CN108558358A - A kind of sintering brick permeable to water and preparation method thereof being not easy to plug - Google Patents
A kind of sintering brick permeable to water and preparation method thereof being not easy to plug Download PDFInfo
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- CN108558358A CN108558358A CN201711401192.7A CN201711401192A CN108558358A CN 108558358 A CN108558358 A CN 108558358A CN 201711401192 A CN201711401192 A CN 201711401192A CN 108558358 A CN108558358 A CN 108558358A
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
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- C04B33/00—Clay-wares
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- C04B33/00—Clay-wares
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63404—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63444—Nitrogen-containing polymers, e.g. polyacrylamides, polyacrylonitriles, polyvinylpyrrolidone [PVP], polyethylenimine [PEI]
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- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0038—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter
- C04B38/0041—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter the particulate matter having preselected particle sizes
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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Abstract
The invention discloses a kind of sintering brick permeable to water being not easy to plug, including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：80 100 parts of aggregate bonds 3 12 parts of base-material, 3 12 parts of liquid glue；Primary raw material of the fabric in terms of mass parts is as follows：0 30 parts of aggregate bonds 04 parts of base-material, 04 parts of liquid glue, 04 parts of colorant；The cohesive base-material is one or more in bentonite, clay；The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；The aggregate first passes through ball-milling treatment in advance.Correspondingly, the invention discloses a kind of preparation methods for the sintering brick permeable to water being not easy to plug.Using the present invention, the intensity of the water-permeable brick is high, frost resistance is strong, excellent water permeability, and particle in rainwater (sewage) or fiber substance are not easy wall built-up, and water-permeable brick hole gap is not easy to plug.
Description
Technical field
The present invention relates to water-permeable brick technical field more particularly to a kind of sintering brick permeable to water being not easy to plug and its preparation sides
Method.
Background technology
Water-permeable brick is to safeguard balance of city ecosystem structure sponge city and grand to alleviate urban waterlogging, while keeping moisture
The century environment-friendly building materials new product being born again.It using useless ceramic tile (useless polished bricks, useless glazed tile, useless tile etc.), stone material particle,
The solid wastes such as slag are primary raw material, are equipped with shaping assistant, add suitable binder, are molded through cloth twice, and high temperature is burnt
At being green product.
Water-permeable brick can consume a large amount of useless ceramic tiles (solid wastes such as stone material particle or slag), this is not only solved at this stage
The processing problem of solid waste, also substantially reduces the pollution to environment.The ceramic water-permeable brick produced can be directly used in city
City is built, and is turned waste into wealth.Therefore, there is apparent social effect.
Water-permeable brick is divided into sintering class water-permeable brick and coagulation great soil group water-permeable brick, wherein sintering class water-permeable brick is needed by high temperature
Firing, and coagulation great soil group water-permeable brick needs not move through high temperature firing.
The prior art 1 is the patent of invention of Publication No. CN 101955349B, and it discloses a kind of water-permeable brick, water-permeable bricks
Using ceramic waste residue powder, cullet powder, useless porcelain fragment powder, the useless mud powder in municipal administration basis, calcium oxide, calcium sulfate, swelling
Soil, talcum powder, cinder powder, useless pure plant powder and water are raw material, stir and use mechanical oscillation extrusion forming in after moist shape
For water-permeable brick lower layer brick, then with secondary material distributing machine one layer of fine flour material (main component is uniformly distributed on the top of water-permeable brick lower layer brick
For waste ceramic fragment powder, bentonite, water), ceramic waste residue sintering pervious environment protection is then manufactured under the pressure of 25~30MPa
Adobe is spontaneously dried.The ceramic waste residue pervious environment protection adobe by molding after natural drying is sent into tunnel oven and roasts again
It burns, temperature control is fired within the scope of 1150~1200 DEG C.In said program, the useless body refuse fine powder in municipal administration basis and bentonite are
Binder.In the prior art 1, the addition of waste ceramic fragment powder is 20-30 parts, and bentonitic addition is 5-8 parts, municipal administration
The addition of the useless mud powder in basis is 20-30 parts, that is to say, that the addition of waste ceramic fragment powder is about 20-30 parts, glues
The addition of knot agent is about 25-38 parts.The addition of waste ceramic fragment powder is less, and consumption of binder is more, and described viscous
The ultimate load for tying agent is relatively low, causes blank strength after molding low.
