CN108610725A - Multiband, multilayer electromagnetic matching camouflage paint system and its application - Google Patents

Multiband, multilayer electromagnetic matching camouflage paint system and its application Download PDF

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Publication number
CN108610725A
CN108610725A CN201810564169.8A CN201810564169A CN108610725A CN 108610725 A CN108610725 A CN 108610725A CN 201810564169 A CN201810564169 A CN 201810564169A CN 108610725 A CN108610725 A CN 108610725A
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parts
resin
coating
powder
infrared
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CN108610725B (en
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蒋宇婷
蒋银祥
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Zhenjiang Yinhai nickel chromium chemical Co.,Ltd.
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Danyang Yinhai Nickel Chromium Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/30Camouflage paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/22Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C09D127/24Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment halogenated
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0862Nickel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2275Ferroso-ferric oxide (Fe3O4)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/01Magnetic additives

Abstract

The invention discloses a kind of multiband, multilayer electromagnetic matching camouflage paint system, including radar wave absorption absorbing coating, insulating moulding coating and infrared coating materials;The radar wave absorption absorbing coating is prepared by following parts by weight each component:10 50 parts of absorbing material, 5 30 parts of functional filler A, 0 10 parts of auxiliary agent A, 10 30 parts of Resin A, 5 20 parts of solvent A;The infrared coating material is prepared by following parts by weight each component:5 10 parts of 10 30 parts of pigment C, functional filler C, 10 20 parts of 08 parts of auxiliary agent C, resin C, 10 30 parts of solvent C.Its comprehensive performance carries out multiband camouflage on a surface target within the scope of the multibands such as visible light, near-infrared, mid and far infrared, radar wave, effectively tackles optical reconnaissance, infrared reconnaissance and radar-reconnaissance.

Description

Multiband, multilayer electromagnetic matching camouflage paint system and its application
Technical field
The present invention relates to chemical field, more particularly, it relates to a kind of multiband, multilayer electromagnetic matching camouflage paint system and its Using.
Background technology
Camouflage is used as a kind of concealed manner, is militarily increasingly taken seriously.In a broad sense, the wavelength of electromagnetic wave is extremely Broadness is the range of electromagnetic wave from hundreds of nano wave lengths to millimeter wave, centimeter wave, metric wave, is usually divided into electromagnetic wave infrared Wave and radar wave, therefore, it is proper a kind of feasible method that subrane, which pretends multilayer electromagnetic matching, and current camouflage applies The research emphasis of material.
Invention content
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of multiband, multilayer electromagnetic matching are pseudo- Coatings system, comprehensive performance within the scope of the multibands such as visible light, near-infrared, mid and far infrared, radar wave on a surface target (Such as various vehicles, weaponry, military installations)Carry out multiband camouflage, effectively tackle optical reconnaissance, infrared reconnaissance and Radar-reconnaissance.
To solve the above problems, the technical solution adopted in the present invention is as follows:
The present invention includes a kind of multiband, multilayer electromagnetic matching camouflage paint system, including radar wave absorption absorbing coating, insulating moulding coating And infrared coating material;
The radar wave absorption absorbing coating is prepared by following parts by weight each component:
10-50 parts of absorbing material,
5-30 parts of functional filler A,
0-10 parts of auxiliary agent A,
10-30 parts of Resin A,
5-20 parts of solvent A;
The insulating moulding coating is prepared by following parts by weight each component:
5-50 parts of pigment B,
0-10 parts of functional filler B,
0-10 parts of auxiliary agent B,
10-30 parts of resin B,
10-50 parts of solvent B;
The infrared coating material is prepared by following parts by weight each component:
10-30 parts of pigment C,
5-10 parts of functional filler C,
0-8 parts of auxiliary agent C,
10-20 parts of resin C,
10-30 parts of solvent C.
Preferably, the absorbing material be iron black powder, copper powder, nickel powder, magnetic powder, cobalt powder, Al contained Ni, nickel coated it is hollow One or more of microballon, graphene.
