fungi, molds or insects

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

本发明公开了一种木质工艺品的处理方法，先将木质工艺品进入苯胺的氨水溶液中，通过真空加压浸渍使苯胺渗透到木质工艺品内部，然后加入过硫酸铵溶液，通过苯胺单体反应在木质工艺品内部原位生成聚苯胺，再将木质工艺品先在硝酸银溶液中浸渍处理，然后在葡萄糖溶液中浸渍处理，将纳米银负载在木质工艺品内部，最后将木质工艺品取出并洗涤、烘干，得到成品。本发明处理方法处理后的木质工艺品不仅具有优良的防腐、抗裂、抗形变性能，长期使用稳定性好，而且能很好地保留木质工艺品原有的外观特性，绿色安全。

Description

一种木质工艺品的处理方法
技术领域
本发明涉及工艺品处理技术领域，尤其涉及一种木质工艺品的处理方法。
背景技术
木质工艺品是以各种木头（包括各种竹类）为主要原料，采用人工制作或者是机器制作而成，具有较高的使用价值和艺术价值，备受广大消费者的欢迎。但是，用于制作木质工艺品的原料木材极易受到菌类的侵染而发生腐朽，使木质工艺品发生损坏。而且，木材的稳定性不强，容易受到外界环境温湿度等条件影响而发生形变、开裂，导致质量下降。为了保证木质工艺品的品质，延长木质工艺品的使用寿命，在使用前对其进行适当的处理至关重要。
目前，对木质工艺品进行处理的方法主要是采用化学药剂进行浸渍，使化学药剂渗透进木材内部，防止生物侵入，这种方法虽然能起到一定的防腐作用，但是不能阻止水汽的渗入，提高木质工艺品长期使用稳定性的作用不足，而且化学药剂的存在会对环境以及人体健康产生潜在的威胁。在木质工艺品表面涂刷涂料虽然能起到防腐抗渗的作用，但是其对工艺品的外观影响较大，不利于保留工艺品原有的外观特性，并且其作用大多停留在表层，对木材内部因此引起的腐坏改善效果不佳。因此，有必要开发既能兼顾木质工艺品防腐、抗裂、抗形变、提高长期使用稳定性的需求，又能较大限度地保留木质工艺品原有外观特性，而且绿色安全的处理方法。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种木质工艺品的处理方法，该方法处理后的工艺品不仅具有优良的防腐、抗裂、抗形变性能，长期使用稳定性好，而且能很好地保留木质工艺品原有的外观特性，绿色安全。
本发明是通过以下技术方案实现的：
一种木质工艺品的处理方法，包括以下步骤：
（1）先向氨水溶液中加入相当于氨水溶液重量1-2%的苯胺单体混合均匀得到混合液，将成型的木质工艺品浸入所述混合液中真空加压浸渍1-2h，然后向混合液中加入相当于所述混合液体积5-10%的过硫酸铵溶液，搅拌均匀后于25-30℃常压浸渍12-24h，再将木质工艺品取出并洗涤、干燥处理；
（2）将步骤（1）处理后的木质工艺品先在硝酸银溶液中浸渍处理12-24h，然后在葡萄糖溶液中浸渍处理0.5-1h，取出后洗涤除去表面杂质，然后烘干，得到成品。
所述的氨水溶液浓度为0.1-0.15mol/L。
所述的过硫酸铵溶液浓度为10-15%。
所述步骤（1）中真空加压浸渍的真空度为0.085-0.095MPa，压力为0.5-1MPa。
所述的硝酸银溶液浓度为0.05-0.1mol/L。
所述葡萄糖溶液的浓度为0.01-0.1mol/L。
所述步骤（2）中在葡萄糖溶液中浸渍处理的温度为30-40℃。
本发明的优点是：
本发明先将木质工艺品浸入苯胺的氨水溶液中，通过真空加压浸渍使苯胺渗透到木质工艺品内部，然后加入过硫酸铵溶液作为氧化剂，通过苯胺单体反应在木质工艺品内部原位生成聚苯胺，再将木质工艺品先在硝酸银溶液中浸渍处理，利用聚苯胺对银离子的络合效应，在木质工艺品内部负载银离子，然后在葡萄糖溶液中浸渍处理，以葡萄糖为还原剂，将木质工艺品内部负载的银离子还原成纳米银，最后将木质工艺品取出并洗涤、烘干，得到成品。本发明通过在木质工艺品内部原位结合聚苯胺，既能提高木质工艺品的化学稳定性，减少外界环境对木质工艺品的侵蚀，使木质工艺品不易发生开裂、形变，又能通过络合以及还原反应，使纳米银稳定、牢固地结合在木质工艺品内部，从而提高木质工艺品的长期抗菌防腐性能，延长木质工艺品的使用寿命。本发明处理方法处理后的木质工艺品不仅具有优良的防腐、抗裂、抗形变性能，长期使用稳定性好，而且能很好地保留木质工艺品原有的外观特性，绿色安全。
具体实施方式
一种木质工艺品的处理方法，包括以下步骤：
（1）先向氨水溶液中加入相当于氨水溶液重量1%的苯胺单体混合均匀得到混合液，将成型的木质工艺品浸入所述混合液中真空加压浸渍1h，然后向混合液中加入相当于所述混合液体积5%的过硫酸铵溶液，搅拌均匀后于25℃常压浸渍12-24h，再将木质工艺品取出并洗涤、干燥处理；
（2）将步骤（1）处理后的木质工艺品先在硝酸银溶液中浸渍处理12h，然后在葡萄糖溶液中浸渍处理0.5h，取出后洗涤除去表面杂质，然后烘干，得到成品。
所述的氨水溶液浓度为0.1mol/L。
所述的过硫酸铵溶液浓度为10-15%。
所述步骤（1）中真空加压浸渍的真空度为0.085MPa，压力为0.5MPa。
所述的硝酸银溶液浓度为0.05mol/L。
所述葡萄糖溶液的浓度为0.01mol/L。
所述步骤（2）中在葡萄糖溶液中浸渍处理的温度为30℃。

