CN108624150A - A kind of fluorescence falsification preventing coding ink - Google Patents
A kind of fluorescence falsification preventing coding ink Download PDFInfo
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- CN108624150A CN108624150A CN201710173979.6A CN201710173979A CN108624150A CN 108624150 A CN108624150 A CN 108624150A CN 201710173979 A CN201710173979 A CN 201710173979A CN 108624150 A CN108624150 A CN 108624150A
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- parts
- ink
- fluorescence
- falsification preventing
- fluorescence falsification
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Ink Jet (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Fluorescence falsification preventing coding ink provided by the invention, in terms of parts by weight, including following components:0.1~0.7 part of 5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, 70~80 parts of organic solvent, 10 0.1~0.5 part of polyoxethylene octylphenyl phenol ether and N methyl pyrrolidones;The solvent type fluorescent dye is orange red selected from fluorescence, one or more in fluorescein and phloxine.Under the synergistic effect of component of the fluorescence falsification preventing coding ink provided by the invention in above-mentioned certain content so that apparent ink is orange-yellow, and is orange fluorescence under ultra violet lamp;Apparent ink is orange red, and is orange red fluorescence under ultra violet lamp, realizes concealed fluorescent ink and the apparent combination for having type ink, therefore, the antiforge function of the fluorescence falsification preventing coding ink is preferable.
Description
Technical field
The present invention relates to coding technical field of ink more particularly to a kind of fluorescence falsification preventing coding inks.
Background technology
Ink jet numbering machine ink be it is a kind of can be sprayed from the nozzle of ink-jet printer, sprayed as required by means of electric field force effect
The liquid ink of pictograph is generated on to stock surface.It is a kind of exigent ink special, it must stablize, nothing
Poison, nonchoking nozzle, moisture retention and sprayable property will be got well, to the corrosion-free effect of the metal objects such as nozzle, nonflammable and colour fading
Deng.Ink jet numbering machine ink kind is various, and the purposes of various inks differs.For example, high adhesion force ink, ink color be mostly black and
Blue, for plastics, metal, food plastic outer packing;Anti- gasoline ink, black ink, coding content contact gasoline or alcohol
Afterwards, good adhesive force is kept, automobile fitting coding is chiefly used in;Anti-fake invisible ink provides the stealth especially helped for product false proof
Ink effectively reaches the anti-counterfeit anti-changing requirement of luxury food and brewing industry, under special light sources (such as ultraviolet, UV lamp)
As it can be seen that ink color is mostly blue, red.
Currently, existing anti-fake coding ink is stealthy blue and red two kinds stealthy in the market, two kinds of inks are only in purple
The irradiation of outer lamp just sends out fluorescence, the basic identification of naked eyes less than, most commonly used in the market is stealthy blue, such as Chinese cigarette,
Most clients do not know the anti-fake coding ink of Chinese cigarette at all, less know have it is anti-fake.Most clients' " turning a blind eye to ", add
Upper propaganda strength is inadequate, and most clients is caused not know whether oneself inhale Chinese cigarette true and false at all.Therefore, existing anti-fake
The antiforge function of coding ink is poor.
Invention content
In view of this, the purpose of the present invention is to provide a kind of fluorescence falsification preventing coding ink, the fluorescence falsification preventing coding ink
Concealed fluorescent and apparent have type combination, antiforge function preferable.
The present invention provides a kind of fluorescence falsification preventing coding inks, in terms of parts by weight, including following components:
It is 5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, organic
0.1~0.7 part of 70~80 parts of solvent, -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether and N-Methyl pyrrolidone;
The solvent type fluorescent dye is orange red selected from fluorescence, one or more in fluorescein and phloxine.
Preferably, the viscosity of the fluorescence falsification preventing coding ink is 5~20S/25 DEG C.
Preferably, the fineness of the fluorescence falsification preventing coding ink is 5 μm or less.
Preferably, the organic solvent is selected from ketones solvent.
Preferably, the ketones solvent is one or more in acetone, butanone and cyclohexanone.
