CN108558208A - A kind of environment protection architecture ceramic glaze and preparation method thereof - Google Patents
A kind of environment protection architecture ceramic glaze and preparation method thereof Download PDFInfo
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- CN108558208A CN108558208A CN201711345827.6A CN201711345827A CN108558208A CN 108558208 A CN108558208 A CN 108558208A CN 201711345827 A CN201711345827 A CN 201711345827A CN 108558208 A CN108558208 A CN 108558208A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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Abstract
Include being prepared by the raw material of following parts by weight the invention discloses a kind of environment protection architecture ceramic glaze and preparation method thereof:20 35 parts of polymeric modification phenolic resin, 20 30 parts of nano-ceramic powder, 15 30 parts of alumina fibre, 10 20 parts of glair, 8 15 parts of kaolin, 20 35 parts of building waste residue soil, 10 12 parts of calcite in powder, 11 22 parts of zirconium oxychloride solution, 7 15 parts of methylene-bisacrylamide, 8 18 parts of magnesia, 5 10 parts of silicon hydroxide, 5 10 parts of spodumene.The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity is long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction;Ceramic waste greatly reduces the production cost of heat-insulating construction material as raw materials for production;Ceramic waste occupies a large amount of soils, causes environmental pollution, and the present invention realizes that the comprehensive utilization to building waste residue soil, energy conservation and environmental protection reduce pollution using it as a kind of raw material of industry.
Description
Technical field
The present invention relates to technical field of ceramic preparation, and in particular to a kind of environment protection architecture ceramic glaze and preparation method thereof.
Background technology
With increasing with wall heat insulation material associated fire disaster accident, building field is proposed in exterior insulation
Using fire prevention isolation and without ways such as cavitys in system, organic insulation material combustion characteristics Flame can be solved in this way and is easily passed
The defect broadcast, easily spread, to avoid the fire incident caused by causing flame spread, propagation inflammable thermal insulation material.But
It is that temperature tolerance, flame resistance and organic guarantor of the organic insulation material on wall body structure are not researched and solved in fireproof construction
Adiabator discharges cigarette poison gas in a fire, and the thermoplasticity such as EPS, XPS organic insulation material itself generates molten in combustion
The problems such as melting, dripping.This mean that fire-protection rating is low existing for organic insulation material technology, stability and durability difference
Inherent shortcoming has not adapted to requirement of the society to building thermal insulation material.
With social economy and the fast development of ceramic industry, ceramic industry waste material is increasing, and handling these waste materials needs
A large amount of social resources are expended, the sustainable development of development and the ceramic industry of urban economy is limited on partial extent.Mesh
Before, the processing of China's ceramic industry waste material and producing level are relatively low, and a large amount of waste residue ties up public resource, make environment by
Pollution.With the increase of ceramics production capacity, the quantity of waste material is more and more, and a large amount of polymeric modification phenolic resin is not
Soluble problem is simply filled, the accumulation of polymeric modification phenolic resin ties up soil, and fine dust influences local air
Quality, and the landfill of polymeric modification phenolic resin expends a large amount of manpower and materials, goes back polluted underground water matter, how to turn waste into wealth,
Polymeric modification phenolic resin progress recycling is rationally utilized, the task of top priority of science and technology and environmental protection administration is had become.
Ceramic material has many advantages, such as, such as beautiful and generous, acid and alkali-resistance, high temperature resistant, adds in daily necessities, building materials, machinery
The various fields such as work have extensive use.Aluminium oxide and zirconium oxide are two kinds of components common in ceramic material, and aluminium oxide has
The excellent properties such as the low, high temperature resistant of proportion have extensive use in ceramic material field, but its flexural strength and fracture toughness are relatively low
;Zirconium oxide has good flexural strength, is known as " Ceramo-steel ", but its proportion is larger, it will usually increase the weight of finished product.Oxygen
The combination for changing both zirconium and aluminium oxide, prepares composite ceramic material technology and receives more and more attention.Nickel oxide is logical
It is commonly used for the pigment of ceramic material.
Invention content
To solve the above problems, the present invention provides a kind of building waste utilization rate height, product water absorption rate is low, antifouling property
Environment protection architecture ceramic glaze and preparation method thereof good, intensity is high.
