CN106905758A - A kind of fluorescence stamp-pad ink and preparation method thereof - Google Patents
A kind of fluorescence stamp-pad ink and preparation method thereof Download PDFInfo
- Publication number
- CN106905758A CN106905758A CN201511025811.8A CN201511025811A CN106905758A CN 106905758 A CN106905758 A CN 106905758A CN 201511025811 A CN201511025811 A CN 201511025811A CN 106905758 A CN106905758 A CN 106905758A
- Authority
- CN
- China
- Prior art keywords
- fluorescent material
- stamp
- pad ink
- self
- fluorescence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of fluorescence stamp-pad ink, by weight percentage including following component：Self-control fluorescent material 0.15~1.9%, solvent 70~83%, ketone resin 16~29%, the self-control fluorescent material are obtained by following methods：By rare earth make a mistake salt, alkali and part 2,6-DHBA reacted in the mixture of water, ethanol or water and ethanol be obtained.The invention also discloses a kind of method for preparing above-mentioned fluorescent ink.Stamp-pad ink of the invention is using the self-control fluorescent material that dissolubility is good, fluorescence intensity is high, formula design is environmentally friendly, not containing benezene and ketones solvent, preparation process is simple, high-efficiency environment friendly, it is easy to use, simple to operate, the water white transparency under trace daylight in transparent plastic film external packing is disguised strong, invention bright green fluorescence under ultraviolet light, differentiability is high, and substantially, homemade fluorescent material improves the difficulty being forged to antifalse effect.
Description
Technical field
The present invention relates to field of anti-counterfeit technology, more particularly to a kind of fluorescence stamp-pad ink and preparation method thereof.
Background technology
With social development, commodity extreme enrichment, all kinds of high-end products such as cigarette, wine and cosmetics are common
Supermarket or scholar be more etc., and small shop can also buy, and be that oneself is sold to mark during Merchant sales this kind of product
Product, generally signed in external packing with ball pen, after preventing consumer from buying back product, filled with secondary
Cause dispute well.This mode is simple, but is easily destroyed commodity external packing, influences attractive in appearance, especially
The commodity given a present, there is the suitable impoliteness of such mark.If a kind of transparent counterfeiting for plastic sheeting
Stamp-pad ink, it is possible to solve this problem.
So far, the anti-counterfeiting stamp ink of document report mainly has Ultraluminescence anti-counterfeit stamping according to false proof core technology
Oil, magnetic anti-counterfeit stamp-pad ink, DNA anti-counterfeiting stamp inks, multiple hidden encryption anti-counterfeiting stamp-pad ink etc., are mainly used in
On the paper materials such as bill, security, certificate, painting and calligraphy, check and file, because the white of paper can be easily
Cover the vestige of various light-colored powders including fluorescent pigment in these formula stamp-pad ink, visual effect is daylight
Under colourless stealth；But in transparent film overwrap, these stamp-pad ink for containing various light-colored powders just show
Shape, there is no the transparent counterfeiting stamp-pad ink Product Report specifically designed for plastic sheeting so far.In the market is existing
Water white transparency anti-counterfeiting stamp ink mainly using the cumarin series of blue light-emitting, is easily copied by people.
The content of the invention
It is good it is an object of the invention to provide a kind of environmental protection, antifalse effect, forge difficulty fluorescence high
Stamp-pad ink.
In order to solve the problems, such as above-mentioned technology, the technical solution adopted by the present invention is：A kind of fluorescence stamp-pad ink,
Include following component by weight percentage：Self-control fluorescent material 0.15~1.9%, solvent 70~83%, keto-aldehyde tree
Fat 16~29%, the self-control fluorescent material is obtained by following methods：Rare earth is made a mistake salt, alkali and part 2,6-
Dihydroxy-benzoic acid reacts in the mixture of water, ethanol or water and ethanol and is obtained.
Used as a preferred embodiment of the present invention, the solvent is glycol monomethyl ether, propane diols list second
Ether and 2- methyl -2, the mixture of 4- pentanediols.
As a preferred embodiment of the present invention, the self-control fluorescent material 0.5%, propylene glycol monomethyl ether
25%th, dihydroxypropane single-ether 38%, 2- methyl -2,4 pentanediols 18.5%, ketone resin 18%.
