CN108610185A - A kind of Citrus shatangju selenium-enriched foliage fertilizer and preparation method thereof - Google Patents
A kind of Citrus shatangju selenium-enriched foliage fertilizer and preparation method thereof Download PDFInfo
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- CN108610185A CN108610185A CN201810815919.4A CN201810815919A CN108610185A CN 108610185 A CN108610185 A CN 108610185A CN 201810815919 A CN201810815919 A CN 201810815919A CN 108610185 A CN108610185 A CN 108610185A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B1/00—Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
- C05B1/02—Superphosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- Life Sciences & Earth Sciences (AREA)
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Abstract
The present invention relates to fertilizer processing technique fields, more particularly to a kind of Citrus shatangju selenium-enriched foliage fertilizer and preparation method thereof, mainly by the raw materials such as people and animals' fecaluria, oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus, gynostemma pentaphylla, k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, rotten powdered glucose, bone meal, adhesive, bleeding agent, chitosan oligosaccharide and Propineb through feedstock processing, fermentation, filtering, allotment and etc. be made.The Citrus shatangju selenium-enriched foliage fertilizer rich in nutrition content, with sterilization and disinsection effect, pest and disease damage is reduced, pesticide and fertilizer application rate are reduced, dramatically increases per mu yield, soluble solid content and the selenium content of Citrus shatangju, nutritive value is high, fruit is very large washiness, pericarp is thin, and pulp is sweet and dilitious, and preparation process is simple, it is easy to produce.
Description
Technical field
The present invention relates to fertilizer processing technique fields, and in particular to a kind of Citrus shatangju selenium-enriched foliage fertilizer and preparation method thereof.
Background technology
Selenium is indispensable a kind of nonmetallic trace element in human life.It can decompose people's interior free yl, make one
The harmful peroxide of body is reduced to harmless hydroxy compounds, to improve flight against senium of human body, immune and hormone secretion energy
Power.There may be the diseases such as energy deficiency malnutrition, blood hemolytic anemia, Keshan disease, Kaschin-Beck disease, hypertension for human body selenium deficiency
Disease.The World Health Organization has appreciated that the harm of selenium deficiency, so various selenium-supply health products largely generate, still, for more next
The modern for more pursuing health, it is highly desirable that replacing building up one's health by taking tonic by tonic.In recent years, with the enhancing of people's health care consciousness
With the promotion to the selenium degree of awareness, selenium-rich agricultural and sideline product has been widely accepted and has accepted, and is formed and a kind of pursuing selenium-rich product
Upsurge, therefore study selenium-rich Citrus shatangju and have great importance.
It is mostly the rush at florescence and result application early period though currently, there are many foliar fertilizer of related fruit tree kind on the market
The foliar fertilizer of flower and fruit etc, rare foliar fertilizer kind that can improve fruit quality especially improve Citrus shatangju selenium-rich fruit product
The special fertilizer of matter, and foliar fertilizer function in the market is more single, obtained fruit not only skin depth, and moisture is few, sugar is few, difficult
To meet the requirement of farmer and market.
Invention content
The goal of the invention of the present invention is：In view of the above problems, provide a kind of Citrus shatangju selenium-enriched foliage fertilizer and its
Preparation method, the Citrus shatangju selenium-enriched foliage fertilizer rich in nutrition content have sterilization and disinsection effect, reduce pest and disease damage, reduce pesticide
And fertilizer application rate, per mu yield, soluble solid content and the selenium content of Citrus shatangju are dramatically increased, nutritive value is high, and fruit is very large
Washiness, pericarp is thin, and pulp is sweet and dilitious, and preparation process is simple, easy to produce.
To achieve the goals above, the technical solution adopted by the present invention is as follows：
A kind of Citrus shatangju selenium-enriched foliage fertilizer, which is characterized in that be mainly made of following raw material：People and animals' fecaluria 10-
30 parts, 15-20 parts of oriental bitteraweet leaf, 10-20 parts of rose of Sharon cauline leaf, 10-20 parts of clover, 10-20 parts of chrysanthemum, 20-25 parts of indocalamus, strand
17-20 parts blue, 10-20 parts of k-selenocarrageenan, 10-12 parts of calcium superphosphate, 13-15 parts of calcium nitrate, becomes 13-15 parts of calcium magnesium phosphate
13-15 parts of matter powdered glucose, 10-12 parts of bone meal, 3-5 parts of adhesive, 3-7 parts of bleeding agent, 3-5 parts of chitosan oligosaccharide and Propineb 3-5
Part.