To achieve the above object, the technical solution that the present invention takes is:
A kind of environment protection architecture ceramic glaze and preparation method thereof, includes being prepared by the raw material of following parts by weight:Polymeric modification
20-35 parts of phenolic resin, 20-30 parts of nano-ceramic powder, 15-30 parts of alumina fibre, 10-20 parts of glair, kaolin 8-15
Part, 20-35 parts of building waste residue soil, 10-12 parts of calcite in powder, 11-22 parts of zirconium oxychloride solution, methylene-bisacrylamide 7-
15 parts, it is 8-18 parts of magnesia, 5-10 parts of silicon hydroxide, 5-10 parts of spodumene, 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
Further, a kind of environment protection architecture ceramic glaze includes being prepared by the raw material of following parts by weight:Polymeric modification
21-34 parts of phenolic resin, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, 11-19 parts of glair, kaolin 9-14
Part, 22-33 parts of building waste residue soil, 11-12 parts of calcite in powder, 15-20 parts of zirconium oxychloride solution, methylene-bisacrylamide 8-
14 parts, it is 9-17 parts of magnesia, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene, 5-7 parts of foaming agent, gelling agent 6-8 parts additional.
Further, the glair is one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
Further, a kind of preparation method of environment protection architecture ceramic glaze, includes the following steps:
S1, by 21-34 parts of polymeric modification phenolic resin, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, kaolin
8-15 parts, 20-35 parts of building waste residue soil, after the mixing of 11-12 parts of calcite in powder, be added after pulverizer crushes, cross 100-
130 mesh screens, obtain material;
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, zirconium oxychloride solution 15-20
Part, 8-14 parts of methylene-bisacrylamide, 9-17 parts of magnesia, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene carry out wet ball mill 10-
20min, repeatedly ball milling 2-3 times, obtains ceramic slurry;
S3,5-7 parts of foaming agent, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly;It is modified
Solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Further, a kind of environment protection architecture ceramic glaze includes being prepared by the raw material of following parts by weight:Polymeric modification
28 parts of phenolic resin, 25 parts of nano-ceramic powder, 19 parts of alumina fibre, 17 parts of glair, 11 parts of kaolin, building waste residue soil 27
Part, 11 parts of calcite in powder, 18 parts of zirconium oxychloride solution, 11 parts of methylene-bisacrylamide, 15 parts of magnesia, silicon hydroxide 7
Part, 8 parts of spodumene, 6 parts of foaming agent, 7 parts of additional gelling agent.
The present invention is useless using polymeric modification phenolic resin, nano-ceramic powder, alumina fibre, glair, kaolin, building
Dregs, calcite in powder, zirconium oxychloride solution, methylene-bisacrylamide, magnesia, silicon hydroxide, spodumene effectively match,
Building ceramics are obtained, temperature in use is up to 900 DEG C, prevents fires completely, and the high service life of intensity is long, alternative existing wall
Body material and inflammable thermal insulation material, the safety enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness
It significantly improves, and high temperature resistant and wear-resisting excellent, can be widely used for various requiring high field to use mineral and change the strength of materials
Work raw material.
The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity
Long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction;Ceramic waste
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced;Ceramic waste occupies a large amount of soils, causes ring
Border is polluted, and the present invention realizes that the comprehensive utilization to building waste residue soil, energy conservation and environmental protection are reduced dirty using it as a kind of raw material of industry
Dye;Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources;Cheap, production
It is simple for process, it is suitble to large-scale production.
Specific implementation mode
In order to make objects and advantages of the present invention be more clearly understood, the present invention is carried out with reference to embodiments further detailed
Explanation.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not intended to limit the present invention.
The present invention includes being prepared by the raw material of following parts by weight:20-35 parts of polymeric modification phenolic resin, nano ceramics
20-30 parts of powder, 15-30 parts of alumina fibre, 10-20 parts of glair, 8-15 parts of kaolin, 20-35 parts of building waste residue soil, Fang Xie
10-12 parts of mountain flour, 11-22 parts of zirconium oxychloride solution, 7-15 parts of methylene-bisacrylamide, 8-18 parts of magnesia, hydroxide
It is 5-10 parts of silicon, 5-10 parts of spodumene, 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
A kind of environment protection architecture ceramic glaze includes being prepared by the raw material of following parts by weight:Polymeric modification phenolic resin
21-34 parts, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, 11-19 parts of glair, 9-14 parts of kaolin, building it is useless
22-33 parts of dregs, 11-12 parts of calcite in powder, 15-20 parts of zirconium oxychloride solution, 8-14 parts of methylene-bisacrylamide, oxidation
It is 9-17 parts of magnesium, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene, 5-7 parts of foaming agent, gelling agent 6-8 parts additional.
The glair is one or more in silica, aluminium oxide, calcium oxide, sodium oxide molybdena and potassium oxide.
