CN108598559A - a kind of flexible lithium ion battery - Google Patents

a kind of flexible lithium ion battery Download PDF

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Publication number
CN108598559A
CN108598559A CN201810817927.2A CN201810817927A CN108598559A CN 108598559 A CN108598559 A CN 108598559A CN 201810817927 A CN201810817927 A CN 201810817927A CN 108598559 A CN108598559 A CN 108598559A
Authority
CN
China
Prior art keywords
positive
ion battery
lithium ion
electrode
negative electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810817927.2A
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Chinese (zh)
Inventor
张小海
徐子福
张明慧
翟传鑫
严涛
张宝凤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ann Price (wuxi) Co Ltd
Original Assignee
Ann Price (wuxi) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ann Price (wuxi) Co Ltd filed Critical Ann Price (wuxi) Co Ltd
Priority to CN201810817927.2A priority Critical patent/CN108598559A/en
Publication of CN108598559A publication Critical patent/CN108598559A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

The present invention relates to a kind of bent polymer Li-ion battery, including soft shell, positive and negative plate is filled in the soft shell;The positive and negative plate is punched out into positive and negative electrode blade unit using punching cutter, is connected by empty foil between the positive and negative electrode blade unit, and positive and negative electrode top draws encapsulation there are lug and carries out charge and discharge, and the positive and negative electrode blade unit lamination assembling is at battery packet;The battery packet is positioned in molding flexible shell, is then packaged to shell.The present invention makes simple, practical, easy to produce bent polymer lithium ion battery cell, is suitable for each mobile device and wearable device.