Claims (7)

1.一种木质工艺品的处理方法，其特征在于，包括以下步骤：
（1）先向氨水溶液中加入相当于氨水溶液重量1-2%的苯胺单体混合均匀得到混合液，将成型的木质工艺品浸入所述混合液中真空加压浸渍1-2h，然后向混合液中加入相当于所述混合液体积5-10%的过硫酸铵溶液，搅拌均匀后于25-30℃常压浸渍12-24h，再将木质工艺品取出并洗涤、干燥处理；
（2）将步骤（1）处理后的木质工艺品先在硝酸银溶液中浸渍处理12-24h，然后在葡萄糖溶液中浸渍处理0.5-1h，取出后洗涤除去表面杂质，然后烘干，得到成品。
2.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述的氨水溶液浓度为0.1-0.15mol/L。
3.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述的过硫酸铵溶液浓度为10-15%。
4.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述步骤（1）中真空加压浸渍的真空度为0.085-0.095MPa，压力为0.5-1MPa。
5.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述的硝酸银溶液浓度为0.05-0.1mol/L。
6.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述葡萄糖溶液的浓度为0.01-0.05mol/L。
7.根据权利要求1所述的一种木质工艺品的处理方法，其特征在于，所述步骤（2）中在葡萄糖溶液中浸渍处理的温度为30-40℃。
CN201810441424.XA 2018-05-10 2018-05-10 一种木质工艺品的处理方法 Pending CN108638251A (zh)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110253703A (zh) * 2019-05-07 2019-09-20 杭州电子科技大学 一种高强度抑菌木材的制备方法及高强度抑菌木材
CN112195649A (zh) * 2020-08-28 2021-01-08 福建农林大学 仿生苍耳型抗菌抗病毒植物纤维的制备方法和应用
US20220081848A1 (en) * 2019-01-23 2022-03-17 Hunan Taohuajiang Bamboo Science & Technology Co., Ltd. One-step integrally-formed bamboo sleeper and preparation method thereof
US20220098799A1 (en) * 2019-01-23 2022-03-31 Hunan Taohuajiang Bamboo Science & Technology Co., Ltd. Assembled bamboo sleeper and preparation method thereof
CN116061278A (zh) * 2022-11-24 2023-05-05 湖北萨莱玛木结构工程有限公司 一种建筑木质结构的胀缩控制设备

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103978524A (zh) * 2014-05-04 2014-08-13 南京林业大学 具有电磁屏蔽功能的人造板及其制造方法
CN104452309A (zh) * 2014-12-31 2015-03-25 东华大学 一种利用聚苯胺引发化学镀银的导电织物的制备方法
CN106217542A (zh) * 2016-08-16 2016-12-14 北京林业大学 环保长效型纳米银基木竹材抗菌防霉剂及其制备方法与应用

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103978524A (zh) * 2014-05-04 2014-08-13 南京林业大学 具有电磁屏蔽功能的人造板及其制造方法
CN104452309A (zh) * 2014-12-31 2015-03-25 东华大学 一种利用聚苯胺引发化学镀银的导电织物的制备方法
CN106217542A (zh) * 2016-08-16 2016-12-14 北京林业大学 环保长效型纳米银基木竹材抗菌防霉剂及其制备方法与应用

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220081848A1 (en) * 2019-01-23 2022-03-17 Hunan Taohuajiang Bamboo Science & Technology Co., Ltd. One-step integrally-formed bamboo sleeper and preparation method thereof
US20220098799A1 (en) * 2019-01-23 2022-03-31 Hunan Taohuajiang Bamboo Science & Technology Co., Ltd. Assembled bamboo sleeper and preparation method thereof
CN110253703A (zh) * 2019-05-07 2019-09-20 杭州电子科技大学 一种高强度抑菌木材的制备方法及高强度抑菌木材
CN112195649A (zh) * 2020-08-28 2021-01-08 福建农林大学 仿生苍耳型抗菌抗病毒植物纤维的制备方法和应用
CN112195649B (zh) * 2020-08-28 2021-10-22 福建农林大学 仿生苍耳型抗菌抗病毒植物纤维的制备方法和应用
CN116061278A (zh) * 2022-11-24 2023-05-05 湖北萨莱玛木结构工程有限公司 一种建筑木质结构的胀缩控制设备

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