A kind of preparation method of environment protection architecture ceramic glaze, includes the following steps:
S1, by 21-34 parts of polymeric modification phenolic resin, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, kaolin
8-15 parts, 20-35 parts of building waste residue soil, after the mixing of 11-12 parts of calcite in powder, be added after pulverizer crushes, cross 100-
130 mesh screens, obtain material;
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, zirconium oxychloride solution 15-20
Part, 8-14 parts of methylene-bisacrylamide, 9-17 parts of magnesia, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene carry out wet ball mill 10-
20min, repeatedly ball milling 2-3 times, obtains ceramic slurry;
S3,5-7 parts of foaming agent, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly;It is modified
Solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
It grinds, crosses 100 mesh sieve, the mixture crossed after shining, which is placed in fireproof die after firing, obtains building composite ceramics.
Embodiment 1:
A kind of preparation method of environment protection architecture ceramic glaze, includes the following steps:
S1, by 26 parts of polymeric modification phenolic resin, 26 parts of nano-ceramic powder, 19 parts of alumina fibre, 12 parts of kaolin, building
After 11 parts of 28 parts of waste residue soil, calcite in powder mixing, after addition pulverizer crushes, 120 mesh screens is crossed, material is obtained;
S2, step S1 is obtained material add water carry out ball milling, then be added 17 parts of glair, 17 parts of zirconium oxychloride solution, methylene
11 parts of base bisacrylamide, 15 parts of magnesia, 7 parts of silicon hydroxide, 7 parts of spodumene carry out wet ball mill 16min, repeatedly ball milling 2-3
It is secondary, obtain ceramic slurry;
S3,6 parts of foaming agent, 7 parts of additional gelling agent plus water are stirred, is heated up to 36 DEG C, stirs evenly;Obtain modified solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Embodiment 2:
A kind of preparation method of environment protection architecture ceramic glaze, includes the following steps:
S1, by 34 parts of polymeric modification phenolic resin, 28 parts of nano-ceramic powder, 27 parts of alumina fibre, 15 parts of kaolin, building
After 12 parts of 35 parts of waste residue soil, calcite in powder mixing, after addition pulverizer crushes, 130 mesh screens is crossed, material is obtained;
S2, step S1 is obtained material add water carry out ball milling, then be added 19 parts of glair, 20 parts of zirconium oxychloride solution, methylene
9 parts of 14 parts of base bisacrylamide, 17 parts of magnesia, 8 parts of silicon hydroxide, spodumene progress wet ball mill 20min, ball milling 3 times repeatedly,
Obtain ceramic slurry;
S3,7 parts of foaming agent, 8 parts of additional gelling agent plus water are stirred, is heated up to 40 DEG C, stirs evenly;Obtain modified solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
Embodiment 3:
A kind of preparation method of environment protection architecture ceramic glaze, includes the following steps:
S1, by 21 parts of polymeric modification phenolic resin, 21 parts of nano-ceramic powder, 16 parts of alumina fibre, 8 parts of kaolin, building
After 11 parts of 20 parts of waste residue soil, calcite in powder mixing, after addition pulverizer crushes, 100 mesh screens is crossed, material is obtained;
S2, step S1 is obtained material add water carry out ball milling, then be added 11 parts of glair, 15 parts of zirconium oxychloride solution, methylene
6 parts of 8 parts of base bisacrylamide, 9 parts of magnesia, 6 parts of silicon hydroxide, spodumene progress wet ball mill 10min, ball milling 2 times, obtain repeatedly
To ceramic slurry;
S3,5 parts of foaming agent, 6 parts of additional gelling agent plus water are stirred, is heated up to 30 DEG C, stirs evenly;Obtain modified solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
The present invention is useless using polymeric modification phenolic resin, nano-ceramic powder, alumina fibre, glair, kaolin, building
Dregs, calcite in powder, zirconium oxychloride solution, methylene-bisacrylamide, magnesia, silicon hydroxide, spodumene effectively match,
Building ceramics are obtained, temperature in use is up to 900 DEG C, prevents fires completely, and the high service life of intensity is long, alternative existing wall
Body material and inflammable thermal insulation material, the safety enhancing ceramics strength that substantially increases building construction is high, compactness is good, toughness
It significantly improves, and high temperature resistant and wear-resisting excellent, can be widely used for various requiring high field to use mineral and change the strength of materials
Work raw material.