The predominantly useless polished bricks of the raw material of water-permeable brick disclosed in the prior art 2, the formula of raw material are：Useless ceramic tile 10-
40 parts, 66-130 parts of binder, wherein binder includes 60-90 parts of bentonite, 5-20 parts of frit (glass powder etc.), carboxymethyl
1-20 parts of sodium cellulosate.In the prior art, the addition of useless ceramic tile is few, and consumption of binder is extremely more.And the pole of the binder
Limit load load is relatively low, generally in 64.8N or so, causes blank strength after molding low.
In addition, the technological process of existing water-permeable brick is complex, production process is more, and time-consuming, of high cost, technological process
Figure is as shown in Figure 1.Referring to Fig. 1, the binder of existing water-permeable brick needs individual ball milling, still, ball milling process operations time
Long, ball-grinding machine is bulky, takes up a large area, and will considerably increase the production cost of water-permeable brick in this way.
Moreover, existing water-permeable brick, particle or fiber substance in rainwater (sewage) are easy wall built-up, in rainwater (sewage)
Particle or fiber substance not easily pass through the hole gap of water-permeable brick, the hole gap of water-permeable brick is easy to block.
Invention content
Technical problem to be solved by the present invention lies in provide a kind of sintering brick permeable to water, the intensity of the water-permeable brick is high, anti-
Jelly property is strong, excellent water permeability, and particle in rainwater (sewage) or fiber substance are not easy wall built-up, and water-permeable brick hole gap is not easy
It blocks.
In order to solve the above technical problem, the present invention provides a kind of sintering brick permeable to water being not easy to plug, including fabric and
Bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
80-100 parts of aggregate
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
The aggregate first passes through ball-milling treatment in advance.
As the improvement of said program, including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is such as
Under：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
The aggregate first passes through ball-milling treatment in advance.
As the improvement of said program, the aggregate first passes through ball-milling treatment in advance, including：
Aggregate is sent into ball mill and is dry grinded, ballstone, the mutual collision friction of aggregate itself are not provided in ball mill.
As the improvement of said program, the aggregate of the fabric includes：
4-20 mesh aggregates 100wt%.
As the improvement of said program, the aggregate of the bottom material includes：
4-20 mesh aggregates 20-50wt%
12-40 mesh aggregates 20-50wt%
40 mesh aggregate 0-60wt% of ＜.
As the improvement of said program, the polyacrylamide solution is Sodium Polyacrylate, polyvinyl pyridine salt, polyethylene
It is one or more in imines；
The clay is one or more in kaolin, black mud, Municipal sludge；
The aggregate includes one or more in useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag；Wherein,
The useless ceramic tile includes one or more in useless polished bricks, useless glazed tile, useless internal wall brick, useless Antique Imitation Tiles；The stone material particle
Including granite, Luoyuan is red, one or more in quartz, porcelain stone, potassium feldspar, albite；The slag include Iron-ore Slag,
It is one or more in Copper Slag.
As the improvement of said program, the dosage weight ratio of the bottom material and fabric is 70-100:0-30.
Correspondingly, the present invention also provides a kind of preparation methods for the sintering brick permeable to water being not easy to plug, including：
(1) aggregate is crushed；
(2) broken aggregate is subjected to ball-milling treatment；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, obtain green body；
(6) green body through in kiln and firing, obtain finished product.
As the improvement of said program, step (2) includes：
Aggregate is sent into ball mill and is dry grinded, ballstone, the mutual collision friction of aggregate itself are not provided in ball mill.
As the improvement of said program, in the compression moulding step, the pressure of press is 1500-2000T；
In the firing step, the temperature of firing is 1100-1220 DEG C.
Implement the present invention, has the advantages that：
Water-permeable brick of the present invention is mainly made of aggregate, binder, wherein aggregate can be useless ceramic tile, stone material particle, mine
Slag, gangue, chain grate furnace slag it is one or more, moreover, the amount ratio of aggregate it is common water-permeable brick it is much higher, the use of aggregate
＞ 85% is measured, the solid wastes such as useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag can be largely consumed, reaches height
The purpose for recycling solid waste, turns waste into wealth, environmental protection and energy saving.