Preferably, the functional filler A be cenosphere, bentonite, aerosil, talcum powder, kaolin, One or more of aluminum magnesium silicate;The functional filler B is cenosphere, bentonite, aerosil, talcum One or more of powder, kaolin, aluminum magnesium silicate;The functional filler C is cenosphere, bentonite, gas phase titanium dioxide One or more of silicon, talcum powder, kaolin, aluminum magnesium silicate.
Preferably, the auxiliary agent A is reactive diluent, wax powder, anti-settling slurry, antifoaming agent, dispersant, levelling agent, adhesive force One or more of accelerating agent, curing accelerator;The auxiliary agent B is in wax powder, antifoaming agent, dispersant, anti-settling slurry, levelling agent One or more;The auxiliary agent C is one or more of wax powder, antifoaming agent, dispersant, anti-settling slurry, levelling agent.
Preferably, the Resin A is one or more of acrylic resin, fluorocarbon resin, epoxy resin;The resin B is one or more of superchlorinated polyvinyl chloride resin, chlorinated rubber, fluorocarbon resin, acrylic resin;The resin C was chloroethene One or more of olefine resin, chlorinated rubber, fluorocarbon resin, acrylic resin.
Preferably, the solvent A is one or more of dimethylbenzene, butyl acetate, ethyl acetate, ethylene glycol ethyl ether; The solvent B is one or more of dimethylbenzene, butyl acetate, ethyl acetate, ethylene glycol ethyl ether;The solvent C is diformazan One or more of benzene, acetate butyl, ethyl acetate, butyl glycol ether, cyclohexanone.
Preferably, the pigment B be iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, titan yellow, zinc yellow, phthalocyanine blue, cobalt blue, chrome green, One or more of dark green, aluminium powder, titanium dioxide;The pigment C be iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, titan yellow, zinc yellow, One or more of phthalocyanine blue, cobalt blue, chrome green, dark green, aluminium powder, titanium dioxide.
The invention also includes a kind of multiband, the preparation method of multilayer electromagnetic matching camouflage paint system, including following steps Suddenly:
1)The preparation of radar wave absorption absorbing coating:Mixing vessel is added in the absorbing material of formula ratio, functional filler A and solvent A It is interior to be uniformly mixed, and pre-dispersed slurry is made to fineness≤50 μm in grinding distribution;Resin A is added in pre-dispersed slurry, high speed is used Dispersion machine stirs 0.5-1h with the rotating speed of 200-400r/min, auxiliary agent A is then added, using high speed dispersor with 400-1000r/ After the rotating speed stirring 3-5h of min, filtered using 120 mesh tulles to obtain the final product;
2)The preparation of insulating moulding coating:It is equal that mixing in mixing vessel is added in the pigment B of formula ratio, functional filler B and solvent B It is even, and pre-dispersed slurry is made to fineness≤100 μm in grinding distribution;Resin B is added in pre-dispersed slurry, high speed dispersor is used 0.5-1h is stirred with the rotating speed of 800-1200r/min, auxiliary agent B is then added, using high speed dispersor with 1200-1500r/min Rotating speed stirring 1-2h after, filtered using 80 mesh tulles to obtain the final product;
3)The preparation of infrared coating material:It is equal that mixing in mixing vessel is added in the solvent C of formula ratio, resin C and auxiliary agent C It is even, pre-dispersed slurry is made;Pigment C and functional filler C are added in pre-dispersed slurry, using high speed dispersor with 800- After the rotating speed stirring 15-30min of 1000r/min, grinding distribution to fineness≤70 μm reuses high speed dispersor with 1000- After the rotating speed stirring 30-45min of 1200r/min, filtered using 80 mesh tulles to obtain the final product.
The invention also includes multiband, the application of multilayer electromagnetic matching camouflage paint system, including steps:
S101. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer;
S102. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer;
S103. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer;
S104. infrared coating material is coated on thermal insulation layer, is formed infrared camouflage layer, that is, is completed application.
Further, the antirust, anti-corrosive layer thickness is 20-40 μm;The thunderstorm activity layer thickness is not less than 0.8mm; The insulation thickness is not less than 0.2mm, and the infrared camouflage layer thickness is not less than 70 μm.