Present invention also offers a kind of method for preparing above-mentioned fluorescence stamp-pad ink, methods described mainly includes following
Step：Precise solvent, ketone resin, stirring at normal temperature to resin are completely dissolved, then weigh a certain amount of
Fluorescent material add mixed solution, stirring at normal temperature to fluorescent material is completely dissolved.
Stamp-pad ink of the invention is using the self-control fluorescent material that dissolubility is good, fluorescence intensity is high, and formula design is environmentally friendly,
Not containing benezene and ketones solvent, preparation process is simple, high-efficiency environment friendly are easy to use, simple to operate,
Water white transparency under trace daylight in transparent plastic film external packing, it is disguised strong, invent under ultraviolet light bright
Green fluorescence, differentiability is high, and substantially, homemade fluorescent material improves the difficulty being forged to antifalse effect.
Can with plastic film packaging, when helping businessman to sell the relatively valuable product such as cigarette, wine and cosmetics,
In plastic sheeting external packing, unobtrusively position leaves stealthy stamp-pad ink anti-fake mark, had both improved and has evaded fake products dispute
Ability, and do not influence exterior of commodity.
Fluorescence stamp-pad ink of the invention is used for the Plastic film surfaces such as PE, OPP, PET and NY, is formed colourless
Transparent trace, sends brilliant green fluorescence under ultraviolet light.Fluorescent material dissolubility is very good, is only stirring
It is completely dissolved by mixing after several minutes, this brings the imprinting effect of production efficiency higher and the high grade of transparency；
Fluorescent phosphor intensity is high, and only the content less than 2% can make the trace of the stamp-pad ink that bright green is presented
Fluorescent effect.
Specific embodiment
Embodiment 1
Fluorescence stamp-pad ink of the invention, by weight percentage including following component：Self-control fluorescent material (0.5%),
Propylene glycol monomethyl ether (25%), dihydroxypropane single-ether (38%) and 2- methyl -2,4-PD (18.5%)
With ketone resin (18%)；Wherein, self-control fluorescent material is obtained by following methods：Rare earth is made a mistake salt, alkali
Reacted in the mixture of water, ethanol or water and ethanol with part 2,6-DHBA and be obtained.
The preparation method of fluorescence stamp-pad ink of the present invention is as follows：25 parts of propylene glycol monomethyl ethers of precise, 38 part third
2-ethoxyethanol, 18.5 parts of 2- methyl -2,4- pentanediols and 18 parts of ketone resins, stirring at normal temperature are complete to resin
CL, then weigh 0.5 part of self-control fluorescent material addition mixed solution, fluorescent material after stirring at normal temperature several minutes
It is completely dissolved.
Embodiment 2
Fluorescence stamp-pad ink of the invention, by weight percentage including following component：Self-control fluorescent material
(1.5%), propylene glycol monomethyl ether (22%), dihydroxypropane single-ether (36%) and 2- methyl -2,4- penta
Glycol (16.5%) and ketone resin (24%)；Wherein, self-control fluorescent material is obtained by following methods：Will
Rare earth makes a mistake salt, alkali and part 2,6-DHBA in water, ethanol or water and the mixture of ethanol
Middle reaction is obtained.
Preparation method is same as Example 1.
Fluorescent ink of the invention mainly has following characteristics：
(1) water white transparency：Can be used in plastic film packaging plan leading market is for cigarette, wine are sold by businessman
During relatively valuable with cosmetics etc. product, in plastic sheeting external packing, unobtrusively position leaves stealthy stamp-pad ink
Anti-fake mark, had both improved the ability for evading fake products dispute, and did not influenceed exterior of commodity.
(2) antifalse effect is good, forges difficulty high：Using homemade rare-earth luminescent material, can be completely molten
Solution, obtains the stamp-pad ink product of water white transparency, and it is Clear ＆ Transparent in the trace of Plastic film surface, and distribution is equal
It is even it is halo-free open, without anti-viscous phenomenon after fully drying, water white transparency in the sunlight, in ultraviolet long wave 365nm
Lower unstressed configuration is presented brilliant green fluorescence, and brilliant green fluorescence, shortwave is presented in ultraviolet medium wave 302nm
Dirty-green is presented under 254nm, disguised high, the intermediate waves ultraviolet anti-fake fluorescence spectrum of feature improves puppet
Difficulty is made, can be applied to the transparent membrane of the high-end product outer layer such as cigarette, wine and cosmetics carries out false proof, is
Businessman provides evidence of identification, and the ability of fake products dispute is evaded in raising.