The binder includes bonding base-material and liquid glue, and it can be bentonite, kaolin, black mud or city to bond base-material
One or more in municipal sludge, liquid glue is innovatively added in binder of the present invention, considerably increases binder first
The ultimate load of ultimate load, binder is up to 150.8N, improves the blank strength of water-permeable brick；Secondly, binder of the present invention
So that green body is easily molded, simplifies molding process, reduce molding difficulty；Finally, binder of the present invention is easy to operate, only needs letter
Single batch mixing simplifies process, reduces cost without the step of being pre-mixed ball milling.
The preparation method of water-permeable brick of the present invention includes broken raw material, screening, compounding, mixing stirring, compression moulding, firing etc.
Step, binder of the invention are not necessarily to ball milling, simplify process, reduce cost, shorten the production time, and pass through above-mentioned preparation method
Water-permeable brick obtained, intensity height, excellent water permeability, frost resistance are strong.
Moreover, the aggregate of fabric of the present invention first passes through ball-milling treatment in advance, specifically under the premise of being added without ball-milling medium
Aggregate is dry grinded, the particle of aggregate becomes relatively round and smooth by ball milling rear surface does not have burr, so that rainwater is (dirty
Water) in particle or fiber substance be not easy wall built-up, be easier to pass through, and hole gap is not easy to plug.
Description of the drawings
Fig. 1 is the process flow chart of the existing sintering brick permeable to water being not easy to plug；
Fig. 2 is the process flow chart for the sintering brick permeable to water that the present invention is not easy to plug.
Specific implementation mode
To make the object, technical solutions and advantages of the present invention clearer, the present invention is made into one below in conjunction with attached drawing
Step ground detailed description.
The present invention provides a kind of sintering brick permeable to water being not easy to plug, including fabric and bottom material, the bottom material and fabric
Dosage weight ratio is 70-100:0-30.Preferably, the dosage weight ratio of the bottom material and fabric is 80-90:10-20.Work as fabric
When mixture is 0, water-permeable brick only includes bottom, and all-body tile is made.When water-permeable brick needs color, water-permeable brick include face layer and
The dosage weight ratio of bottom, bottom material mixture and fabric mixture is 70-99.9:0.1-30.
Wherein, primary raw material of the bottom material in terms of mass parts is as follows：
80-100 parts of aggregate
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more.
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more.
The present invention selects specific binder, is formed by bonding base-material and liquid glue, wherein, base-material is bonded with plastic
Property, it can help to be molded and enhance blank strength, liquid glue can make clinker and bond the combination of base-material more closely.The two is matched
It closes, it can be ensured that the intensity and good firing property that water-permeable brick has had in process of production.
Specifically, the intensity of water-permeable brick of the present invention mainly respectively refers to two stages：After one stage is press-molding
Shaping strength (mainly ensures molding blank not cracky before firing), and one is that product intensity after firing (mainly produces
The final performance of product, product using when can bear great pressure, such as vehicle can be forced up directly).This hair
Prescribed liquid glue is mainly used for ensureing the processability and shaping strength of formula；Bond the base-material mainly energy after high temperature sintering
It is enough that cementation is played between particle and particle, it is the intensity for ensureing final products.
The aggregate first passes through ball-milling treatment in advance, including：Aggregate is sent into ball mill and is dry grinded, is not set in ball mill
There are ballstone, the mutual collision friction of aggregate itself.
The aggregate of fabric of the present invention first passes through ball-milling treatment in advance, and the particle of aggregate becomes relatively round and smooth by ball milling rear surface
There is no burr, so that the particle or fiber substance in rainwater (sewage) are not easy wall built-up, is easier to pass through, and hole gap is not
Easily block.
As the preferred embodiment of the present invention, primary raw material of the bottom material in terms of mass parts is as follows：
90-96 parts of aggregate
Bond 5-8 parts of base-material
8-8 parts of liquid glue
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more.
It is additionally added frit as the present invention more preferably embodiment, the binder, that is,
Primary raw material of the bottom material in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more.
The aggregate first passes through ball-milling treatment in advance, including：Aggregate is sent into ball mill and is dry grinded, is not set in ball mill
There are ballstone, the mutual collision friction of aggregate itself.
The aggregate of fabric of the present invention first passes through ball-milling treatment in advance, and the particle of aggregate becomes relatively round and smooth by ball milling rear surface
There is no burr, so that the particle or fiber substance in rainwater (sewage) are not easy wall built-up, is easier to pass through, and hole gap is not
Easily block.
After frit is added in the present invention, product strength can be improved and reduce the firing temperature of water-permeable brick.
