Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other
Embodiment shall fall within the protection scope of the present invention.
As shown in Figure 1, be a kind of printing film battery preparation method flow chart of the embodiment of the present invention, the printing film electricity
Pool preparation method includes:
101, an anode is prepared, the anode is that anode slurry coating is carried out by way of printing using anode slurry
It is made;The anode slurry includes:Collector, active material, conductive additive, binder and the solvent suitable for printing;
102, a cathode is prepared, the cathode is that cathode slurry coating is carried out by way of printing using cathode slurry
It is made;The cathode slurry includes:Collector, active material, conductive additive, binder and the solvent suitable for printing;
103, it prepares and can print electrolyte, be placed between the anode and the cathode.
Preferably, the active material is as follows one or more:Nano metal cluster NMC, cobalt acid lithium LCO, ferric phosphate
Lithium LFP.
Preferably, the conductive additive includes:Carbon black.
Preferably, the binder is as follows one or more:Methylcellulose, polytetrafluoroethylene PTFE, styrene
Butadiene resin, sodium alginate, carrageenan, epoxy resin, xanthans.
Preferably, the solvent for being suitable for printing is as follows one or more:Methanol, ethyl alcohol, isopropanol, positive fourth
Alcohol, Propylene Glycol, ethohexadiol, n-propyl ethylene glycol, normal-butyl ethylene glycol, methoxypropanol, methyl acetate, acetic acid second
Ester, ethyl acetate -3- ethyoxyl propyl alcohol, methyl iso-butyl ketone (MIBK), toluene, dimethylbenzene.
Preferably, the solvent for being suitable for printing is the solvent suitable for silk-screen printing or the rheological characteristic of mould printing.
Preferably, the silk-screen printing includes:Rotary screen prints;The mould printing includes:Intaglio printing.
Preferably, the printable electrolyte contains following component of polymer:Polyethylene glycol oxide PEO, polyetherimide
PEI, carboxyl methyl cellulose, Kynoar PVDF, Peroxyacetyl nitrate PAN, PVAC polyvinylalcohol;The electrolyte tool
There are ion liquid addictive or ceramic oxide additive to improve the ionic conductivity of polymer gel, ceramic oxide addition
Agent includes following one or more:SiO2, TiO2, ZnO, AlOx;The printable electrolyte be by inert environments into
Row prints the deposition of electrolyte and obtains.
Preferably, the collector is the metallized metal in a kind of embedded packaging material laminate, is aluminium or copper, the layer
Pressing plate has opening to expose the metal and external contact region in electrode print region.
In addition, the embodiment of the present invention also provides a kind of printing film battery, the printing film battery includes:One or more
Printing film battery prepared by a above-mentioned preparation method.
A lithium ion battery main cause of high cost is the complexity of assembling process.Especially since to flexible electrical
The requirement of the processing of pole and diaphragm and higher alignment so that the process efficiency for creating battery pack is low.In conventional batteries, electrode material
Material is applied to by continuous coating processes in metal foil.Then the paillon of gained is cut into the shape of battery and stacked with shape
At complete battery core.Although this process is complicated cumbersome, the making to rectangular battery can technically facilitate realization.But
It is that, using the technology of the present invention method, electrode material and electrolyte can be directly printed in collector, pass through the printing that is layering
Solves the problems, such as alignment.Simultaneously can also real shape flexible design.This makes the design of electrode shape have more certainly
By spending, and the more simple realization for thin battery.
It should be noted that similar with standard lithium battery, the deposition of electrode can occur at ambient conditions, but depend on
Used particular electrolyte.May need using inert environments come carry out printing electrolyte deposition.
In general, printing slurry is made of carrier and inorganic powder materials, wherein carrier refers to solvent, resin and additive, nothing
Machine powder refers to functional powders and ceramic powders.It is needed to prepare various functions slurry according to printing, and the mobility of slurry is touched
The rheological behaviours such as denaturation and viscoplasticity will influence printing quality.Preparation of the printable slurry Jing Guo dispensing reaches with enough
High viscosity, so as to optimize the quality of printing film.This is related to adjusting solvent mixture to obtain optimal drying and choosing
Select the adhesive composition of suitable printability and electrochemical stability.Solvent includes but not limited to:Methanol, ethyl alcohol, isopropanol, just
Butanol, Propylene Glycol, ethohexadiol, n-propyl ethylene glycol, normal-butyl ethylene glycol, methoxypropanol, methyl acetate, acetic acid
Ethyl ester, ethyl acetate -3- ethyoxyl propyl alcohol, methyl iso-butyl ketone (MIBK), toluene, dimethylbenzene.Adhesive includes but not limited to:Methyl is fine
Dimension element, PTFE, styrene-butadiene resin, sodium alginate, carrageenan, epoxy resin, xanthans etc..
