CN108486692A - A kind of processing method and system of high-strength high-modules carbon fibre - Google Patents
A kind of processing method and system of high-strength high-modules carbon fibre Download PDFInfo
- Publication number
- CN108486692A CN108486692A CN201810339670.4A CN201810339670A CN108486692A CN 108486692 A CN108486692 A CN 108486692A CN 201810339670 A CN201810339670 A CN 201810339670A CN 108486692 A CN108486692 A CN 108486692A
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- Prior art keywords
- carbon fibre
- modules carbon
- strength high
- strength
- heated drying
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Links
- 239000000835 fiber Substances 0.000 title claims abstract description 93
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 54
- 238000003672 processing method Methods 0.000 title claims abstract description 10
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 44
- 238000001035 drying Methods 0.000 claims abstract description 35
- 230000001590 oxidative effect Effects 0.000 claims abstract description 28
- 230000003647 oxidation Effects 0.000 claims abstract description 27
- 238000005406 washing Methods 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 23
- 230000008569 process Effects 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000001681 protective effect Effects 0.000 claims abstract description 5
- 239000007791 liquid phase Substances 0.000 claims description 3
- 238000001802 infusion Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 238000002386 leaching Methods 0.000 claims 1
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 22
- 239000004917 carbon fiber Substances 0.000 abstract description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 22
- 230000007420 reactivation Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 9
- 239000000243 solution Substances 0.000 description 5
- 238000004381 surface treatment Methods 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000010301 surface-oxidation reaction Methods 0.000 description 3
- 238000007605 air drying Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D01F11/122—Oxygen, oxygen-generating compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/16—Chemical after-treatment of artificial filaments or the like during manufacture of carbon by physicochemical methods
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B13/00—Machines and apparatus for drying fabrics, fibres, yarns, or other materials in long lengths, with progressive movement
- F26B13/10—Arrangements for feeding, heating or supporting materials; Controlling movement, tension or position of materials
- F26B13/14—Rollers, drums, cylinders; Arrangement of drives, supports, bearings, cleaning
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B23/00—Heating arrangements
- F26B23/04—Heating arrangements using electric heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B25/00—Details of general application not covered by group F26B21/00 or F26B23/00
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F26—DRYING
- F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
- F26B3/00—Drying solid materials or objects by processes involving the application of heat
- F26B3/28—Drying solid materials or objects by processes involving the application of heat by radiation, e.g. from the sun
Abstract
The invention discloses a kind of processing systems of high-strength high-modules carbon fibre, including sequentially connected surface processing device, water washing device and heated drying oxidation unit;The heated drying oxidation unit is made of heated drying system and oxidative system, and heated drying system includes protection incubator, light source and exhaust passage;Oxidative system includes oxidizing atmosphere reactor, secondary light source and protective housing.A kind of processing method of high-strength high-modules carbon fibre is also disclosed, including:(1) high-strength high-modules carbon fibre tow carries out oxidation processes continuously across surface processing device to fiber surface;(2) high-strength high-modules carbon fibre surface is washed using water washing device;(3) wash after high-strength high-modules carbon fibre tow pass through heated drying oxidation unit, receive silk to get.The present invention method is easy to operate, controllability is strong, and it is small to consume energy, can realize high-strength high-modules carbon fibre it is continuous, quickly, high efficiency drying on the basis of, realize the re-activation of carbon fiber surface.
Description
Technical field
The invention belongs to carbon fiber production technical fields, and in particular to a kind of processing method of high-strength high-modules carbon fibre and be
System.
Background technology
High-strength high-modules carbon fibre is prepared by 2000 DEG C~3000 DEG C high temperature graphitization processing, and fiber surface is presented
High inertia, it is therefore desirable to its surface be handled to improve fiber surface activity.At present carbon fiber surface treatment method compared with
It is more, especially with solution oxides such as anodic oxidations using in the majority, meeting residual solution after surface oxidation treatment, thus washed
Processing removes fiber surface residual solvent, washing and drying is then carried out, in order to subsequent sizing technique.
The most commonly used method of carbon fiber surface washing and drying is that processing, such as Publication No. is dried in blowing-type drying oven
It is real by heated-air drying mode that the Chinese invention patent document of CN102645091A discloses drying device etc. after carbon fiber is washed
Existing fiber surface drying.But for high-strength high-modules carbon fibre, since high brittleness is presented in fiber, in process of production by
It is easily formed surface lousiness in reasons such as tension drafts, if washing and drying easily causes fiber surface using heated-air drying mode
Lousiness aggravates, and then influences the mechanical property of fiber.
It is done for the washing of carbon fiber in addition, the Chinese invention patent document of Publication No. CN107385735A is disclosed
The system of dry, starching and dryness finalization, using hot-rolling contact furnace drying method, although this method can fast implement carbon fiber baking
It is dry, but since fiber surface is thermally contacted with hot-rolling, cause the active group of carbon fiber surface generation after surface treatment to be sent out
Raw damage, fiber surface activity decline so that surface treatment loses meaning.
