CN108483990A - A kind of preparation method of anti-hollowing high bond strength glue for tile - Google Patents
A kind of preparation method of anti-hollowing high bond strength glue for tile Download PDFInfo
- Publication number
- CN108483990A CN108483990A CN201810297625.7A CN201810297625A CN108483990A CN 108483990 A CN108483990 A CN 108483990A CN 201810297625 A CN201810297625 A CN 201810297625A CN 108483990 A CN108483990 A CN 108483990A
- Authority
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- Prior art keywords
- hollowing
- fermentation
- tile
- bond strength
- high bond
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0046—Premixtures of ingredients characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The present invention relates to a kind of preparation methods of anti-hollowing high bond strength glue for tile, belong to ornament materials preparing technical field.The present invention is first using main component as silicon carbide, magnesia, the ceramic tile polishing waste residue of magnesium chloride and brick fine powder is raw material, by itself and absolute ethyl alcohol Wet blend-milling, potassium permanganate oxidation is used after wet-milling again, and it ferments and is modified through lemon juice, last dehydration obtains reaction filter residue, then white lime soda boiling rice straw is used, sealing and fermenting obtains careless muscle, reaction filter residue is blended with careless muscle and other auxiliary materials, anti- hollowing high bond strength glue for tile is finally made, anti- hollowing high bond strength glue for tile adhesive strength and flexibility produced by the present invention are splendid, it is not likely to produce hollowing, it has broad application prospects.
Description
Technical field
The present invention relates to a kind of preparation methods of anti-hollowing high bond strength glue for tile, belong to ornament materials technology of preparing neck
Domain.
Background technology
Glue for tile is also known as Ceramic Tiles adhesive, is mainly used for pasting the ornament materials such as ceramic tile, face brick, floor tile, generally applicable
In the facing decoration places of the buildings such as inside and outside metope, ground, bathroom, kitchen.It is high, water-fast, resistance to that it is mainly characterized by adhesive strength
Freeze thawing, ageing-resistant performance are good and easy for construction, are a kind of ideal binding materials.It is the new material of modern decoration, replaces
For conventional cement yellow sand, gluing knot power, which is the several times of cement mortar, can effectively paste large-scale ceramic tile stone material, avoid brick
Risk.
But since glue for tile thermal deformation resistant ability and absorption deformational stress are poor.Use the hollowing that will appear ceramic tile after several years
And fall off, i.e. ceramic tile is when different temperature fields are expanded with heat and contract with cold, since ceramic tile adhesive lacks enough adhesive strengths and soft
Toughness and cannot discharge well ceramic tile heat expansion condensation generate internal stress, eventually lead to and go out small split between glue for tile and ceramic tile
Gap, these cracks can gradually form hollowing after running up to certain quantity, and lead to final fall off.
Therefore, invention one kind can prevent hollowing, and the glue for tile with high bond strength prepares skill to ornament materials
Art field has positive meaning.
Invention content
The technical problems to be solved by the invention：For current glue for tile thermal deformation resistant ability and absorb deformational stress compared with
Difference lacks enough adhesive strength and flexibility, causes to go out small crack between glue for tile and ceramic tile, formation hollowing, and final
The defect to fall off provides a kind of preparation method of anti-hollowing high bond strength glue for tile.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of preparation method of anti-hollowing high bond strength glue for tile, it is characterised in that specifically preparation process is：
（1）Ceramic tile polishing waste residue and zirconium oxide ball milling pearl are put into ball grinder, then absolute ethyl alcohol is added into ball grinder, it is wet
3~4h is ground, wet-milling waste residue is obtained；
（2）After the liquor potassic permanganate that above-mentioned wet-milling waste residue and mass fraction are 30% is mixed, 70~80 DEG C are heated to,
It is stirred to react 1~2h, after reaction, is separated by filtration to obtain filter residue, is mixed after obtained filter residue and lemon juice are mixed
Object；
（3）Mixture is laid in pallet, is put into greenhouse, mouldy processing 3~5 days is stood, obtains mouldy object, then will be mouldy
Object is transferred in fermentation tank, is sealed by fermentation, and is separated by filtration to obtain fermentation filter residue after fermentation, by fermentation filter residue and phosphorus pentoxide
120~130 DEG C, 1~2h of insulation reaction are heated to after mixing, reaction terminates to be rinsed with water 10~15min, obtains reaction filter
Slag, it is spare；
（4）The stalk section that rice straw is ground into 5~6cm long is weighed, is packed into after stalk section and calcium hydroxide and water are mixed
In autoclaving tank, it is heated to 150~160 DEG C under conditions of 1.2~1.5MPa, 1~2h of boiling is kept the temperature, after boiling
Product pour into fermentation tank, be sealed by fermentation 15~20 days under room temperature, take out tunning after fermentation, be rinsed with water 15~
20min obtains making careless muscle by oneself；
（5）Count in parts by weight, weigh 50~60 parts of spare reaction filter residues, 10~15 parts of polyacrylate dispersions, 8~12 parts
Above-mentioned self-control grass muscle, 2~5 parts of triethylamines, 1~3 part of calcium formate and 3~5 parts of flyash, are fitted into batch mixer, in 70~80 DEG C
Lower insulated and stirred reacts 10~15min, and packaging is to get anti-hollowing high bond strength glue for tile after discharging.
Step（1）Described in ceramic tile polishing waste residue and zirconium oxide ball milling pearl ball material mass ratio be 30:1, anhydrous second
The addition of alcohol is 5~10 times of ceramic tile polishing slag quality, and it is 250~260r/min that the condition of wet-milling, which is revolution rotating speed,
Rotation rotating speed is 500~550r/min.
Step（2）Described in wet-milling waste residue and mass fraction be 30% the mass ratio of liquor potassic permanganate be 1:5, filter
The mass ratio of slag and lemon juice is 1:5.
Step（3）Described in greenhouse temperature be 30~35 DEG C, relative air humidity be 70~80%, sealing and fermenting
Temperature is 38~45 DEG C, and the time of sealing and fermenting is 7~9 days, and the mass ratio of fermentation filter residue and phosphorus pentoxide is 3:1.
Step（4）Described in stalk section and the mass ratio of calcium hydroxide and water be 1:2:5.
The beneficial effects of the invention are as follows：
（1）The present invention is first former using main component as the ceramic tile polishing waste residue of silicon carbide, magnesia, magnesium chloride and brick fine powder
Itself and absolute ethyl alcohol Wet blend-milling are used potassium permanganate oxidation, and ferment and be modified through lemon juice, are finally dehydrated by material again after wet-milling
Reaction filter residue is obtained by the reaction, white lime soda boiling rice straw, sealing and fermenting is then used to obtain careless muscle, will reaction filter residue and careless muscle with
And other auxiliary materials are blended, and anti-hollowing high bond strength glue for tile is finally made, ceramic tile polishing waste residue is mainly used in the present invention
Generated during the grinding of Ceramic Tiles, polishing, ingredient mainly grind silicon carbide in the block, magnesia, magnesium chloride and
Brick fine powder etc..For ceramic tile polishing waste residue because its grain diameter is tiny, specific surface area is high, in addition also contains a small amount of glass phase, is suitble to
As supplementary cementitious material, itself and absolute ethyl alcohol wet-milling are subjected to hydroxylating modification, then with potassium permanganate oxidation so that hydroxyl oxygen
It is melted into carboxyl, then is mixed with the lemon juice and waste residue for being rich in organic carboxyl acid, it is first mouldy under conditions of high temperature and humidity, followed by
Mould microorganism degrades lemon juice, generates the amino, carboxyl and other active groups of a large amount of free properties, and microorganism from
These amino, carboxyl and active group are introduced into waste residue surface under crosslinked action, later using phosphorus pentoxide as dehydrating agent
So that waste residue surface carboxyl groups are dehydrated into acid anhydride, the waste residue that surface carries anhydride group is obtained, the present invention then chooses rice straw, uses
White lime soda boiling stalk removes alkali-soluble impurity in stalk fibre by soda boiling, and so that stalk fibre is absorbed heat by boiling
Can, stronger activity occurs for strand, and within the scope of a relatively narrow temperature, intermolecular connection rupture is intermolecular mutual
Displacement aggravates, and polymer property is varied from, and unformed fiber is plasticizing state from glassy transition, makes fiber preliminarily softened, it
Afterwards in hydrothermal lower hydrolysis, hydrolysis can promote the generation of chemical action that is parallel, subsequent, or even intersecting, and can
Promote high glycan to be degraded to oligosaccharide, be even monosaccharide, xylan, hydrolysis causes furfural to generate, and the furfural of generation again can be in height
Condensation and polycondensation voluntarily occurs under conditions of pressure boiling heat, that is, makes stalk fibre tree esterification reaction, to improve straw
The mechanical property of stalk fiber, toughness improve, and obtain high strength and the careless muscle of high tenacity, last of the invention by careless muscle and reaction
Filter residue and polymer emulsion are blended, so that the hydroxyl on high tenacity grass muscle surface and modified waste residue under the catalytic action of triethylamine
The anhydride group on surface is crosslinked at ester, the Chemical bonding of formation bond energy bigger, rather than simple Hydrogen Binding Adsorption so that ceramic tile
Glue cohesive force increases, to greatly improve ceramic tile adhesive knotting strength, and careless muscle be added can as the conductor of stress,
Its good toughness can discharge the internal stress that the condensation of ceramic tile heat expansion generates well, avoid occurring between glue for tile and ceramic tile small
Crack prevents hollowing, has broad application prospects.
Specific implementation mode
It is 30 by ball material mass ratio:1 is put into ceramic tile polishing waste residue and zirconium oxide ball milling pearl in ball grinder, then to ball milling
The absolute ethyl alcohol of 5~10 times of ceramic tile polishing slag quality is added in tank, with the rotating speed that revolves round the sun for 250~260r/min, walks around certainly
Speed is condition 3~4h of wet-milling of 500~550r/min, obtains wet-milling waste residue；The Gao Meng for being 30% by wet-milling waste residue and mass fraction
Sour potassium solution is 1 in mass ratio:After 5 mixing, 70~80 DEG C are heated to, 1~2h is stirred to react, after reaction, filtering
Obtained filter residue and lemon juice are 1 in mass ratio by isolated filter residue:Mixture is obtained after 5 mixing；Mixture is laid in
In pallet, it is 30~35 DEG C to be put into temperature, in the greenhouse that relative air humidity is 70~80%, stands mouldy processing 3~5 days, obtains
It is transferred in fermentation tank to mouldy object, then by mouldy object, is sealed by fermentation 7~9 days at 38~45 DEG C, is separated by filtration after fermentation
Fermentation filter residue is obtained, is 3 in mass ratio by fermentation filter residue and phosphorus pentoxide:120~130 DEG C are heated to after 1 mixing, is protected
Temperature 1~2h of reaction, reaction terminate to be rinsed with water 10~15min, obtain reaction filter residue, spare；Weigh rice straw be ground into 5~
Stalk section and calcium hydroxide and water are 1 in mass ratio by the stalk section of 6cm long:2:It is fitted into autoclaving tank after 5 mixing,
It is heated to 150~160 DEG C under conditions of 1.2~1.5MPa, keeps the temperature 1~2h of boiling, the product after boiling is poured into hair
It in fermentation tank, is sealed by fermentation 15~20 days under room temperature, takes out tunning after fermentation, be rinsed with water 15~20min, obtained certainly
The careless muscle of system；Count in parts by weight, weigh 50~60 parts of spare reaction filter residues, 10~15 parts of polyacrylate dispersions, 8~12 parts
Above-mentioned self-control grass muscle, 2~5 parts of triethylamines, 1~3 part of calcium formate and 3~5 parts of flyash, are fitted into batch mixer, in 70~80 DEG C
Lower insulated and stirred reacts 10~15min, and packaging is to get anti-hollowing high bond strength glue for tile after discharging.
Example 1
It is 30 by ball material mass ratio:1 is put into ceramic tile polishing waste residue and zirconium oxide ball milling pearl in ball grinder, then into ball grinder
The absolute ethyl alcohol of 5 times of ceramic tile polishing slag quality is added, with the rotating speed that revolves round the sun for 250r/min, rotation rotating speed is 500r/min's
Condition wet-milling 3h, obtains wet-milling waste residue；It is 1 in mass ratio by the liquor potassic permanganate that wet-milling waste residue and mass fraction are 30%:5
After mixing, 70 DEG C are heated to, is stirred to react 1h, after reaction, is separated by filtration to obtain filter residue, by obtained filter residue and lemon
Lemon juice is 1 in mass ratio:Mixture is obtained after 5 mixing；Mixture is laid in pallet, it is 30 DEG C to be put into temperature, air phase
In the greenhouse for being 70% to humidity, mouldy processing 3 days are stood, mouldy object are obtained, then mouldy object is transferred in fermentation tank, at 38 DEG C
It is lower to be sealed by fermentation 7 days, it is separated by filtration to obtain fermentation filter residue after fermentation, is in mass ratio by fermentation filter residue and phosphorus pentoxide
3:120 DEG C, insulation reaction 1h are heated to after 1 mixing, reaction terminates to be rinsed with water 10min, obtains reaction filter residue, spare；
The stalk section that rice straw is ground into 5cm long is weighed, is 1 in mass ratio by stalk section and calcium hydroxide and water:2:After 5 mixing
It is fitted into autoclaving tank, 150 DEG C is heated under conditions of 1.2MPa, keep the temperature boiling 1h, the product after boiling is fallen
Enter in fermentation tank, be sealed by fermentation 15 days under room temperature, take out tunning after fermentation, be rinsed with water 15min, obtains self-control grass
Muscle；Count in parts by weight, weigh 50 parts of spare reaction filter residues, 10 parts of polyacrylate dispersions, 8 parts of above-mentioned self-control grass muscle, 2 parts
Triethylamine, 1 part of calcium formate and 3 parts of flyash, are fitted into batch mixer, and insulated and stirred reacts 10min at 70 DEG C, is wrapped after discharging
Dress is to get anti-hollowing high bond strength glue for tile.
Example 2
It is 30 by ball material mass ratio:1 is put into ceramic tile polishing waste residue and zirconium oxide ball milling pearl in ball grinder, then into ball grinder
The absolute ethyl alcohol of 8 times of ceramic tile polishing slag quality is added, with the rotating speed that revolves round the sun for 255r/min, rotation rotating speed is 530r/min's
Condition wet-milling 4h, obtains wet-milling waste residue；It is 1 in mass ratio by the liquor potassic permanganate that wet-milling waste residue and mass fraction are 30%:5
After mixing, 75 DEG C are heated to, is stirred to react 1h, after reaction, is separated by filtration to obtain filter residue, by obtained filter residue and lemon
Lemon juice is 1 in mass ratio:Mixture is obtained after 5 mixing；Mixture is laid in pallet, it is 33 DEG C to be put into temperature, air phase
In the greenhouse for being 75% to humidity, mouldy processing 4 days are stood, mouldy object are obtained, then mouldy object is transferred in fermentation tank, at 41 DEG C
It is lower to be sealed by fermentation 8 days, it is separated by filtration to obtain fermentation filter residue after fermentation, is in mass ratio by fermentation filter residue and phosphorus pentoxide
3:125 DEG C, insulation reaction 2h are heated to after 1 mixing, reaction terminates to be rinsed with water 13min, obtains reaction filter residue, spare；
The stalk section that rice straw is ground into 5cm long is weighed, is 1 in mass ratio by stalk section and calcium hydroxide and water:2:After 5 mixing
It is fitted into autoclaving tank, 155 DEG C is heated under conditions of 1.3MPa, keep the temperature boiling 2h, the product after boiling is fallen
Enter in fermentation tank, be sealed by fermentation 18 days under room temperature, take out tunning after fermentation, be rinsed with water 18min, obtains self-control grass
Muscle；It counts in parts by weight, weighs 58 parts of spare reaction filter residues, 13 parts of polyacrylate dispersions, 10 parts of above-mentioned self-control grass muscle, 4
Part triethylamine, 2 parts of calcium formates and 4 parts of flyash, are fitted into batch mixer, and insulated and stirred reacts 13min at 75 DEG C, is wrapped after discharging
Dress is to get anti-hollowing high bond strength glue for tile.
Example 3
It is 30 by ball material mass ratio:1 is put into ceramic tile polishing waste residue and zirconium oxide ball milling pearl in ball grinder, then into ball grinder
The absolute ethyl alcohol of 10 times of ceramic tile polishing slag quality is added, with the rotating speed that revolves round the sun for 260r/min, rotation rotating speed is 550r/min
Condition wet-milling 4h, obtain wet-milling waste residue；It is 1 in mass ratio by the liquor potassic permanganate that wet-milling waste residue and mass fraction are 30%:
After 5 mixing, be heated to 80 DEG C, be stirred to react 2h, after reaction, be separated by filtration to obtain filter residue, by obtained filter residue and
Lemon juice is 1 in mass ratio:Mixture is obtained after 5 mixing；Mixture is laid in pallet, it is 35 DEG C to be put into temperature, air
In the greenhouse that relative humidity is 80%, mouldy processing 5 days are stood, mouldy object are obtained, then mouldy object is transferred in fermentation tank, 45
Be sealed by fermentation 9 days at DEG C, be separated by filtration to obtain fermentation filter residue after fermentation, will fermentation filter residue and phosphorus pentoxide in mass ratio
It is 3:130 DEG C, insulation reaction 2h are heated to after 1 mixing, reaction terminates to be rinsed with water 15min, obtains reaction filter residue, standby
With；The stalk section that rice straw is ground into 6cm long is weighed, is 1 in mass ratio by stalk section and calcium hydroxide and water:2:5 is mixed
It is fitted into after conjunction in autoclaving tank, 160 DEG C is heated under conditions of 1.5MPa, boiling 2h is kept the temperature, by the production after boiling
Object pours into fermentation tank, is sealed by fermentation 20 days under room temperature, takes out tunning after fermentation, be rinsed with water 20min, obtains certainly
The careless muscle of system；It counts in parts by weight, weighs 60 parts of spare reaction filter residues, 15 parts of polyacrylate dispersions, 12 parts of above-mentioned self-control grass
Muscle, 5 parts of triethylamines, 3 parts of calcium formates and 5 parts of flyash, are fitted into batch mixer, and insulated and stirred reacts 15min, discharging at 80 DEG C
After pack to get anti-hollowing high bond strength glue for tile.
Reference examples
With the glue for tile example as a contrast of Changzhou company production
Performance detection is carried out to the glue for tile in glue for tile produced by the present invention and reference examples, testing result is as shown in table 1：
1 performance test results of table
The anti-hollowing high bond strength glue for tile adhesive strength produced by the present invention and soft it can be seen from the detection data in upper table
Toughness is splendid, is not likely to produce hollowing, has broad application prospects.
Claims (5)
1. a kind of preparation method of anti-hollowing high bond strength glue for tile, it is characterised in that specifically preparation process is：
（1）Ceramic tile polishing waste residue and zirconium oxide ball milling pearl are put into ball grinder, then absolute ethyl alcohol is added into ball grinder, it is wet
3~4h is ground, wet-milling waste residue is obtained；
（2）After the liquor potassic permanganate that above-mentioned wet-milling waste residue and mass fraction are 30% is mixed, 70~80 DEG C are heated to,
It is stirred to react 1~2h, after reaction, is separated by filtration to obtain filter residue, is mixed after obtained filter residue and lemon juice are mixed
Object；
（3）Mixture is laid in pallet, is put into greenhouse, mouldy processing 3~5 days is stood, obtains mouldy object, then will be mouldy
Object is transferred in fermentation tank, is sealed by fermentation, and is separated by filtration to obtain fermentation filter residue after fermentation, by fermentation filter residue and phosphorus pentoxide
120~130 DEG C, 1~2h of insulation reaction are heated to after mixing, reaction terminates to be rinsed with water 10~15min, obtains reaction filter
Slag, it is spare；
（4）The stalk section that rice straw is ground into 5~6cm long is weighed, is packed into after stalk section and calcium hydroxide and water are mixed
In autoclaving tank, it is heated to 150~160 DEG C under conditions of 1.2~1.5MPa, 1~2h of boiling is kept the temperature, after boiling
Product pour into fermentation tank, be sealed by fermentation 15~20 days under room temperature, take out tunning after fermentation, be rinsed with water 15~
20min obtains making careless muscle by oneself；
（5）Count in parts by weight, weigh 50~60 parts of spare reaction filter residues, 10~15 parts of polyacrylate dispersions, 8~12 parts
Above-mentioned self-control grass muscle, 2~5 parts of triethylamines, 1~3 part of calcium formate and 3~5 parts of flyash, are fitted into batch mixer, in 70~80 DEG C
Lower insulated and stirred reacts 10~15min, and packaging is to get anti-hollowing high bond strength glue for tile after discharging.
2. a kind of preparation method of anti-hollowing high bond strength glue for tile according to claim 1, it is characterised in that：Step
（1）Described in ceramic tile polishing waste residue and zirconium oxide ball milling pearl ball material mass ratio be 30:1, the addition of absolute ethyl alcohol is
5~10 times of ceramic tile polishing slag quality, it is 250~260r/min that the condition of wet-milling, which is revolution rotating speed, and rotation rotating speed is 500
~550r/min.
3. a kind of preparation method of anti-hollowing high bond strength glue for tile according to claim 1, it is characterised in that：Step
（2）Described in wet-milling waste residue and mass fraction be 30% the mass ratio of liquor potassic permanganate be 1:5, filter residue and lemon juice
Mass ratio is 1:5.
4. a kind of preparation method of anti-hollowing high bond strength glue for tile according to claim 1, it is characterised in that：Step
（3）Described in the temperature in greenhouse be 30~35 DEG C, relative air humidity is 70~80%, and the temperature of sealing and fermenting is 38~45
DEG C, the time of sealing and fermenting is 7~9 days, and the mass ratio of fermentation filter residue and phosphorus pentoxide is 3:1.
5. a kind of preparation method of anti-hollowing high bond strength glue for tile according to claim 1, it is characterised in that：Step
（4）Described in stalk section and the mass ratio of calcium hydroxide and water be 1:2:5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810297625.7A CN108483990A (en) | 2018-04-04 | 2018-04-04 | A kind of preparation method of anti-hollowing high bond strength glue for tile |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810297625.7A CN108483990A (en) | 2018-04-04 | 2018-04-04 | A kind of preparation method of anti-hollowing high bond strength glue for tile |
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Family
ID=63314643
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| CN201810297625.7A Pending CN108483990A (en) | 2018-04-04 | 2018-04-04 | A kind of preparation method of anti-hollowing high bond strength glue for tile |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117521A (en) * | 2019-12-23 | 2020-05-08 | 杨建� | Preparation method of quick-drying high-bonding-strength ceramic tile adhesive |
| CN111154408A (en) * | 2020-01-10 | 2020-05-15 | 林培双 | Preparation method of antibacterial high-strength ceramic tile glue |
| CN113817429A (en) * | 2021-09-26 | 2021-12-21 | 广西绿桂装饰材料有限公司 | High-permeability tile adhesive with humidity adjusting function |
| CN114804687A (en) * | 2022-04-07 | 2022-07-29 | 江苏雄鹰建材科技有限公司 | Ceramic tile binder and preparation method and preparation system thereof |
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| CN106082875A (en) * | 2016-06-25 | 2016-11-09 | 仇颖超 | A kind of preparation method of anti-hollowing sag resistance glue for tile |
| CN106278058A (en) * | 2016-08-28 | 2017-01-04 | 仇颖超 | A kind of preparation method of moistureproof Salt And Alkali Tolerance building mortar |
| CN106366845A (en) * | 2016-08-29 | 2017-02-01 | 丁玉琴 | Preparation method of high-bonding power impact-resistant epoxy terrace coating |
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| KR101008570B1 (en) * | 2009-12-30 | 2011-01-17 | 유한회사 삼흥산업 | Manufacturing method of material having the green cement |
| CN106082875A (en) * | 2016-06-25 | 2016-11-09 | 仇颖超 | A kind of preparation method of anti-hollowing sag resistance glue for tile |
| CN106278058A (en) * | 2016-08-28 | 2017-01-04 | 仇颖超 | A kind of preparation method of moistureproof Salt And Alkali Tolerance building mortar |
| CN106366845A (en) * | 2016-08-29 | 2017-02-01 | 丁玉琴 | Preparation method of high-bonding power impact-resistant epoxy terrace coating |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117521A (en) * | 2019-12-23 | 2020-05-08 | 杨建� | Preparation method of quick-drying high-bonding-strength ceramic tile adhesive |
| CN111154408A (en) * | 2020-01-10 | 2020-05-15 | 林培双 | Preparation method of antibacterial high-strength ceramic tile glue |
| CN113817429A (en) * | 2021-09-26 | 2021-12-21 | 广西绿桂装饰材料有限公司 | High-permeability tile adhesive with humidity adjusting function |
| CN114804687A (en) * | 2022-04-07 | 2022-07-29 | 江苏雄鹰建材科技有限公司 | Ceramic tile binder and preparation method and preparation system thereof |
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Application publication date: 20180904 |