Compared with prior art, the beneficial effects of the present invention are:
1, in the present invention, radar wave absorption absorbing coating is under conditions of coating layer thickness 0.5mm, surface density≤2kg/ ㎡, 8 ~ 18GHZ (X、KUWave band)Reflectivity≤- 4dB, have good radar wave camouflage performance, can effectively tackle radar imagery scout and Detection;
2, in the present invention, insulating moulding coating has the features such as solar reflectivity is high, and thermal resistance is big, can generate good heat-insulation and heat-preservation and make With;
3, in the present invention, infrared coating material has a variety of army's mark colors such as yellow, green, sandy soil, in visible light, near infrared band, light It learns camouflage characteristic and complies with standard GJB798-90, have good adaptability with natural background;In thermal infrared(In, far infrared)Wave band, Infrared emittance shows high, medium and low three levels, and low-launch-rate is not more than 0.6, and the difference of high low-launch-rate is more than 0.25, By the implementation of different colours camouflage pattern, can not only visible light, near-infrared camouflage be carried out to target, effectively tackle visual sight It examines, near-infrared observation, lll night vision, it is seen that the optical reconnaissances such as light and near-infrared photograph, and the infrared heat of camouflaged target can be made Figure generates brightness, and the different spot of grey grade reaches segmentation and destroys IR signature, tackles the purpose of thermal imaging scouting.
Specific implementation mode
Invention is further described in detail With reference to embodiment.
The present invention includes a kind of multiband, multilayer electromagnetic matching camouflage paint system, including radar wave absorption absorbing coating, heat-insulated Coating and infrared coating material;
The radar wave absorption absorbing coating is prepared by following parts by weight each component:10-50 parts of absorbing material, functional filler 5-30 parts of A, 0-10 parts of auxiliary agent A, 10-30 parts of Resin A, 5-20 parts of solvent A;
The insulating moulding coating is prepared by following parts by weight each component:0-10 parts of 5-50 parts of pigment B, functional filler B, are helped 0-10 parts of agent B, 10-30 parts of resin B, 10-50 parts of solvent B;
The infrared coating material is prepared by following parts by weight each component:10-30 parts of pigment C, functional filler C 5-10 Part, 10-20 parts of 0-8 parts of auxiliary agent C, resin C, 10-30 parts of solvent C.
Preferably, the absorbing material be iron black powder, copper powder, nickel powder, magnetic powder, cobalt powder, Al contained Ni, nickel coated it is hollow One or more of microballon, graphene.The functional filler A is cenosphere, bentonite, aerosil, talcum One or more of powder, kaolin, aluminum magnesium silicate;The functional filler B is cenosphere, bentonite, gas phase dioxy One or more of SiClx, talcum powder, kaolin, aluminum magnesium silicate;The functional filler C be cenosphere, bentonite, One or more of aerosil, talcum powder, kaolin, aluminum magnesium silicate.The auxiliary agent A be reactive diluent, wax powder, One or more of anti-settling slurry, antifoaming agent, dispersant, levelling agent, adhesion promoter, curing accelerator;The auxiliary agent B is One or more of wax powder, antifoaming agent, dispersant, anti-settling slurry, levelling agent;The auxiliary agent C be wax powder, antifoaming agent, dispersant, One or more of anti-settling slurry, levelling agent.The Resin A be acrylic resin, fluorocarbon resin, one kind in epoxy resin or It is several;The resin B is one or more of superchlorinated polyvinyl chloride resin, chlorinated rubber, fluorocarbon resin, acrylic resin;It is described Resin C is one or more of superchlorinated polyvinyl chloride resin, chlorinated rubber, fluorocarbon resin, acrylic resin.The solvent A is two One or more of toluene, butyl acetate, ethyl acetate, ethylene glycol ethyl ether;The solvent B is dimethylbenzene, butyl acetate, vinegar One or more of acetoacetic ester, ethylene glycol ethyl ether;The solvent C is dimethylbenzene, acetate butyl, ethyl acetate, ethylene glycol fourth One or more of ether, cyclohexanone.The pigment B be iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, titan yellow, zinc yellow, phthalocyanine blue, One or more of cobalt blue, chrome green, dark green, aluminium powder, titanium dioxide;The pigment C be iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, One or more of titan yellow, zinc yellow, phthalocyanine blue, cobalt blue, chrome green, dark green, aluminium powder, titanium dioxide.