Fluorescence falsification preventing coding ink provided by the invention, in terms of parts by weight, including following components:5~10 parts of nitrocotton,
5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, 70~80 parts of organic solvent, polyoxyethylene
0.1~0.7 part of -10 0.1~0.5 parts of octyl phenol ether and N-Methyl pyrrolidone;The solvent type fluorescent dye is selected from fluorescence
It is one or more in orange red, fluorescein and phloxine.Fluorescence falsification preventing coding ink provided by the invention specific contains above-mentioned
Under the synergistic effect of the component of amount so that apparent ink is orange-yellow, and is orange fluorescence under ultra violet lamp;Ink is apparent
To be orange red, and it is orange red fluorescence under ultra violet lamp, realizes concealed fluorescent ink and the apparent organic knot for having type ink
It closes, therefore, the antiforge function of the fluorescence falsification preventing coding ink is preferable.
Specific implementation mode
The present invention provides a kind of fluorescence falsification preventing coding inks, in terms of parts by weight, including following components:
It is 5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, organic
0.1~0.7 part of 70~80 parts of solvent, -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether and N-Methyl pyrrolidone;
The solvent type fluorescent dye is orange red selected from fluorescence, one or more in fluorescein and phloxine.
Under the synergistic effect of component of the fluorescence falsification preventing coding ink provided by the invention in above-mentioned certain content so that ink
Apparent is orange-yellow, and is orange fluorescence under ultra violet lamp;Apparent ink is orange red, and is orange under ultra violet lamp
Red fluorescence realizes concealed fluorescent ink and the apparent combination for having type ink, and therefore, which prevents
Pseudo- function is preferable.
Fluorescence falsification preventing coding ink provided by the invention is in terms of parts by weight, including 5~10 parts of nitrocotton, and preferably 5.5
~9.5 parts.In the present invention, the nitrogen content of the nitrocotton is preferably 99%.The present invention does not have the source of the nitrocotton
Special limitation such as uses its commercial goods using nitrocotton well known to those skilled in the art.In the specific of the present invention
In embodiment, the nitrocotton purchase is in Hengshui Jian Min celluloses Co., Ltd.
Fluorescence falsification preventing coding ink provided by the invention includes 5~10 parts of epoxy resin, preferably 5.3~9.7 parts.At this
In invention, the appearance of the epoxy resin is transparency liquid, without apparent mechanical admixture;210~244g/eq of epoxide equivalent;Softening
15~23 DEG C of point;6~10Pa.S/25 DEG C of viscosity;Easy saponification chlorine≤0.5%;Inorganic chlorine≤200ppm;Fugitive constituent≤1.0%;Color
Pool number≤3.The present invention does not have the source of the epoxy resin special limitation, using epoxy well known to those skilled in the art
Resin such as uses its commercial goods.In a specific embodiment of the present invention, the epoxy resin purchase is in Wuxi Qian Guanghua
Work Co., Ltd.
Fluorescence falsification preventing coding ink provided by the invention includes 5~10 parts of solvent type fluorescent dye, and preferably 5.2~9.6
Part.In the present invention, the solvent type fluorescent dye is orange red selected from fluorescence, one or more in fluorescein and phloxine.
The present invention does not have special limitation to the source of the solvent type fluorescent dye, using above-mentioned kind well known to those skilled in the art
The solvent type fluorescent dye of class, such as may be used its commercial goods.In a specific embodiment of the present invention, the solvent type
Fluorescent dye is bought in Hunan Chemical Co., Ltd. of Golden Bridge.
Fluorescence falsification preventing coding ink provided by the invention includes 1~2 part of fluorescent powder, preferably 1.1~1.9 parts.In this hair
In bright, the fluorescent powder is preferably selected from one or more in anti-fake fluorescent powder on sale in the market.The present invention is to the fluorescence
The source of powder does not have special limitation, using the fluorescent powder of mentioned kind well known to those skilled in the art, can such as adopt
With its commercial goods.In a specific embodiment of the present invention, the fluorescent powder produces for Beijing indigo europium Fine Chemical Works.
Fluorescence falsification preventing coding ink provided by the invention includes 70~80 parts of organic solvent, preferably 71~78 parts.At this
In invention, the organic solvent is preferably selected from ketones solvent;It is highly preferred that the ketones solvent is selected from acetone, butanone and hexamethylene
It is one or more in ketone.The present invention does not have the source of the organic solvent special limitation, using those skilled in the art
Its commercial goods such as may be used in the organic solvent of well known mentioned kind.