(3) feature of environmental protection：Formula design benzene-free ketone-free；Simple production process efficiently, is ground without heating,
Energy-conserving and environment-protective.
The technical scheme for being provided the embodiment of the present invention above is described in detail, used herein
Specific case is set forth to the principle and implementation method of the embodiment of the present invention, and above example is said
It is bright to be only applicable to help the principle for understanding the embodiment of the present invention；Simultaneously for the general technology people of this area
Member, according to the embodiment of the present invention, will change in specific embodiment and range of application,
In sum, this specification content should not be construed as limiting the invention.
Claims (4)
1. a kind of fluorescence stamp-pad ink, it is characterised in that by weight percentage including following component：Self-control fluorescent material
0.15~1.9%, solvent 70~83%, ketone resin 16~29%, the self-control fluorescent material is by following methods system
：Rare earth is made a mistake into salt, alkali and part 2,6-DHBA in the mixed of water, ethanol or water and ethanol
Reacted in compound and be obtained.
2. a kind of fluorescence stamp-pad ink according to claim 1, it is characterised in that：The solvent be glycol monomethyl ether,
Dihydroxypropane single-ether and 2- methyl -2, the mixture of 4- pentanediols.
3. a kind of fluorescence stamp-pad ink according to claim 1 and 2, it is characterised in that include by weight percentage
Following component：It is described self-control fluorescent material 0.5%, propylene glycol monomethyl ether 25%, dihydroxypropane single-ether 38%,
2- methyl -2,4 pentanediols 18.5%, ketone resin 18%.
4. a kind of method of the fluorescence stamp-pad ink prepared as described in claims 1 to 3 any one, it is characterised in that bag
Include following steps：Precise solvent, ketone resin, stirring at normal temperature to resin are completely dissolved, then weigh
A certain amount of fluorescent material adds mixed solution, and stirring at normal temperature to fluorescent material is completely dissolved.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511025811.8A CN106905758B (en) | 2015-12-29 | 2015-12-29 | Fluorescent stamp-pad ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511025811.8A CN106905758B (en) | 2015-12-29 | 2015-12-29 | Fluorescent stamp-pad ink and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106905758A true CN106905758A (en) | 2017-06-30 |
| CN106905758B CN106905758B (en) | 2020-08-18 |
Family
ID=59206274
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511025811.8A Active CN106905758B (en) | 2015-12-29 | 2015-12-29 | Fluorescent stamp-pad ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106905758B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903703A (en) * | 2017-11-24 | 2018-04-13 | 深圳市裕同包装科技股份有限公司 | A kind of colorless and odorless fluorescence stamp-pad ink and its preparation process |
| CN108725002A (en) * | 2017-04-21 | 2018-11-02 | 南京爱丽斯包装有限公司 | A kind of double anti-forge print production technology |
| CN109777285A (en) * | 2018-03-09 | 2019-05-21 | 广东轻工职业技术学院 | The antibacterial coating of fluorescence, fluorescence Bactericidal paper and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1139133A (en) * | 1996-04-25 | 1997-01-01 | 南开大学戈德防伪技术公司 | Anti-forgery penetrant atomic stamp pad ink and its prepn |
| CN104087067A (en) * | 2014-03-11 | 2014-10-08 | 广东轻工职业技术学院 | Novel fluorescent material made gravure table printing fluorescent anti-counterfeit ink |
| CN105111820A (en) * | 2015-09-17 | 2015-12-02 | 佛山斯玛图科技有限公司 | Novel thick film printing oil stamp-pad ink and application thereof |
-
2015
- 2015-12-29 CN CN201511025811.8A patent/CN106905758B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1139133A (en) * | 1996-04-25 | 1997-01-01 | 南开大学戈德防伪技术公司 | Anti-forgery penetrant atomic stamp pad ink and its prepn |
| CN104087067A (en) * | 2014-03-11 | 2014-10-08 | 广东轻工职业技术学院 | Novel fluorescent material made gravure table printing fluorescent anti-counterfeit ink |