The invention also includes a kind of multiband, the preparation method of multilayer electromagnetic matching camouflage paint system, including following steps Suddenly:
1)The preparation of radar wave absorption absorbing coating:Mixing vessel is added in the absorbing material of formula ratio, functional filler A and solvent A It is interior to be uniformly mixed, and pre-dispersed slurry is made to fineness≤50 μm in grinding distribution;Resin A is added in pre-dispersed slurry, high speed is used Dispersion machine stirs 0.5-1h with the rotating speed of 200-400r/min, auxiliary agent A is then added, using high speed dispersor with 400-1000r/ After the rotating speed stirring 3-5h of min, filtered using 120 mesh tulles to obtain the final product;
2)The preparation of insulating moulding coating:It is equal that mixing in mixing vessel is added in the pigment B of formula ratio, functional filler B and solvent B It is even, and pre-dispersed slurry is made to fineness≤100 μm in grinding distribution;Resin B is added in pre-dispersed slurry, high speed dispersor is used 0.5-1h is stirred with the rotating speed of 800-1200r/min, auxiliary agent B is then added, using high speed dispersor with 1200-1500r/min Rotating speed stirring 1-2h after, filtered using 80 mesh tulles to obtain the final product;
3)The preparation of infrared coating material:It is equal that mixing in mixing vessel is added in the solvent C of formula ratio, resin C and auxiliary agent C It is even, pre-dispersed slurry is made;Pigment C and functional filler C are added in pre-dispersed slurry, using high speed dispersor with 800- After the rotating speed stirring 15-30min of 1000r/min, grinding distribution to fineness≤70 μm reuses high speed dispersor with 1000- After the rotating speed stirring 30-45min of 1200r/min, filtered using 80 mesh tulles to obtain the final product.
The invention also includes multiband, the application of multilayer electromagnetic matching camouflage paint system, including steps:
S101. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer;
S102. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer;
S103. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer;
S104. infrared coating material is coated on thermal insulation layer, is formed infrared camouflage layer, that is, is completed application.
Further, the antirust, anti-corrosive layer thickness is 20-40 μm;The thunderstorm activity layer thickness is not less than 0.8mm; The insulation thickness is not less than 0.2mm, and the infrared camouflage layer thickness is not less than 70 μm.
Embodiment 1
Prepare coating system T-1
The preparation of 1.1 radar wave absorption absorbing coatings:
1.1 radar wave absorption absorbing coating formula table of table
The absorbing material of formula ratio, functional filler A and solvent A are added in mixing vessel and are uniformly mixed, and grinding distribution is extremely Pre-dispersed slurry is made in fineness≤50 μm;Resin A is added in pre-dispersed slurry, using high speed dispersor with the rotating speed of 400r/min 1h is stirred, auxiliary agent A is then added, after stirring 4h using high speed dispersor with the rotating speed of 800r/min, 120 mesh tulles is used to filter To obtain the final product.
The preparation of 1.2 insulating moulding coatings:
1.2 insulating moulding coating formula table of table
The pigment B of formula ratio, functional filler B and solvent B are added in mixing vessel and are uniformly mixed, and grinding distribution is to fineness ≤ 100 μm, pre-dispersed slurry is made;Resin B is added in pre-dispersed slurry, is stirred with the rotating speed of 1100r/min using high speed dispersor 0.5h is mixed, auxiliary agent B is then added, after stirring 2h using high speed dispersor with the rotating speed of 1500r/min, uses 80 mesh tulle mistakes It filters to obtain the final product.
The preparation of 1.3 infrared coating materials:
1.3 infrared coating material formula table of table
The solvent C of formula ratio, resin C and auxiliary agent C are added in mixing vessel and are uniformly mixed, pre-dispersed slurry is made;By pigment C and functional filler C are added in pre-dispersed slurry, after stirring 15min using high speed dispersor with the rotating speed of 1000r/min, grind Mill is dispersed to fineness≤70 μm, after reusing high speed dispersor with the rotating speed stirring 45min of 1200r/min, uses 80 mesh tulles It filters to obtain the final product.
The application of 1.4 coating system T-1:
S101. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer, and thickness is 20 μm;
S102. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer, thickness 0.8mm;
S103. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer, insulation thickness 0.2mm;
S104. infrared coating material is coated on thermal insulation layer, forms infrared camouflage layer, the infrared camouflage layer thickness is 80 μm, Complete application.
Embodiment 2
Prepare coating system T-2
The preparation of 2.1 radar wave absorption absorbing coatings:
2.1 radar wave absorption absorbing coating formula table of table
The absorbing material of formula ratio, functional filler A and solvent A are added in mixing vessel and are uniformly mixed, and grinding distribution is extremely Pre-dispersed slurry is made in fineness≤50 μm;Resin A is added in pre-dispersed slurry, using high speed dispersor with the rotating speed of 400r/min 0.5h is stirred, auxiliary agent A is then added, after stirring 3h using high speed dispersor with the rotating speed of 1000r/min, uses 120 mesh tulles It filters to obtain the final product.
The preparation of 2.2 insulating moulding coatings:
2.2 insulating moulding coating formula table of table
The pigment B of formula ratio, functional filler B and solvent B are added in mixing vessel and are uniformly mixed, and grinding distribution is to fineness ≤ 100 μm, pre-dispersed slurry is made;Resin B is added in pre-dispersed slurry, 1h is stirred with the rotating speed of 800n using high speed dispersor, Then auxiliary agent B is added, after stirring 2h using high speed dispersor with the rotating speed of 1200r/min, is filtered using 80 mesh tulles to obtain the final product.
The preparation of 2.3 infrared coating materials:
2.3 infrared coating material formula table of table
The solvent C of formula ratio, resin C and auxiliary agent C are added in mixing vessel and are uniformly mixed, pre-dispersed slurry is made;By pigment C and functional filler C are added in pre-dispersed slurry, after stirring 30min using high speed dispersor with the rotating speed of 1000r/min, grind Mill is dispersed to fineness≤70 μm, after reusing high speed dispersor with the rotating speed stirring 30min of 1200r/min, uses 80 mesh tulles It filters to obtain the final product.
The application of 2.4 coating system T-2:
S201. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer, and thickness is 30 μm;
S202. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer, thickness 0.9mm;
S203. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer, insulation thickness 0.3mm;
S204. infrared coating material is coated on thermal insulation layer, forms infrared camouflage layer, the infrared camouflage layer thickness is 75 μm, Complete application.
Embodiment 3
Prepare coating system T-3
The preparation of 3.1 radar wave absorption absorbing coatings:
3.1 radar wave absorption absorbing coating formula table of table
The absorbing material of formula ratio, functional filler A and solvent A are added in mixing vessel and are uniformly mixed, and grinding distribution is extremely Pre-dispersed slurry is made in fineness≤50 μm;Resin A is added in pre-dispersed slurry, using high speed dispersor with the rotating speed of 200r/min 1h is stirred, auxiliary agent A is then added, after stirring 5h using high speed dispersor with the rotating speed of 1000r/min, uses 120 mesh tulle mistakes It filters to obtain the final product.
The preparation of 3.2 insulating moulding coatings:
3.2 insulating moulding coating formula table of table
The pigment B of formula ratio, functional filler B and solvent B are added in mixing vessel and are uniformly mixed, and grinding distribution is to fineness ≤ 100 μm, pre-dispersed slurry is made;Resin B is added in pre-dispersed slurry, is stirred with the rotating speed of 1200r/min using high speed dispersor 0.5h is mixed, auxiliary agent B is then added, after stirring 2h using high speed dispersor with the rotating speed of 1500r/min, uses 80 mesh tulle mistakes It filters to obtain the final product.