Description

A kind of flexible lithium ion battery
Technical field
The present invention relates to technical field of lithium ion, and in particular to a kind of flexible lithium ion battery.
Background technology
Lithium ion is with its high-energy density, the advantages that high working voltage, long circulation life Environmental Safety, all the time Largely universal use is obtained in portable battery product.As battery industry continues to develop, portable consumer class battery product work( Can be more and more, increasingly improve powerful, especially the appearance of smart mobile phone, tablet computer, wearable device, function are strong Greatly, component is various, larger to electrical demand, and charge and discharge number is frequent, to the battery energy density that random fit arrives, recycles the longevity Life, security performance require higher and higher.Mobile device, wearable device lithium ion battery external form type are more.The present invention is for existing Shape provides a kind of flexible polymer lithium ion battery, has in mobile device, wearable field and stronger manufacture and apply Property.
Invention content
The purpose of the present invention is being directed to existing technology vacancy, provide a kind of flexible polymer flexible package aluminum plastic film polymer lithium from Sub- battery, make it is simple, practical, it is easy to produce and be suitable for each mobile device and wearable device.
In order to solve the above technical problems, technical solution provided by the invention is:
A kind of flexible lithium ion battery, including soft shell are filled with positive and negative plate in the soft shell;It is described just, Negative plate is punched out into positive and negative electrode blade unit using punching cutter, is connected by empty foil between the positive and negative electrode blade unit, just, Cathode top draws encapsulation there are lug and carries out charge and discharge, and the positive and negative electrode blade unit lamination assembling is at battery packet;The electricity Chi Xin packets are positioned in molding flexible shell, are then packaged to shell.
Further, the outer housing is flexible shell, it is preferred that using comprising PP, PE, PET, nylon and with metal layer Flexible material, such as aluminum plastic film, steel plastic film.
The positive and negative electrode electrode is electrode slice made from traditional lithium-ion battery material, by being punched into pattern in flakes.
The positive and negative electrode combination is lamination, and the diaphragm forms an entirety with anode.
The diaphragm is adopted as PP or PE or mixed matrix, and PAA or PVDF or PAA, PVDF and pottery are coated in membrane surface The coat that the mixture of porcelain powder is formed.
It is that rectangular disjunctor rushes shell that hull shape shape is rushed in the shell molding.
A in the positive plate is electrode width 10-50mm, and b is electrode spacing 4-10mm, and c is electrode length 10- 50mm., positive-pole base material thickness 10um~25um.
D in the negative plate is electrode width 10-50mm, and e is electrode spacing 4-10mm, and f is electrode length 10- 50mm, base material of cathode thickness 6um~15um.
Battery size is as follows, and it is 4-60mm that g, which is battery core body width for battery core width 6-70mm, h, and I is that battery core unit is wide Degree is 6-50mm, and it be battery core package width is 3~8mm that J, which is battery core cell spacing 2~8mm, M, K be battery core height 30~ 300mm。
Compared with prior art, the beneficial effects of the invention are as follows:
The present invention mainly uses laminated type technique, and positive electrode and negative electrode are all punched out squarely using punching cutter Trellis, positive and negative electrode are dielectrically separated from using diaphragm paper before, and foil of leaving a blank at the top of electrode slice carries out transfer electrode lug.Lamination is made Core packet be positioned in the grid shell of forming and be packaged obtained battery core, battery core is because electrode is formed one by one with shell Unit, main stress is the flexible membrane between unit during bending, will not damage internal electrode.The battery core of flexible bendable It is applicable to each field of mobile equipment, especially has higher applicability in wearable device.
Description of the drawings
Fig. 1:Diaphragm body diagram.
Fig. 2:The structural schematic diagram of positive plate, negative plate.
Fig. 3:The assembly dimensional structure diagram of battery packet.
Fig. 4:Battery core finished product schematic diagram.
In figure:1- positive or negative pole ears, 2- cathode or anode ear, 3- battery case body edge sealing, this position of 4- battery pole pieces Value, 5- are the foil position of electrode unit junction.
Specific implementation mode
The present invention is further explained in the light of specific embodiments.
A kind of flexible lithium ion battery, including soft shell are filled with positive and negative plate in the soft shell;It is described just, Negative plate is punched out into positive and negative electrode blade unit using punching cutter, is connected by empty foil between the positive and negative electrode blade unit, just, Cathode top draws encapsulation there are lug and carries out charge and discharge, and the positive and negative electrode blade unit lamination assembling is at battery packet;The electricity Chi Xin packets are positioned in molding flexible shell, are then packaged to shell.
The positive and negative plate of the present invention for using punching cutter to be punched applies for the pole piece coated with electrode active material It is techniques well known to cover adoptable material and method, is not specifically noted herein.
Battery capacity, the size of flexible bendable lithium ion battery are measured below, used material etc. is specific Content is only to carry out measuring to the flexible type lithium ion battery of invention to be illustrated, and non-specifically limit.
Embodiment 1
By positive active material LiCo2, positive electrode binder PVDF, conductive agent carbon black, solvent NMP is with ratio 100: 1.6.1.2:45 batching mode dispensing is mixed to prepare slurry, and slurry is coated uniformly on aluminium foil afflux using transfer coated mode On body it is two-sided and dry, roll, cut after be prepared into anode pole piece.Negative electrode active material graphite, cathode dispersing agent C MC, cathode Binder SBR, conductive agent conductive carbon black and aqueous solvent are with ratio 100:2:3:2:90 mode dispensing is mixed to prepare slurry.It will slurry Material using transfer coated mode be coated uniformly on two-sided in copper foil current collector and dry, roll, be punched after be prepared into thickness 100um, charge level product is 10cm2,8 layers of the number of plies, corresponding cathode have the identical number of plies, battery core unit number 3 to correspond to negative electrode Wide and height all standing is more than anode.
Positive and negative plate obtained above and diaphragm (PP/PE/PP) are pressed into lamination process into a square by certain together Lithium-ion electric core, the lithium ion battery for entering to be made to have after shell (plastic-aluminum packaging film is formed), fluid injection electrolyte.After being melted into advance. Exhaust sealing, trimming, room temperature standing are after 3 days, sorting capacity (charges:0.5 charges to 4.35V, and constant-voltage charge to electric current is less than 0.02C, electric discharge with 0.5C are discharged to 3.0V) it 3.86V is charged to 0.5C measures its thickness and capacity, finished product electricity Pond.
Embodiment 2
The present embodiment and raw material used by embodiment 1, production stage, detection method are essentially identical, unique difference Place, this example provide thickness 100um, have charge level product to be 10cm2, and 8 layers of the number of plies, corresponding cathode have the identical number of plies, correspond to negative electricity Extremely wide and height all standing is more than anode, battery core unit number 5.
Embodiment 3
The present embodiment and raw material used by embodiment 1, production stage, detection method are essentially identical, unique difference Place, this example provide thickness 100um, have charge level product to be 10cm2, and 8 layers of the number of plies, corresponding cathode have the identical number of plies, correspond to negative electricity Extremely wide and height all standing is more than anode, battery core unit number 7.
Embodiment 4
The present embodiment and raw material used by embodiment 1, production stage, detection method are essentially identical, unique difference Place, this example provide thickness 100um, have charge level product to be 10cm2, and 8 layers of the number of plies, corresponding cathode have the identical number of plies, correspond to negative electricity Extremely wide and height all standing is more than anode, battery core unit number 9.
Embodiment 5
The present embodiment and raw material used by embodiment 1, production stage, detection method are essentially identical, unique difference Place, this example provide thickness 100um, have charge level product to be 10cm2, and 8 layers of the number of plies, corresponding cathode have the identical number of plies, correspond to negative electricity Extremely wide and height all standing is more than anode, battery core unit number 11.
Table 1
As shown in Table 1, normal using the lithium ion battery and thickness measurement of invention preparation, electrode fabrication provided by the invention Mode and all great operability use of battery appearance and practical application.
The above is only presently preferred embodiments of the present invention, is not intended to limit the present invention in any form, any ripe Professional and technical personnel is known, without departing from the scope of the present invention, according to the technical essence of the invention, to above real Apply any simple modification, equivalent replacement and improvement etc. made by example, still fall within technical solution of the present invention protection domain it It is interior.