Carbon fiber product UV curing disclosed in the Chinese utility model patent document of Publication No. CN201122045Y
It is proposed to utilize ultraviolet light or infrared light mode of heating in equipment, but its there are following two points essence is different from the present invention:First, answering
With field difference, patent be dried using infrared lamp and quartz burner for carbon fiber product it is ultraviolet on product
Line coating, the present invention are happened in carbon fiber production process, are dried for fiber washing;Second, apparatus structure is totally different, energy consumption is poor
Different larger, patent need to carry out baking vanish to carbon fiber surface, therefore need to carry out under excessive temperature, thus plant energy consumption is higher, and
Equipment is complicated, and as needed supply air system to cool down in time to device in its device, and the present invention is simple and practicable, and visible
Also carbon fiber rapid draing can be realized under the conditions of light etc..
Invention content
The present invention in view of the deficiencies of the prior art, and combines high-strength high-modules carbon fibre structure and performance characteristics, the present invention to set
A kind of processing method and system of high-strength high-modules carbon fibre have been counted, the method for the present invention is easy to operate, controllability is strong, low energy consumption,
Realize high-strength high-modules carbon fibre surface it is continuous, quickly, highly effective drying simultaneously, it can be achieved that fiber surface secondary oxidation, substantially carry
High microsteping surface-active.
The invention is realized by the following technical scheme:
A kind of processing system of high-strength high-modules carbon fibre, including sequentially connected surface processing device, water washing device and heat
Drying-oxidation unit;
Heated drying-the oxidation unit is made of heated drying system and oxidative system, and heated drying system includes that protection is kept the temperature
Case, light source and exhaust passage;Oxidative system includes oxidizing atmosphere reactor, secondary light source and protective housing.
The surface processing device is used to carry out oxidation processes to high-strength high-modules carbon fibre surface, improves surface-active;Institute
It is liquid phase oxidation device or anodic oxidation device to state surface processing device, can be arranged as required to as one, twice or multiple tracks.
The water washing device removes the remaining solution of fiber surface for being washed to high-strength high-modules carbon fibre surface.
The water washing device can be arranged as required to as one, twice or multiple tracks.
Heated drying-the oxidation unit realizes high-strength high-modules carbon fibre table using the uniform heat-field of heated drying system in device
The efficient of face, rapid draing processing, surface second oxidation is carried out followed by oxidative system.
The light source includes one or more in visible light, infrared light and ultraviolet light.By the way that one or more light are arranged
Source forms the uniform thermal field of temperature using luminous energy in the device, is carried out to high-strength high-modules carbon fibre surface using thermal diffusion effect
It is dry.Since thermal field is uniform inside the device, air-flow is not will produce, thus avoids the generation of high-strength high-modules carbon fibre lousiness, and
And it is not in contact directly with fiber surface so that greater activity is still presented in fiber surface after surface treatment.
The secondary light source is ultraviolet light and/or infrared light, and on the one hand secondary light source forms the uniform thermal field of temperature, improve
The oxidation efficiency of oxidative system;Another aspect catalytic oxidative atmosphere realizes surface second activation to fiber surface oxidation processes,
And then the combination of high-strength high-modules carbon fibre and matrix greatly improved, realize that fiber surface activity is substantially improved.
The present invention also provides a kind of processing methods of high-strength high-modules carbon fibre, including:
(1) high-strength high-modules carbon fibre tow carries out oxidation processes continuously across surface processing device to fiber surface;
(2) high-strength high-modules carbon fibre surface is washed using water washing device, removes the remaining solution of fiber surface;
(3) wash after high-strength high-modules carbon fibre tow pass through heated drying-oxidation unit, receive silk to get.
In step (1), oxidation processes are carried out to fiber surface using solution treatment mode, such as using liquid phase oxidation, anode
Oxidation etc..
In step (2), using one or more to high-strength high-modules carbon fibre surface in spray process, infusion process and moisture film method
It is washed.
In step (3), including:High-strength high-modules carbon fibre tow after washing is dry by the heat in heated drying-oxidation unit
Drying system heats 1~5min at 50~120 DEG C;With laggard peroxidating system, oxidization time is 1~3min, and oxidizing temperature is
80~150 DEG C.
In conclusion the invention has the advantages that:
(1) in the heated drying system of heated drying-oxidation unit of the present invention, by using luminous energy heating means to high-strength and high-modulus
Carbon fiber washed after drying and processing, processing is dried conducive to uniform heat-field in device, effectively can avoid fiber
While surface generates lousiness, the continuous, quick of high-strength high-modules carbon fibre, highly effective drying are realized;In oxidative system, pass through oxygen
The property changed atmosphere realizes surface second activation, and then greatly improve high-strength high-modules carbon fibre and matrix to fiber surface oxidation processes
Combination.
(2) apparatus of the present invention are simple and easy to do, controllability is strong, energy consumption is small, and fiber surface washing and drying and two can be achieved at the same time
Secondary activation is remarkably improved fiber surface activity while the effectively save energy.
Description of the drawings
Fig. 1 is the schematic diagram of the processing system of high-strength high-modules carbon fibre of the embodiment of the present invention;
Fig. 2 is that the surface-element before the processing of high-strength high-modules carbon fibre of the embodiment of the present invention analyzes data;
Fig. 3 is that the surface-element after high-strength high-modules carbon fibre of embodiment of the present invention surface treated and washing analyzes data;
Fig. 4 is that surface-element of the high-strength high-modules carbon fibre of the embodiment of the present invention after complete process analyzes data.
Specific implementation mode
The specific implementation mode of the present invention is described in further detail with embodiment with reference to the accompanying drawings of the specification, but is answered
When understanding that following embodiment for illustrating the present invention, is not limited to the scope of the present invention.
As shown in Figure 1, an embodiment of the present invention provides a kind of processing systems of high-strength high-modules carbon fibre, including it is sequentially connected
Surface processing device 3, water washing device 8 and heated drying-oxidation unit;
Heated drying-the oxidation unit is made of heated drying system and oxidative system, and heated drying system includes that protection is kept the temperature
Case 10, light source 11 and exhaust passage 12;Oxidative system includes oxidizing atmosphere reactor 14, secondary light source 15 and protective housing 13,
Heated drying-oxidation unit power supply is controlled by power switch 16.
The embodiment of the present invention additionally provides a kind of processing method of high-strength high-modules carbon fibre, including:
(1) high-strength high-modules carbon fibre tow 1 is entered by conductive rollers 2 in surface processing device 3, conductive rollers 2 and conduction
Roller 6 is passed through DC current, is cathode by anode, graphite cake 5 of carbon fiber, to carbon fiber due to the conductive energy of carbon fiber
Surface carries out Continuous Anodic Oxidation Treatment, to realize that carbon fiber surface activates.
(2) after being surface-treated, high-strength high-modules carbon fibre tow enters by rolling roller 7 in water washing device 8, uses deionization
Water carries out infiltration cleaning to fiber, removes the remaining electrolyte solution of fiber surface.
(3) fiber is entered the heated drying system of heated drying-oxidation unit by rolling roller 9 after washing, and light source 11 is in electricity
Under source 16 controls, by Effective Regulations such as light source power, quantity of light source, it is uniformly hot that temperature can be formed in protection incubator 10
, fiber surface is dried using thermal diffusion effect, realizes continuous, the flash baking of carbon fiber surface, is dried to ensure
Water vapour excludes in time during dry, and exhaust passage 12 is equipped in light source both sides.The gases such as air enter oxidizing atmosphere hair
Raw device 14 forms oxidizing atmosphere by physical-chemical reaction, and subsequent oxidizing atmosphere enters heated drying-oxidation through gas passage
The oxidative system of device, fiber after drying enter in oxidative system protective housing 13, under the effect of secondary light source 15, to fiber
Surface carries out oxidation processes.
As shown in Figure 1, the surface processing device 3 and water washing device 8 can be by one, twice or multiple tracks device groups
At;Preferably, the present embodiment surface processing device 3 by forming together, and water washing device 8 by forming together.
Different number illumination lamp, illumination lamp can be arranged in light source 11 in the heated drying system of the heated drying-oxidation unit
Shape can also rectangular, arc etc., and illumination lamp can be the different light sources such as visible light, ultraviolet light, infrared light;As preferred side
Case, the present embodiment light source 11 are visible light source, amount to 4 arc light sources, fibre bundle both sides up and down are distributed in, per side 2
Arc light source, high-strength high-modules carbon fibre tow after washing is in heated drying system to heat 1min at 110 DEG C.
The secondary light source 15 of the oxidative system of the heated drying-oxidation unit is ultraviolet light, one kind of infrared light or mixing.
Preferably, the present embodiment secondary light source 15 amounts to 2 rectangular light sources, is distributed in oxidative system using ultraviolet light as light source
The both sides up and down of middle fibre bundle, the fiber after drying is in oxidative system with 150 DEG C of oxidation 1min.
Fig. 2, Fig. 3, Fig. 4 be respectively be surface-treated before, surface treatment and washing process after, high-strength and high-modulus carbon after secondary oxidation
Fiber surface Elemental analysis data, O constituent contents are only 1.67% before being surface-treated, and are increased to after anodized
4.10%, after the secondary oxidation using heated drying-oxidation unit oxidative system, O constituent contents can be improved to 10.58%, real
Existing fiber surface activity greatly improves.