The preparation of 3.3 infrared coating materials:
3.3 infrared coating material formula table of table
The solvent C of formula ratio, resin C and auxiliary agent C are added in mixing vessel and are uniformly mixed, pre-dispersed slurry is made;By pigment C and functional filler C are added in pre-dispersed slurry, after stirring 30min using high speed dispersor with the rotating speed of 1000r/min, grind Mill is dispersed to fineness≤70 μm, after reusing high speed dispersor with the rotating speed stirring 30 of 1200r/min, is filtered using 80 mesh tulles To obtain the final product.
3.4 the application of coating system T-3:
S301. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer, and thickness is 40 μm;
S302. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer, thickness 1.0mm;
S303. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer, insulation thickness 0.3mm;
S304. infrared coating material is coated on thermal insulation layer, forms infrared camouflage layer, the infrared camouflage layer thickness is 80 μm, Complete application.
Embodiment 4
Conventional detection is carried out to coating system T-1 ~ T-3 prepared by embodiment 1-3, testing result is as follows:
4.1 radar wave absorption absorbing coating:
Adhesive force:>=12MPa,
Flexibility:≤ 3mm,
Reflectivity(8~18GHZ): ≤-8dB.
4.2 insulating moulding coating:
Sun light reflectivity:≥70%(White),
Thermal coefficient(50℃):≤0.2w/m.k.
4.3 infrared coating material:
Color:Army's mark is assorted,
Spectral reflectance performance:Meet GJB798-90《Camouflage paint paint film color》In corresponding tinctorial pattern requirement,
Thermal infrared camouflage performance:Emissivity ε≤0.6 of low emissivity coatings,
ε >=0.25 difference △ of the emissivity of high and low emissivity coating,
Coating with pattern painting has apparent thermal map segmentation effect.
Carry out the detection of optics, thermal infrared, thunderstorm activity effect respectively to the ground after application, discovery reaches outstanding Camouflage effectiveness.Coating can be within the scope of the multibands such as visible light, near-infrared, mid and far infrared, radar wave on a surface target(Such as Various vehicles, weaponry, military installations etc.)Multiband camouflage is carried out, optical reconnaissance, infrared reconnaissance and radar are effectively tackled It scouts.
In the present invention, radar wave absorption absorbing coating is under conditions of coating layer thickness 0.9mm, surface density≤4kg/ ㎡, 8 ~ 18GHZ (X、KUWave band)Reflectivity≤- 8dB, have good radar wave camouflage performance, can effectively tackle radar imagery scout and Detection;Insulating moulding coating has the features such as solar reflectivity is high, and thermal resistance is big, can generate good thermal insulation function;Infrared camouflage Coating has a variety of army's mark colors such as yellow, green, sandy soil, and in visible light, near infrared band, optical camouflage characteristic complies with standard GJB798-90 has good adaptability, in thermal infrared with natural background(In, far infrared)Wave band, infrared emittance show High, medium and low three levels, and low-launch-rate is not more than 0.6, the difference of high low-launch-rate is more than 0.25, passes through different colours camouflage color The implementation of pattern not only can carry out visible light, near-infrared camouflage to target, effectively tackle visual observation, and near-infrared observation is micro- Light night vision, it is seen that the optical reconnaissances such as light and near-infrared photograph, and the infrared chart of camouflaged target can be made to generate brightness, grey grade is not Same spot reaches segmentation and destroys IR signature, tackles the purpose of thermal imaging scouting;Triplicity becomes more waves Section, multilayer electromagnetic matching camouflage paint.
It will be apparent to those skilled in the art that technical solution that can be as described above and design, make various other Corresponding change and deformation, and all these changes and deformation should all belong to the protection domain of the claims in the present invention Within.

