CN108531007A - A kind of anticorrosive aqueous turn fire prevention priming paint and preparation method thereof that becomes rusty - Google Patents
A kind of anticorrosive aqueous turn fire prevention priming paint and preparation method thereof that becomes rusty Download PDFInfo
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- CN108531007A CN108531007A CN201810488312.XA CN201810488312A CN108531007A CN 108531007 A CN108531007 A CN 108531007A CN 201810488312 A CN201810488312 A CN 201810488312A CN 108531007 A CN108531007 A CN 108531007A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/08—Homopolymers or copolymers of vinylidene chloride
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/329—Phosphorus containing acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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Abstract
The invention discloses a kind of anticorrosive aqueous turn of rust fire prevention priming paint, the component containing following mass parts:Water 10~15, xanthans 0.15~0.25, antifoaming agent 0.2~0.3, ethylene glycol monomethyl ether 1.6~2.1, alcohol ester 12~0.5, wetting agent 0.3~0.4, barium sulfate 17~19, vinylidene chloride acrylic acid copolymer water-base resin 60~65, tannic acid 1.5~2.5, phosphoric acid 0.5~0.8.The anticorrosive water of the present invention turn rust fire prevention priming paint can roller coating, spray, rinse painting, is easy for construction; exempt rust; exempt to polish; directly add water; be particularly suitable for large-scale public place, the present invention in it is anticorrosive aqueous turn rust fire prevention priming paint economize on resources, environmental protection, the present invention in it is anticorrosive aqueous turn rust fire prevention priming paint in contained halogenic ingredient can play fire-retardant effect; and can be more permanent than common product anticorrosive protection, it is better than property to the matching of finishing coat.Also disclose the preparation method of above-mentioned priming paint.
Description
Technical field
The invention belongs to priming paint technical fields of preventing fires, and in particular to a kind of anticorrosive aqueous turn become rusty fire prevention priming paint and its preparation
Method.
Background technology
It has been more than the disasters such as fire, floods, drought and typhoon institute band that the corrosion loss in China, which accounts for the ratio of GDP, at present
The loss summation come.Anticorrosive fire prevention priming paint can be the loss that party in request reduces metal erosion.Especially in southern relative humidity
Area, the anticorrosion of metal seems even more important.After spraying anticorrosive fire prevention priming paint, can suitably it be closed immediately, group
Meet protection system at metal and organic coating, may significantly improve the protective of system, the protection service life further increases.
Current fire prevention priming paint, general molecular weight is big, poor permeability, can only convert relatively thin iron rust, and fire-proof function is poor,
It has a single function, in addition, traditional solvent-borne turns also to contain a large amount of volatile organic solvent and heavy metal in rust fire prevention priming paint
Deng be easy to causeing environmental pollution.
Invention content
The purpose of the present invention is to provide a kind of anticorrosive aqueous turn of rust fire prevention priming paint, and the fire prevention priming paint molecular weight is small, oozes
Permeability is strong, can convert thicker iron rust and can be fire-retardant, is a kind of multi-functional anticorrosive aqueous turn of rust fire prevention priming paint.
The present invention also aims to provide the preparation method of above-mentioned anticorrosive aqueous turn of rust fire prevention priming paint, the preparation method
Concise in technology, it is at low cost.
Above-mentioned first purpose of the present invention is achieved through the following technical solutions:A kind of anticorrosive aqueous turn of rust is anti-
Ashes after a fire paint includes the component of following mass parts:
Preferably, the proportion by weight of each component is:
More preferably, the proportion by weight of each component is:
Preferably, antifoaming agent of the present invention is the antifoaming agent of model BYK028.
Preferably, wetting agent of the present invention is that enlightening is high by 4100.
Preferably, the model PERMAX 805 of vinylidene chloride acrylic acid copolymer water-base resin of the present invention,
PERMAX 805 is a kind of APE-free, low VOC, and the vinylidene chloride acrylate copolymer emulsion of small particle possesses extremely low water
Vapour permeability, splendid corrosion resistance has the storage stability more lengthened relative to traditional vinylidene chloride product, more excellent
Different corrosion resistance has good adhesive force to most of metal substrate.
So the vinylidene chloride acrylic acid copolymer water-base resin in the present invention is low VOC, permeates the inclined of strong small particle
Dichloroethylene acrylic acid copolymer water-base resin, this Resin permeability is strong, has higher changing effect, can solve the thickness due to rust
The disadvantage that degree is high and causes conversion insufficient;And its VOC content is low, more environmentally friendly, is conducive to environment;And the vinylidene chloride propylene
Contain halogen in sour copolymerized waterborne resin, halogen can eliminate high molecular material combustion reaction and generate living radical, make above-mentioned trip
It is reduced from base concentration, to slow down or terminate the chain reaction of burning, achievees the purpose that fire-retardant, effectively act as fireproofing function.
Therefore, the priming paint made of PERMAX 805 applies product by coated side and can get excellent extended protection, contained in coating
Halogenic ingredient can play fire-retardant effect.
Xanthans in the present invention is thickener, with excellent anti-reflection consistence and water solubility, and with good
Ph stability selects xanthans more environmentally friendly safer.
Ethylene glycol monomethyl ether in the present invention is the secondary solvent of water paint, each raw material can be made preferably to be dispersed in
In coating system, it more better than other solvents can help to form a film, improve paint film appearance and initial stage water resistance.
Alcohol ester 12 in the present invention, uses as coalescents, and hydrolytic stability is very good, can be with softening lotion grain
Son, and be to cause preferably to merge in japanning, it will not also be sucked into permeable matrix, can effectively coalescence emulsion grain
Son, freezing point is very low, and winter will not freeze, and has higher stability dissolving power.
Barium sulfate in the present invention is rust resisting pigment, and the potential difference that can reduce metal erosion is reduced into opposite steel substrate
Stable alkali iron construction makes have better anti-corrosion function, and oil absorption is low, and filling effect is good, at low cost.
Phosphoric acid in the present invention can make base material generation complex reaction and chelation, adhesive force more preferable.
Tannic acid in the present invention, have the advantages that it is reproducible, in the presence of phosphoric acid, it is easier to generate it is more steady
Fixed complex compound forms the protective film of reticular structure.
To sum up, the present invention is based on the vinylidene chloride acrylic acid copolymer water-based emulsion of the strong small particle of low VOC, permeability
Component is wanted, tannic acid, phosphoric acid is added, makes the Fe in steel surface and rusty scale3+Complex reaction occurs, forms stable complex compound,
Tannic acid can carry out multiple spot complexing, the webbed protective film of shape with iron.Rust resisting pigment barium sulfate, which is added, reduces metal erosion
Potential difference is reduced into the alkali iron construction that opposite steel substrate is stablized, and has gathered a variety of spies such as stabilization, conversion, permeability in formula
Point, and contained halogenic ingredient can play fire-retardant effect in coating, and a kind of multi-functional anti-corrosion water of formation turns to become rusty and adhere to
The good anticorrosive water of power turns rust fire prevention priming paint.
Above-mentioned second purpose of the present invention is achieved through the following technical solutions:It is anti-that above-mentioned anticorrosive water turns rust
The preparation method of ashes after a fire paint, includes the following steps:
(1) above-mentioned dosage relation is pressed, xanthans and water is taken, stirs evenly, obtain mixed liquor 1;
(2) above-mentioned dosage relation is pressed, cancels infusion, ethylene glycol monomethyl ether, alcohol ester 12 and wetting agent, stirs evenly, obtain mixed liquor
2;
(3) mixed liquor 1 and mixed liquor 2 are stirred evenly, then barium sulfate is added by dosage relation, mixed liquor is obtained after stirring evenly and grinding
3;
(4) it after taking vinylidene chloride acrylic acid copolymer water-base resin, tannic acid and phosphoric acid to stir evenly by dosage relation, is added mixed
It closes in liquid 3, is filtered after stirring evenly and turn rust fire prevention priming paint to get anticorrosive water.
In the preparation method that above-mentioned anticorrosive water turns rust fire prevention priming paint:
Preferably, stir speed (S.S.) is 500~800rpm when being stirred evenly in step (1).
Preferably, stir speed (S.S.) is 80~200rpm when being stirred evenly in step (2).
Preferably, stir speed (S.S.) is 1200~1400rpm when being stirred evenly in step (3).
Preferably, stir speed (S.S.) is 500~800rpm when being stirred evenly in step (4).
It is stirred evenly in step (3) and is ground to fineness at 20 μm or less.
It is filtered with 800 mesh filter screens after being stirred evenly in step (4).
Compared with prior art, the invention has the advantages that:
(1) the anticorrosive aqueous turn of rust fire prevention priming paint of the present invention can roller coating, spray, rinse paintings, is easy for construction, exempt rust, exempt from dozen
Mill directly adds water, is particularly suitable for large-scale public place, such as the renovation of railway station waiting room steel construction and roofing, profiled piece etc. is no
The use constructed well is also very convenient, and the fire prevention priming paint in the present invention can also directly construct on the steel of 40~100 μm of rusty scale,
The potential difference that addition rust resisting pigment barium sulfate can reduce metal erosion is reduced into the alkali iron construction that opposite steel substrate is stablized, set
Stabilization, conversion, the multi-functional feature of permeability, therefore, anticorrosive aqueous turn of rust fire prevention priming paint strong adhesive force in the present invention,
Anti-corrosive properties performance is good, easy for construction;
(2) present invention in it is anticorrosive aqueous turn rust fire prevention priming paint economize on resources, environmental protection, compared to traditional solvent-borne
Property turn rust paint containing a large amount of volatile organic solvent and heavy metal etc., the anticorrosive aqueous turn of rust fire prevention priming paint in the present invention
It is a kind of water paint of low VOC;
(3) the raw material vinylidene chloride acrylic acid copolymer water-base resin of the anticorrosive aqueous turn of rust fire prevention priming paint in the present invention
Containing halogen, halogen can eliminate high molecular material combustion reaction and generate living radical, and above-mentioned free radical concentration is made to reduce, from
And slow down or terminate the chain reaction of burning, achieve the purpose that fire-retardant, effectively acts as fireproofing function, therefore, present invention fire prevention
Contained halogenic ingredient can play fire-retardant effect in aqueous turn of rust priming paint, form a kind of multi-functional anticorrosion water-soluble and turn rust and attached
The coating puted forth effort;
(4) the anticorrosive protection that the anticorrosive aqueous turn of rust fire prevention priming paint in the present invention can be more permanent than common product,
Better than property to the matching of finishing coat, not bleeding is not stratified, and storage period is long, can solve the primer for rusted steel of market simple function not
Foot, wide market have huge economic benefit.
Description of the drawings
Fig. 1 is that 1 moderate resistance of embodiment corrodes the material picture before aqueous turn of rust fire prevention priming paint coating;
Fig. 2 is the material picture that 1 moderate resistance of embodiment corrodes that aqueous turn of rust fire prevention priming paint has just coated;
Fig. 3 be 1 moderate resistance of embodiment corrode aqueous turn rust fire prevention priming paint coated the picture after being dried at room temperature for.
Specific implementation mode
Below by a part of the embodiment, the present invention will be described, it is necessary to which indicated herein is following specific examples
It is served only for that the invention will be further described, does not represent limiting the scope of the invention.Other people make according to the present invention
Some it is nonessential modification and adjustment still fall within protection scope of the present invention.
Embodiment 1
Anticorrosive water provided in this embodiment turns rust fire prevention priming paint, is grouped as by the group of following mass parts:
The anticorrosive water turns the preparation method of rust fire prevention priming paint, includes the following steps:
(1) above-mentioned dosage relation is pressed, xanthans and water is taken, stirs evenly, obtain mixed liquor 1;
(2) above-mentioned dosage relation is pressed, cancels infusion, ethylene glycol monomethyl ether, alcohol ester 12 and wetting agent, stirs evenly, obtain mixed liquor
2;
(3) mixed liquor 1 and mixed liquor 2 are stirred evenly, then barium sulfate is added by dosage relation, mixed liquor is obtained after stirring evenly and grinding
3;
(4) it after taking vinylidene chloride acrylic acid copolymer water-base resin, tannic acid and phosphoric acid to stir evenly by dosage relation, is added mixed
It closes in liquid 3, is filtered after stirring evenly and turn rust fire prevention priming paint to get anticorrosive water.
Stir speed (S.S.) is 500~800rpm when being stirred evenly in step (1).
Stir speed (S.S.) is 80~200rpm when being stirred evenly in step (2).
Stir speed (S.S.) is 1200~1400rpm when being stirred evenly in step (3).
Stir speed (S.S.) is 500~800rpm when being stirred evenly in step (4).
It is stirred evenly in step (3) and is ground to fineness at 20 μm or less.
It is filtered with 800 mesh filter screens after being stirred evenly in step (4).
Embodiment 2
Anticorrosive water provided in this embodiment turns rust fire prevention priming paint, is grouped as by the group of following mass parts:
The anticorrosive water turns the preparation method of rust fire prevention priming paint, with embodiment 1.
Embodiment 3
Anticorrosive water provided in this embodiment turns rust fire prevention priming paint, is grouped as by the group of following mass parts:
The anticorrosive water turns the preparation method of rust fire prevention priming paint, with embodiment 1.
Embodiment 4
Anticorrosive water provided in this embodiment turns rust fire prevention priming paint, is grouped as by the group of following mass parts:
The anticorrosive water turns the preparation method of rust fire prevention priming paint, with embodiment 1.
Embodiment 5
Anticorrosive water provided in this embodiment turns rust fire prevention priming paint, is grouped as by the group of following mass parts:
The anticorrosive water turns the preparation method of rust fire prevention priming paint, with embodiment 1.
Anticorrosive water in embodiment 1-5 is turned rust fire prevention priming paint to be tested for the property, as a result as shown in Table 1 below.
Anticorrosive water in 1 embodiment 1-5 of table turns the performance test results of rust fire prevention priming paint
From table 1 it follows that the anticorrosive aqueous turn of rust fire prevention priming paint in the present invention, turn rust effect is good, strong adhesive force,
Water resistance is strong, and salt-fog resistant time is long, can play certain fire retardation.
Anticorrosive water in embodiment 1-5 is turned into rust fire prevention priming paint and carries out spraying test as coating, coating tests effect
Show that (3# rotors, rotating speed 100rpm) pH value is 1.40 when viscosity is 265cps when the solid content of priming paint is 60.72%, rust
Changing effect does not have to derusting as can be seen that the anticorrosive water of the present invention turns to become rusty when fire prevention priming paint as illustrated in fig. 1-3, from Fig. 1-3,
Rust can be switched to a part for priming paint, and it is good to turn rust effect, strong adhesive force, with it is conventional turn rust paint compared with, permeate, convert and
Filling effect more preferably, also has flame retardant effect, function is more comprehensively.
A part of specific embodiment is enumerated above, and the present invention will be described, it is necessary to which indicated herein is the above specific reality
It applies example and is served only for that the invention will be further described, do not represent limiting the scope of the invention.Other people are according to the present invention
Some the nonessential modifications and adjustment made still fall within protection scope of the present invention.
Claims (10)
1. a kind of anticorrosive aqueous turn of rust fire prevention priming paint, it is characterized in that including the component of following mass parts:
2. anticorrosive aqueous turn of rust fire prevention priming paint according to claim 1, it is characterized in that the proportion by weight of each component is:
3. anticorrosive aqueous turn of rust fire prevention priming paint according to claim 2, it is characterized in that the proportion by weight of each component is:
4. according to the anticorrosive aqueous turn of rust fire prevention priming paint of claim 1-3 any one of them, it is characterized in that:The antifoaming agent
It is the antifoaming agent of model BYK028.
5. according to the anticorrosive aqueous turn of rust fire prevention priming paint of claim 1-3 any one of them, it is characterized in that:The wetting agent
It is high by 4100 for enlightening.
6. according to the anticorrosive aqueous turn of rust fire prevention priming paint of claim 1-3 any one of them, it is characterized in that:The inclined dichloro
The model PERMAX 805 of ethylene-acrylic acid copolymer water-base resin.
7. claim 1-3 any one of them it is anticorrosive aqueous turn rust fire prevention priming paint preparation method, it is characterized in that include with
Lower step:
(1) above-mentioned dosage relation is pressed, xanthans and water is taken, stirs evenly, obtain mixed liquor 1;
(2) above-mentioned dosage relation is pressed, cancels infusion, ethylene glycol monomethyl ether, alcohol ester 12 and wetting agent, stirs evenly, obtain mixed liquor 2;
(3) mixed liquor 1 and mixed liquor 2 are stirred evenly, then barium sulfate is added by dosage relation, mixed liquor 3 is obtained after stirring evenly and grinding;
(4) after taking vinylidene chloride acrylic acid copolymer water-base resin, tannic acid and phosphoric acid to stir evenly by dosage relation, mixed liquor is added
It is filtered in 3, after stirring evenly and turns rust fire prevention priming paint to get anticorrosive water.
8. the preparation method of anticorrosive aqueous turn of rust fire prevention priming paint according to claim 7, it is characterized in that:In step (1)
Stir speed (S.S.) is 500~800rpm when stirring evenly;Stir speed (S.S.) is 80~200rpm when being stirred evenly in step (2);Step stirs evenly in (3)
When stir speed (S.S.) be 1200~1400rpm;Stir speed (S.S.) is 500~800rpm when being stirred evenly in step (4).
9. the preparation method of anticorrosive aqueous turn of rust fire prevention priming paint according to claim 7, it is characterized in that:In step (3)
It stirs evenly and is ground to fineness at 20 μm or less.
10. the preparation method of anticorrosive aqueous turn of rust fire prevention priming paint according to claim 7, it is characterized in that:In step (4)
It is filtered with 800 mesh filter screens after stirring evenly.
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Cited By (2)
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CN112795260A (en) * | 2021-01-18 | 2021-05-14 | 成都华兴邦得建筑装饰材料有限公司 | Water-based rust conversion shielding coating and preparation method thereof |
CN115651436A (en) * | 2022-11-04 | 2023-01-31 | 中海油常州涂料化工研究院有限公司 | Water-based rust conversion anticorrosive paint for maintenance and preparation method thereof |
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CN112795260B (en) * | 2021-01-18 | 2022-05-27 | 成都华兴邦得建筑装饰材料有限公司 | Water-based rust conversion shielding coating and preparation method thereof |
CN115651436A (en) * | 2022-11-04 | 2023-01-31 | 中海油常州涂料化工研究院有限公司 | Water-based rust conversion anticorrosive paint for maintenance and preparation method thereof |
CN115651436B (en) * | 2022-11-04 | 2024-04-30 | 中海油常州涂料化工研究院有限公司 | Maintenance water-based corrosion-conversion anticorrosive paint and preparation method thereof |
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