| CN105111820A (en) * | 2015-09-17 | 2015-12-02 | 佛山斯玛图科技有限公司 | Novel thick film printing oil stamp-pad ink and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨伟民等: "《塑料软包装制作及应用技术问答》", 30 September 2007, 印刷工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108725002A (en) * | 2017-04-21 | 2018-11-02 | 南京爱丽斯包装有限公司 | A kind of double anti-forge print production technology |
| CN108725002B (en) * | 2017-04-21 | 2020-10-16 | 南京爱丽斯包装有限公司 | Dual anti-counterfeiting printing production technology |
| CN107903703A (en) * | 2017-11-24 | 2018-04-13 | 深圳市裕同包装科技股份有限公司 | A kind of colorless and odorless fluorescence stamp-pad ink and its preparation process |
| CN109777285A (en) * | 2018-03-09 | 2019-05-21 | 广东轻工职业技术学院 | The antibacterial coating of fluorescence, fluorescence Bactericidal paper and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106905758B (en) | 2020-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106752378B (en) | Fluorescent ink and preparation method thereof | |
| CN104703805B (en) | Luminescent lanthanide coordination compound, and comprise goods and the ink of this emitting complexes | |
| CN106905758A (en) | A kind of fluorescence stamp-pad ink and preparation method thereof | |
| CN104708933A (en) | Novel new-formula fragrance microcapsule printing ink | |
| CN103436093A (en) | Anti-counterfeiting stamp-pad ink and preparation method thereof | |
| CN104220270A (en) | Multilayer flake with high level of coding | |
| CN103996061A (en) | Anti-fake two-dimensional code | |
| CN105469701A (en) | Anti-counterfeit label for random three-dimensional mirror surface graph and preparing method thereof | |
| CN101245200B (en) | UV gloss oil, preparation method and application thereof | |
| CN110049876A (en) | Low energy curability lithographic printing ink and letterpress ink and printing process | |
| CN110049875A (en) | Low energy curability lithographic printing ink and letterpress ink and printing process | |
| CN107586487A (en) | A kind of anti-counterfeiting stamp ink and preparation method thereof | |
| CN104760437A (en) | Invisible ultraviolet fluorescent falsification-preventing low-temperature bright hot-stamping paper and printing method thereof | |
| CN105419485A (en) | Anti-counterfeiting aqueous irreversible thermochromic printing ink and preparation method therefor | |
| CN107298899A (en) | A kind of transparent quick-drying fluorescent antifake stamp-pad ink and preparation method | |
| CN104789036A (en) | Photosensitive and temperature-sensitive aromatic ink and printing method thereof | |
| CN205354524U (en) | Protect card membrane antifalsification label | |
| CN108587325A (en) | Photic colour developing offset ink of one kind and preparation method thereof | |
| CN105051796B (en) | The method for checking the authenticity of secure file | |
| Mogharbel et al. | Preparation of self-healing Anthocyanidin-containing Thermochromic alginate ink for authentication purposes | |
| CN106448435A (en) | Anti-counterfeit label and manufacturing method and application of same | |
| CN205556537U (en) | 3D nanostructured's anti -fake joint sealing sticky tape | |
| CN108912841A (en) | A kind of fluorescent ink and preparation method thereof | |
| CN105882184A (en) | Anti-fake method for displaying hidden red, green and yellow graphical and textual information on orange printing substrate | |
| CN105658654A (en) | Chiral dopant and identification and authentication using polymeric liquid crystal material markings |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20181204 Address after: 516039 Tortoise Village Committee Planting Village Group, Tonghu Town, Zhongkai High-tech Zone, Huizhou City, Guangdong Province Applicant after: Huizhou City Suihe Science & Technology Co., Ltd. Address before: 510300 No. 152 Xingang West Road, Haizhuqu District, Guangzhou, Guangdong. Applicant before: Guangdong Industry Technical College Applicant before: Huizhou City Suihe Science & Technology Co., Ltd. |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |