CN108499337A - One kind efficiently removing nitrogenous contamination gas build air purifying preparation composition - Google Patents

One kind efficiently removing nitrogenous contamination gas build air purifying preparation composition Download PDF

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CN108499337A
CN108499337A CN201810221739.3A CN201810221739A CN108499337A CN 108499337 A CN108499337 A CN 108499337A CN 201810221739 A CN201810221739 A CN 201810221739A CN 108499337 A CN108499337 A CN 108499337A
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parts
extract
chlorine dioxide
sodium chlorate
air purifying
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CN108499337B (en
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王婧宁
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Shanghai Borunke Biotechnology Co ltd
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Guorun Biotechnology (shenzhen) Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/014Deodorant compositions containing sorbent material, e.g. activated carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/108Halogens or halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

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Abstract

The present invention provides one kind and efficiently removing nitrogenous contamination gas build air purifying preparation composition, calculates by weight, described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:0.5 15 parts of palm oil, 15 parts of Acer palmatum extract, 17 parts of Lombardy poplar tree extract, 15 parts of Cedarwood extract, 14 parts of Lignum Santali Albi extract, 2 10 parts of tea tree ethereal oil, 25 parts of cus-cus extract, 2 15 parts of Lignum cinnamomi camphorae extract, 13 parts of lavender extract, 12 parts of needle juniper extract, 5 10 parts of surfactant, 5 10 parts of chlorine dioxide and sodium chlorate slow-releasing composite material, 10 30 parts of ethyl alcohol, 1 15 parts of glycerine, wherein, the chlorine dioxide and sodium chlorate slow-releasing composite material are that beeswax coats activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate.

Description

One kind efficiently removing nitrogenous contamination gas build air purifying preparation composition
Technical field
The present invention relates to air purifying preparation fields, in particular it relates to which a kind of efficiently removing nitrogenous contamination gas build Air purifying preparation composition.
Background technology
With the development of society, environmental problem has become focus of people's attention, air quality is must in people's life The big problem that must be faced because in the modern life various chemical substances it is a large amount of use, the substantial increase gesture of consumption of petroleum The different degrees of pollution of air must be caused, and with the development of the social economy, requirement of the people to quality of life is also continuous It improves, it is to improve local air matter using air purification and deodorization and disinfection class product to contradictory effective way to solve this Amount.
Currently, it is many in relation to the method for polluting air purification, wherein making the pollution in air using adsorbent adsorption method Object concentration is reduced, and is the main method of air purification.CN101422722 is basic material with activated carbon, is added on the activated carbon Soluble cupric salt and simple substance iodine keep filtered air cleaner to eliminate ammonia, nitrogen dioxide, ozone etc..Often Activated carbon have charcoal, bamboo charcoal, fruit stone (shell) charcoal, coal quality charcoal, graphite and expanded graphite and its relevant product such as carbon fiber, Carbon black etc., on the whole, this kind of adsorbent is based on activated carbon, but the aperture difference of most activated carbons is big, is inhaled to pollutant Attached selectivity is bad.
In view of the above-mentioned problems, the present invention, which provides one kind, efficiently removing nitrogenous contamination gas build air purifying preparation composition, have Have in high efficiency of additive capability and degradation air containing pollutants such as polluted by nitrogen.
Invention content
In view of the above-mentioned problems, the present invention, which provides one kind, efficiently removing nitrogenous contamination gas build air purifying preparation composition, press Listed as parts by weight, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:0.5-15 parts of palm oil, chicken feet 1-5 parts of maple extract, 1-7 parts of Lombardy poplar tree extract, 1-5 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, tea tree ethereal oil 2- 10 parts, 2-5 parts of cus-cus extract, 2-15 parts of Lignum cinnamomi camphorae extract, 1-3 parts of lavender extract, 1-2 parts of needle juniper extract, table 5-10 parts of activating agent 5-10 parts of face, chlorine dioxide and sodium chlorate slow-releasing composite material, 10-30 parts of ethyl alcohol, 1-15 parts of glycerine, In, the chlorine dioxide and sodium chlorate slow-releasing composite material are that beeswax coats activated carbon fibre, described activated carbon fiber-loaded two Chlorine monoxid and sodium chlorate.
In one embodiment, it calculates by weight, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation group Closing object includes:3-10 parts of palm oil, 2-5 parts of Acer palmatum extract, 1-3 parts of Lombardy poplar tree extract, 1-3 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, 2-8 parts of tea tree ethereal oil, 2-5 parts of cus-cus extract, 2-10 parts of Lignum cinnamomi camphorae extract, lavender extract 1-3 parts, 1-2 parts of needle juniper extract, 5-10 parts of surfactant, 5-10 parts of chlorine dioxide and sodium chlorate slow-releasing composite material, second 10-30 parts of alcohol, 1-10 parts of glycerine.
In one embodiment, it calculates by weight, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation group Closing object includes:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, Lignum Santali Albi extract 3 parts, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, 8 parts of Lignum cinnamomi camphorae extract, 2 parts of lavender extract, 1 part of needle juniper extract, 7 parts of 8 parts of surfactant, chlorine dioxide and sodium chlorate slow-releasing composite material, 20 parts of ethyl alcohol, 8 parts of glycerine.
In one embodiment, the surfactant includes dodecyl sodium sulfate, palmityl sodium glutamate, tristearin It is one or more in acyl sodium glutamate, Hamposyl L ammonium, cocounut oil acyl Sodium L-alaninate.
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:(0.1-0.4).
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:(0.1-0.2).
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:0.16.
In one embodiment, the ethyl alcohol is the ethyl alcohol that mass fraction is 50-80%.
In one embodiment, the ethyl alcohol is the ethyl alcohol that mass fraction is 70%.
Another aspect of the present invention provides a kind of preparation side efficiently removing nitrogenous contamination gas build air purifying preparation composition Method includes the following steps:
(1)Palm oil, Acer palmatum extract, Lombardy poplar tree extract, Cedarwood extract, wingceltis are added by weight into reactor Fragrant extract, tea tree ethereal oil, cus-cus extract, Lignum cinnamomi camphorae extract, lavender extract, cus-cus extract, needle juniper extraction Object, surfactant are heated to 60 DEG C, are uniformly mixed with the high-shear emulsion machine of 6000rpm;
(2)To glycerine, ethyl alcohol and chlorine dioxide and sodium chlorate slow-releasing composite material are added in step 1, with the high shear of 6000rpm Mulser mixing;After stirring and stablizing, obtains and described efficiently remove nitrogenous contamination gas build air purifying preparation composition.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to following detailed description.
Specific implementation mode
The detailed description for preferred implementation method of the invention below of participating in the election of and including embodiment this hair can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with fields of the present invention The normally understood identical meaning of technical staff.When there is a conflict, the definition in this specification shall prevail.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover non-exclusionism includes.For example, the combination comprising listed elements Object, step, method, product or device are not necessarily limited to those elements, but may include not expressly listed other elements or Such composition, step, method, product or the intrinsic element of device.
Conjunction " Consists of " excludes any element that do not point out, step or component.If in claim, this Phrase will make claim be closed, so that it is not included the material in addition to the material of those descriptions, but relative normal Except rule impurity.When being rather than immediately following after theme in the clause that phrase " Consists of " appears in claim main body, It is only limited to the element described in the clause;Other elements are not excluded except the claim as a whole.
Equivalent, concentration or other values or parameter are excellent with range, preferred scope or a series of upper limit preferred values and lower limit When the Range Representation that choosing value limits, this, which should be understood as, specifically discloses by any range limit or preferred value and any range Any pairing of lower limit or preferred value is formed by all ranges, regardless of whether the range separately discloses.For example, when open When range " 1 to 5 ", described range should be interpreted as including range " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When numberical range is described herein, unless otherwise stated, otherwise range intention includes its end Value and all integers and score in the range.
Singulative includes that plural number discusses object, unless the context clearly dictates otherwise." optional " or it is " arbitrary It is a kind of " refer to that the item described thereafter or event may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, and it is specific to indicate that the present invention is not limited to this Quantity further includes the modified part of the acceptable change without lead to related basic function close to the quantity.Phase It answers, modifies a numerical value with " about ", " about " etc., mean that the present invention is not limited to the exact numericals.In some examples, approximate Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, range limits can be with Combination and/or exchange, these ranges include all subranges contained therebetween if not stated otherwise.
In addition, indefinite article "an" before element of the present invention or component and "one" quantitative requirement to element or component (i.e. occurrence number) unrestriction.Therefore "one" or "an" should be read as including one or at least one, and odd number The element or component of form also include plural form, unless the apparent purport of the quantity refers to singulative.
" polymer " means the polymerizable compound prepared by the monomer by the identical or different type of polymerization.Generic term " polymer " includes term " homopolymer ", " copolymer ", " terpolymer " and " copolymer ".
" copolymer " means the polymer prepared by polymerizeing at least two different monomers.Generic term " copolymer " includes (it is general with term " terpolymer " for term " copolymer " (its generally to refer to the polymer prepared by two kinds of different monomers) To refer to the polymer prepared by three kinds of different monomers).It also includes the polymer manufactured by polymerizeing more kinds of monomers. " blend " means the polymer that two or more polymer is formed by mixing jointly by physics or chemical method.
The present invention provides one kind and efficiently removing nitrogenous contamination gas build air purifying preparation composition, calculates by weight, institute It states and efficiently removes nitrogenous contamination gas build air purifying preparation composition and include:0.5-15 parts of palm oil, Acer palmatum extract 1-5 Part, 1-7 parts of Lombardy poplar tree extract, 1-5 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, 2-10 parts of tea tree ethereal oil, cus-cus 2-5 parts of extract, 2-15 parts of Lignum cinnamomi camphorae extract, 1-3 parts of lavender extract, 1-2 parts of needle juniper extract, surfactant 5-10 Part, 5-10 parts of chlorine dioxide and sodium chlorate slow-releasing composite material, 10-30 parts of ethyl alcohol, 1-15 parts of glycerine, wherein the titanium dioxide Chlorine and sodium chlorate slow-releasing composite material are that beeswax coats activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and chloric acid Sodium.
In one embodiment, it calculates by weight, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation group Closing object includes:3-10 parts of palm oil, 2-5 parts of Acer palmatum extract, 1-3 parts of Lombardy poplar tree extract, 1-3 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, 2-8 parts of tea tree ethereal oil, 2-5 parts of cus-cus extract, 2-10 parts of Lignum cinnamomi camphorae extract, lavender extract 1-3 parts, 1-2 parts of needle juniper extract, 5-10 parts of surfactant, 5-10 parts of chlorine dioxide and sodium chlorate slow-releasing composite material, second 10-30 parts of alcohol, 1-10 parts of glycerine.
In one embodiment, it calculates by weight, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation group Closing object includes:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, Lignum Santali Albi extract 3 parts, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, 8 parts of Lignum cinnamomi camphorae extract, 2 parts of lavender extract, 1 part of needle juniper extract, 7 parts of 8 parts of surfactant, chlorine dioxide and sodium chlorate slow-releasing composite material, 20 parts of ethyl alcohol, 8 parts of glycerine.
Acer palmatum extract
Acer palmatum alias:Five jiaos of crow maples of leaflet, A Douxian, willow leaf maple;Medicine elementary source is branch, the leaf of Aceraceae plant Acer palmatum; Summer harvests branches and leaves, dries, segment;Nature and flavor:Pungent, slight bitter is put down;Effect:Promoting qi circulation and relieving pain, removing toxicity for eliminating carbuncles, qi-stagnating abdominalgia, carbuncle Swollen carbuncle on the back;Chemical composition:Leaf contains Du Jingsu, saponarin, and orientin molds orientin, cyanidin monoglycoside, delphinidin Monosaccharide glucoside, peonidin monosaccharide glucoside;Extracting method:Using the extraction of steam distillation method obtained by branches and leaves.
Lombardy poplar tree extract
Lombardy poplar alias lombardy poplar, white poplar;Medicine elementary source:For the bark or leaf of Salicaceous Plants lombardy poplar.Nature and flavor:Hardship, property It is cold;Major function dispelling wind and eliminating dampness;Removing pattogenic heat from the blood and toxic material from the body.Main arthralgia pain due to rheumatism;Tinea pedis is swollen;Hepatitis;Dysentery;Burn and scald;The mange favus of the scalp;Extraction Method:Using the extraction of steam distillation method obtained by wood chip or sawdust.
Cedarwood extract
Deodar alias:Arborvitae, pagoda pine, kind cypress, Himalayas deodar;Contain very abundant essential oil in cedar wood, it can be with It is extracted from wood chip or sawdust via the mode of distillation.The main component of cedar oil includes A-Cedrene, B- Cedrene, Thujopsene, Sesquiterpenes, cedrol and Wei De alcohol.Cedar oil have anti-grease leakage, anti-corrosion, sterilization, The medical functions such as qi-restoratives, convergence, diuresis, menstruation regulating, eliminating the phlegm, desinsection and calmness;Extracting method:It is extracted from wood using steam distillation method Obtained by piece or sawdust.
Lignum Santali Albi extract
Santal alias:Asiatic sweet leaf, sandalwood;Nature and flavor:It is acrid in flavour and warm in nature;Channel tropism:Returns spleen, stomach, the heart, lung channel;Major function:Promoting the circulation of qi middle benefit gas, is opened Stomach and alleviating pain.For cold obstruction causing qi stagnation, pectoralgia, abdominal pain, deficiency of food of having a stomachache;Coronary heart disease, angina pectoris.Source:For sandalwood plants santal Heartwood.Chemical composition:Heartwood contains volatile oil(Oleum Ligni Santali)3~5%, oil contains α-santalol and 90% or more β-santalol, Wingceltis terpenes, α-santal terpenes and β-santal terpenes, santenone, santenone alcohol and a small amount of santalene acid, teresantalic acid, red sandalwood Terpene aldehyde;Extracting method:It is extracted obtained by branch using steam distillation method.
Tea tree ethereal oil
Tea tree ethereal oil has bactericidal antiphlogistic, convergence pore, treatment cold, cough, rhinitis, asthma, improves dysmenorrhoea, menstruation not Tune and genital infection and other effects;Suitable for oiliness and acne-prone skin, treats suppurative wound and burn, tan severely, athlete's foot and head Bits;It clears the head, rejuvenates, anti-depression;Extracting method:Using blade and tender tip as raw material, carried using vapor distillation method It takes.
Cus-cus extract
Cus-cus alias:VETIVERT;Medical value:Antibacterial is promoted the sexual maturity, profit nerve, calm, benefit body;It can be received with purifying skin It holds back, it is anti-infective;Improve greasy unclean skin;Anti-inflammation and sterilization treats acne and sore;Treat tinea pedis and a variety of scytitis;It calls out Awake cell, improves impaired skin;Mosquito repellent catches up with fly, antipruritic antibacterial;Uniqueness Xin Xiangweidao is carried again with strong lemon, is enabled People's nerve is rouse oneself;Immunocompetence can be enhanced, reduce morbidity chance;The effect of reinforcing red blood cell, promoting blood circulation, joint can be treated Scorching, rheumatism and myalgia;Extracting method:It is extracted obtained by root using steam distillation method.
Lignum cinnamomi camphorae extract
Camphor tree alias:Camphor tree material, lignum cinnamomi camphorae, oblongleaf kadsura stem or root;Channel tropism:It is acrid in flavour and warm in nature;Major function:Sensible to ward off dirty, warm in pain, dampness removing kills Worm.It vomits and diarrhoea for cold-dampness, stomach abdomen pain;External application controls scabies, tinea, saprodontia and has a pain.Source is Lauraceae cinnamon camphor tree, with root, branch, leaf And crystalline particulate of the waste wood through distillation gained.
Lavender extract
Lavender is herbaceous plant.Rhizome is crawled, and stem is upright, has striped;Take turns umbrella inflorescence;Ovary is hairless.Peppermint is dispelled all heat, is dissipated Wind sweating, refresh oneself, throat.Cure the wound wind headache, aphonia, discomfort in the throat, small hidden pain of wind infantile convulsion etc..The inflorescence and leaf of lavender Oil yield be 0.23-1.1%, oily ingredient master be pulegol, menthol and menthones;Extracting method:Use steam distillation Method extracts obtained by inflorescence and leaf.
Needle juniper extract
Needle juniper alias:Chinese juniper, juniperko collapse pine, stick pine;Nature and flavor:It is sweet, it is bitter, it is mild-natured;Major function:Wind-dispelling;Analgesia;Dehumidifying;Profit Urine.Main rheumatic arthritis;Gout;Ephritis;Oedema;Urinary tract infections.Chemical analysis:Cone contains volatile oil, mainly there is australene (α- Pinene), laurene (myrcene), limonene (limonene), to P-cymene (p-cymene), beta-elemene (β- Elemene), cloves alkene (caryophyllene), Humuleno (humulene), γ-cadinene (γ-cadinene), pine tar Alkene -4- alcohol (terpinen-4-ol), borneol (borneol), citronellol (citronellol) and anisole (anethole) etc., Leaf (amentoflavone) containing amentoflavone, podocarpusflavone (podocar-pusflavone) A, hinokiflavone (hinokiflavone).Branch, leaf contain volatile oil, and ingredient is similar to fruit volatile oil;Extracting method:Use steam distillation method It extracts obtained by cone, branch, leaf.
In the present invention, the preparation method of the chlorine dioxide and sodium chlorate slow-releasing composite material includes the following steps:
(1)Chlorine dioxide and sodium chlorate are added into reactor, water dissolution is used at 30-40 DEG C;The chlorine dioxide and sodium chlorate The weight ratio of gross mass and the water be 1:3;
(2)Activated carbon fibre is added in the solution, is uniformly mixed, is heated to being warming up to 50 DEG C, keeps the temperature 5h, be made and suspend Liquid;
(3)To step(2)Gained suspension is filtered, and constant pressure and dry 10h in 35 DEG C of baking ovens is subsequently placed in, and active carbon fibre is made Dimension load chlorine dioxide and sodium chlorate;
(4)To step(3)Middle addition beeswax high-speed stirred is uniformly mixed;Obtain chlorine dioxide and sodium chlorate sustained release composite wood Material.
In one embodiment, the weight ratio of the gross mass of the chlorine dioxide and sodium chlorate and the activated carbon fibre It is 1:(2-7).
Preferably, the weight ratio of the gross mass of the chlorine dioxide and sodium chlorate and the activated carbon fibre is 1:4.2.
In one embodiment, the beeswax is with the activated carbon fiber-loaded chlorine dioxide and sodium chlorate weight ratio 1:(1-2.5).
Preferably, the beeswax and the activated carbon fiber-loaded chlorine dioxide and sodium chlorate weight ratio are 1:2.
Activated carbon fibre(ACF), also known as fibrous activated carbon, be high-efficiency activated sorbing material of the performance better than activated carbon and Environment-friendly engineering material.Activated carbon fibre is " combination of ultramicron, the construction of surface imperfection and pole small space ", diameter It is 10 μm~30 μm.Hole is directly opened on fiber surface, and ultramicron is combined in a variety of ways together, is formed abundant Nano-space, size and the ultramicron in these spaces of formation are in the same order of magnitude, to create larger ratio table Area.Its many irregular structure-heterocycle structure contained or the micro-structure containing surface functional group have great surface Can, it also creates micropore and cooperatively forms powerful molecular field with respect to hole wall molecule, provide an ADSORPTION STATE molecular physics With the high pressure system of chemical change.So that the diffusion path specific activity charcoal of adsorbate arrival adsorption potential is short, driving force is big and aperture Distribution is concentrated, this be cause ACF specific activity charcoals large specific surface area, the main reason for adsorption desorption rate is fast, adsorption efficiency is high.
Beeswax (Beeswax) is secreted by the abdomen of honeybee, is the material of honeybee nesting, wax ester (Triacontanyl Palmitate it is) its main component, chemical constitution is:CH3(CH2)29O-CO-(CH2)14CH3, the molecular weight of wax ester is larger, it Space structure as a root long hair fastener, the presence of double bond makes the polymerization of hair fastener be overlapping, easily formed 3 D stereo netted knot Structure frame configuration;The oil droplet that beeswax itself contains mass efficient ingredient can pass freely through in frame, gaseous pollutant and fat Matter pollutant is easy to by the oil droplet adherency in frame.
The degerming performance of chlorine dioxide is that when it is contacted with microorganism nascent oxygen and hypochlorous acid molecule can be released, right Microbial cell has preferable adsorptivity and penetrability, can effectively in oxidative cell nitrogenous base enzyme, destroy enzyme system, simultaneously So that the amino-acid oxidase in protein is decomposed, quickly controls microprotein synthesis, reach the growth or killing for inhibiting bacterium Effect, also have good killing effect to gemma, virus, algae, fungi, iron blood bacterium, sulfate reducing bacteria etc., and to height Equal animal cellular structures are entirely without influence.The deodorization mechanism of chlorine dioxide is it with extremely strong oxidisability, can in air Redox reaction, including organic sulfur compound, organic amine, phenols, aromatic hydrocarbons and unsaturation occur for many organic matters and inorganic matter Compound etc. achievees the purpose that decompose peculiar smell, purification air;But chlorine dioxide chemical property is active, less stable.
In the present invention, the chlorine dioxide and sodium chlorate slow-releasing composite material are that beeswax coats activated carbon fibre, the work Property Carbon fibe load chlorine dioxide and sodium chlorate;By containing many irregular structure-heterocycle structures or contain surface function The micro-structure of group has great surface energy, provides the work of the high pressure system of an ADSORPTION STATE molecular physics and chemical change Property Carbon fibe cladding chlorine dioxide and sodium chlorate, adsorb strong oxidizer chlorine dioxide and sodium chlorate, slowly-releasing chlorine dioxide and chloric acid Sodium;Activated carbon fibre is coated additionally by beeswax, is efficiently inhaled using the reticular structure frame configuration of the 3 D stereo of beeswax Nitrogen-containing pollutant in attached air, then activated carbon fibre slowly-releasing chlorine dioxide and sodium chlorate oxidation stain object, and then remove depollution Object.
In one embodiment, the surfactant includes dodecyl sodium sulfate, palmityl sodium glutamate, tristearin It is one or more in acyl sodium glutamate, Hamposyl L ammonium, cocounut oil acyl Sodium L-alaninate;Preferably, the surfactant packet It includes one or more in dodecyl sodium sulfate, palmityl sodium glutamate, stearoyl-glutamic acid sodium;It is highly preferred that the surface Activating agent is dodecyl sodium sulfate, palmityl sodium glutamate.
In one embodiment, dodecyl sodium sulfate described in the surfactant and the palmityl glutamic acid The weight ratio of sodium is 1:(0.7-1.2)
Preferably, the weight ratio of dodecyl sodium sulfate described in the surfactant and the palmityl sodium glutamate is 1: 0.9。
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:(0.1-0.4).
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:(0.1-0.2).
In one embodiment, chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material with it is described The molar ratio 1 of sodium chlorate:0.16.
In one embodiment, the ethyl alcohol is the ethyl alcohol that mass fraction is 50-80%.
In one embodiment, the ethyl alcohol is the ethyl alcohol that mass fraction is 70%.
Another aspect of the present invention provides a kind of preparation side efficiently removing nitrogenous contamination gas build air purifying preparation composition Method includes the following steps:
(1)Palm oil, Acer palmatum extract, Lombardy poplar tree extract, Cedarwood extract, wingceltis are added by weight into reactor Fragrant extract, tea tree ethereal oil, cus-cus extract, Lignum cinnamomi camphorae extract, lavender extract, cus-cus extract, needle juniper extraction Object, surfactant are heated to 60 DEG C, are uniformly mixed with the high-shear emulsion machine of 6000rpm;
(2)To glycerine, ethyl alcohol and chlorine dioxide and sodium chlorate slow-releasing composite material are added in step 1, with the high shear of 6000rpm Mulser mixing;After stirring and stablizing, obtains and described efficiently remove nitrogenous contamination gas build air purifying preparation composition.
Make product formation microemulsion of the present invention using natural plant extracts in the present invention, sustained release can be reached in air Effect so that this product long duration of action is in air.The present invention air purifying preparation with contacted containing smell substance after draw React, and play and eliminate the unusual smell, eliminate nitrogen-containing pollutant and other effects.
The air purifying preparation composition duration is long in the present invention, effectively clears the pollution off, strong adsorption, safety and environmental protection, Using simple, addition plant extraction liquid enhances the effect and biocidal property for absorbing nitrogenous polluted gas.
The present invention is specifically described below by embodiment.It is necessarily pointed out that following embodiment is only used In the invention will be further described, it should not be understood as limiting the scope of the invention, professional and technical personnel in the field Some the nonessential modifications and adaptations made according to the content of aforementioned present invention, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used to be all commercially available, it is purchased from traditional Chinese medicines chemical reagent.
Embodiment 1
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
The preparation method for efficiently removing nitrogenous contamination gas build air purifying preparation composition, includes the following steps:
(1)Palm oil, Acer palmatum extract, Lombardy poplar tree extract, Cedarwood extract, wingceltis are added by weight into reactor Fragrant extract, tea tree ethereal oil, cus-cus extract, Lignum cinnamomi camphorae extract, lavender extract, cus-cus extract, needle juniper extraction Object, surfactant are heated to 60 DEG C, are uniformly mixed with the high-shear emulsion machine of 6000rpm;
(2)To glycerine, ethyl alcohol and chlorine dioxide and sodium chlorate slow-releasing composite material are added in step 1, with the high shear of 6000rpm Mulser mixing;After stirring and stablizing, obtains and described efficiently remove nitrogenous contamination gas build air purifying preparation composition.
The preparation method of the chlorine dioxide and sodium chlorate slow-releasing composite material, includes the following steps:
(1)Chlorine dioxide and sodium chlorate are added into reactor, water dissolution is used at 35 DEG C;The chlorine dioxide and sodium chlorate it is total Quality and the weight ratio of the water are 1:3;
(2)Activated carbon fibre is added in the solution, is uniformly mixed, is heated to being warming up to 50 DEG C, keeps the temperature 5h, be made and suspend Liquid;The weight ratio of the gross mass of the chlorine dioxide and sodium chlorate and the activated carbon fibre is 1:4.2;
(3)To step(2)Gained suspension is filtered, and constant pressure and dry 10h in 35 DEG C of baking ovens is subsequently placed in, and active carbon fibre is made Dimension load chlorine dioxide and sodium chlorate;
(4)To step(3)Middle addition beeswax high-speed stirred is uniformly mixed;Obtain chlorine dioxide and sodium chlorate sustained release composite wood Material;The beeswax is 1 with the activated carbon fiber-loaded chlorine dioxide and sodium chlorate weight ratio:2.
Embodiment 2
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.1;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 3
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.4;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 4
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 50%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 5
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 80%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 6
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.7.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 7
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:1.2.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Embodiment 8
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material;Difference lies in the chlorine dioxide and sodium chlorate slow-releasing composite material Preparation method described in the gross mass of chlorine dioxide and sodium chlorate and the weight ratio of the activated carbon fibre be 1:2.
Embodiment 9
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant Weight ratio with the palmityl sodium glutamate is 1:0.9.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material, and difference lies in the chlorine dioxide and sodium chlorate slow-releasing composite material Preparation method described in beeswax and the activated carbon fiber-loaded chlorine dioxide and sodium chlorate weight ratio be 1:1.
Comparative example 1
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material coat for beeswax Activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide and sodium chlorate are sustained composite wood The molar ratio 1 of chlorine dioxide described in material and the sodium chlorate:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;It is described Surfactant is dodecyl sodium sulfate.
Preparation method, the chlorine dioxide and the chlorine for efficiently removing nitrogenous contamination gas build air purifying preparation composition The preparation method is the same as that of Example 1 for sour sodium slow-releasing composite material.
Comparative example 2
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide slow-release composite material 7 Part, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide slow-release composite material is that beeswax coats activated carbon fibre, the work Property Carbon fibe load chlorine dioxide;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;The surfactant is dodecyl sulphur Sour sodium, palmityl sodium glutamate;Dodecyl sodium sulfate described in the surfactant and the palmityl sodium glutamate Weight ratio is 1:0.9.
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition the preparation method is the same as that of Example 1.
The preparation method of the chlorine dioxide slow-release composite material, includes the following steps:
(1)Chlorine dioxide is added into reactor, water dissolution is used at 35 DEG C;The weight of the gross mass of the chlorine dioxide and the water Amount is than being 1:3;
(2)Activated carbon fibre is added in the solution, is uniformly mixed, is heated to being warming up to 50 DEG C, keeps the temperature 5h, be made and suspend Liquid;The weight ratio of the gross mass of the chlorine dioxide and the activated carbon fibre is 1:4.2;
(3)To step(2)Gained suspension is filtered, and constant pressure and dry 10h in 35 DEG C of baking ovens is subsequently placed in, and active carbon fibre is made Dimension load chlorine dioxide;
(4)To step(3)Middle addition beeswax high-speed stirred is uniformly mixed;Obtain chlorine dioxide slow-release composite material;It is described Beeswax is 1 with the activated carbon fiber-loaded chlorine dioxide weight ratio:2.
Comparative example 3
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, sodium chlorate slow-releasing composite material 7 Part, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the sodium chlorate slow-releasing composite material is that beeswax coats activated carbon fibre, the activity Carbon fibe loads sodium chlorate;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;The surfactant is dodecyl sodium sulfonate Sodium, palmityl sodium glutamate;The weight of dodecyl sodium sulfate described in the surfactant and the palmityl sodium glutamate Amount is than being 1:0.9.
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition the preparation method is the same as that of Example 1.