Claims (10)

1. a kind of multiband, multilayer electromagnetic matching camouflage paint system, which is characterized in that including radar wave absorption absorbing coating, heat-insulated Coating and infrared coating material;
The radar wave absorption absorbing coating is prepared by following parts by weight each component:
10-50 parts of absorbing material,
5-30 parts of functional filler A,
0-10 parts of auxiliary agent A,
10-30 parts of Resin A,
5-20 parts of solvent A;
The insulating moulding coating is prepared by following parts by weight each component:
5-50 parts of pigment B,
0-10 parts of functional filler B,
0-10 parts of auxiliary agent B,
10-30 parts of resin B,
10-50 parts of solvent B;
The infrared coating material is prepared by following parts by weight each component:
10-30 parts of pigment C,
5-10 parts of functional filler C,
0-8 parts of auxiliary agent C,
10-20 parts of resin C,
10-30 parts of solvent C.
2. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the suction wave material Material is iron black powder, copper powder, nickel powder, magnetic powder, cobalt powder, Al contained Ni, the cenosphere of nickel coated, one kind in graphene or several Kind.
3. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the functionality Filler A is one or more of cenosphere, bentonite, aerosil, talcum powder, kaolin, aluminum magnesium silicate;Institute It is one kind in cenosphere, bentonite, aerosil, talcum powder, kaolin, aluminum magnesium silicate to state functional filler B Or it is several;The functional filler C is cenosphere, bentonite, aerosil, talcum powder, kaolin, aluminum magnesium silicate One or more of.
4. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the auxiliary agent A is Reactive diluent, wax powder, anti-settling slurry, antifoaming agent, dispersant, levelling agent, adhesion promoter, one kind in curing accelerator or It is several;The auxiliary agent B is one or more of wax powder, antifoaming agent, dispersant, anti-settling slurry, levelling agent;The auxiliary agent C is wax One or more of powder, antifoaming agent, dispersant, anti-settling slurry, levelling agent.
5. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the Resin A is One or more of acrylic resin, fluorocarbon resin, epoxy resin;The resin B be superchlorinated polyvinyl chloride resin, chlorinated rubber, One or more of fluorocarbon resin, acrylic resin;The resin C be superchlorinated polyvinyl chloride resin, chlorinated rubber, fluorocarbon resin, One or more of acrylic resin.
6. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the solvent A For one or more of dimethylbenzene, butyl acetate, ethyl acetate, ethylene glycol ethyl ether;The solvent B is dimethylbenzene, acetic acid fourth One or more of ester, ethyl acetate, ethylene glycol ethyl ether;The solvent C is dimethylbenzene, acetate butyl, ethyl acetate, second two One or more of alcohol butyl ether, cyclohexanone.
7. multiband as described in claim 1, multilayer electromagnetic matching camouflage paint system, which is characterized in that the pigment B For one in iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, titan yellow, zinc yellow, phthalocyanine blue, cobalt blue, chrome green, dark green, aluminium powder, titanium dioxide Kind is several;The pigment C be iron oxide red, molybdenum chromium pigment scarlet powder, chrome yellow, titan yellow, zinc yellow, phthalocyanine blue, cobalt blue, chrome green, dark green, One or more of aluminium powder, titanium dioxide.
8. the preparation method of any one of the claim 1-7 multibands, multilayer electromagnetic matching camouflage paint system, including it is following Step:
1)The preparation of radar wave absorption absorbing coating:Mixing vessel is added in the absorbing material of formula ratio, functional filler A and solvent A It is interior to be uniformly mixed, and pre-dispersed slurry is made to fineness≤50 μm in grinding distribution;Resin A is added in pre-dispersed slurry, high speed is used Dispersion machine stirs 0.5-1h with the rotating speed of 200-400r/min, auxiliary agent A is then added, using high speed dispersor with 400-1000r/ After the rotating speed stirring 3-5h of min, filtered using 120 mesh tulles to obtain the final product;
2)The preparation of insulating moulding coating:It is equal that mixing in mixing vessel is added in the pigment B of formula ratio, functional filler B and solvent B It is even, and pre-dispersed slurry is made to fineness≤100 μm in grinding distribution;Resin B is added in pre-dispersed slurry, high speed dispersor is used 0.5-1h is stirred with the rotating speed of 800-1200r/min, auxiliary agent B is then added, using high speed dispersor with 1200-1500r/min Rotating speed stirring 1-2h after, filtered using 80 mesh tulles to obtain the final product;
3)The preparation of infrared coating material:It is equal that mixing in mixing vessel is added in the solvent C of formula ratio, resin C and auxiliary agent C It is even, pre-dispersed slurry is made;Pigment C and functional filler C are added in pre-dispersed slurry, using high speed dispersor with 800- After the rotating speed stirring 15-30min of 1000r/min, grinding distribution to fineness≤70 μm reuses high speed dispersor with 1000- After the rotating speed stirring 30-45min of 1200r/min, filtered using 80 mesh tulles to obtain the final product.