Preferably, it is mainly made of following raw material：20 parts of people and animals' fecaluria, 17 parts of oriental bitteraweet leaf, rose of Sharon cauline leaf 15
Part, 15 parts of clover, 15 parts of chrysanthemum, 23 parts of indocalamus, 18.5 parts of gynostemma pentaphylla, 15 parts of k-selenocarrageenan, 14 parts of calcium magnesium phosphate, peroxophosphoric acid
11 parts of calcium, 14 parts of calcium nitrate, rotten 14 parts of powdered glucose, 11 parts of bone meal, 4 parts of adhesive, 5 parts of bleeding agent, 4 parts of chitosan oligosaccharide and third
4 parts of gloomy zinc.
Preferably, the adhesive is mainly by the animal glue of isometric ratio, shellac, polyvinyl alcohol, carboxymethyl cellulose
One or more mix.
Preferably, the bleeding agent is mainly by the fatty alcohol polyoxyethylene ether of equal mass ratioes, sulfated castor oil, alkyl sulphur
One or more in sour sodium and sulfamic acid sodium mix.
The preparation method of Citrus shatangju selenium-enriched foliage fertilizer as described above, specifically includes following steps：
(1) people and animals' fecaluria is weighed by weight and is placed in fermentation vat interior sealing fermentation 3-5 days, and during which stirring is primary daily, standby
With；
(2) it rubs and is slurried and rotten Portugal after desilting oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus and gynostemma pentaphylla
Grape Icing Sugar, bone meal are added together in step (1), after being uniformly mixed, are continued to be sealed by fermentation 3-5 days, are during which stirred one daily
It is secondary, fermentate is obtained, it is spare；
(3) by k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, adhesive, bleeding agent, chitosan oligosaccharide and Propineb
It is dissolved in the water uniformly mixed, adds in the fermentate of step (2), be uniformly mixed, after filtering, it is rich that the Citrus shatangju is made
Selenium foliar fertilizer.
Preferably, the Citrus shatangju selenium-enriched foliage fertilizer obtained above is diluted with water 80-120 times to can be used, is now matched
It is current.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
The Citrus shatangju selenium-enriched foliage fertilizer of the present invention is mainly by people and animals' fecaluria, oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus
Bamboo, gynostemma pentaphylla, k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, rotten powdered glucose, bone meal, adhesive, infiltration
The raw materials such as agent, chitosan oligosaccharide and Propineb through feedstock processing, fermentation, filtering, allotment and etc. be made.The Citrus shatangju selenium-enriched foliage fertilizer
Rich in nutrition content is provided in particular in abundant selenium element, has sterilization and disinsection effect, reduces pest and disease damage, reduces pesticide and change
Fertile utilization rate dramatically increases per mu yield, soluble solid content and the selenium content of Citrus shatangju, and nutritive value is high, fruit is very large moisture
More, pericarp is thin, and pulp is sweet and dilitious, and preparation process is simple, easy to produce.
Wherein, people and animals' fecaluria, calcium magnesium phosphate, calcium superphosphate, calcium nitrate and rotten powdered glucose are rich in relatively rich kind of mine
The nutrients such as material element provide abundant calcium, phosphorus, boron element for fruit tree, can improve the toughness of cell and intercellular connect
Conjunction property increases pericarp toughness, reduces dehiscent fruit；Cell membrane stability enzyme can increase pericarp toughness, enhancing pericarp membrane interstitial, intercellular
The toughness of layer and plasmodesmus；Contain abundant selenium element in clover, chrysanthemum, indocalamus, gynostemma pentaphylla, k-selenocarrageenan and bone meal,
Abundant selenium nutrient is provided for Citrus shatangju；Contain abundant active insecticidal components in oriental bitteraweet leaf and rose of Sharon cauline leaf, to disease pest
Evil has the function of good antibacterial, prevention, poisoning, inhibits growth and development and population to be formed, plays good pesticide-germicide work(
Effect reduces Pesticide use；Bleeding agent has bleed water-reduction, plays good permeability, wetability and ductility, adhesive
Adhesion strength of the foliar fertilizer on plant leaf blade can be improved, these substances can more efficiently facilitate the absorption of fertilizer, improve foliar fertilizer
Utilization rate；Chitosan oligosaccharide and Propineb have good preventive effect to blooming of fruit trees freeze injury；The above substance after retting fermentation process,
The battalion of root system of plant can be promoted by the material conversion for being not easy to root system absorption at the small-molecule substance for being easy to root system of plant absorption
It supports and absorbs, improve foliar fertilizer utilization rate, moreover it is possible to which the normal physiological activity for effectively inhibiting harmful disease pest is played and killed well
The effect of worm.