Claims (9)

1. a kind of flexible lithium ion battery, it is characterised in that:Including soft shell, positive and negative electrode is filled in the soft shell Piece;The positive and negative plate is punched out into positive and negative electrode blade unit using punching cutter, by sky between the positive and negative electrode blade unit Foil connects, and positive and negative electrode top draws encapsulation there are lug and carries out charge and discharge, and the positive and negative electrode blade unit lamination assembling is at battery Core packet;The battery packet is positioned in molding flexible shell, is then packaged to shell.
2. flexible lithium ion battery according to claim 1, it is characterised in that:The outer housing is flexible shell, using packet Containing PP, PE, PET, nylon and with the flexible material of metal layer.
3. flexible lithium ion battery according to claim 1, it is characterised in that:The positive and negative electrode electrode is conventional lithium Electrode slice made from ion battery material, by being punched into pattern in flakes.
4. flexible lithium ion battery according to claim 1, it is characterised in that:The positive and negative electrode combination is lamination Structure, the diaphragm form an entirety with anode.
5. flexible lithium ion battery according to claim 4, it is characterised in that:The diaphragm is adopted as PP or PE or mixing Matrix, in the coat that membrane surface is coated with PAA or PVDF or PAA, the mixture of PVDF and ceramic powder is formed.
6. flexible lithium ion battery according to claim 1, it is characterised in that:It is rectangular that hull shape shape is rushed in the shell molding Disjunctor rushes shell.
7. flexible lithium ion battery according to claim 1:A in the positive plate is that electrode width 10-50mm, b are Electrode spacing 4-10mm, c are electrode length 10-50mm, positive-pole base material thickness 10um~25um.
8. flexible lithium ion battery according to claim 1:D in the negative plate is that electrode width 10-50mm, e are Electrode spacing 4-10mm, f are electrode length 10-50mm, base material of cathode thickness 6um~15um.
9. flexible lithium ion battery according to claim 1:Battery size is as follows, and g is battery core width 6-70mm, and h is electricity Core body width is 4-60mm, and I is that battery core cell width is 6-50mm, and J is that battery core cell spacing 2~8mm, M encapsulate for battery core Width is 3~8mm, and K is 30~300mm of battery core height.
CN201810817927.2A 2018-07-24 2018-07-24 a kind of flexible lithium ion battery Pending CN108598559A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109449493A (en) * 2018-11-02 2019-03-08 深圳市浩然电池有限公司 A kind of flexible wearable lithium ion battery
CN110277584A (en) * 2019-06-24 2019-09-24 湖南聚锂能源科技有限公司 A kind of production technology and rotary disc type device of laminated batteries
WO2020025067A1 (en) * 2018-08-03 2020-02-06 中兴通讯股份有限公司 Foldable battery and manufacturing method therefor
CN112751143A (en) * 2019-10-31 2021-05-04 Oppo广东移动通信有限公司 Electricity core subassembly and electronic equipment
CN113258175A (en) * 2021-04-28 2021-08-13 山东金品能源有限公司 Battery energy storage module
CN113794010A (en) * 2021-09-09 2021-12-14 嘉兴极展科技有限公司 Flexible battery pack of stretching
US20220011817A1 (en) * 2018-12-17 2022-01-13 Samsung Electronics Co., Ltd. Foldable battery, and electronic device including same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103928715A (en) * 2014-04-25 2014-07-16 广西师范大学 Battery cell of flexible laminated lithium ion battery, manufacturing method of battery cell as well as battery
CN104466229A (en) * 2013-09-25 2015-03-25 华为技术有限公司 Flexible lithium secondary battery and preparation method thereof
CN208690415U (en) * 2018-07-24 2019-04-02 安普瑞斯(无锡)有限公司 A kind of flexible lithium ion battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104466229A (en) * 2013-09-25 2015-03-25 华为技术有限公司 Flexible lithium secondary battery and preparation method thereof
CN103928715A (en) * 2014-04-25 2014-07-16 广西师范大学 Battery cell of flexible laminated lithium ion battery, manufacturing method of battery cell as well as battery
CN208690415U (en) * 2018-07-24 2019-04-02 安普瑞斯(无锡)有限公司 A kind of flexible lithium ion battery

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020025067A1 (en) * 2018-08-03 2020-02-06 中兴通讯股份有限公司 Foldable battery and manufacturing method therefor
CN110797565A (en) * 2018-08-03 2020-02-14 中兴通讯股份有限公司 Foldable battery and preparation method thereof
CN109449493A (en) * 2018-11-02 2019-03-08 深圳市浩然电池有限公司 A kind of flexible wearable lithium ion battery
US20220011817A1 (en) * 2018-12-17 2022-01-13 Samsung Electronics Co., Ltd. Foldable battery, and electronic device including same
CN110277584A (en) * 2019-06-24 2019-09-24 湖南聚锂能源科技有限公司 A kind of production technology and rotary disc type device of laminated batteries
CN110277584B (en) * 2019-06-24 2022-02-01 湖南聚锂能源科技有限公司 Rotating disc type device for producing laminated batteries
CN112751143A (en) * 2019-10-31 2021-05-04 Oppo广东移动通信有限公司 Electricity core subassembly and electronic equipment
CN113258175A (en) * 2021-04-28 2021-08-13 山东金品能源有限公司 Battery energy storage module
CN113258175B (en) * 2021-04-28 2023-06-16 山东金品能源有限公司 Battery energy storage module
CN113794010A (en) * 2021-09-09 2021-12-14 嘉兴极展科技有限公司 Flexible battery pack of stretching
CN113794010B (en) * 2021-09-09 2023-09-19 嘉兴极展科技有限公司 Flexible stretchable battery pack

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