9. the application of claim 1-7 any one of them multiband, multilayer electromagnetic matching camouflage paint system, including step:
S101. the commercially available antirust, anti-corrosive priming paint of application on clean ground, forms antirust, anti-corrosive layer;
S102. the multiple batches of coating radar wave absorption absorbing coating on antirust, anti-corrosive layer forms thunderstorm activity layer;
S103. the coating thermal insulating on thunderstorm activity layer forms thermal insulation layer;
S104. infrared coating material is coated on thermal insulation layer, is formed infrared camouflage layer, that is, is completed application.
10. the application of multiband as claimed in claim 9, multilayer electromagnetic matching camouflage paint system, which is characterized in that described Antirust, anti-corrosive layer thickness is 20-40 μm;The thunderstorm activity layer thickness is not less than 0.8mm;The insulation thickness is not less than 0.2mm, the infrared camouflage layer thickness are not less than 70 μm.
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CN111572156A (en) * 2020-05-29 2020-08-25 江苏雷鸟伪装纺织新材料有限公司 Take anti-flaming function's ripples of inhaling camouflage surface fabric
CN111876046A (en) * 2019-12-12 2020-11-03 温州市鹿城印染厂 Visible light-near infrared-thermal infrared-millimeter wave-centimeter wave multi-spectrum stealth integrated composite coating
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CN113834383A (en) * 2021-10-12 2021-12-24 南京南大波平电子信息有限公司 Sandwich structure camouflage net and preparation method thereof

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CN109536133A (en) * 2018-12-21 2019-03-29 北京圣盟科技有限公司 A kind of graphene-based infrared stealth composite material and preparation method
CN109536133B (en) * 2018-12-21 2021-10-01 北京圣盟科技有限公司 Graphene-based infrared stealth composite material and preparation method thereof
CN110157226A (en) * 2019-05-23 2019-08-23 哈尔滨工业大学 A kind of high temperature resistant antiradar coatings and preparation method thereof
CN110157226B (en) * 2019-05-23 2021-04-20 哈尔滨工业大学 High-temperature-resistant wave-absorbing coating and preparation method thereof
CN111876046A (en) * 2019-12-12 2020-11-03 温州市鹿城印染厂 Visible light-near infrared-thermal infrared-millimeter wave-centimeter wave multi-spectrum stealth integrated composite coating
CN111363423A (en) * 2020-04-13 2020-07-03 无锡市恒创嘉业纳米材料科技有限公司 Fluorine-containing coating material for outdoor protection of 5G communication base station and preparation method thereof
CN111572156A (en) * 2020-05-29 2020-08-25 江苏雷鸟伪装纺织新材料有限公司 Take anti-flaming function's ripples of inhaling camouflage surface fabric
CN111978846A (en) * 2020-09-08 2020-11-24 安徽省金盾涂料有限责任公司 Bionic visible light and near infrared detection-resistant camouflage coating composition and preparation method thereof
CN112123997A (en) * 2020-09-27 2020-12-25 中国人民解放军96901部队25分队 Invisible tire decorative cover and preparation method thereof
CN112143362A (en) * 2020-10-15 2020-12-29 安徽省金盾涂料有限责任公司 Water-based chemical-medium-resistant and weather-resistant visible light near-infrared camouflage coating and preparation method thereof
CN112409913A (en) * 2020-11-19 2021-02-26 青岛九维华盾科技研究院有限公司 Light salt-fog-resistant wave-absorbing coating and preparation method thereof
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CN113834383A (en) * 2021-10-12 2021-12-24 南京南大波平电子信息有限公司 Sandwich structure camouflage net and preparation method thereof

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