In any of the above-described formula, the polyacrylamide solution is preferably Sodium Polyacrylate, polyvinyl pyridine salt, poly- second
It is one or more in alkene imines.The present invention selects the macromolecules such as Sodium Polyacrylate, polyvinyl pyridine salt, polyethyleneimine organic
Flocculant so that liquid glue can fully wrap up the surface of water-permeable brick particles of aggregates, improve the intensity of water-permeable brick.
The clay is one or more in kaolin, black mud, Municipal sludge.The present invention can singly not use swollen
Profit soil can also use the clays such as kaolin, black mud, Municipal sludge, substantially increase the convenience of application, raw material sources
It is abundant.
The present invention is using base-material and liquid glue composition binder is bonded, and binder is in the case where being added equivalent, the present invention
The performance comparison of binder and existing binder is as follows：
| Binder | Test green body size (mm) | Ultimate load (N) | Cost |
| The existing binder in market | 80×40×15 | 62-65 | 7.92 yuan/square |
| Binder of the present invention | 80×40×15 | 150-160 | 3.2 yuan/square |
Liquid glue is innovatively added in binder of the present invention, considerably increases the ultimate load of binder first, the present invention
The ultimate load of binder is up to 150.8N, improves the blank strength of water-permeable brick；Secondly, binder of the present invention so that green body is easy
Molding simplifies molding process, reduces molding difficulty；Finally, binder of the present invention is easy to operate, and only the simple batch mixing of need is
Can, without the step of being pre-mixed ball milling, simplifies process, reduce cost.
Further, the aggregate includes one kind or more in useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag
Kind；Wherein, the useless ceramic tile includes one or more in useless polished bricks, useless glazed tile, useless internal wall brick, useless Antique Imitation Tiles；It is described
Stone material particle includes one or more in red granite, Luoyuan, quartz, porcelain stone, potassium feldspar, albite；The slag packet
It includes one or more in Iron-ore Slag, Copper Slag.
Preferably, the aggregate includes one kind in useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag；Wherein,
The useless ceramic tile includes one kind in useless polished bricks, useless glazed tile, useless internal wall brick, useless Antique Imitation Tiles；The stone material particle includes flower
Gang Yan, Luoyuan be red, one kind in quartz, porcelain stone, potassium feldspar, albite；The slag includes one in Iron-ore Slag, Copper Slag
Kind.
The aggregate of the present invention can select plurality of raw materials, and be not limited solely to useless polished bricks, moreover, the amount ratio of aggregate
Common water-permeable brick is much higher, and the dosage ＞ 85% of aggregate can largely consume useless ceramic tile, stone material particle, slag, bastard coal
The solid wastes such as stone, chain grate furnace slag, achieve the purpose that height recycle solid waste, turn waste into wealth, environmental protection and energy saving.
In order to improve the intensity of water-permeable brick, the processability of water-permeable brick green body is improved, the aggregate selects specific granularity
Collocation, it is specific as follows：
The aggregate of the fabric includes：
4-20 mesh aggregates 100wt%.
The aggregate of the fabric selects the aggregate of 4-20 mesh, this grain composition to contribute to finished product to form hole, reach
Water effect, and obtain good appearance property and comfort level.
If fabric particle is too big, one side finished surface is too coarse, be not suitable for square brick use, people go to above or
Person's bicycle rides over influences comfort level above, and on the other hand, the flatness on adobe surface can be poor, and especially marginal position is uneven
Whole, paving comes out aesthetics and adaptation is poor.
The aggregate of the bottom material includes：
4-20 mesh aggregates 20-50wt%
12-40 mesh aggregates 20-50wt%
40 mesh aggregate 0-60wt% of ＜.
The aggregate of the bottom material selects the aggregate of 4-20 mesh, 40 mesh of 12-40 mesh and ＜, and 4-20 mesh, 12-40 mesh with
And the aggregate of 40 mesh of ＜ mixes according to a certain ratio, this grain composition contributes to finished product to form hole, reaches permeable effect.And
And can also allow the material for breaking off and that can all be finished substantially as far as possible in the case where meeting product final strength, there are remaining
Material, it is cost-effective, it avoids wasting.
Correspondingly, as shown in Fig. 2, the present invention also provides a kind of preparation methods for the sintering brick permeable to water being not easy to plug, including：
(1) aggregate is crushed；
(2) broken aggregate is subjected to ball-milling treatment；
Specifically, the aggregate first passes through ball-milling treatment in advance, including：Aggregate is sent into ball mill and is dry grinded, ball milling
Ballstone, the mutual collision friction of aggregate itself are not provided in machine.