The present invention in the heated drying system of heated drying-oxidation unit by forming uniform heat-field, due to not generating air-flow,
Therefore carbon fiber surface will not be caused to generate lousiness, and will not be thermally contacted with fiber surface in drying process, therefore can
To keep fiber-reactive in fiber surface drying process, to realize that carbon fiber is continuous, fast and efficiently dries;And in oxygen
In change system, re-activation is carried out to fiber surface by using oxidizing atmosphere such as ozone etc., high-strength and high-modulus can be greatly improved
Carbon fiber and matrix binding ability.
The basic principles and main features and advantages of the present invention of the present invention only have been shown and described in the above.This implementation
Example is unrestricted for illustrating technical scheme of the present invention, and those of ordinary skill in the art do technical scheme of the present invention
Other modifications or equivalent replacement should all cover the present invention's as long as it does not depart from the spirit and scope of the technical scheme of the present invention
In right.
Claims (9)
1. a kind of processing system of high-strength high-modules carbon fibre, which is characterized in that including sequentially connected surface processing device, washing
Device and heated drying-oxidation unit;
Heated drying-the oxidation unit is made of heated drying system and oxidative system, and heated drying system includes protection incubator, light
Source and exhaust passage;Oxidative system includes oxidizing atmosphere reactor, secondary light source and protective housing.
2. the processing system of high-strength high-modules carbon fibre according to claim 1, which is characterized in that the surface processing device
For liquid phase oxidation device or anodic oxidation device.
3. the processing system of high-strength high-modules carbon fibre according to claim 2, which is characterized in that the surface processing device
Be set as together, twice or multiple tracks.
4. the processing system of high-strength high-modules carbon fibre according to claim 1, which is characterized in that the water washing device setting
For one, twice or multiple tracks.
5. the processing system of high-strength high-modules carbon fibre according to claim 1, which is characterized in that the light source includes visible
It is one or more in light, infrared light and ultraviolet light.
6. the processing system of high-strength high-modules carbon fibre according to claim 1, which is characterized in that the secondary light source is purple
Outer light and/or infrared light.
7. a kind of processing method of high-strength high-modules carbon fibre, which is characterized in that high using claim 1~6 any one of them
The processing system of strong high-modules carbon fibre is handled, including:
(1) high-strength high-modules carbon fibre tow carries out oxidation processes continuously across surface processing device to fiber surface;
(2) high-strength high-modules carbon fibre surface is washed using water washing device, removes the remaining solution of fiber surface;
(3) wash after high-strength high-modules carbon fibre tow pass through heated drying-oxidation unit, receive silk to get.
8. the processing method of high-strength high-modules carbon fibre according to claim 7, which is characterized in that in step (2), using spray
One or more in leaching method, infusion process and moisture film method wash high-strength high-modules carbon fibre surface.
9. the processing method of high-strength high-modules carbon fibre according to claim 7, which is characterized in that in step (3), including:
High-strength high-modules carbon fibre tow after washing is heated by the heated drying system in heated drying-oxidation unit at 50~120 DEG C
1~5min;With laggard peroxidating system, oxidization time is 1~3min, and oxidizing temperature is 80~150 DEG C.
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CN108486692B CN108486692B (en) | 2024-01-02 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113048739A (en) * | 2021-03-12 | 2021-06-29 | 罗世霞 | Improve weaving processing of sunning efficiency to fabrics and use sunning frame |
CN113502566A (en) * | 2021-09-08 | 2021-10-15 | 江苏美得妮纺织品有限公司 | Carbon fiber precursor pre-oxidation device and use method thereof |
CN114182453A (en) * | 2021-12-22 | 2022-03-15 | 张家港市港鹰实业有限公司 | Carbon fiber surface treatment device and use method thereof |
CN114250562A (en) * | 2021-12-28 | 2022-03-29 | 张家港市港鹰实业有限公司 | Improved carbon fiber precursor washing device and washing method |
CN114775262A (en) * | 2022-04-22 | 2022-07-22 | 常州爱特恩新材料科技有限公司 | Carbon fiber processing method and system |
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CN114182453B (en) * | 2021-12-22 | 2023-12-05 | 张家港市港鹰实业有限公司 | Carbon fiber surface treatment device and application method thereof |
CN114250562A (en) * | 2021-12-28 | 2022-03-29 | 张家港市港鹰实业有限公司 | Improved carbon fiber precursor washing device and washing method |
CN114250562B (en) * | 2021-12-28 | 2024-01-02 | 张家港市港鹰实业有限公司 | Improved carbon fiber precursor water washing device and method |
CN114775262A (en) * | 2022-04-22 | 2022-07-22 | 常州爱特恩新材料科技有限公司 | Carbon fiber processing method and system |
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