Fluorescence falsification preventing coding ink provided by the invention includes -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether, preferably
It is 0.13~0.47 part.The present invention does not have special limitation to the source of the polyoxethylene octylphenyl phenol ether -10, using ability
The polyoxethylene octylphenyl phenol ether -10 of mentioned kind known to field technique personnel, such as may be used its commercial goods.At this
In the specific embodiment of invention, the purchase of polyoxethylene octylphenyl phenol ether -10 is in Jiangsu Province Hai'an Chemical Co., Ltd..
Fluorescence falsification preventing coding ink provided by the invention includes 0.1~0.7 part of N-Methyl pyrrolidone, preferably 0.13~
0.67 part.The present invention does not have the source of the N-Methyl pyrrolidone special limitation, using known to those skilled in the art
Mentioned kind N-Methyl pyrrolidone, its commercial goods such as may be used.In a specific embodiment of the present invention, institute
N-Methyl pyrrolidone purchase is stated in Wan Qi Chemical Co., Ltd.s.
In the present invention, the viscosity of the fluorescence falsification preventing coding ink is preferably 5~20S/25 DEG C.The fluorescence falsification preventing spray
The fineness of code ink is preferably 5 μm or less.
In the present invention, the preparation method of the fluorescence falsification preventing coding ink is preferably made according to the following steps:
By 5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, have
0.1~0.7 part of 70~80 parts of solvent, -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether and N-Methyl pyrrolidone are mixed
It closes, rolls and grind, obtain fluorescence falsification preventing coding ink.
In the present invention, the temperature of the mixing is preferably 25~40 DEG C;The time of the mixing is preferably 10~
30min.In the present invention, the temperature ground of rolling is preferably 25~50 DEG C.
Fluorescence falsification preventing coding ink provided by the invention, in terms of parts by weight, including following components:5~10 parts of nitrocotton,
5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, 70~80 parts of organic solvent, polyoxyethylene
0.1~0.7 part of -10 0.1~0.5 parts of octyl phenol ether and N-Methyl pyrrolidone;The solvent type fluorescent dye is selected from fluorescence
It is one or more in orange red, fluorescein and phloxine.Fluorescence falsification preventing coding ink provided by the invention specific contains above-mentioned
Under the synergistic effect of the component of amount so that apparent ink is orange-yellow, and is orange fluorescence under ultra violet lamp;Ink is apparent
To be orange red, and it is orange red fluorescence under ultra violet lamp, realizes concealed fluorescent ink and the apparent organic knot for having type ink
It closes, therefore, the antiforge function of the fluorescence falsification preventing coding ink is preferable.
In order to further illustrate the present invention, with reference to embodiment to a kind of fluorescence falsification preventing coding ink provided by the invention
It is described in detail, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
By 5 parts of nitrocotton, 10 parts of epoxy resin, fluorescence is 7 parts orange red, 1 part of fluorescent powder, 70 parts of butanone, polyoxethylene octylphenyl
0.1 part of 0.4 part of phenol ether -10 and N-Methyl pyrrolidone mix 20min at 30 DEG C, roll and grind at 45 DEG C, obtain fluorescence falsification preventing
Coding ink.
Fluorescence falsification preventing coding ink prepared by the embodiment of the present invention 1 is apparent to be orange red, is orange red under ultra violet lamp
Color fluorescence, realizes concealed fluorescent and the apparent combination for having type, and antiforge function is higher.
Embodiment 2
By 8 parts of nitrocotton, 5 parts of epoxy resin, 10 parts of fluorescein, 2 parts of fluorescent powder, 75 parts of butanone, polyoxethylene octylphenyl benzene
0.7 part of 0.5 part of phenolic ether -10 and N-Methyl pyrrolidone mix 30min at 35 DEG C, roll and grind at 40 DEG C, obtain fluorescence falsification preventing spray
Code ink.