The aggregate of fabric of the present invention first passes through ball-milling treatment in advance, and the particle of aggregate becomes relatively round and smooth by ball milling rear surface
There is no burr, so that the particle or fiber substance in rainwater (sewage) are not easy wall built-up, is easier to pass through, and hole gap is not
Easily block.
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, obtain green body；
In the compression moulding step, the pressure of press is 1500-2000T.Preferably, the pressure of press is 1600-
1800T。
(6) green body through in kiln and firing, obtain finished product.
In the firing step, the temperature of firing is 1100-1220 DEG C.Preferably, the temperature of firing is 1180-1200
℃。
Water-permeable brick produced by the present invention and existing water-permeable brick, performance comparison are as follows：
It should be noted that compression strength of the present invention passes through under conditions of being 27 DEG C of temperature, humidity 53%
YQ027SHT4305 microcomputer controlled electro-hydraulic servo testing machines measure, and the specimen sample specification of the water-permeable brick is as follows：Long 68mm, width
64mm.The examination criteria reference standard JG/T 376-2012 of frost resistance are carried out.
From the foregoing, it will be observed that compared with prior art, compression strength of the invention, which has, to be obviously improved, coefficient of permeability there has also been
Significantly improve, and frost resistance might as well, wherein after 25 Frozen-thawed cycleds, mass loss is few, loss of strength is few.
With specific embodiment, the present invention is further explained below
Embodiment 1
(1) it is formulated：Including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
Aggregate 80kg
Bond base-material 3kg
Liquid glue 3kg；
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
(2) preparation method
(1) aggregate is crushed；
(2) broken aggregate is sent into ball mill and is dry grinded, ballstone is not provided in ball mill, aggregate itself is mutual
Collision friction；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, the pressure of press is 1500T, obtains base
Body；
(6) green body through in kiln and firing, the temperature of firing is 1100 DEG C, obtains finished product.
Embodiment 2
(1) it is formulated：Including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
Aggregate 90kg
Bond base-material 4kg
Liquid glue 4kg；
The cohesive base-material is kaolin, and the liquid glue is Sodium Polyacrylate；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is kaolin, and the liquid glue is Sodium Polyacrylate；
(2) preparation method
(1) aggregate is crushed；
(2) broken aggregate is sent into ball mill and is dry grinded, ballstone is not provided in ball mill, aggregate itself is mutual
Collision friction；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, the pressure of press is 1800T, obtains base
Body；
(6) green body through in kiln and firing, the temperature of firing is 1180 DEG C, obtains finished product.
Embodiment 3
(1) it is formulated：Including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
Aggregate 95kg
Bond base-material 8kg
Liquid glue 8kg；
The cohesive base-material is Municipal sludge, and the liquid glue is guar gum solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is Municipal sludge, and the liquid glue is guar gum solution；
(2) preparation method
(1) aggregate is crushed；
(2) broken aggregate is sent into ball mill and is dry grinded, ballstone is not provided in ball mill, aggregate itself is mutual
Collision friction；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, the pressure of press is 1900T, obtains base
Body；
(6) green body through in kiln and firing, the temperature of firing is 1200 DEG C, obtains finished product.
Embodiment 4
(1) it is formulated：Including fabric and bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
Aggregate 100kg
Bond base-material 6kg
Liquid glue 6kg；
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is bentonite, and the liquid glue is silicon sol solution；
(2) preparation method
(1) aggregate is crushed；
(2) broken aggregate is sent into ball mill and is dry grinded, ballstone is not provided in ball mill, aggregate itself is mutual
Collision friction；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；It will sieving
Particles of aggregates afterwards is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, the pressure of press is 1900T, obtains base
Body；
(6) green body through in kiln and firing, the temperature of firing is 1210 DEG C, obtains finished product.
Embodiment 5
(1) it is formulated：Including bottom material, wherein primary raw material of the bottom material in terms of mass parts is as follows：
Aggregate 100kg
Bond base-material 12kg
Liquid glue 12kg；
The cohesive base-material is bentonite, and the liquid glue is Sodium Polyacrylate；
(2) preparation method
(1) aggregate is crushed；
(2) broken aggregate is sent into ball mill and is dry grinded, ballstone is not provided in ball mill, aggregate itself is mutual
Collision friction；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；
(5) by the bottom material after stirring through cloth and compression moulding, the pressure of press is 2000T, obtains green body；
(6) green body through in kiln and firing, the temperature of firing is 1220 DEG C, obtains finished product.