The preparation method of the sodium chlorate slow-releasing composite material, includes the following steps:
(1)Sodium chlorate is added into reactor, water dissolution is used at 35 DEG C;The weight ratio of the gross mass of the sodium chlorate and the water It is 1:3;
(2)Activated carbon fibre is added in the solution, is uniformly mixed, is heated to being warming up to 50 DEG C, keeps the temperature 5h, be made and suspend Liquid;The weight ratio of the gross mass of the sodium chlorate and the activated carbon fibre is 1:4.2;
(3)To step(2)Gained suspension is filtered, and constant pressure and dry 10h in 35 DEG C of baking ovens is subsequently placed in, and active carbon fibre is made Dimension load sodium chlorate;
(4)To step(3)Middle addition beeswax high-speed stirred is uniformly mixed;Obtain sodium chlorate slow-releasing composite material;The bee Wax is 1 with the activated carbon fiber-loaded sodium chlorate weight ratio:2.
Comparative example 4
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 4 parts of Acer palmatum extract, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, 3 parts of cus-cus extract, camphor tree Set 8 parts of extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate sustained release 7 parts of composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate slow-releasing composite material are active carbon fibre Dimension load chlorine dioxide and sodium chlorate;Chlorine dioxide described in the chlorine dioxide and sodium chlorate slow-releasing composite material and the chlorine The molar ratio 1 of sour sodium:0.16;The ethyl alcohol is the ethyl alcohol that mass fraction is 70%;The surfactant is dodecyl sodium sulfonate Sodium, palmityl sodium glutamate;The weight of dodecyl sodium sulfate described in the surfactant and the palmityl sodium glutamate Amount is than being 1:0.9.
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition the preparation method is the same as that of Example 1.
The preparation method of the chlorine dioxide and sodium chlorate slow-releasing composite material, includes the following steps:
(1)Chlorine dioxide and sodium chlorate are added into reactor, water dissolution is used at 35 DEG C;The chlorine dioxide and sodium chlorate it is total Quality and the weight ratio of the water are 1:3;
(2)Activated carbon fibre is added in the solution, is uniformly mixed, is heated to being warming up to 50 DEG C, keeps the temperature 5h, be made and suspend Liquid;The weight ratio of the gross mass of the chlorine dioxide and sodium chlorate and the activated carbon fibre is 1:4.2;
(3)To step(2)Gained suspension is filtered, and constant pressure and dry 10h in 35 DEG C of baking ovens is subsequently placed in, and active carbon fibre is made Dimension load chlorine dioxide and sodium chlorate.
Comparative example 5
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, 8 parts of surfactant, two 7 parts of chlorine monoxid and sodium chlorate slow-releasing composite material, 20 parts of ethyl alcohol, 8 parts of glycerine, wherein the chlorine dioxide and sodium chlorate sustained release Composite material is that beeswax coats activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate;The chlorine dioxide With the molar ratio 1 of chlorine dioxide described in sodium chlorate slow-releasing composite material and the sodium chlorate:0.16;The ethyl alcohol is quality point The ethyl alcohol that number is 70%;The surfactant is dodecyl sodium sulfate, palmityl sodium glutamate;In the surfactant The weight ratio of the dodecyl sodium sulfate and the palmityl sodium glutamate is 1:0.9.
It is described efficiently to remove nitrogenous contamination gas build air purifying preparation preparation method of composition, include the following steps:
(1)Palm oil, surfactant are added by weight into reactor, is heated to 60 DEG C, with the high shear breast of 6000rpm Change machine is uniformly mixed;
(2)To glycerine, ethyl alcohol and chlorine dioxide and sodium chlorate slow-releasing composite material are added in step 1, with the high shear of 6000rpm Mulser mixing;After stirring and stablizing, obtains and described efficiently remove nitrogenous contamination gas build air purifying preparation composition.
The preparation method is the same as that of Example 1 for the chlorine dioxide and sodium chlorate slow-releasing composite material.
Performance test:
1, pollutants removal rate
In 1m3In the experiment bin of sealing, the pure nitrogen dioxide (or ozone or ammonia) of injection certain volume chemistry, unlatching storehouse internal fan, 1 Gas concentration is initial concentration in the storehouse of sampling test immediately after hour.In 1m3It is in the experiment bin of sealing, just air obtained is net Agent composition is put into the storehouse, and gas concentration in the storehouse of sampling test immediately, calculates removal rate after 72 hours.Removal rate=(initial Concentration-sample solution concentration) × 100/ initial concentration.
2, bacteriostasis rate
Using staphylococcus aureus agent as strain, anti-microbial property test, the antibacterial of sample are carried out to sample using concussion flask method Performance is evaluated by bacteriostasis rate.
1 air purifying preparation composition removal rate of table is tested
As can be seen that provided by the invention efficiently remove nitrogenous contamination gas build air purifying preparation composition and hold from above-mentioned data The continuous time is long, effectively clears the pollution off, strong adsorption, safety and environmental protection, and using simple, addition plant extraction liquid enhances absorption and contains The effect and biocidal property of polluted by nitrogen gas.