As shown in Fig. 2, being the example schematic diagram of one silk-screen printing NMC and graphite electrode of the embodiment of the present invention.This method
Using silk-screen printing, this technology is similar to the technology for label printing, to allow to produce the battery of any size and shape.
Each layer (anode, cathode and electrolyte) can print or separately print successively, then be stacked together.It is logical to print electrolyte
It overregulates the rheological property of polyethylene oxide base electrolyte and is adjusted to printable obtain.As shown in figure 3, for this
The image schematic diagram of the NMC and graphite laminate of inventive embodiments collector foil and silk-screen printing.As shown in figure 4, for the present invention
Embodiment printing film battery schematic diagram.
In addition, by suitably designing laminate packaging, metallic substrates barrier can be used to carry out afflux simultaneously, will be isolated
Two kinds of functions of water oxygen and afflux are integrated into a layer, to reduce cell thickness.Which saves needs and is placed on tradition
External contacts in soft-package battery and label film.These components increase the reliable of battery design for integral battery
Property and complexity.This mode is especially suitable for thin battery.
Hull cell provided in an embodiment of the present invention manufactures:The printing of function layered material is carried out first, then can be passed through
Laminate is sealed.Sealing can be heat-sealing or laminar manner.Then, single battery is finally identical to be produced with label
Mode is die cut or is cut by laser, ultra-thin to obtain, low cost and the lithium ion battery quickly manufactured.
As shown in figure 5, being discharge curve schematic diagram of the embodiment of the present invention, 3 squares be made of NMC cathodes and graphite anode
Centimetre silk-screen printing lithium ion battery discharge curve.Electrolyte is the LiPF of 1M6Solution, the wherein ratio of EC+DEC are 1:
1, measurement carries out at room temperature.Hull cell of the embodiment of the present invention shows good capacity and this electrode combination
Document is consistent.The NMC electrode capacities of monomer are 140mAh/g, and graphite electrode capacity is 339mAh/g.This explanation passes through this hair
The printed battery of bright gained is not lost to the capacity of active material.
Above-mentioned technical proposal has the advantages that:Printing film battery preparation method provided in an embodiment of the present invention and
Printing film battery, single battery is finally to be die cut or be cut by laser with the same way that label produces, to be surpassed
It is thin, low cost and the lithium ion battery that quickly manufactures, it can be achieved that battery flexible shapes design, while setting by packaged electrode
Meter reaches ultra-thin thickness, can meet some device such as active RFID tags, intelligent IC for having particular/special requirement to cell thickness
Card and certain wearable devices.
It should be understood that the particular order or level of the step of during disclosed are the examples of illustrative methods.Based on setting
Count preference, it should be appreciated that in the process the step of particular order or level can be in the feelings for the protection domain for not departing from the disclosure
It is rearranged under condition.Appended claim to a method is not illustratively sequentially to give the element of various steps, and not
It is to be limited to the particular order or level.
In above-mentioned detailed description, various features are combined together in single embodiment, to simplify the disclosure.No
This published method should be construed to reflect such intention, that is, the embodiment of theme claimed needs to compare
The more features of feature clearly stated in each claim.On the contrary, as appended claims is reflected
Like that, the present invention is in the state fewer than whole features of disclosed single embodiment.Therefore, appended claims
It is hereby expressly incorporated into detailed description, wherein each claim is used as alone the individual preferred embodiment of the present invention.
For so that any technical staff in the art is realized or using the present invention, above to disclosed embodiment into
Description is gone.To those skilled in the art;The various modifications mode of these embodiments will be apparent from, and this
The General Principle of text definition can also be suitable for other embodiments on the basis of not departing from the spirit and scope of the disclosure.
Therefore, the disclosure is not limited to embodiments set forth herein, but most wide with principle disclosed in the present application and novel features
Range is consistent.
Described above includes the citing of one or more embodiments.Certainly, in order to describe above-described embodiment and description portion
The all possible combination of part or method is impossible, but it will be appreciated by one of ordinary skill in the art that each implementation
Example can do further combinations and permutations.Therefore, embodiment described herein is intended to cover fall into the appended claims
Protection domain in all such changes, modifications and variations.In addition, with regard to the term used in specification or claims
The mode that covers of "comprising", the word is similar to term " comprising ", just as " including " solved in the claims as link word
As releasing.In addition, the use of any one of specification in claims term "or" being to indicate " non-exclusionism
Or ".
Above-described specific implementation mode has carried out further the purpose of the present invention, technical solution and advantageous effect
It is described in detail, it should be understood that the foregoing is merely the specific implementation mode of the present invention, is not intended to limit the present invention
Protection domain, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should all include
Within protection scope of the present invention.