Embodiment 1-5 is done into technology detection, it is as a result as follows：
(1) Mechanics Performance Testing:
From the foregoing, it will be observed that sintering brick permeable to water of the present invention, compression strength >=55MPa, coefficient of permeability >=4.2*10-2, and 25 jellies
Melt cycle after mass loss and compression strength loss rate it is all very small, it was demonstrated that frost resistance is good.
(2) water permeability is tested:
The common water-permeable brick a and water-permeable brick b of the present invention for taking same weight, toward common water-permeable brick a and this within the same time
The equal area of invention water-permeable brick b pours into the sewage slurry that 100g is in suspended state respectively, will be general after sewage slurry has all flowed
Logical water-permeable brick a and water-permeable brick b of the present invention weighs respectively, and the weightening of common water-permeable brick a and water-permeable brick b of the present invention are specific as follows:
| Project | Common water-permeable brick | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Weightening | 26.21g | 16.01g | 15.85g | 17.15g | 15.87g | 16.34g | 15.91g |
From the foregoing, it will be observed that when the particle or fiber substance in rainwater (sewage) flow through water-permeable brick of the present invention, it is not easy wall built-up, compared with
Easily pass through, after sewage slurry flows through, the sewage remained in water-permeable brick is few, is reduced close to 40% compared with common water-permeable brick.
In conclusion implementing the present invention, have the advantages that：
Water-permeable brick of the present invention is mainly made of aggregate, binder, wherein aggregate can be useless ceramic tile, stone material particle, mine
Slag, gangue, chain grate furnace slag it is one or more, moreover, the amount ratio of aggregate it is common water-permeable brick it is much higher, the use of aggregate
＞ 85% is measured, the solid wastes such as useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag can be largely consumed, reaches height
The purpose for recycling solid waste, turns waste into wealth, environmental protection and energy saving.
The binder includes bonding base-material and liquid glue, and it can be bentonite, kaolin, black mud or city to bond base-material
One or more in municipal sludge, liquid glue is innovatively added in binder of the present invention, considerably increases binder first
The ultimate load of ultimate load, binder is up to 150.8N, improves the blank strength of water-permeable brick；Secondly, binder of the present invention
So that green body is easily molded, simplifies molding process, reduce molding difficulty；Finally, binder of the present invention is easy to operate, only needs letter
Single batch mixing simplifies process, reduces cost without the step of being pre-mixed ball milling.
The preparation method of water-permeable brick of the present invention includes broken raw material, screening, compounding, mixing stirring, compression moulding, firing etc.
Step, binder of the invention are not necessarily to ball milling, simplify process, reduce cost, shorten the production time, and pass through above-mentioned preparation method
Water-permeable brick obtained, intensity height, excellent water permeability, frost resistance are strong.
Moreover, the aggregate of fabric of the present invention first passes through ball-milling treatment in advance, specifically under the premise of being added without ball-milling medium
Aggregate is dry grinded, the particle of aggregate becomes relatively round and smooth by ball milling rear surface does not have burr, so that rainwater is (dirty
Water) in particle or fiber substance be not easy wall built-up, be easier to pass through, and hole gap is not easy to plug.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than is protected to the present invention
The limitation of range is protected, although being explained in detail to the present invention with reference to preferred embodiment, those skilled in the art should
Understand, technical scheme of the present invention can be modified or replaced equivalently, without departing from the essence of technical solution of the present invention
And range.
Claims (10)
1. a kind of sintering brick permeable to water being not easy to plug, which is characterized in that including fabric and bottom material, wherein the bottom material is with quality
The primary raw material of part meter is as follows：
80-100 parts of aggregate
Bond 3-12 parts of base-material
3-12 parts of liquid glue；
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
The aggregate first passes through ball-milling treatment in advance.
2. the sintering brick permeable to water being not easy to plug as described in claim 1, which is characterized in that including fabric and bottom material, wherein institute
It is as follows to state primary raw material of the bottom material in terms of mass parts：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
Primary raw material of the fabric in terms of mass parts is as follows：
The cohesive base-material is one or more in bentonite, clay；
The liquid glue be silicon sol solution, polyacrylamide solution, guar gum solution it is one or more；
The aggregate first passes through ball-milling treatment in advance.