Example above-mentioned is merely illustrative, some features of the feature for explaining the disclosure.The attached claims It is intended to the range as wide as possible for requiring to be contemplated that, and embodiments as presented herein is only according to all possible embodiment Combination selection embodiment explanation.Therefore, the purpose of applicant is that the attached claims are not illustrated the present invention Feature exemplary selectional restriction.And the progress in science and technology will be formed language express inaccuracy due to and not The possible equivalent or son being presently considered are replaced, and these variations also should in the conceived case be interpreted by appended Claim covers.

Claims (10)

1. one kind efficiently removing nitrogenous contamination gas build air purifying preparation composition, which is characterized in that it calculates by weight, it is described Efficiently removing nitrogenous contamination gas build air purifying preparation composition includes:0.5-15 parts of palm oil, 1-5 parts of Acer palmatum extract, 1-7 parts of Lombardy poplar tree extract, 1-5 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, 2-10 parts of tea tree ethereal oil, cus-cus extraction 2-5 parts of object, 2-15 parts of Lignum cinnamomi camphorae extract, 1-3 parts of lavender extract, 1-2 parts of needle juniper extract, 5-10 parts of surfactant, 5-10 parts of chlorine dioxide and sodium chlorate slow-releasing composite material, 10-30 parts of ethyl alcohol, 1-15 parts of glycerine, wherein the chlorine dioxide and Sodium chlorate slow-releasing composite material is that beeswax coats activated carbon fibre, the activated carbon fiber-loaded chlorine dioxide and sodium chlorate.
2. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 1, which is characterized in that by weight Part is measured to calculate, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:3-10 parts of palm oil, Acer palmatum carries Take 2-5 parts of object, 1-3 parts of Lombardy poplar tree extract, 1-3 parts of Cedarwood extract, 1-4 parts of Lignum Santali Albi extract, 2-8 parts of tea tree ethereal oil, 2-5 parts of cus-cus extract, 2-10 parts of Lignum cinnamomi camphorae extract, 1-3 parts of lavender extract, 1-2 parts of needle juniper extract, surface-active 5-10 parts of 5-10 parts of agent, chlorine dioxide and sodium chlorate slow-releasing composite material, 10-30 parts of ethyl alcohol, 1-10 parts of glycerine.
3. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 2, which is characterized in that by weight Part is measured to calculate, it is described efficiently to remove nitrogenous contamination gas build air purifying preparation composition and include:7 parts of palm oil, Acer palmatum extraction 4 parts of object, 2 parts of Lombardy poplar tree extract, 2 parts of Cedarwood extract, 3 parts of Lignum Santali Albi extract, 6 parts of tea tree ethereal oil, cus-cus extract 3 Part, 8 parts of Lignum cinnamomi camphorae extract, 2 parts of lavender extract, 1 part of needle juniper extract, 8 parts of surfactant, chlorine dioxide and sodium chlorate 7 parts of slow-releasing composite material, 20 parts of ethyl alcohol, 8 parts of glycerine.
4. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 1, which is characterized in that described Surfactant includes dodecyl sodium sulfate, palmityl sodium glutamate, stearoyl-glutamic acid sodium, Hamposyl L ammonium, coconut palm It is one or more in oleoyl Sodium L-alaninate.
5. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 1, which is characterized in that described The molar ratio 1 of chlorine dioxide and the sodium chlorate described in chlorine dioxide and sodium chlorate slow-releasing composite material:(0.1-0.4).
6. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 5, which is characterized in that described The molar ratio 1 of chlorine dioxide and the sodium chlorate described in chlorine dioxide and sodium chlorate slow-releasing composite material:(0.1-0.2).
7. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 6, which is characterized in that described The molar ratio 1 of chlorine dioxide and the sodium chlorate described in chlorine dioxide and sodium chlorate slow-releasing composite material:0.16.
8. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 1, which is characterized in that described Ethyl alcohol is the ethyl alcohol that mass fraction is 50-80%.
9. efficiently removing nitrogenous contamination gas build air purifying preparation composition according to claim 7, which is characterized in that described Ethyl alcohol is the ethyl alcohol that mass fraction is 70%.
10. according to the preparation method for efficiently removing nitrogenous contamination gas build air purifying preparation composition described in claim 1-9, It is characterized in that, includes the following steps:
(1)Palm oil, Acer palmatum extract, Lombardy poplar tree extract, Cedarwood extract, wingceltis are added by weight into reactor Fragrant extract, tea tree ethereal oil, cus-cus extract, Lignum cinnamomi camphorae extract, lavender extract, cus-cus extract, needle juniper extraction Object, surfactant are heated to 60 DEG C, are uniformly mixed with the high-shear emulsion machine of 6000rpm;
(2)To glycerine, ethyl alcohol and chlorine dioxide and sodium chlorate slow-releasing composite material are added in step 1, with the high shear of 6000rpm Mulser mixing;After stirring and stablizing, obtains and described efficiently remove nitrogenous contamination gas build air purifying preparation composition.
CN201810221739.3A 2018-03-18 2018-03-18 Air purifying agent composition for efficiently removing nitrogen-containing polluted gas Active CN108499337B (en)

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