Specific implementation mode
Technical scheme of the present invention will be clearly and completely described below, it is clear that described embodiment is only
A part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art
The every other embodiment obtained without making creative work, shall fall within the protection scope of the present invention.
Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention
The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases
Any and all combinations of the Listed Items of pass.
Embodiment 1
A kind of Citrus shatangju selenium-enriched foliage fertilizer, is mainly made of following raw material：10 parts of people and animals' fecaluria, oriental bitteraweet leaf 15
Part, 10 parts of rose of Sharon cauline leaf, 10 parts of clover, 10 parts of chrysanthemum, 20 parts of indocalamus, 17 parts of gynostemma pentaphylla, 10 parts of k-selenocarrageenan, calcium magnesium phosphate
13 parts, 10 parts of calcium superphosphate, 13 parts of calcium nitrate, rotten 13 parts of powdered glucose, 10 parts of bone meal, 3 parts of adhesive, 3 parts of bleeding agent, shell
3 parts of 3 parts of oligosaccharides and Propineb；
Wherein, adhesive is mainly polyvinyl alcohol；Bleeding agent is mainly fatty alcohol polyoxyethylene ether.
The expectation of said ratio is prepared into Citrus shatangju selenium-enriched foliage fertilizer using following methods, specifically includes following steps：
(1) people and animals' fecaluria is weighed by weight and is placed in fermentation vat interior sealing fermentation 3 days, and during which stirring is primary daily, spare；
(2) it rubs and is slurried and rotten Portugal after desilting oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus and gynostemma pentaphylla
Grape Icing Sugar, bone meal are added together in step (1), after being uniformly mixed, continue to be sealed by fermentation 3 days, and during which stirring is primary daily,
Fermentate is obtained, it is spare；
(3) by k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, adhesive, bleeding agent, chitosan oligosaccharide and Propineb
It is dissolved in the water uniformly mixed, adds in the fermentate of step (2), be uniformly mixed, after filtering, it is rich that the Citrus shatangju is made
Selenium foliar fertilizer.
(4) the Citrus shatangju selenium-enriched foliage fertilizer obtained above 80 times are diluted with water to can be used, it is now with the current.
Embodiment 2
A kind of Citrus shatangju selenium-enriched foliage fertilizer, is mainly made of following raw material：20 parts of people and animals' fecaluria, oriental bitteraweet leaf 17
Part, 15 parts of rose of Sharon cauline leaf, 15 parts of clover, 15 parts of chrysanthemum, 23 parts of indocalamus, 18.5 parts of gynostemma pentaphylla, 15 parts of k-selenocarrageenan, calcium and magnesium phosphorus
14 parts of fertilizer, 11 parts of calcium superphosphate, 14 parts of calcium nitrate, rotten 14 parts of powdered glucose, 11 parts of bone meal, 4 parts of adhesive, 5 parts of bleeding agent,
4 parts of 4 parts of chitosan oligosaccharide and Propineb；
Wherein, adhesive is mainly mixed by the animal glue and shellac of isometric ratio；
Bleeding agent is mainly mixed by the sodium alkyl sulfonate and sulfamic acid sodium of equal mass ratioes.
The expectation of said ratio is prepared into Citrus shatangju selenium-enriched foliage fertilizer using following methods, specifically includes following steps：
(1) people and animals' fecaluria is weighed by weight and is placed in fermentation vat interior sealing fermentation 4 days, and during which stirring is primary daily, spare；
(2) it rubs and is slurried and rotten Portugal after desilting oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus and gynostemma pentaphylla
Grape Icing Sugar, bone meal are added together in step (1), after being uniformly mixed, continue to be sealed by fermentation 4 days, and during which stirring is primary daily,
Fermentate is obtained, it is spare；
(3) by k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, adhesive, bleeding agent, chitosan oligosaccharide and Propineb
It is dissolved in the water uniformly mixed, adds in the fermentate of step (2), be uniformly mixed, after filtering, it is rich that the Citrus shatangju is made
Selenium foliar fertilizer.
(4) the Citrus shatangju selenium-enriched foliage fertilizer obtained above 100 times are diluted with water to can be used, it is now with the current.