3. the sintering brick permeable to water being not easy to plug such as claim 1-2 any one of them, which is characterized in that the aggregate passes through in advance
Ball-milling treatment is crossed, including：
Aggregate is sent into ball mill and is dry grinded, ballstone, the mutual collision friction of aggregate itself are not provided in ball mill.
4. the sintering brick permeable to water being not easy to plug as claimed in claim 3, which is characterized in that the aggregate of the fabric includes：
4-20 mesh aggregates 100wt%.
5. the sintering brick permeable to water being not easy to plug as claimed in claim 3, which is characterized in that the aggregate of the bottom material includes：
4-20 mesh aggregates 20-50wt%
12-40 mesh aggregates 20-50wt%
40 mesh aggregate 0-60wt% of ＜.
6. the sintering brick permeable to water being not easy to plug such as claim 1-2 any one of them, which is characterized in that the polyacrylamide
Solution is one or more in Sodium Polyacrylate, polyvinyl pyridine salt, polyethyleneimine；
The clay is one or more in kaolin, black mud, Municipal sludge；
The aggregate includes one or more in useless ceramic tile, stone material particle, slag, gangue, chain grate furnace slag；Wherein, described
Useless ceramic tile includes one or more in useless polished bricks, useless glazed tile, useless internal wall brick, useless Antique Imitation Tiles；The stone material particle includes
Granite, Luoyuan be red, one or more in quartz, porcelain stone, potassium feldspar, albite；The slag includes Iron-ore Slag, copper mine
It is one or more in slag.
7. the sintering brick permeable to water being not easy to plug such as claim 1-2 any one of them, which is characterized in that the bottom material and fabric
Dosage weight ratio be 70-100:0-30.
8. a kind of preparation method of sintering brick permeable to water being not easy to plug as described in claim 1-7, which is characterized in that including：
(1) aggregate is crushed；
(2) broken aggregate is subjected to ball-milling treatment；
(3) aggregate after ball milling is sieved, obtains the particle of different grain size range；
(4) it by the particles of aggregates after sieving, is added and bonds base-material, liquid glue, and stir evenly, obtain bottom material；After sieving
Particles of aggregates is added and bonds base-material, liquid glue and colorant, and stirs evenly, and obtains fabric；
(5) by after stirring fabric and bottom material through cloth twice and compression moulding, obtain green body；
(6) green body through in kiln and firing, obtain finished product.
9. the preparation method for the sintering brick permeable to water being not easy to plug as claimed in claim 8, which is characterized in that step (2) packet
It includes：
Aggregate is sent into ball mill and is dry grinded, ballstone, the mutual collision friction of aggregate itself are not provided in ball mill.
10. the preparation method for the sintering brick permeable to water being not easy to plug as claimed in claim 8, which is characterized in that described to be pressed into
In type step, the pressure of press is 1500-2000T；
In the firing step, the temperature of firing is 1100-1220 DEG C.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711401192.7A CN108558358A (en) | 2017-12-22 | 2017-12-22 | A kind of sintering brick permeable to water and preparation method thereof being not easy to plug |
| PCT/CN2018/100125 WO2019119824A1 (en) | 2017-12-22 | 2018-08-11 | Non-clogging sintered water-permeable brick and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711401192.7A CN108558358A (en) | 2017-12-22 | 2017-12-22 | A kind of sintering brick permeable to water and preparation method thereof being not easy to plug |
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| Publication Number | Publication Date |
|---|---|
| CN108558358A true CN108558358A (en) | 2018-09-21 |
Family
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| CN201711401192.7A Withdrawn CN108558358A (en) | 2017-12-22 | 2017-12-22 | A kind of sintering brick permeable to water and preparation method thereof being not easy to plug |
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| CN (1) | CN108558358A (en) |
| WO (1) | WO2019119824A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109369211A (en) * | 2018-12-25 | 2019-02-22 | 佛山科学技术学院 | A kind of light ceramics and preparation method thereof |
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| 戴武斌等: "工艺条件对环保型透水砖基本性能的影响分析", 《中国陶瓷工业》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109369211A (en) * | 2018-12-25 | 2019-02-22 | 佛山科学技术学院 | A kind of light ceramics and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2019119824A1 (en) | 2019-06-27 |
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