The present invention is integrally made of ceramic material, and temperature in use is up to 900 DEG C, is prevented fires completely, and the high service life of intensity
Long, alternative existing materials for wall and inflammable thermal insulation material substantially increase the safety of building construction;Ceramic waste
As raw materials for production, the production cost of heat-insulating construction material is greatly reduced;Ceramic waste occupies a large amount of soils, causes ring
Border is polluted, and the present invention realizes that the comprehensive utilization to building waste residue soil, energy conservation and environmental protection are reduced dirty using it as a kind of raw material of industry
Dye;Production cost is relatively low, is easy to large-scale production, can make a variety of moulding and texture, saves mineral resources;Cheap, production
It is simple for process, it is suitble to large-scale production.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
1. a kind of environment protection architecture ceramic glaze, which is characterized in that include being prepared by the raw material of following parts by weight:Polymeric modification
20-35 parts of phenolic resin, 20-30 parts of nano-ceramic powder, 15-30 parts of alumina fibre, 10-20 parts of glair, kaolin 8-15
Part, 20-35 parts of building waste residue soil, 10-12 parts of calcite in powder, 11-22 parts of zirconium oxychloride solution, methylene-bisacrylamide 7-
15 parts, it is 8-18 parts of magnesia, 5-10 parts of silicon hydroxide, 5-10 parts of spodumene, 4-8 parts of foaming agent, gelling agent 5-9 parts additional.
2. a kind of environment protection architecture ceramic glaze according to claim 1, which is characterized in that include by the original of following parts by weight
Material is prepared:21-34 parts of polymeric modification phenolic resin, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, glair
11-19 parts, 9-14 parts of kaolin, 22-33 parts of building waste residue soil, 11-12 parts of calcite in powder, 15-20 parts of zirconium oxychloride solution,
It is 8-14 parts of methylene-bisacrylamide, 9-17 parts of magnesia, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene, 5-7 parts of foaming agent, outer
Add 6-8 parts of gelling agent.
3. a kind of environment protection architecture ceramic glaze according to claim 1, which is characterized in that the glair is silica, oxygen
Change one or more in aluminium, calcium oxide, sodium oxide molybdena and potassium oxide.
4. a kind of preparation method of environment protection architecture ceramic glaze according to claim 1, which is characterized in that including walking as follows
Suddenly:
S1, by 21-34 parts of polymeric modification phenolic resin, 21-28 parts of nano-ceramic powder, 16-27 parts of alumina fibre, kaolin
8-15 parts, 20-35 parts of building waste residue soil, after the mixing of 11-12 parts of calcite in powder, be added after pulverizer crushes, cross 100-
130 mesh screens, obtain material;
S2, step S1 is obtained material add water carry out ball milling, then be added 11-19 parts of glair, zirconium oxychloride solution 15-20
Part, 8-14 parts of methylene-bisacrylamide, 9-17 parts of magnesia, 6-8 parts of silicon hydroxide, 6-9 parts of spodumene carry out wet ball mill 10-
20min, repeatedly ball milling 2-3 times, obtains ceramic slurry;
S3,5-7 parts of foaming agent, additional gelling agent 6-8 parts are added into water stirring, is heated up to 30-40 DEG C, stirs evenly;It is modified
Solution;
S4, by obtained by step S2 ceramic slurry and step S3 obtain modified solution and be uniformly mixed, the powder after green compact, heat treatment
Mill, sieves with 100 mesh sieve, and the mixture crossed after shining is placed in fireproof die to fire obtains building composite ceramics later.
5. a kind of environment protection architecture ceramic glaze according to claim 1, which is characterized in that include by the original of following parts by weight
Material is prepared:28 parts of polymeric modification phenolic resin, 25 parts of nano-ceramic powder, 19 parts of alumina fibre, 17 parts of glair, kaolinite
11 parts of soil, 27 parts of building waste residue soil, 11 parts of calcite in powder, 18 parts of zirconium oxychloride solution, 11 parts of methylene-bisacrylamide, oxygen
Change 15 parts of magnesium, 7 parts of silicon hydroxide, 8 parts of spodumene, 6 parts of foaming agent, 7 parts of additional gelling agent.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111499198A (en) * | 2020-04-29 | 2020-08-07 | 佛山科学技术学院 | High-strength ceramic glaze for splicing ceramic body and preparation method thereof |
CN115093250A (en) * | 2022-05-16 | 2022-09-23 | 江苏拜富科技股份有限公司 | Wrapping color luster glaze for building ceramic bricks and preparation method thereof |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111499198A (en) * | 2020-04-29 | 2020-08-07 | 佛山科学技术学院 | High-strength ceramic glaze for splicing ceramic body and preparation method thereof |
CN115093250A (en) * | 2022-05-16 | 2022-09-23 | 江苏拜富科技股份有限公司 | Wrapping color luster glaze for building ceramic bricks and preparation method thereof |
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