Embodiment 3
A kind of Citrus shatangju selenium-enriched foliage fertilizer, is mainly made of following raw material：30 parts of people and animals' fecaluria, oriental bitteraweet leaf 20
Part, 20 parts of rose of Sharon cauline leaf, 20 parts of clover, 20 parts of chrysanthemum, 25 parts of indocalamus, 20 parts of gynostemma pentaphylla, 20 parts of k-selenocarrageenan, calcium magnesium phosphate
15 parts, 12 parts of calcium superphosphate, 15 parts of calcium nitrate, rotten 15 parts of powdered glucose, 12 parts of bone meal, 5 parts of adhesive, 7 parts of bleeding agent, shell
5 parts of 5 parts of oligosaccharides and Propineb；
Wherein, adhesive is mainly mixed by animal glue, shellac, polyvinyl alcohol, the carboxymethyl cellulose of isometric ratio；
Bleeding agent is mainly by fatty alcohol polyoxyethylene ether, sulfated castor oil, sodium alkyl sulfonate and the amino of equal mass ratioes
Sodium sulfonate mixes.
The expectation of said ratio is prepared into Citrus shatangju selenium-enriched foliage fertilizer using following methods, specifically includes following steps：
(1) people and animals' fecaluria is weighed by weight and is placed in fermentation vat interior sealing fermentation 5 days, and during which stirring is primary daily, spare；
(2) it rubs and is slurried and rotten Portugal after desilting oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus and gynostemma pentaphylla
Grape Icing Sugar, bone meal are added together in step (1), after being uniformly mixed, continue to be sealed by fermentation 5 days, and during which stirring is primary daily,
Fermentate is obtained, it is spare；
(3) by k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, adhesive, bleeding agent, chitosan oligosaccharide and Propineb
It is dissolved in the water uniformly mixed, adds in the fermentate of step (2), be uniformly mixed, after filtering, it is rich that the Citrus shatangju is made
Selenium foliar fertilizer.
(4) the Citrus shatangju selenium-enriched foliage fertilizer obtained above 120 times are diluted with water to can be used, it is now with the current.
Citrus shatangju selenium-enriched foliage fertilizer produced by the present invention and commercially available foliar fertilizer are applied in Citrus shatangju plantation by applicant,
Citrus shatangju selenium-enriched foliage fertilizer and commercially available foliar fertilizer are diluted with water into 100 times, are uniformly sprayed on the Citrus shatangju richness for starting result
It is primary every sprinkling in 15 days on selenium tree, until being sprayed to moisture drippage every time, and detection and the statistics of correlated performance are carried out, tied
Fruit is as shown in table 1.
Comparative example 1：Using the foliar fertilizer sold on the market.
Comparative example 2：Primary raw material behaviour domestic animals manure, calcium magnesium phosphate, calcium superphosphate, the calcium nitrate of Citrus shatangju selenium-enriched foliage fertilizer
And rotten powdered glucose, other are identical as the embodiment of the present invention 1.
Comparative example 3：Primary raw material behaviour domestic animals manure, clover, chrysanthemum, indocalamus, gynostemma pentaphylla, the selenium of Citrus shatangju selenium-enriched foliage fertilizer
Acid esters polysaccharide and bone meal, other are identical as the embodiment of the present invention 1.
Comparative example 4：The primary raw material behaviour domestic animals manure of Citrus shatangju selenium-enriched foliage fertilizer, oriental bitteraweet leaf, rose of Sharon cauline leaf, adherency
Agent, bleeding agent, chitosan oligosaccharide and Propineb, other are identical as the embodiment of the present invention 1.
As known from Table 1, using Citrus shatangju selenium-enriched foliage fertilizer produced by the invention, rich in nutrition content, Citrus shatangju fruit tree branch
Item is luxuriant, the Citrus shatangju selenium-enriched foliage fertilizer rich in nutrition content, have sterilization and disinsection effect, reduce pest and disease damage, reduction pesticide and
Fertilizer application rate dramatically increases per mu yield, soluble solid content and the selenium content of Citrus shatangju, and nutritive value is high, fruit is very large water
Point more, pericarp is thin, and pulp is sweet and dilitious, to improve the economic benefit that Citrus shatangju is planted.