Fluorescence falsification preventing coding ink prepared by the embodiment of the present invention 2 is apparent to be orange-yellow, is orange under ultra violet lamp
Color fluorescence, realizes concealed fluorescent and the apparent combination for having type, and antiforge function is higher.
Embodiment 3
10 parts of nitrocotton, 7 parts of epoxy resin, 5 parts of phloxine, 1.5 parts of fluorescent powder, 80 parts of butanone, polyoxyethylene is pungent
0.4 part of 0.15 part of alkylphenol ether -10 and N-Methyl pyrrolidone mix 10min at 40 DEG C, roll and grind at 30 DEG C, obtain fluorescence
Anti-fake coding ink.
Fluorescence falsification preventing coding ink prepared by the embodiment of the present invention 3 is apparent to be orange red, is orange red under ultra violet lamp
Color fluorescence, realizes concealed fluorescent and the apparent combination for having type, and antiforge function is higher.
As seen from the above embodiment, fluorescence falsification preventing coding ink provided by the invention, in terms of parts by weight, including with the following group
Point:5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, organic solvent
0.1~0.7 part of 70~80 parts, -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether and N-Methyl pyrrolidone;The solvent
Type fluorescent dye is orange red selected from fluorescence, one or more in fluorescein and phloxine.Fluorescence falsification preventing spray provided by the invention
Code ink is under the synergistic effect of the component of above-mentioned certain content so that apparent ink is orange-yellow, and under ultra violet lamp
For orange fluorescence;Apparent ink is orange red, and is orange red fluorescence under ultra violet lamp, realizes concealed fluorescent ink and table
Seeing has the combination of type ink, and therefore, the antiforge function of the fluorescence falsification preventing coding ink is preferable.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of fluorescence falsification preventing coding ink, in terms of parts by weight, including following components:
5~10 parts of nitrocotton, 5~10 parts of epoxy resin, 5~10 parts of solvent type fluorescent dye, 1~2 part of fluorescent powder, organic solvent
0.1~0.7 part of 70~80 parts, -10 0.1~0.5 parts of polyoxethylene octylphenyl phenol ether and N-Methyl pyrrolidone;
The solvent type fluorescent dye is selected from the one or more of orange red fluorescence, fluorescein and phloxine.
2. fluorescence falsification preventing coding ink according to claim 1, which is characterized in that the fluorescence falsification preventing coding ink glues
Degree is 5~20S/25 DEG C.
3. fluorescence falsification preventing coding ink according to claim 1, which is characterized in that the fluorescence falsification preventing coding ink it is thin
Degree is 5 μm or less.
4. fluorescence falsification preventing coding ink according to claim 1, which is characterized in that it is molten that the organic solvent is selected from ketone
Agent.
5. fluorescence falsification preventing coding ink according to claim 4, which is characterized in that the ketones solvent is selected from acetone, fourth
It is one or more in ketone and cyclohexanone.
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CN201710173979.6A CN108624150A (en) | 2017-03-22 | 2017-03-22 | A kind of fluorescence falsification preventing coding ink |
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CN201710173979.6A CN108624150A (en) | 2017-03-22 | 2017-03-22 | A kind of fluorescence falsification preventing coding ink |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113549373A (en) * | 2021-06-24 | 2021-10-26 | 无锡佰广包装材料有限公司 | Novel label anti-counterfeiting technology |
Citations (2)
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---|---|---|---|---|
CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
CN106366763A (en) * | 2016-06-17 | 2017-02-01 | 临泉县亚泰包装有限公司 | Production method of anti-counterfeiting ink used for carton printing |
-
2017
- 2017-03-22 CN CN201710173979.6A patent/CN108624150A/en not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103396699A (en) * | 2013-07-30 | 2013-11-20 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
CN106366763A (en) * | 2016-06-17 | 2017-02-01 | 临泉县亚泰包装有限公司 | Production method of anti-counterfeiting ink used for carton printing |
Non-Patent Citations (1)
Title |
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张天胜: "《表面活性剂应用技术》", 30 September 2001, 化学工业出版社 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113549373A (en) * | 2021-06-24 | 2021-10-26 | 无锡佰广包装材料有限公司 | Novel label anti-counterfeiting technology |
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Application publication date: 20181009 |