The comparative analysis situation of 1 each group Citrus shatangju of table
| Group | Per mu yield/kg | Se content (mg/g) | Soluble solid content % | Pest and disease damage % |
| Comparative example 1 | 3846 | 9 | 15 | 45 |
| Comparative example 2 | 4475 | 12 | 18 | 37 |
| Comparative example 3 | 4275 | 34 | 26 | 31 |
| Comparative example 4 | 4008 | 18 | 20 | 20 |
| Embodiment 1 | 4779 | 43 | 35 | 10 |
| Embodiment 2 | 5034 | 45 | 38 | 8.5 |
| Embodiment 3 | 5195 | 48 | 40 | 6.5 |
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair
Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to
In the covered the scope of the claims of the present invention.
Claims (6)
1. a kind of Citrus shatangju selenium-enriched foliage fertilizer, which is characterized in that be mainly made of following raw material：People and animals' fecaluria 10-30
Part, 15-20 parts of oriental bitteraweet leaf, 10-20 parts of rose of Sharon cauline leaf, 10-20 parts of clover, 10-20 parts of chrysanthemum, 20-25 parts of indocalamus, gynostemma pentaphylla
17-20 parts, it is 10-20 parts of k-selenocarrageenan, 13-15 parts of calcium magnesium phosphate, 10-12 parts of calcium superphosphate, 13-15 parts of calcium nitrate, rotten
3-5 parts of 13-15 parts of powdered glucose, 10-12 parts of bone meal, 3-5 parts of adhesive, 3-7 parts of bleeding agent, 3-5 parts of chitosan oligosaccharide and Propineb.
2. Citrus shatangju selenium-enriched foliage fertilizer according to claim 1, which is characterized in that mainly by following raw material system
At：20 parts of people and animals' fecaluria, 17 parts of oriental bitteraweet leaf, 15 parts of rose of Sharon cauline leaf, 15 parts of clover, 15 parts of chrysanthemum, 23 parts of indocalamus, gynostemma pentaphylla
18.5 parts, 15 parts of k-selenocarrageenan, 14 parts of calcium magnesium phosphate, 11 parts of calcium superphosphate, 14 parts of calcium nitrate, rotten 14 parts of powdered glucose,
4 parts of 11 parts of bone meal, 4 parts of adhesive, 5 parts of bleeding agent, 4 parts of chitosan oligosaccharide and Propineb.
3. Citrus shatangju selenium-enriched foliage fertilizer according to claim 1 or 2, it is characterised in that：The adhesive is mainly by equal bodies
One or more in the product animal glue of ratio, shellac, polyvinyl alcohol, carboxymethyl cellulose mix.
4. Citrus shatangju selenium-enriched foliage fertilizer according to claim 1 or 2, it is characterised in that：The bleeding agent mainly by etc. matter
Measure one or more mixing in fatty alcohol polyoxyethylene ether, sulfated castor oil, sodium alkyl sulfonate and the sulfamic acid sodium of ratio
It forms.
5. the preparation method of the Citrus shatangju selenium-enriched foliage fertilizer according to any one of claim 1-4, which is characterized in that specific
Include the following steps：
(1) people and animals' fecaluria is weighed by weight and is placed in fermentation vat interior sealing fermentation 3-5 days, and during which stirring is primary daily, spare；
(2) it rubs and is slurried and rotten glucose after desilting oriental bitteraweet leaf, rose of Sharon cauline leaf, clover, chrysanthemum, indocalamus and gynostemma pentaphylla
Powder, bone meal are added together in step (1), after being uniformly mixed, continue to be sealed by fermentation 3-5 days, during which stirring is primary daily, obtains
It is spare to fermentate；
(3) k-selenocarrageenan, calcium magnesium phosphate, calcium superphosphate, calcium nitrate, adhesive, bleeding agent, chitosan oligosaccharide and Propineb are dissolved
Yu Shuizhong is uniformly mixed, and is added in the fermentate of step (2), is uniformly mixed, and after filtering, the Citrus shatangju selenium-rich leaf is made
Leaven.
6. the preparation method of Citrus shatangju selenium-enriched foliage fertilizer according to claim 5, it is characterised in that：By institute obtained above
State Citrus shatangju selenium-enriched foliage fertilizer be diluted with water 80-120 times i.e. can be used, it is now with the current.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109553472A (en) * | 2018-12-26 | 2019-04-02 | 龙蟒大地农业有限公司 | A kind of Citrus shatangju selenium-enriched foliage fertilizer and preparation method thereof |
| CN111960880A (en) * | 2020-05-28 | 2020-11-20 | 内蒙古朵日纳硒科生物技术有限公司 | Production method of selenium-rich alfalfa water-soluble fertilizer |
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